Search

It was found in this study that fluorinated microporous carbon aerogels with enhanced hydrophobicity could be successfully prepared by direct fluorination to separate water-in-oil emulsions at high flux. The fluorinated carbon aerogel (F-CA) surface treated by the fluorination method had a water contact angle of 151.2° and could immediately absorb oil. In addition, the unique network structure of F-CA and its hydrophobicity allow surfactant-stabilized water-in-oil emulsions to be effectively and simply separated under gravity without requiring external forces such as vacuum or pressurization. The network structure of F-CAs consists of randomly connected spherical particles that form fluorinated permeation channels, which induce high flux during emulsion separation. The F-CA spherical particles have nanosized pores and high hydrophobicity, which repel and trap water droplets to increase the separation purity. Therefore, F-CA exhibited excellent performance, such as high filtrate purity (up to 99.9954%) and flux (up to 11,710 L/m2h). Furthermore, F-CA reusability was demonstrated as it did not lose its hydrophobicity and maintained its performance even after repeated use. This type of aerogel has great potential to be utilized throughout various environmental fields, including oil remediation.

Fluorine heteroatoms were introduced to increase the limited specific capacitances of electric double-layer capacitors (EDLCs), and the effects of the fluorine atoms were analyzed. To introduce the fluorine, a CF4plasma treatment was used that introduced the fluorine atoms quickly. Among the fluorine functional groups in the F6-ACA framework, the semi-ionic C–F bonds induced rapid charge transfer and imparted pseudocapacitance. Consequently, we achieved a specific capacitance of 325.68 F/g for the F6-CA sample at 0.5 A/g. By analyzing the contributions of the electric double-layer capacitance and the pseudocapacitance, we determined that the contribution from the pseudocapacitance was 37.57%. A remarkable specific capacitance retention rate of 95.87% was obtained over 1000 charge/discharge cycles with a high current density of 3 A/g. Additionally, the semi-ionic C–F bonds reduced the charge transfer resistance (Rct) by 36.8%. Therefore, the specific capacitance was improved by the fluorine heteroatoms, and the semi-ionic C–F bonds played a pivotal role in this improvement.

Graphical abstract:

In this study, we investigate the opportunity of using waste tire char as a cathode material for lithium-ion primary batteries (LPBs). The char obtained by carbonizing waste tires was washed with acid and thermally fluorinated to produce CFX. The structural and chemical properties of the char and CFXwere analyzed to evaluate the effect of thermal fluorination. The carbon structure of the char was increasingly converted to CFXstructure as the fluorination temperature increased. In addition, the manufactured CFX-based LPBs were evaluated through electrochemical analysis. The discharge capacity of the CFXreached a maximum of 800 mAh/g, which is comparable to that of CFX-based LPBs manufactured from other carbon sources. On the basis of these results, the use of waste tire char-based CFXas a cathode material for LPBs is presented as a new opportunity in the field of waste tire recycling.