Search

During the SALSA experiment, in 2014, twelve combined wide-angle refraction and coincident multi-channel seismic profiles were acquired in the Jequitinhonha-Almada-Camamu, Jacuípe, and Sergipe-Alagoas basins, NE Brazil. Profile SL09 images the Almada-Camamu basin and the São Francisco craton, with 18 four-channel ocean-bottom seismometers and 22 land stations. The datasets were forward modelled and combined with pre-stack depth migration to increase the horizontal resolution of the velocity models. Our results show that sediment thickness varies between 3.8 km in the oceanward part of the profile, 4.3 km in the Almada basin and 6.5 km in the Camamu basin. Crustal thickness at the north-western edge of the profile is of around 40 km, with velocity gradients indicating a continental origin. The Camamu basin, which corresponds to the triple junction between the aborted N–S oriented Tucano rift, the SW-NE oriented Jacuipe-Sergipe-Alagoas branch, and the N–S Jequitinhonha-Almada branch, presents two crustal layers: a very thin upper layer, about 1.5 km thick, which increases seawards to 3 km in the Almada basin, and an higher velocity (HV) layer (6.8–7.2 km/s) about 4 km thick. This lower layer gradually disappears in the Almada basin. At the south-eastern edge of the profile, the resolution is lower but the thickness of the crust seems to increase up to 5 km. Deep wide-angle reflections indicate upper mantle stratification. Crustal organisation and P-wave propagation velocities in the Almada and Camamu basins indicate a transitional crust domain of exhumed continental crust affinity. In the Camamu triple junction and beneath this thin exhumed continental crust, the HV layer may probably reflect intruded materials. No exhumed upper mantle is observed along the entire profile. The easternmost part of the profile may correspond to a proto-oceanic crust. Typical oceanic crust is never imaged along the 260 km-long offshore profile.

The existence of gas hydrate systems along Brazil’s vast continental margin has been known since the 1980s, based on observations of bottom simulating reflectors (BSRs) in two large shelf-slope depocenters: (1) the Amazon deep-sea fan in the Foz do Amazonas Basin and (2) Rio Grande Cone in Pelotas Basin. These depocenters are both undergoing gravitational collapse above deep detachment surfaces, resulting in upslope extensional and downslope compressional domains. The BSR is discontinuous across the Amazon deep-sea fan, mainly observed at water depths of 600–2800 m and at anticlines within an upper slope thrust-fold belt related to the compressional domain of the fan. Conversely, a fairly continuous BSR extends across Rio Grande Cone at water depths of 520–3500 m, within both extensional and compressional domains. Interestingly, the well-defined BSR that spans Rio Grande Cone rises to meet the seafloor at water depths of 515–520 m, forming an unusual ‘BSR outcrop’. This phenomenon has been observed previously in only a few locations worldwide. Gas hydrates have been recovered within piston cores taken from seafloor seeps in both depocenters, and analyses reveal that gas is dominated by methane of microbial origin.

During the MAGIC (Margins of brAzil, Ghana, and Ivory Coast) experiment, five combined wide-angle, and reflection seismic profiles were acquired in the Pará-Maranhão/Barreirinhas/Ceará basins northern Brazil. This is a pull-apart passive margin, with two strike-slip borders. The equipment deployed includes 143 sea-bottom seismometers (OBS), a 4.5-km seismic streamer, and a 7587-in3 airgun array. In this paper, we focus on the distal parts of three profiles, and one entire transverse NW-SE profile, located on the presumed Cretaceous oceanic crust. Forward modelling of these wide-angle data sets reveals an E-W lateral evolution of the oceanic crust spreading initiation with: 1) just after the so-called intermediate domain, 60 km-wide domain that consists of a 5-km-thick crystalline crust. The basement presents two layers characterized by high acoustic velocity. This domain is bounded to the NW by a NW-SE volcanic line (Volcano Alignment), and 2) a 5-km-thick oceanic crust consisting of two layers characterized by “normal velocities” spanning between the two main fracture zones that fringe the Pará-Maranhão-Barreirinhas-Ceará segment. Despite a similar thickness, these two sub-domains present different velocity distribution in their two layers. They are both overlain by 5.5 km of sedimentary deposits. Forward wide-angle modelling confirms that the seafloor spreading process was progressive, with firstly the emplacement of a proto-oceanic crust, and then a thin oceanic crust. The “proto-oceanic” crust presents a similar seismic velocity with the intermediate domain interpreted as exhumed lower continental crust except for the lower part where the intruded lower crust gives place to a very sharp Moho at the base of the proto-oceanic domain. By contrast, the thin oceanic crust domain has a lower velocity structure in its upper layer, that is interpreted as basalt and is absent in the proto-oceanic crust. This eastward evolution, as also observed in the Provençal Basin, an

