1. Improvement of energy storage performance by controlling the crystallinity of Aurivillius BaBi4Ti4O15thin films
- Author
-
Keum, Yoon Hyung, Shin, Hyun Wook, and Son, Jong Yeog
- Abstract
We investigated the crystallinity, ferroelectric properties, and energy storage efficiency of Aurivillius BaBi4Ti4O15(BBTO) thin films epitaxially deposited on single-crystal (001) Rh substrates by pulsed laser deposition method. From X-ray diffraction experiments, it was confirmed that the BBTO thin films had a mixed crystallinity of a-oriented crystallinity and c-oriented crystallinity. The BBTO thin films fabricated by a low substrate temperature and a high deposition rate showed highly a-oriented crystallinity. On the other hand, the BBTO thin films deposited by a high substrate temperature and a low deposition rate showed improved crystallinity with highly c-oriented crystallinity. The BBTO thin film with the highly a-oriented crystallinity showed large remanent polarization, and the BBTO thin film with the highly c-oriented crystallinity showed small remanent polarization but excellent leakage current characteristics. In addition, the BBTO thin film with the highly c-oriented crystallinity exhibited superior energy storage characteristics with a high energy storage density of 32.5 J/cm3and a high efficiency of 0.8 compared to the BBTO thin film with the highly a-oriented crystallinity.
- Published
- 2023
- Full Text
- View/download PDF