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In coastal alluvial plains, the variability of sedimentary inputs, tectonic and eustatism causes a complex subsurface geology which influences the position of fresh/saltwater interface. Furthermore, in these areas densely populated, the over-pumping of freshwater, coupled with the climate change events, promotes the landward migration of freshwater/saltwater boundary. This research illustrates the ability of geophysical tools to recognize the presence of salt/brackish water at Volturno Coastal Plain, Southern Italy. This area is characterized by a peculiar geological setting, due to the proximity at Somma–Vesuvio and Campi Flegrei volcanic areas, which profoundly influences the circulation of groundwater. The subsurface is mainly characterized by: (i) two denser layers located at − 10 m and − 20 m depth which in part prevents the vertical migration of groundwater, (ii) facies heteropy that facilitates the hydraulic connection between the different geological bodies, (iii) a discontinuous Campanian Ignimbritedeposits which favor the hydraulic connection between deeper and shallower aquifers. In this geological framework, 2D-ERT and 3D-ERT integrated with Downhole, Multichannel Analysis of Surface Waves and boreholes made possible to recognize the presence of two main zones with salt and brackish waters, respectively. The first zone, characterized by very low resistivity (≤ 1 Ωm) typical of salt water, stretches 1.5 km inland from the coast. The second zone, with a resistivity between 2 and 5 Ωm typical of brackish water, continues for other 3 km inland. This knowledge is useful for the engagement of all stakeholders (farmers, ranchers and policy makers) in the sustainable use of fresh water and for making water management plan operational tools.