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Abstract Omphacite grains ftom UHP eclogite of the Dabie Mountains in eastern China are elongated and show strong lattice preferred orientations (LPOs). Observations by the transmission electron microscopy (TEM) identified not only structures of plastic deformation occurring as free dislocation, dislocation loops and dislocation walls, but also bubbles of water present in the deformed omphacite. The bubbles attach to the dislocation loops which are often connected to one another via a common bubble. Using infrared spectroscopy (IR), two types of hydrous components are identified as hydroxyl and free‐water in the omphacite. An analysis of deformation mechanism of microstructure in omphacite suggests that the mineral deformed plastically under UHP metamorphic conditions by dislocation creep through hydrolitic weakening.

Critical but controversial problems in the study of UHP metamorphic rocks from the Dabie-Sulu region include: (1) the possible existence of ophiolitic melange; (2) the “in situ” versus “foreign” origin of UHP eclogites and their enclosing gneisses; (3) the possible presence and role of fluids during ultrahigh-pressure (UHP) recrystallization; (4) the timing of collision between the Yangtze and Sino-Korean continental blocks; (5) the polarity of syncollisional subduction; and (6) a single-versus multistage exhumation scenario for the UHP rocks. These questions are discussed in light of new geological, geochemical, and isotopic constraints.Our conclusions for the Dabie-Sulu belt are as follows: (1) Mafic-ultramafic blocks are of two distinct origins: one group samples lithosphere of the suprasubductionzone mantle wedge, whereas the second group represents postcollisional magmatic intrusions. Neither lithologic group represents true oceanic crust. (2) Quartzofeldspathic gneisses enveloping the eclogites are of two types— metasedimentary “in situ” and igneous “foreign.” The paragneisses contain UHP garnets + white micas, and are uniformly older (235 ± 5 Ma) than the orthogneisses (210 ± 5 Ma), which are devoid of UHP mineralogic indicators. (3) Fluids were active under UHP conditions and allowed the formation of UHP hydrous phases such as phengite and zoisite. However, the aqueous fluids may have been restricted to certain channels/pathways during exhumation. External fluids were absent until ascent of the UHP rocks to middle-crustal levels. (4) The Yangtze and Sino-Korean continental blocks collided during 230 to 240 Ma, when supracontinental rocks experienced UHP metamorphism. The HP metamorphic event dated as >400 Ma might record a subduction of oceanic crust during the Paleozoic. (5) An ancient mantle wedge is revealed by geochemical characteristics of Mesozoic magmatic rocks developed on the southern margin of the Sino-Korean craton, the hanging wall of the UHP-rock-bearing unit. Seismic tomography images reveal that the Yangtze block extends beneath the Dabie-Sulu orogenic belt. This indicates that both oceanic and continental crust had a northward subduction polarity. (6) Taking petrologic and geochronological data into account, we prefer a multistage exhumation model. The UHP rocks were exhumed rapidly during the first stage (230 to 200 Ma), perhaps reflecting a corner-flow mechanism. Then, buoyancy and mantle upwelling brought the UHP rocks up to middle-crustal levels during the second stage (200 to 170 Ma). Extension and thermal uplift, as well as erosion, eventually exposed the UHP rocks to the surface in the third stage (170 to 120 Ma).