The Pará-Maranhão/Barreirinhas margin, North Brazil, is a pull-apart passive margin, with two strike-slip borders, formed during the opening of the Equatorial Atlantic Ocean during Cretaceous time. Its geometry and evolution are speculative due to the lack of information on the crustal structure and the crustal nature. We present here the E-W profiles of the MAGIC (Margins of brAzil, Ghana and Ivory Coast) deep seismic experiment, a joint project between French and Brazilian universities, research institutes and the industry. Fifty-six Ocean Bottom Seismometers (OBS) and a 4.5 seismic streamer were deployed at sea along 2 of the 5 MAGIC profiles. One profile was extended onshore by installing 8 land stations. We perform forward modelling through combined interpretation of the multichannel seismic and of the main reflected and refracted of these phases recorded by the OBSs. The final P-wave velocity models reveal distinct structural domains from onshore Brazil towards the Atlantic Ocean characterized by variations of the crustal thicknesses and velocities: (1) an unthinned continental crust below the São Luís Craton, where the crust is 33 km thick, (2) a 60 km wide necking domain below the Ilha de Santana Platform; (3) offshore, east of the continental slope, a 10 km-thick deep sedimentary basin underlain by a 5 km thick crust with velocity of 6.2–6.9 km/s that we interpret as an exhumed lower continental crust, on the top of an Anomalous Velocity Layer (AVL) probably made of intrusions of mantle-derived melts into the lower continental crust, or a mixture of them; (4) eastwards, the limit of the previous domain is marked by NW-SE aligned volcanoes and the disappearance of the AVL. The sedimentary succession becomes thinner (6 km) overlaying a proto-oceanic crust characterized by seismic velocities higher than “normal” oceanic crust in its upper part, but in continuity with the velocity described in the previous domain; (5) followed by a more characteristic but thin

Highlights • A new description of a non-synchronous Mixed Turbidite-Contourite System. • Alternated and cyclic deposits of down-slope and along-slope processes with a transitional stage of flow interaction. • Dominant flow depositional systems identification based on seismic response. • How mixed systems are organized through time and space. Abstract A new mixed turbidite-contourite system is described in the northern Campos Basin, southeastern Brazilian margin. This system is developed in a middle slope setting, and was formed through non-synchronous interaction between the turbidity current and a contour current in the same stratigraphic interval (Miocene). Depositional cycles were differentiated based on diagnostic seismic features. Seismic attributes, seismic facies, and isochron maps were used to identify alternating cycles of downslope and alongslope processes in the study area, along with the intermediate stage with features from both processes (mixed system). Seismic units were then associated with the dominant type of current. Alongslope current activity can be distinguished from the downslope current based on its acoustic characteristics (mainly low root-mean-square (RMS) amplitude values), internal architecture (clinoforms), and external geometry pattern (alongslope trend). On the other hand, downslope gravity currents develop deposits with high-amplitude or chaotic seismic facies, usually higher values of RMS amplitude, channel or channel-lobe features, erosive surfaces, and a basinward depositional trend. The first and oldest seismic unit (S1) was interpreted as a dominantly alongslope system, with vertical aggrading sigmoidal clinoforms and high-frequency, low-amplitude reflections commonly associated with fine-grained sedimentary deposits, typical of a plastered drift, along with a basinward mass transport deposit (MTD) from previous drift instability. Seismic unit S2 represents the intermediate stage where both gravity-driven and along-slope currents

During the MAGIC (Margins of brAzil, Ghana, and Ivory Coast) experiment, five combined wide-angle, and reflection seismic profiles were acquired in the Pará-Maranhão/Barreirinhas/Ceará basins northern Brazil. This is a pull-apart passive margin, with two strike-slip borders. The equipment deployed includes 143 sea-bottom seismometers (OBS), a 4.5-km seismic streamer, and a 7587-in3 airgun array. In this paper, we focus on the distal parts of three profiles, and one entire transverse NW-SE profile, located on the presumed Cretaceous oceanic crust. Forward modelling of these wide-angle data sets reveals an E-W lateral evolution of the oceanic crust spreading initiation with: 1) just after the so-called intermediate domain, 60 km-wide domain that consists of a 5-km-thick crystalline crust. The basement presents two layers characterized by high acoustic velocity. This domain is bounded to the NW by a NW-SE volcanic line (Volcano Alignment), and 2) a 5-km-thick oceanic crust consisting of two layers characterized by “normal velocities” spanning between the two main fracture zones that fringe the Pará-Maranhão-Barreirinhas-Ceará segment. Despite a similar thickness, these two sub-domains present different velocity distribution in their two layers. They are both overlain by 5.5 km of sedimentary deposits. Forward wide-angle modelling confirms that the seafloor spreading process was progressive, with firstly the emplacement of a proto-oceanic crust, and then a thin oceanic crust. The “proto-oceanic” crust presents a similar seismic velocity with the intermediate domain interpreted as exhumed lower continental crust except for the lower part where the intruded lower crust gives place to a very sharp Moho at the base of the proto-oceanic domain. By contrast, the thin oceanic crust domain has a lower velocity structure in its upper layer, that is interpreted as basalt and is absent in the proto-oceanic crust. This eastward evolution, as also observed in the Provençal Basin, an

