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A well-established constraint on the size of non-porous olivine grains or the porosity of aggregates consisting of small olivine grains from prominent narrow peaks in thermal infrared spectra characteristic of crystalline silicates is reexamined. To thoroughly investigate thermal infrared peaks, we make theoretical argument for the absorption and scattering of light by non-porous, non-spherical olivine particles, which is followed by numerical verification. Our study provides perfectly rational explanations of the physics behind the small-particle effect of emission peaks in the framework of classical electrodynamics and convincing evidence of small-particle's emission peaks in the literature. While resonant absorption excited by surface roughness on the order of submicrometer scales can be identified even for non-porous olivine particles with a radius of $10~{\rm \mu m}$, it makes only a negligible contribution to thermal infrared spectra of the particles. In contrast, the porosity of non-spherical particles has a significant impact on the strength and wavelength of the peaks, while the resonant absorption excited by an ensemble of small grains takes place at a wavelength different than one expects for surface roughness. We finally reaffirm that twin peaks of olivine in thermal infrared spectra of dust particles in astronomical environments are the intrinsic diagnostic characters of submicrometer-sized small grains and their aggregate particles in fluffy and porous configurations., Comment: 16 pages, 8 figures, to appear in Icarus

Basaltic rocks occur widely on the terrestrial planets and differentiated asteroids, including the asteroid 4 Vesta. We conducted a shock recovery experiment with decaying compressive pulses on a terrestrial basalt at Chiba Institute of Technology, Japan. The sample recorded a range of pressures, and shock physics modeling was conducted to add a pressure scale to the observed shock features. The shocked sample was examined by optical and electron microscopy, electron back-scattered diffractometry, and Raman spectroscopy. We found that localized melting occurs at a lower pressure (~10 GPa) than previously thought (>20 GPa). The shocked basalt near the epicenter represents shock degree C of a recently proposed classification scheme for basaltic eucrites and, as such, our results provide a pressure scale for the classification scheme. Finally, we estimated the total fraction of the basaltic eucrites classified as shock degree C to be ~15% by assuming the impact velocity distribution onto Vesta., Comment: 17 pages, 4 figures, 1 table, 1 supplementary Information, accepted for publication in Geophysical Research Letters

Carbonaceous asteroids, including Ryugu and Bennu, which have been explored by the Hayabusa2 and OSIRIS-REx missions, were probably important carriers of volatiles to the inner Solar System. However, Ryugu has experienced significant volatile loss, possibly from hypervelocity impact heating. Here we present impact experiments at speeds comparable to those expected in the main asteroid belt (3.7 km s-1 and 5.8 km s-1) and with analogue target materials. We find that loss of volatiles from the target material due to impacts is not sufficient to account for the observed volatile depletion of Ryugu. We propose that mutual collisions in the main asteroid belt are unlikely to be solely responsible for the loss of volatiles from Ryugu or its parent body. Instead, we suggest that additional processes, for example associated with the diversity in mechanisms and timing of their formation, are necessary to account for the variable volatile contents of carbonaceous asteroids., Comment: Author version, 12 pages, 4 figures, 1 supplementary information

Shock metamorphism of minerals in meteorites provides insights into the ancient Solar System. Calcite is an abundant aqueous alteration mineral in carbonaceous chondrites. Return samples from the asteroids Ryugu and Bennu are expected to contain calcite-group minerals. Although shock metamorphism in silicates has been well studied, such data for aqueous alteration minerals are limited. Here, we investigated the shock effects in calcite with marble using impact experiments at the Planetary Exploration Research Center of Chiba Institute of Technology. We produced decaying compressive pulses with a smaller projectile than the target. A metal container facilitates recovery of a sample that retains its pre-impact stratigraphy. We estimated the peak pressure distributions in the samples with the iSALE shock physics code. The capability of this method to produce shocked grains that have experienced different degrees of metamorphism from a single experiment is an advantage over conventional uniaxial shock recovery experiments. The shocked samples were investigated by polarizing microscopy and X-ray diffraction analysis. We found that more than half of calcite grains exhibit undulatory extinction when peak pressure exceeds 3 GPa. This shock pressure is one order of magnitude higher than the Hugoniot elastic limit (HEL) of marble, but it is close to the HEL of a calcite crystal, suggesting that the undulatory extinction records dislocation-induced plastic deformation in the crystal. Finally, we propose a strategy to re-construct the maximum depth of calcite grains in a meteorite parent body, if shocked calcite grains are identified in chondrites and/or return samples from Ryugu and Bennu., Comment: 25 pages, 9 figures, 1 table, 1 supporting information, accepted for publication in Journal of Geophysical Research Planets

