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Start Over Author "Carr, Andrew G" Publication Type Magazines
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1. The [Zr(N{SiMe3}2)3]+cation as a novel initiator for carbocationic isobutene homo‐ and isobutene/isoprene co‐polymerisations

Author

Carr, Andrew G., Dawson, David M., and Bochmann, Manfred

Abstract

Methyl abstraction of ZrMe{N(SiMe3)2}3with B(C6F5)3gives the cationic zirconium amide complex [Zr{N(SiMe3)2}3]+which acts as an initiator for the carbocationic polymerisation of isobutene and for isobutene‐isoprene copolymerisations. High molecular weight homo‐ and co‐polymers are obtained at temperatures up to −30°C. Molecular weights are less temperature dependent than in metal halide initiated systems.

Published
1998
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