Two processes are suggested to explain how UHP rocks are exhumed from mantle depths. One is removal of the overburden either by erosion or by extension, whereas the other involves the uplifting of the UHP rocks through the overburden. Application of either of these mechanisms to the Dabie Mountains, however, is fraught with difficulty. When combined with previously published data, new studies on metamorphic P-T paths, regional structures, and deep upper-mantle architecture revealed by seismic tomography lend support to a multi-stage exhumation process that operated in the Dabie Mountains.The first stage (230 to 200 Ma) is characterized by ductile deformation, produced during eclogite-facies recrystallization under a geothermal gradient as low as 10°C/km, implying a synsubduction exhumation. Some of the UHP rocks evidently were exhumed to a depth of ~60 km, as indicated by petrological study of the Shuanghe eclogite. The second stage (200 to 170 Ma) attended ductile deformation and amphibolite-facies retrograde metamorphism. Subduction of the Yangtze block was halted by slab breakoff at a depth of ∼200 km. The resultant geothermal gradient recovered to ∼20''C/km. Slab breakoff permitted buoyancy-driven ascent of the UHP low-density melange to shallow crustal levels in a diapir structure. When the UHP portion of the mountain root rose, the shallow portion was heated to a temperature higher than that of the peak metamorphic pressure. The third stage (170 to 120 Ma) is characterized by extension and thermal uplift, as well as erosion. Sedimentary basins and volcanic rocks developed on both sides of the Dabie Mountains. Gab-bro-pyroxenite intruded the hanging wall of the UHP terrane, and granite, as well as migmatite, developed in that stage.Exhumation mechanisms might include corner flow for the first stage, buoyancy-driven squeezing-up for the second stage, and crustal extension, as well as erosion, for the third. Rupture and loss of the subducted lithospheric plate generated the gravity instability that resulted in exhumation of the subducted UHP section.

The northern Dabieshan metamorphic terrain (NDT) is an analogue of an Andean-type magmatic arc. The predominant rock type is a trondhjemitic-tonalitic-granodioritic (TTG) gneiss with bodies of meta-ultramafic-gabbroic rocks, basic granulite, and metasedimentary horizons. The TTG gneisses occupy about 70-80 vol% of the metamorphic rock outcrop and constitute two gneiss domes. Several approximately E-W- or NW-SE-trending ductile deforma- tion belts cut through the TTG gneisses and are especially developed in the northern and southern margins of the NDT and around the domes. Most ultramafic-mafic rocks occur as lenses in ductile deformation belts. Metasedimentary horizons consist of marble, biotite quartz schist, metaquartzite, metamorphosed calc-silicate rocks, fine-grained biotite gneiss, banded iron formation, and amphibolite. Petrographic and geochemical studies show that: (1) meta- morphic rocks in the NDT underwent amphibolite-granulite facies metamorphism, and no eclogite-facies high-pressure mineral relicts were found in any rocks; and (2) ultramafic-mafic rocks do not have the petrological and geochemical characteristics of ophiolitic rocks; they appear to be an island-arc ultramafic-gabbroic intrusion. The limited isotopic data indicate that the northern Dabieshan terrain is possibly a Paleozoic magmatic arc. The data in this paper provide some implications for formation and exhumation of ultra-high pressure metamorphic (UHPM) rocks.

Abstract Coesite in a granulite host-rock is reported from Weihai City, northeastern Shandong Province, China. Coesite occurs as inclusions in garnet, which is separated from the fine-grained matrix of quartz + clinopyroxene + hornblende by a zoned corona of plagioclase + clinopyroxene + orthopyroxene + hornblende. Petrological evidence shows that the coesite-bearing granulite is retrograded from eclogite. Three stages in the metamorphic history of the granulite have been recognized, (i) Coesite-eclogite stage: The assemblage reconstructed from the inclusions in garnet is Mg-rich garnet + omphacite + coesite + rutile. (ii) During the granulite stage, these minerals reacted to form quartz + clinopyroxene + hornblende (in the matrix), clinopyroxene + albite (omphacite pseudomorphs) and plagioclase + clinopyroxene + orthopyroxene + hornblende (as corona around garnet), (iii) Amphibolite stage: Earlier minerals were replaced by biotite, epidote and hornblende. The P-T conditions estimated with various geothermobarometers show a T-increasing and P-decreasing path from the eclogite stage (T ~ 720°C, P > 28 kbar) to the granulite stage (T ~ 850°C, P ~ 10 kbar). Thus the exhumation of the ultra-high-pressure rocks in Weihai proceeded under increasing temperature, and may not have been as fast as it was thought before