A well-established constraint on the size of non-porous olivine grains or the porosity of aggregates consisting of small olivine grains from prominent narrow peaks in thermal infrared spectra characteristic of crystalline silicates is reexamined. To thoroughly investigate thermal infrared peaks, we make theoretical argument for the absorption and scattering of light by non-porous, non-spherical olivine particles, which is followed by numerical verification. Our study provides perfectly rational explanations of the physics behind the small-particle effect of emission peaks in the framework of classical electrodynamics and convincing evidence of small-particle's emission peaks in the literature. While resonant absorption excited by surface roughness on the order of submicrometer scales can be identified even for non-porous olivine particles with a radius of $10~{\rm \mu m}$, it makes only a negligible contribution to thermal infrared spectra of the particles. In contrast, the porosity of non-spherical particles has a significant impact on the strength and wavelength of the peaks, while the resonant absorption excited by an ensemble of small grains takes place at a wavelength different than one expects for surface roughness. We finally reaffirm that twin peaks of olivine in thermal infrared spectra of dust particles in astronomical environments are the intrinsic diagnostic characters of submicrometer-sized small grains and their aggregate particles in fluffy and porous configurations., Comment: 16 pages, 8 figures, to appear in Icarus

High-speed impact ejecta at velocities comparable to the impact velocity are expected to contribute to material transport between planetary bodies and deposition of ejecta far from the impact crater. We investigated the behavior of high-speed ejecta produced at angles of 45 and 90 degrees, using both experimental and numerical methods. The experimental system developed at the Planetary Exploration Research Center of Chiba Institute of Technology (Japan) allowed us to observe the initial growth of the ejecta. We succeeded in imaging high-speed ejecta at 0.2 $\mathrm{{\mu}}$s intervals for impacts of polycarbonate projectiles of 4.8 mm diameter onto a polycarbonate plate at an impact velocity of ~4 km s$^{-1}$. Smoothed particle hydrodynamics (SPH) simulations of various numerical resolutions were conducted for the same impact conditions as pertaining to the experiments. We compared the morphology and velocities of the ejecta for the experiments and simulations, and we confirmed a close match for high-resolution simulations (with $\geq10^6$ SPH particles representing the projectile). According to the ejecta velocity distributions obtained from our high-resolution simulations, the ejection velocities of the high-speed ejecta for oblique impacts are much greater than those for vertical impacts. The translational motion of penetrating projectiles parallel to the target surface in oblique impacts could cause long-term, sustained acceleration at the root of the ejecta., Comment: 33 pages, 16 figures, 1 supporting information, accepted for publication in Journal of Geophysical Research: Planets

High-speed impact ejecta at velocities comparable to the impact velocity are expected to contribute to material transport between planetary bodies and deposition of ejecta far from the impact crater. We investigated the behavior of high-speed ejecta produced at angles of 45 and 90 degrees, using both experimental and numerical methods. The experimental system developed at the Planetary Exploration Research Center of Chiba Institute of Technology (Japan) allowed us to observe the initial growth of the ejecta. We succeeded in imaging high-speed ejecta at 0.2 $\mathrm{{\mu}}$s intervals for impacts of polycarbonate projectiles of 4.8 mm diameter onto a polycarbonate plate at an impact velocity of ~4 km s$^{-1}$. Smoothed particle hydrodynamics (SPH) simulations of various numerical resolutions were conducted for the same impact conditions as pertaining to the experiments. We compared the morphology and velocities of the ejecta for the experiments and simulations, and we confirmed a close match for high-resolution simulations (with $\geq10^6$ SPH particles representing the projectile). According to the ejecta velocity distributions obtained from our high-resolution simulations, the ejection velocities of the high-speed ejecta for oblique impacts are much greater than those for vertical impacts. The translational motion of penetrating projectiles parallel to the target surface in oblique impacts could cause long-term, sustained acceleration at the root of the ejecta., Comment: 33 pages, 16 figures, 1 supporting information, accepted for publication in Journal of Geophysical Research: Planets

