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Particulate pyrogenic carbon (PyC) transported by rivers and aerosols, and deposited in marine sediments, is an important part of the carbon cycle. The chemical composition of PyC is temperature dependent and levoglucosan is a source‐specific burning marker used to trace low‐temperature PyC. Levoglucosan associated to particulate material has been shown to be preserved during riverine transport and marine deposition in high‐ and mid‐latitudes, but it is yet unknown if this is also the case for (sub)tropical areas, where 90% of global PyC is produced. Here, we investigate transport and deposition of levoglucosan in suspended and riverbed sediments from the Amazon River system and adjacent marine deposition areas. We show that the Amazon River exports negligible amounts of levoglucosan and that concentrations in sediments from the main Amazon tributaries are not related to long‐term mean catchment‐wide fire activity. Levoglucosan concentrations in marine sediments offshore the Amazon Estuary are positively correlated to total organic content regardless of terrestrial or marine origin, supporting the notion that association of suspended or dissolved PyC to biogenic particles is critical in the preservation of PyC. We estimate that 0.5–10 × 106g yr−1of levoglucosan is exported by the Amazon River. This represents only 0.5–10 ppm of the total exported PyC and thereby an insignificant fraction, indicating that riverine derived levoglucosan and low‐temperature PyC in the tropics are almost completely degraded before deposition. Hence, we suggest caution in using levoglucosan as tracer for past fire activity in tropical settings near rivers. During plant organic matter burning, most of the carbon is emitted to the atmosphere as CO2, but a fraction is retained as pyrogenic biomass. The chemical composition of pyrogenic biomass depends on fire temperature and allows to differentiate between high and low‐temperature pyrogenic biomass. Here, we analyzed if low‐temperature pyrogenic biomass is preserved during transport in the Amazon River and deposited in western tropical Atlantic sediments. We found that only negligible amounts of low‐temperature pyrogenic biomass reach the Atlantic through riverine transport. While most pyrogenic carbon (PyC) originates in the tropics, our study suggests that only an insignificant fraction of low‐temperature PyC is permanently stored in marine sediments, where it would be removed from the short‐term carbon cycle. Only negligible amounts of the source‐specific low‐temperature biomass burning tracer levoglucosan are exported by the Amazon River systemMarine sediment levoglucosan yields are controlled by organic carbon content regardless of marine or terrestrial source of organic matterDust and river derived levoglucosan escape burial in the tropical Atlantic, despite the dominant tropical source of pyrogenic carbon Only negligible amounts of the source‐specific low‐temperature biomass burning tracer levoglucosan are exported by the Amazon River system Marine sediment levoglucosan yields are controlled by organic carbon content regardless of marine or terrestrial source of organic matter Dust and river derived levoglucosan escape burial in the tropical Atlantic, despite the dominant tropical source of pyrogenic carbon

Fire causes dramatic energy and matter exchanges between biosphere and atmosphere on a regional to global scale. Predicting fires, however, is hindered by the complex interplay of fire, climate, and vegetation. Paleo‐fire records provide critical information beyond instrumental records that cover only the past few decades and may be used to assess the role of fire in large‐scale and long‐term environmental changes. Here we present a 22,000‐year multiproxy record of fire regime from a sediment core retrieved offshore South Java, Indonesia. We use microcharcoal in combination with two molecular markers of burning, levoglucosan and polycyclic aromatic hydrocarbons, to reconstruct fire occurrence as well as fire intensity in the past. We show that fire occurrence and intensity were high during the Last Glacial Maximum (LGM; around 21,000 years ago) and low during the Heinrich Stadial 1 and the early Holocene. Both fire regime and vegetation in tropical regions with high annual rainfall were primarily controlled by rainfall seasonality. However, fire additionally stabilized the savannah (rainforest)‐dominated ecosystem during the LGM (early Holocene) but caused transitions between the two vegetation types during the deglaciation and the late Holocene. Microcharcoal reflects regional fire occurrence, while the ratio between two novel molecular markers reflects past fire intensityRainfall seasonality controlled both fire regime and vegetationFires of different frequencies and intensities were capable of either stabilizing or destabilizing savannah/rainforest vegetation