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Antimony is a naturally occurring element. It belongs to group 15 of the periodic table of the elements. Antimony can exist in a variety of oxidation states (–III, 0, III, V) but it is mainly found in two oxidation states (III and V) in environmental, biological, and geochemical samples. Although antimony was already known to the ancients, it is still often overlooked, both as an element of environmental concern and as a subject for study, probably because of its lower abundance and the relative insolubility of most of its compounds. This is reflected in the poor standard of existing data on the behavior of antimony in natural waters. However, interest in the study of this element seems to be growing and an increasing number of papers on the subject are being published. A useful series of comprehensive reviews on antimony in the environment has recently been published (1, 2).

Différentes méthodes fondées sur l'exploitation d'un même réactif à savoir le carmin indigo ont été mises en œuvre pour réaliser le suivi du dioxyde de chlore et des sous-produits de dégradation que sont les ions chlorite et chlorate.L'étude de la stabilité du carmin indigo a permis de montrer que la détermination du dioxyde de chlore doit être effectuée dans les premières heures qui suivent l'ajout de carmin indigo, une légère diminution de l'absorbance étant observée au delà de vingt heures. L'absorbance du carmin indigo en présence d'ions chlorite et chlorate reste en revanche stable plusieurs jours.La recherche d'éventuelles interférences (substances humiques, ozone, hypochlorite) a également été effectuée. Les ions chlorite et chlorate réagissent avec les substances humiques en milieu acide selon une cinétique réactionnelle beaucoup plus lente que celle des ions chlorite et chlorate sur le carmin indigo. De ce fait, les pourcentages d'erreur sur les concentrations restent faibles. L'hypochlorite ou plus précisément l'acide hypochloreux réagit avec le carmin indigo ce qui conduit à des erreurs dans la détermination du dioxyde de chlore, des ions chlorite et chlorate. Dans le cas du dosage du dioxyde de chlore, les sources d'erreur peuvent être éliminées en ajoutant de l'ammoniaque avant l'introduction du carmin indigo dans l'échantillon.Après avoir été validés dans des milieux synthétiques, les protocoles ont été appliqués à un milieu naturel : l'eau de distribution de la ville de Brest. Une analyse statistique a été effectuée dans le but de comparer les résultats avec ceux déduits d'autres méthodes basées sur des principes différents., Over the last decade, chlorine dioxide has been increasingly used for disinfecting drinking water in many countries. A guarantee for the protection of the consumer is the presence of a sufficient residual concentration of the bactericidal reagent in drinking water. Thus it is important to determine exactly and accurately the levels of chlorine dioxide at the tap. During water treatment and subsequent distribution, chlorine dioxide can undergo a variety of reduction and disproportionation reactions producing primarily chloride but also chlorite and chlorate, which have been shown to cause haemolytic anemia. Reliable analytical methods are needed to identify and determine levels of chlorine dioxide, chlorite and chlorate in drinking water. A procedure based on the use of indigo carmine for the determination of each species in natural waters is suggested in this paper.In phosphate buffer (pH 6.8), two moles of chlorine dioxide oxidize one mole of indigo carmine. The concentration of the bactericidal reagent can be determined by measuring the difference in absorbance of the dye at 610 nm before and after reaction with chlorine dioxide. This method is selective as chlorite and chlorate do not react with indigo carmine in phosphate buffer at pH 6.8. Although the spectrophotometric method can be used successfully used at levels of chlorine dioxide down to 30 µg/l, the determination of lower levels in tap water requires a more sensitive method such as an electrochemical stripping procedure. This analysis is based on the measurement of the decrease in the indigo carmine signal after addition of chlorine dioxide. The detection limit is around 1 µg/l.At pH=2, one mole of indigo carmine reduces one mole of chlorite. Thus the chlorite concentration can be determined by measuring the indigo carmine absorbance at pH=2. At pH=0, indigo carmine reacts with both chlorite and chlorate. A measurement at pH=0 allows chlorate concentrations to be determined since the decrease in absorban

The use is described of single particle counting based on light scattering combined with transmission electronic microscopy coupled with energy dispersive spectroscopy and selected area electron diffraction to study the particle size distributions and the mineralogy of the inorganic colloids. The results showed that the dependence of the colloid number concentration on colloid diameters can be described by a power-law distribution in all cases. The same main mineral types were found in the different samples including phyllosilicates (illite and mica), chlorite, feldspars (albite and orthoclase), calcite and quartz, with a variable number of Fe oxide particles. The mineralogy closely resembles that of the parent rock. Spatial variations in the structure and composition of the rock in contact with the waters, such as fissured rock and shear joints, are reflected in the colloid composition. The properties of the colloids and the processes affecting them can be considered as representative of the colloids present in groundwaters., The use is described of single particle counting based on light scattering combined with transmission electronic microscopy coupled with energy dispersive spectroscopy and selected area electron diffraction to study the particle size distributions and the mineralogy of the inorganic colloids. The results showed that the dependence of the colloid number concentration on colloid diameters can be described by a power-law distribution in all cases. The same main mineral types were found in the different samples including phyllosilicates (illite and mica), chlorite, feldspars (albite and orthoclase), calcite and quartz, with a variable number of Fe oxide particles. The mineralogy closely resembles that of the parent rock. Spatial variations in the structure and composition of the rock in contact with the waters, such as fissured rock and shear joints, are reflected in the colloid composition. The properties of the colloids and the processes affecting them can be considered as representative of the colloids present in groundwaters.