Dry lakebeds might constitute large volatile reservoirs on Mars. Hypervelocity impacts onto ancient dry lakebeds would have affected the volatile distribution on Mars. We developed a new experimental method to investigate the response of evaporitic minerals (halite and gypsum) to impact shocks in an open system. This technique does not result in chemical contamination from the operation of the gas gun. The technique is termed the two-valve method and the gun system is located in the Planetary Exploration Research Center, Chiba Institute of Technology, Japan. We detected the vaporization of halite at 31 GPa and devolatilization from gypsum at 11 GPa, suggesting that impact-induced volatile release from dry lakebeds has periodically occurred throughout Martian history. The vaporization of halite deposits might have enhanced the production of perchlorates, which are found globally on Mars. The water loss from gypsum possibly explains the coexisting types of Ca-sulfates found in Gale Crater., Comment: 17 pages, 4 figures, 1 supporting information, accepted for publication in Geophysical Research Letters

type:text, Dry lakebeds might constitute large volatile reservoirs on Mars. Hypervelocity impacts onto ancient dry lakebeds would have affected the volatile distribution on Mars. We developed a new experimental method to investigate the response of evaporitic minerals (halite and gypsum) to impact shocks in an open system. This technique does not result in chemical contamination from the operation of the gas gun. The technique is termed the “two‐valve method,” and the gun system is located in the Planetary Exploration Research Center, Chiba Institute of Technology, Japan. We detected the vaporization of halite at 31 GPa and devolatilization from gypsum at 11 GPa, suggesting that impact‐induced volatile release from dry lakebeds has periodically occurred throughout Martian history. The vaporization of halite deposits might have enhanced the production of perchlorates, which are found globally on Mars. The water loss from gypsum possibly explains the coexisting types of Ca‐sulfates found in Gale Crater., This work was supported by ISAS/JAXA as a collaborative program with its Hypervelocity Impact Facility.

Dry lakebeds might constitute large volatile reservoirs on Mars. Hypervelocity impacts onto ancient dry lakebeds would have affected the volatile distribution on Mars. We developed a new experimental method to investigate the response of evaporitic minerals (halite and gypsum) to impact shocks in an open system. This technique does not result in chemical contamination from the operation of the gas gun. The technique is termed the “two‐valve method,” and the gun system is located in the Planetary Exploration Research Center, Chiba Institute of Technology, Japan. We detected the vaporization of halite at 31 GPa and devolatilization from gypsum at 11 GPa, suggesting that impact‐induced volatile release from dry lakebeds has periodically occurred throughout Martian history. The vaporization of halite deposits might have enhanced the production of perchlorates, which are found globally on Mars. The water loss from gypsum possibly explains the coexisting types of Ca‐sulfates found in Gale Crater., This work was supported by ISAS/JAXA as a collaborative program with its Hypervelocity Impact Facility.

This work synthesized oxygen sensitive and near infrared (NIR) luminescent Yb(III) coordination polymers incorporating ligands based on pyrene derivatives: Yb(III)-TBAPy and Yb(III)-TIAPy (TBAPy: 1,3,6,8-tetrskis(p-benzoate)pyrene, TIAPy: 1,3,6,8-tetrakis(3,5-isophtalic acid)pyrene). The coordination structures of these materials were characterized using electrospray ionization mass spectrometry, X-ray diffraction and thermogravimetric analysis, while the porous structure of the Yb(III)-TIAPy was evaluated based on its adsorption isotherm. The NIR luminescence properties of the Yb(III)-TBAPy and Yb(III)-TIAPy were examined by acquiring emission spectra and determining emission lifetimes under air, argon and vacuum. The Yb(III)-TIAPy exhibited high thermal stability (with a decomposition temperature of 400 °C), intense luminescence (with an emission quantum yield under argon of 6.6%) and effective oxygen-sensing characteristics. These results suggest that NIR luminescent Yb(III) coordination polymers made using pyrene derivatives could have applications in novel thermo-stable oxygen sensors.

Dry lakebeds might constitute large volatile reservoirs on Mars. Hypervelocity impacts onto ancient dry lakebeds would have affected the volatile distribution on Mars. We developed a new experimental method to investigate the response of evaporitic minerals (halite and gypsum) to impact shocks in an open system. This technique does not result in chemical contamination from the operation of the gas gun. The technique is termed the “two‐valve method,” and the gun system is located in the Planetary Exploration Research Center, Chiba Institute of Technology, Japan. We detected the vaporization of halite at 31 GPa and devolatilization from gypsum at 11 GPa, suggesting that impact‐induced volatile release from dry lakebeds has periodically occurred throughout Martian history. The vaporization of halite deposits might have enhanced the production of perchlorates, which are found globally on Mars. The water loss from gypsum possibly explains the coexisting types of Ca‐sulfates found in Gale Crater., This work was supported by ISAS/JAXA as a collaborative program with its Hypervelocity Impact Facility.