The Pará-Maranhão/Barreirinhas margin, North Brazil, is a pull-apart passive margin, with two strike-slip borders, formed during the opening of the Equatorial Atlantic Ocean during Cretaceous time. Its geometry and evolution are speculative due to the lack of information on the crustal structure and the crustal nature. We present here the E-W profiles of the MAGIC (Margins of brAzil, Ghana and Ivory Coast) deep seismic experiment, a joint project between French and Brazilian universities, research institutes and the industry. Fifty-six Ocean Bottom Seismometers (OBS) and a 4.5 seismic streamer were deployed at sea along 2 of the 5 MAGIC profiles. One profile was extended onshore by installing 8 land stations. We perform forward modelling through combined interpretation of the multichannel seismic and of the main reflected and refracted of these phases recorded by the OBSs. The final P-wave velocity models reveal distinct structural domains from onshore Brazil towards the Atlantic Ocean characterized by variations of the crustal thicknesses and velocities: (1) an unthinned continental crust below the São Luís Craton, where the crust is 33 km thick, (2) a 60 km wide necking domain below the Ilha de Santana Platform; (3) offshore, east of the continental slope, a 10 km-thick deep sedimentary basin underlain by a 5 km thick crust with velocity of 6.2–6.9 km/s that we interpret as an exhumed lower continental crust, on the top of an Anomalous Velocity Layer (AVL) probably made of intrusions of mantle-derived melts into the lower continental crust, or a mixture of them; (4) eastwards, the limit of the previous domain is marked by NW-SE aligned volcanoes and the disappearance of the AVL. The sedimentary succession becomes thinner (6 km) overlaying a proto-oceanic crust characterized by seismic velocities higher than “normal” oceanic crust in its upper part, but in continuity with the velocity described in the previous domain; (5) followed by a more characteristic but thin

Highlights • A new description of a non-synchronous Mixed Turbidite-Contourite System. • Alternated and cyclic deposits of down-slope and along-slope processes with a transitional stage of flow interaction. • Dominant flow depositional systems identification based on seismic response. • How mixed systems are organized through time and space. Abstract A new mixed turbidite-contourite system is described in the northern Campos Basin, southeastern Brazilian margin. This system is developed in a middle slope setting, and was formed through non-synchronous interaction between the turbidity current and a contour current in the same stratigraphic interval (Miocene). Depositional cycles were differentiated based on diagnostic seismic features. Seismic attributes, seismic facies, and isochron maps were used to identify alternating cycles of downslope and alongslope processes in the study area, along with the intermediate stage with features from both processes (mixed system). Seismic units were then associated with the dominant type of current. Alongslope current activity can be distinguished from the downslope current based on its acoustic characteristics (mainly low root-mean-square (RMS) amplitude values), internal architecture (clinoforms), and external geometry pattern (alongslope trend). On the other hand, downslope gravity currents develop deposits with high-amplitude or chaotic seismic facies, usually higher values of RMS amplitude, channel or channel-lobe features, erosive surfaces, and a basinward depositional trend. The first and oldest seismic unit (S1) was interpreted as a dominantly alongslope system, with vertical aggrading sigmoidal clinoforms and high-frequency, low-amplitude reflections commonly associated with fine-grained sedimentary deposits, typical of a plastered drift, along with a basinward mass transport deposit (MTD) from previous drift instability. Seismic unit S2 represents the intermediate stage where both gravity-driven and along-slope currents

Ocean warming related to climate change has been proposed to cause the dissociation of gas hydrate deposits and methane leakage on the seafloor. This process occurs in places where the edge of the gas hydrate stability zone in sediments meets the overlying warmer oceans in upper slope settings. Here we present new evidence based on the analysis of a large multidisciplinary and multi-scale dataset from such a location in the western South Atlantic, which records massive gas release to the ocean. The results provide a unique opportunity to examine ocean-hydrate interactions over millennial and decadal scales, and the first evidence from the southern hemisphere for the effects of contemporary ocean warming on gas hydrate stability. Widespread hydrate dissociation results in a highly focused advective methane flux that is not fully accessible to anaerobic oxidation, challenging the assumption that it is mostly consumed by sulfate reduction before reaching the seafloor.

The Rio Grande Cone is a major fanlike depositional feature in the continental slope of the Pelotas Basin, Southern Brazil. Two representative sediment cores collected in the Cone area were retrieved using a piston core device. In this work, the organic matter (OM) in the sediments was characterized for a continental vs. marine origin using chemical proxies to help constrain the origin of gas in hydrates. The main contribution of OM was from marine organic carbon based on the stable carbon isotope (δ13C-org) and total organic carbon/total nitrogen ratio (TOC:TN) analyses. In addition, the 14C data showed important information about the origin of the OM and we suggest some factors that could modify the original organic matter and therefore mask the “real” 14C ages: (1) biological activity that could modify the carbon isotopic composition of bulk terrestrial organic matter values, (2) the existence of younger sediments from mass wasting deposits unconformably overlying older sediments, and (3) the deep-sediment-sourced methane contribution due to the input of “old” (>50 ka) organic compounds from migrating fluids.

Ocean warming related to climate change has been proposed to cause the dissociation of gas hydrate deposits and methane leakage on the seafloor. This process occurs in places where the edge of the gas hydrate stability zone in sediments meets the overlying warmer oceans in upper slope settings. Here we present new evidence based on the analysis of a large multidisciplinary and multi-scale dataset from such a location in the western South Atlantic, which records massive gas release to the ocean. The results provide a unique opportunity to examine ocean-hydrate interactions over millennial and decadal scales, and the first evidence from the southern hemisphere for the effects of contemporary ocean warming on gas hydrate stability. Widespread hydrate dissociation results in a highly focused advective methane flux that is not fully accessible to anaerobic oxidation, challenging the assumption that it is mostly consumed by sulfate reduction before reaching the seafloor.

