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Composite microcrystals of the cyclic nitramines 2,4,6,8,10,12-hexanitro-2,4,6,8,10,12-hexaazaisowurtzitane (ε-CL-20), 1,3,5-trinitro-1,3,5-triazinane(RDX), 1,3,5,7-tetranitro-1,3,5,7-tetrazocane (β-HMX), and cis-1,3,4,6-tetranitrooctahydroimidazo-[4,5-d]imidazole (BCHMX) with polyaniline (PANi) have been prepared and thoroughly characterized in terms of morphology and phase purity. PANi outperformed other conducting polymers in terms of selectivity towards NAs due to its better interaction with NAs, low production cost, and ease of preparation. The bonding of nitramines with the polymeric PANi chain has been examined by means of Fourier transform infrared (FTIR), Raman spectroscopy methods, and fluorescence quenching; the Raman spectrum has shown the laser sensitivity of these microcrystals. Powder X-ray diffraction results have shown changes in polymorph modifications in CL20 (from ɛ to β) and HMX (from β to α) during the preparation of the composites, which have also been confirmed by spectral and differential thermal analysis techniques. The structural orientations found in these composites significantly stabilize nitramines against impact; their detonation properties have slightly deteriorated, but the PANi electrical conductivity has strongly increased their electric-spark sensitivity. The above properties of the prepared composites determine their potential use mainly as parts of the electric or laser impulse initiators, having “a green character”, for various charges.

The compounds CoNd2W2O10and MnNd2W2O10were prepared by solid state reaction between CoWO4, resp. MnWO4and Nd2WO6. Intermediates were prepared in laboratory by a solid state reaction and by a co-precipitation reaction. The new single-phase compounds CoNd2W2O10and MnNd2W2O10were prepared only from intermediates prepared by solid state reaction, as in second case the morphology of particles is inappropriate and during the reaction an unknown phase (Nd–W–O) is formed. To describe the processes during thermal reactions, the DTA/TG were used. CoNd2W2O10and MnNd2W2O10belong to the orthorhombic crystallographic system, their diffraction pattern were indexed. The new compounds were tested as inorganic pigments. Application of the prepared compounds in ceramic glazes did not provide technological interesting results. The reason is probably the low thermal stability of the prepared compounds CoNd2W2O10and MnNd2W2O10. In particle form CoNd2W2O10has blue color and MnNd2W2O10has brown color.