This work synthesized oxygen sensitive and near infrared (NIR) luminescent Yb(III) coordination polymers incorporating ligands based on pyrene derivatives: Yb(III)-TBAPy and Yb(III)-TIAPy (TBAPy: 1,3,6,8-tetrskis(p-benzoate)pyrene, TIAPy: 1,3,6,8-tetrakis(3,5-isophtalic acid)pyrene). The coordination structures of these materials were characterized using electrospray ionization mass spectrometry, X-ray diffraction and thermogravimetric analysis, while the porous structure of the Yb(III)-TIAPy was evaluated based on its adsorption isotherm. The NIR luminescence properties of the Yb(III)-TBAPy and Yb(III)-TIAPy were examined by acquiring emission spectra and determining emission lifetimes under air, argon and vacuum. The Yb(III)-TIAPy exhibited high thermal stability (with a decomposition temperature of 400 °C), intense luminescence (with an emission quantum yield under argon of 6.6%) and effective oxygen-sensing characteristics. These results suggest that NIR luminescent Yb(III) coordination polymers made using pyrene derivatives could have applications in novel thermo-stable oxygen sensors.

Dry lakebeds might constitute large volatile reservoirs on Mars. Hypervelocity impacts onto ancient dry lakebeds would have affected the volatile distribution on Mars. We developed a new experimental method to investigate the response of evaporitic minerals (halite and gypsum) to impact shocks in an open system. This technique does not result in chemical contamination from the operation of the gas gun. The technique is termed the two-valve method and the gun system is located in the Planetary Exploration Research Center, Chiba Institute of Technology, Japan. We detected the vaporization of halite at 31 GPa and devolatilization from gypsum at 11 GPa, suggesting that impact-induced volatile release from dry lakebeds has periodically occurred throughout Martian history. The vaporization of halite deposits might have enhanced the production of perchlorates, which are found globally on Mars. The water loss from gypsum possibly explains the coexisting types of Ca-sulfates found in Gale Crater., Comment: 17 pages, 4 figures, 1 supporting information, accepted for publication in Geophysical Research Letters

The amorphous nature of a series of zinc-porphyrins bearing two 3,4,5-tri((S)-3,7-dimethyloctyloxy) phenyl groups at the meso-positions, named "porphyrin glass", were tolerant of pi-conjugation engineering in ethynylene-linked dimers. The butadiyne-linked dimeric porphyrin glass formed an intermolecular excimer, which exhibited bright and exceptionally long-lived, near-infrared (NIR) luminescence at approximately 970 nm in the solid state. Therefore, porphyrin glasses overcame a general bottleneck for NIR-luminescence, such as an undesired pi-stacked aggregation of a large porphyrin plane in addition to the energy gap law. The formation of amorphous molecular glasses from a series of meso-ethynylene-conjugated zinc-porphyrins, named "porphyrin glass", is described. The butadiyne-linked dimeric porphyrin glass formed an intermolecular excimer, which exhibited solid-state, near-infrared (NIR) luminescence at approximately 970 nm.

The amorphous nature of a series of zinc-porphyrins bearing two 3,4,5-tri((S)-3,7-dimethyloctyloxy) phenyl groups at the meso-positions, named "porphyrin glass", were tolerant of pi-conjugation engineering in ethynylene-linked dimers. The butadiyne-linked dimeric porphyrin glass formed an intermolecular excimer, which exhibited bright and exceptionally long-lived, near-infrared (NIR) luminescence at approximately 970 nm in the solid state. Therefore, porphyrin glasses overcame a general bottleneck for NIR-luminescence, such as an undesired pi-stacked aggregation of a large porphyrin plane in addition to the energy gap law. The formation of amorphous molecular glasses from a series of meso-ethynylene-conjugated zinc-porphyrins, named "porphyrin glass", is described. The butadiyne-linked dimeric porphyrin glass formed an intermolecular excimer, which exhibited solid-state, near-infrared (NIR) luminescence at approximately 970 nm.

Excavation flow in impact cratering has been usually modeled by Maxwells Z-model. However few laboratory experiments and/or numerical simulations have been done to examine whether or not the Z-model's streamlines actually express the excavation flow. A numerical simulation of impact onto granular materials by the Discrete Element Method (DEM) is suitable to trace directly the trajectories of target particles. Then a numerical code was developed to simulate impact onto granular materials. The results show that the target particles move along the Z-model's streamlines in the following cases: Z = 3 (effective origin of flow (EOF) is located at the target surface) or Z = 2.7 (EOF is located at the depth of one projectile radius). These results indicate that the Z-model is a reasonable first-order quantitative approximation for excavation flow in impact cratering process.

