1. Anti-perovskites with long carrier lifetime for ultralow dose and stable X-ray detection
- Author
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Liu, Lang, Liu, Shi-Yu, Shi, Yuanpeng, Fang, Cui-Ling, Zhao, Shan, Shen, Huai-Yi, Chen, Ming-Xing, Wang, Ze-Jie, Ma, Yan, Liu, Yan, Feng, Yan, Tang, Jiang, Ye, Heng-Yun, and Niu, Guangda
- Abstract
Halide perovskites have shown promising potential for direct X-ray detection due to their high X-ray absorption coefficient, low trap states and convenient fabrication process. However, it is still a challenge to achieve high sensitivity, low dark current and low detection limit in a single material. The deep reason for this is the trade-off between the material’s μτproduct and resistivity. Here we report the construction of an organic–inorganic hybrid anti-perovskite ((2-Habch)3Cl(PtI6)) with indirect transition and low orbital symmetry at the band edge to achieve an ultralong intrinsic lifetime and thus break the trade-off. (2-Habch)3Cl(PtI6) achieves an unprecedented long carrier lifetime of >3 ms, leading to a large μτproduct of 6.25 × 10−3cm2V−1and high resistivity of 1012Ω cm, outperforming most X-ray detection materials. These properties enabled the development of X-ray detectors that simultaneously achieve an ultralow dark current of 0.21 nA cm−2, high sensitivity of 1.0 × 104µC Gyair−1cm−2, ultralow detection limit of 2.4 nGyairs−1and excellent operational stability with no observable baseline drift, outperforming state-of-the-art perovskite single-crystal detectors. The rare combination of high performance in almost every figure of merit in the anti-perovskite-based X-ray detector could enable new-generation X-ray detection systems.
- Published
- 2024
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