Ocean warming related to climate change has been proposed to cause the dissociation of gas hydrate deposits and methane leakage on the seafloor. This process occurs in places where the edge of the gas hydrate stability zone in sediments meets the overlying warmer oceans in upper slope settings. Here we present new evidence based on the analysis of a large multidisciplinary and multi-scale dataset from such a location in the western South Atlantic, which records massive gas release to the ocean. The results provide a unique opportunity to examine ocean-hydrate interactions over millennial and decadal scales, and the first evidence from the southern hemisphere for the effects of contemporary ocean warming on gas hydrate stability. Widespread hydrate dissociation results in a highly focused advective methane flux that is not fully accessible to anaerobic oxidation, challenging the assumption that it is mostly consumed by sulfate reduction before reaching the seafloor.

Ocean warming related to climate change has been proposed to cause the dissociation of gas hydrate deposits and methane leakage on the seafloor. This process occurs in places where the edge of the gas hydrate stability zone in sediments meets the overlying warmer oceans in upper slope settings. Here we present new evidence based on the analysis of a large multidisciplinary and multi-scale dataset from such a location in the western South Atlantic, which records massive gas release to the ocean. The results provide a unique opportunity to examine ocean-hydrate interactions over millennial and decadal scales, and the first evidence from the southern hemisphere for the effects of contemporary ocean warming on gas hydrate stability. Widespread hydrate dissociation results in a highly focused advective methane flux that is not fully accessible to anaerobic oxidation, challenging the assumption that it is mostly consumed by sulfate reduction before reaching the seafloor.

Ocean warming related to climate change has been proposed to cause the dissociation of gas hydrate deposits and methane leakage on the seafloor. This process occurs in places where the edge of the gas hydrate stability zone in sediments meets the overlying warmer oceans in upper slope settings. Here we present new evidence based on the analysis of a large multi-disciplinary and multi-scale dataset from such a location in the western South Atlantic, which records massive gas release to the ocean. The results provide a unique opportunity to examine ocean-hydrate interactions over millennial and decadal scales, and the first evidence from the southern hemisphere for the effects of contemporary ocean warming on gas hydrate stability. Widespread hydrate dissociation results in a highly focused advective methane flux that is not fully accessible to anaerobic oxidation, challenging the assumption that it is mostly consumed by sulfate reduction before reaching the seafloor.

Deep subsurface microbial communities are more abundant in coarse-grained sedimentary rocks such as sandstones than in fine-grained mudstones. The low porosity and low permeability of mudstones are believed to restrict microbial life. Then, it is expected that distinct, isolated microbial communities may form in sandstones separated by mudstones. In this context, the connectivity between microbial communities in different sandstone units can be investigated to infer evolutionary patterns of diversification in space-time, which may potentially contribute with relevant data for analyses of hydraulic connectivity and stratigraphic correlation. In this work, we used high throughput DNA sequencing of a ribosomal 16S gene fragment to characterize the prokaryotic communities found in Permian sandstone samples of the same core that are separated by one mudstone interval, in the Charqueadas coal field, Parana Basin (Southern Brazil). Our samples were collected at ∌300 m deep, in porous sandstones separated by a thick mudstone package. Differences in the bacterial community structure between samples were observed for the classified OTUs, from phylum to genus. Molecular biology might be further applied as a possible tool to help to understand the spatial and temporal distribution of depositional facies, and the efficiency of low permeability rocks to compartmentalize reservoirs. Ongoing studies aim to extend the present investigation into further analyses regarding lateral changes in microbial communities present in the same sandstone units.

The stability of methane hydrates on continental margins worldwide is sensitive to changes in temperature and pressure conditions. It has been shown how gradual increases in bottom water temperatures due to ocean warming over post-glacial timescales can destabilize shallow oceanic hydrate deposits, causing their dissociation and gas release into the ocean. However, bottom water temperatures (BWT) may also vary significantly over much shorter timescales, including due to seasonal temperature oscillations of the ocean bottom currents. In this study, we investigate how a shallow methane hydrate deposit responds to seasonal BWT oscillations with an amplitude of up to 1.5 °C. We use the TOUGH + HYDRATE code to model changes in the methane hydrate stability zone (MHSZ) using data from the Rio Grande Cone, in the South Atlantic Ocean off the Brazilian coast. In all the cases studied, BWT oscillations resulted in significant gaseous methane fluxes into the ocean for up to 10 years, followed by a short period of small fluxes of gaseous methane into the ocean, until they stopped completely. On the other hand, aqueous methane was released into the ocean during the 100 years simulated, for all the cases studied. During the temperature oscillations, the MHSZ recedes continuously both horizontally and, in a smaller scale, vertically, until a permanent and a seasonal region in MHSZ are defined. Sensitivity tests were carried out for parameters of porosity, thermal conductivity and initial hydrate saturation, which were shown to play an important role on the volume of methane released into the ocean and on the time interval in which such release occurs. Overall, the results indicate that in a system with no gas recharge from the bottom, seasonal temperature oscillations alone cannot account for long-term gas release into the ocean.

