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2. ChemInform Abstract: Kinetics and Mechanism of X + ClNO → XCl + NO (X: Cl, F, Br, OH, O, N) from 220 to 450 K. Correlation of Reactivity and Activation Energy with Electron Affinity of X.

Author

ABBATT, J. P. D., TOOHEY, D. W., FENTER, F. F., STEVENS, P. S., BRUNE, WM. H., and ANDERSON, J. G.

Abstract

Both the reaction activation energies and the logarithms of the room temp. rate constants of the title reactions are found to correlate strongly with the electron affinity of the radical in such a way that high electron affinity leads to enhanced reactivity.

Published
1989
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