In this work, we investigated the molecular stable isotope compositions of hydrate-bound and dissolved gases in sediments of the Amazon deep-sea fan and adjacent continental slope, Foz do Amazonas Basin, Brazil. Some cores were obtained in places with active gas venting on the seafloor and, in one of the locations, the venting gas is probably associated with the dissociation of hydrates near the edge of their stability zone. Results of the methane stable isotopes (δ13C and δD) of hydrate-bound and dissolved gases in sediments for the Amazon fan indicated the dominant microbial origin of methane via carbon dioxide reduction, in which 13C and deuterium isotopes were highly depleted (δ13C and δD of −102.2% to −74.2% V-PDB and −190 to −150% V-SMOW, respectively). The combination of C1/(C2+C3) versus δ13C plot also suggested a biogenic origin for methane in all analysed samples (commonly >1000). However, a mixture of thermogenic and microbial gases was suggested for the hydrate-bound and dissolved gases in the continental slope adjacent to the Amazon fan, in which the combination of chemical and isotopic gas compositions in the C1/(C2+C3) versus δ13C plot were <100 in one of the recovered cores. Moreover, the δ13C-ethane of −30.0% indicates a thermogenic origin.

We report major, trace elements and Pb, Hf, Nd and Sr isotopes in 61-54 Ma old basalts from Svartenhuk Halve Peninsula (Greenland). This area corresponds to the northernmost exposure of the West Greenland volcanic province, of which the emplacement marks the continental thinning and breakup process leading to the opening of Baffin Bay during the Eocene. Its wedge structure displays typical characteristics of inner seaward-dipping-reflectors (SDR) with an exposed volcanic sequence thicker than 7 km. Our results cover the entire volcanic sequence starting with an earliest V1 unit reflecting rather low degree partial melts (transitional basalts), which are geochemically imprinted by continental crust contamination. This unit is followed by much thicker and mainly tholeiitic V2 and V3 basaltic lava piles, and ends with a rather thin V4 unit, consisting of alkali basalts and associated trachytes. Pressures and temperatures of melt extraction were estimated based on major element concentrations and rare earth elements patterns. Our results suggest that melts were extracted from the garnet-spinet transition zone at greater depths for the initial V1 and the final V4 lavas (alkali to transitional basaltic compositions) than for the main V2 and V3 mostly tholeiitic lava piles (at 2 +/- 0.5 GPa and 1350 +/- 100 degrees C). Isotope signatures suggest that mantle sources of the melts were controlled by the mixing of ambient upper mantle and Icelandic plume-type materials. The proportion of ambient upper mantle involved in the lava source appears to increase together with melting rates and the upward propagation of melting zone during V3 emplacement, suggesting that melting in this area progessed as follows: 1. Initiation of partial melting (low degrees) of deep-seated Icelandic plume-type material (V1 and V2); 2. Upward propagation of the melting area within the shallower mixed upper mantle (V3); 3. Progressive decrease of "ambient upper mantle" involvement, deepening of magma e

We report major, trace elements and Pb, Hf, Nd and Sr isotopes in 61-54 Ma old basalts from Svartenhuk Halve Peninsula (Greenland). This area corresponds to the northernmost exposure of the West Greenland volcanic province, of which the emplacement marks the continental thinning and breakup process leading to the opening of Baffin Bay during the Eocene. Its wedge structure displays typical characteristics of inner seaward-dipping-reflectors (SDR) with an exposed volcanic sequence thicker than 7 km. Our results cover the entire volcanic sequence starting with an earliest V1 unit reflecting rather low degree partial melts (transitional basalts), which are geochemically imprinted by continental crust contamination. This unit is followed by much thicker and mainly tholeiitic V2 and V3 basaltic lava piles, and ends with a rather thin V4 unit, consisting of alkali basalts and associated trachytes. Pressures and temperatures of melt extraction were estimated based on major element concentrations and rare earth elements patterns. Our results suggest that melts were extracted from the garnet-spinet transition zone at greater depths for the initial V1 and the final V4 lavas (alkali to transitional basaltic compositions) than for the main V2 and V3 mostly tholeiitic lava piles (at 2 +/- 0.5 GPa and 1350 +/- 100 degrees C). Isotope signatures suggest that mantle sources of the melts were controlled by the mixing of ambient upper mantle and Icelandic plume-type materials. The proportion of ambient upper mantle involved in the lava source appears to increase together with melting rates and the upward propagation of melting zone during V3 emplacement, suggesting that melting in this area progessed as follows: 1. Initiation of partial melting (low degrees) of deep-seated Icelandic plume-type material (V1 and V2); 2. Upward propagation of the melting area within the shallower mixed upper mantle (V3); 3. Progressive decrease of "ambient upper mantle" involvement, deepening of magma e

We report major, trace elements and Pb, Hf, Nd and Sr isotopes in 61-54 Ma old basalts from Svartenhuk Halve Peninsula (Greenland). This area corresponds to the northernmost exposure of the West Greenland volcanic province, of which the emplacement marks the continental thinning and breakup process leading to the opening of Baffin Bay during the Eocene. Its wedge structure displays typical characteristics of inner seaward-dipping-reflectors (SDR) with an exposed volcanic sequence thicker than 7 km. Our results cover the entire volcanic sequence starting with an earliest V1 unit reflecting rather low degree partial melts (transitional basalts), which are geochemically imprinted by continental crust contamination. This unit is followed by much thicker and mainly tholeiitic V2 and V3 basaltic lava piles, and ends with a rather thin V4 unit, consisting of alkali basalts and associated trachytes. Pressures and temperatures of melt extraction were estimated based on major element concentrations and rare earth elements patterns. Our results suggest that melts were extracted from the garnet-spinet transition zone at greater depths for the initial V1 and the final V4 lavas (alkali to transitional basaltic compositions) than for the main V2 and V3 mostly tholeiitic lava piles (at 2 +/- 0.5 GPa and 1350 +/- 100 degrees C). Isotope signatures suggest that mantle sources of the melts were controlled by the mixing of ambient upper mantle and Icelandic plume-type materials. The proportion of ambient upper mantle involved in the lava source appears to increase together with melting rates and the upward propagation of melting zone during V3 emplacement, suggesting that melting in this area progessed as follows: 1. Initiation of partial melting (low degrees) of deep-seated Icelandic plume-type material (V1 and V2); 2. Upward propagation of the melting area within the shallower mixed upper mantle (V3); 3. Progressive decrease of "ambient upper mantle" involvement, deepening of magma e

Mapping of natural gas hydrate systems has been performed successfully in the past using the controlled-source electromagnetic (CSEM) method. This method relies on differentiating resistive highly saturated free gas or hydrate-bearing host sediment from a less resistive low-saturated gas or brine-bearing host sediments. Knowledge of the lateral extent and resistivity variations (and hence the saturation variations) within sediments that host hydrates is crucial to be able to accurately quantify the presence of saturated gas hydrates. A 3D CSEM survey (PUCRS14) was acquired in 2014 in the Pelotas Basin offshore Brazil, with hydrate resistivity mapping as the main objective. The survey was acquired within the context of the CONEGAS research project, which investigated the origin and distribution of gas hydrate deposits in the Pelotas Basin. We have inverted the acquired data using a proprietary 3D CSEM anisotropic inversion algorithm. Inversion was purely CSEM data driven, and we did not include any a priori information in the process. Prior to CSEM, interpretation of near-surface geophysical data including 2D seismic, sub-bottom profiler, and multibeam bathymetry data indicated possible presence of gas hydrates within features identified such as faults, chimneys, and seeps leading to pockmarks, along the bottom simulating reflector and within the gas hydrate stability zone. Upon integration of the same with CSEM-derived resistivity volume, the interpretation revealed excellent spatial correlation with many of these features. The interpretation further revealed new features with possible hydrate presence, which were previously overlooked due to a lack of a clear seismic and/or multibeam backscatter signature. In addition, features that were previously mapped as gas hydrate bearing had to be reinterpreted as residual or low-saturated gas/hydrate features, due to the lack of significant resistivity response associated with them. Furthermore, we used the inverted resisti

Gas hydrate provinces occur in two sedimentary basins along Brazil’s continental margin: (1) The Rio Grande Cone in the southeast, and (2) the Amazon deep-sea fan in the equatorial region. The occurrence of gas hydrates in these depocenters was first detected geophysically and has recently been proven by seafloor sampling of gas vents, detected as water column acoustic anomalies rising from seafloor depressions (pockmarks) and/or mounds, many associated with seafloor faults formed by the gravitational collapse of both depocenters. The gas vents include typical features of cold seep systems, including shallow sulphate reduction depths (<4 m), authigenic carbonate pavements, and chemosynthetic ecosystems. In both areas, gas sampled in hydrate and in sediments is dominantly formed by biogenic methane. Calculation of the methane hydrate stability zone for water temperatures in the two areas shows that gas vents occur along its feather edge (water depths between 510 and 760 m in the Rio Grande Cone and between 500 and 670 m in the Amazon deep-sea fan), but also in deeper waters within the stability zone. Gas venting along the feather edge of the stability zone could reflect gas hydrate dissociation and release to the oceans, as inferred on other continental margins, or upward fluid flow through the stability zone facilitated by tectonic structures recording the gravitational collapse of both depocenters. The potential quantity of venting gas on the Brazilian margin under different scenarios of natural or anthropogenic change requires further investigation. The studied areas provide natural laboratories where these critical processes can be analyzed and quantified.

Conspicuous physicochemical vertical stratification in the deep sea is one of the main forces driving microbial diversity in the oceans. Oxygen and sunlight availability are key factors promoting microbial diversity throughout the water column. Ocean currents also play a major role in the physicochemical stratification, carrying oxygen down to deeper zones as well as moving deeper water masses up towards shallower depths. Water samples within a 50-km radius in a pockmark location of the southwestern Atlantic Ocean were collected and the prokaryotic communities from different water depths - chlorophyll maximum, oxygen minimum and deep-sea bottom (down to 1355 m) - were described. At phylum level, Proteobacteria were the most frequent in all water depths, Cyanobacteria were statistically more frequent in chlorophyll maximum zone, while Thaumarchaeota were significantly more abundant in both oxygen minimum and bottom waters. The most frequent microorganism in the chlorophyll maximum and oxygen minimum zones was a Pelagibacteraceae operational taxonomic unit (OTU). At the bottom, the most abundant genus was the archaeon Nitrosopurnilus. Beta diversity analysis of the 16S rRNA gene sequencing data uncovered in this study shows high spatial hetero-geneity among water zones communities. Our data brings important contribution for the characterisation of oceanic microbial diversity, as it consists of the first description of prokaryotic communities occurring in different oceanic water zones in the southwestern Atlantic Ocean.

Much research has been published regarding the relation between major gas hydrate accumulations and the global carbon cycle. In this context, the determination of the sulfate/methane interface (SMI) depth is of primary importance in order to understand the dynamics of methane flux in the shallow section. This paper identifies the depth of the SMI in sediments based on sulfate and methane concentration profiles in cores recovered in the Rio Grande Cone Gas Hydrate Province, Pelotas Basin, southern Brazil. The shape of methane and sulfate concentration profiles in the sediments can be linked to the local methane flux rate as follows: (i) near linear, high upward-diffusing methane flux coupled with high sulfate diffusion from seawater; (ii) irregular, variable methane flux rates; and (iii) kink-type profile, which is indicative of variable rather than strictly high upward methane flux. The areas in which a high methane flux was identified are spatially associated with gas chimneys in sediments within pockmarks, whereas profiles with low methane flux are present in adjacent areas. These chimneys appear as acoustic blankings in seismic records and can therefore be mapped in subsurface. The wavy-like seismic reflection following the SMI coincides with the occurrence of authigenic carbonate nodules and concretions. In addition, high methane fluxes and the occurrence of concretions and nodules carbonates were correlated by stratigraphic position of the concretions bearing intervals and sulfate profiles, Muitas pesquisas têm sido publicadas relacionando elevadas acumulações de hidrato de gás e o ciclo global do carbono. Nesse contexto, a determinação da profundidade da interface sulfato/metano (SMI) é importante para entender a dinâmica do fluxo de metano em locais rasos. Este artigo científico identifica a profundidade da SMI em sedimentos com base em perfis de concentração de sulfato e metano em testemunhos recuperados na Província do Hidrato de Gás do Cone do Rio Grande, Bacia de Pelotas, no Sul do Brasil. A forma dos perfis de concentração de metano e sulfato nos sedimentos pode ser relacionada à taxa de fluxo de metano da seguinte forma: (i) fluxo de metano quase linear, de alta difusão ascendente, com alta difusão de sulfato da água do mar; (ii) fluxo de metano irregular e taxas variáveis;(iii) perfil de tipo torção, que é indicativo de um fluxo de metano variável em vez de somente alto fluxo ascendente. As áreas em que o alto fluxo de metano foi identificado estão associadas com chaminés de gás em sedimentos dentro de pockmarks, enquanto perfis com baixo fluxo de metano estão presentes em áreas adjacentes. Essas chaminés aparecem como brancos acústicos nos dados sísmicos e, portanto, podem ser mapeadas na subsuperfície. A variação da reflexão sísmica que segue o SMI coincide com a ocorrência de nódulos e concreções de carbonato autigênicos. Além disso, elevados fluxos de metano e a ocorrência de concreções e nódulos de carbonatos foram correlacionados pela posição estratigráfica dos intervalos de concreções e perfis de sulfato.

As the depth increases and the light fades in oceanic cold seeps, a variety of chemosynthetic-based benthic communities arise. Previous assessments reported polychaete annelids belonging to the family Siboglinidae as part of the fauna at cold seeps, with the ‘Vestimentifera’ clade containing specialists that depend on microbial chemosynthetic endosymbionts for nutrition. Little information exists concerning the microbiota of the external portion of the vestimentiferan trunk wall. We employed 16S rDNA-based metabarcoding to describe the external microbiota of the chitin tubes from the vestimentiferan Escarpia collected from a chemosynthetic community in a cold seep area at the southwestern Atlantic Ocean. The most abundant operational taxonomic unit (OTU) belonged to the family Pirellulaceae (phylum Planctomycetes), and the second most abundant OTU belonged to the order Methylococcales (phylum Proteobacteria), composing an average of 21.1 and 15.4% of the total reads on tubes, respectively. These frequencies contrasted with those from the surrounding environment (sediment and water), where they represent no more than 0.1% of the total reads each. Moreover, some taxa with lower abundances were detected only in Escarpia tube walls. These data constitute on the first report of an epibiont microbial community found in close association with external surface of a cold-seep metazoan, Escarpia sp., from a chemosynthetic community in the southwestern Atlantic Ocean.

Chemosynthetic communities have been described from a variety of deep-sea environments across the world's oceans. They constitute very interesting biological systems in terms of their ecology, evolution and biogeography, and also given their potential as indicators of the presence and abundance of consistent hydrocarbon-based nutritional sources. Up to now such peculiar biotic assemblages have not been reported for the western South Atlantic Ocean, leaving this large region undocumented with respect to the presence, composition and history of such communities. Here we report on the presence of a chemosynthetic community off the coast of southern Brazil, in an area where high-levels of methane and the presence of gas hydrates have been detected. We performed metagenomic analyses of the microbial community present at this site, and also employed molecular approaches to identify components of its benthic fauna. We conducted phylogenetic analyses comparing the components of this assemblage to those found elsewhere in the world, which allowed a historical assessment of the structure and dynamics of these systems. Our results revealed that the microbial community at this site is quite diverse, and contains many components that are very closely related to lineages previously sampled in ecologically similar environments across the globe. Anaerobic methanotrophic (ANME) archaeal groups were found to be very abundant at this site, suggesting that methane is indeed an important source of nutrition for this community. In addition, we document the presence at this site of a vestimentiferan siboglinid polychaete and the bivalve Acharax sp., both of which are typical components of deep-sea chemosynthetic communities. The remarkable similarity in biotic composition between this area and other deep-sea communities across the world supports the interpretation that these assemblages are historically connected across the global oceans, undergoing colonization from distant sites and inf

The Rio Grande Cone is a large-scale fanlike feature in the continental slope of the Pelotas Basin, Southern Brazil, where ubiquitous world-class bottom simulating reflectors (BSRs) are readily observed in seismic records. With the purpose of searching for natural gas hydrate deposits in the Cone area, four oceanographic cruises were carried out between May 2011 and July 2013, leading to the discovery of two pockmark fields, active faults and gas hydrates in shallow sediments. Multichannel seismic, multibeam echo sounder, side scan sonar and sub-bottom profiler records were used to map the shallow section and select sites for piston core sampling. Gas hydrates were recovered in several piston cores within muddy sediments collected inside pockmarks displaying high backscatter in the multibeam and side scan sonar data. We present two representative piston cores where numerous levels of gas hydrates occur, along with degassing features, authigenic carbonate and soupy sediments. Gas dissociated from gas hydrate samples is dominantly methane (>99.78%) with minor quantities of ethane. The chemical and isotopic compositions of the gas strongly suggest a biogenic origin for the analyzed samples. These new findings are regarded as strong enough evidence to consider the Rio Grande Cone as a new gas hydrate province. (C) 2015 Elsevier Ltd. All rights reserved.

This paper provides both an introduction to and summary for the Atlas of Contourite Systems that has been compiled as part of the International Geological Correlation Project - IGCP 432. Following the seminal works of George Wust on the physical oceanography of bottom currents, and Charley Hollister on contourite sediments, a series of significant advances have been made over the past few decades. While accepting that ideas and terms must remain flexible as our knowledge base continues to increase, we present a consensus view on terminology and definitions of bottom currents, contourites and drifts. Both thermohaline and wind-driven circulation, influenced by Coriolis Force and molded by topography, contribute to the oceanic system of bottom currents. These semi-permanent currents show significant variability in time and space, marked by periodic benthic storm events in areas of high surface kinetic energy. Six different drift types are recognized in the ocean basins and margins at depths greater than about 300 m: (i) contourite sheet drifts; (ii) elongate mounded drifts; (iii) channel related drifts; (iv) confined drifts; (v) infill drifts; and (vi) modified drift-turbidite systems. In addition to this overall geometry, their chief seismic characteristics include: a uniform reflector pattern that reflects long-term stability, drift-wide erosional discontinuities caused by periodic changes in bottom current regime, and stacked broadly lenticular seismic depositional units showing oblique to downcurrent migration. At a smaller scale, a variety of seismic facies can be recognized that are here related to bottom current intensity. A model for seismic facies cyclicity (alternating transparent/reflector zones) is further elaborated, and linked to bottom current/climate change. Both erosional features and depositional bedforms are diagnostic of bottom current systems and velocities. Many different contourite facies are now known to exist, encompassing all compositional ty

This paper provides both an introduction to and summary for the Atlas of Contourite Systems that has been compiled as part of the International Geological Correlation Project - IGCP 432. Following the seminal works of George Wust on the physical oceanography of bottom currents, and Charley Hollister on contourite sediments, a series of significant advances have been made over the past few decades. While accepting that ideas and terms must remain flexible as our knowledge base continues to increase, we present a consensus view on terminology and definitions of bottom currents, contourites and drifts. Both thermohaline and wind-driven circulation, influenced by Coriolis Force and molded by topography, contribute to the oceanic system of bottom currents. These semi-permanent currents show significant variability in time and space, marked by periodic benthic storm events in areas of high surface kinetic energy. Six different drift types are recognized in the ocean basins and margins at depths greater than about 300 m: (i) contourite sheet drifts; (ii) elongate mounded drifts; (iii) channel related drifts; (iv) confined drifts; (v) infill drifts; and (vi) modified drift-turbidite systems. In addition to this overall geometry, their chief seismic characteristics include: a uniform reflector pattern that reflects long-term stability, drift-wide erosional discontinuities caused by periodic changes in bottom current regime, and stacked broadly lenticular seismic depositional units showing oblique to downcurrent migration. At a smaller scale, a variety of seismic facies can be recognized that are here related to bottom current intensity. A model for seismic facies cyclicity (alternating transparent/reflector zones) is further elaborated, and linked to bottom current/climate change. Both erosional features and depositional bedforms are diagnostic of bottom current systems and velocities. Many different contourite facies are now known to exist, encompassing all compositional ty