According to our common understandings, the original surface of a short-period comet nucleus has been lost by sublimation processes during its close approaches to the Sun. Sublimation results in the formation of a dust mantle on the retreated surface and in chemical differentiation of ices over tens or hundreds of meters below the mantle. In the course of NASA's Deep Impact mission, optical and infrared imaging observations of the ejecta plume were conducted by several researchers, but their interpretations of the data came as a big surprise: (1) The nucleus of comet 9P/Tempel 1 is free of a dust mantle, but maintains its pristine crust of submicron-sized carbonaceous grains; (2) Primordial materials are accessible already at a depth of several tens of cm with abundant silicate grains of submicrometer sizes. In this study, we demonstrate that a standard model of cometary nuclei explains well available observational data: (1) A dust mantle with a thickness of ~1-2 m builds up on the surface, where compact aggregates larger than tens of micrometers dominate; (2) Large fluffy aggregates are embedded in chemically differentiated layers as well as in the deepest part of the nucleus with primordial materials. We conclude that the Deep Impact results do not need any peculiar view of a comet nucleus., Comment: 11 pages, 1 figure, 1 table. ApJ letters, 673, L199-202

According to our common understandings, the original surface of a short-period comet nucleus has been lost by sublimation processes during its close approaches to the Sun. Sublimation results in the formation of a dust mantle on the retreated surface and in chemical differentiation of ices over tens or hundreds of meters below the mantle. In the course of NASA's Deep Impact mission, optical and infrared imaging observations of the ejecta plume were conducted by several researchers, but their interpretations of the data came as a big surprise: (1) The nucleus of comet 9P/Tempel 1 is free of a dust mantle, but maintains its pristine crust of submicron-sized carbonaceous grains; (2) Primordial materials are accessible already at a depth of several tens of cm with abundant silicate grains of submicrometer sizes. In this study, we demonstrate that a standard model of cometary nuclei explains well available observational data: (1) A dust mantle with a thickness of ~1-2 m builds up on the surface, where compact aggregates larger than tens of micrometers dominate; (2) Large fluffy aggregates are embedded in chemically differentiated layers as well as in the deepest part of the nucleus with primordial materials. We conclude that the Deep Impact results do not need any peculiar view of a comet nucleus., Comment: 11 pages, 1 figure, 1 table. ApJ letters, 673, L199-202

According to our common understandings, the original surface of a short-period comet nucleus has been lost by sublimation processes during its close approaches to the Sun. Sublimation results in the formation of a dust mantle on the retreated surface and in chemical differentiation of ices over tens or hundreds of meters below the mantle. In the course of NASA's Deep Impact mission, optical and infrared imaging observations of the ejecta plume were conducted by several researchers, but their interpretations of the data came as a big surprise: (1) The nucleus of comet 9P/Tempel 1 is free of a dust mantle, but maintains its pristine crust of submicron-sized carbonaceous grains; (2) Primordial materials are accessible already at a depth of several tens of cm with abundant silicate grains of submicrometer sizes. In this study, we demonstrate that a standard model of cometary nuclei explains well available observational data: (1) A dust mantle with a thickness of ~1-2 m builds up on the surface, where compact aggregates larger than tens of micrometers dominate; (2) Large fluffy aggregates are embedded in chemically differentiated layers as well as in the deepest part of the nucleus with primordial materials. We conclude that the Deep Impact results do not need any peculiar view of a comet nucleus., Comment: 11 pages, 1 figure, 1 table. ApJ letters, 673, L199-202

Dry lakebeds might constitute large volatile reservoirs on Mars. Hypervelocity impacts onto ancient dry lakebeds would have affected the volatile distribution on Mars. We developed a new experimental method to investigate the response of evaporitic minerals (halite and gypsum) to impact shocks in an open system. This technique does not result in chemical contamination from the operation of the gas gun. The technique is termed the “two‐valve method,” and the gun system is located in the Planetary Exploration Research Center, Chiba Institute of Technology, Japan. We detected the vaporization of halite at 31 GPa and devolatilization from gypsum at 11 GPa, suggesting that impact‐induced volatile release from dry lakebeds has periodically occurred throughout Martian history. The vaporization of halite deposits might have enhanced the production of perchlorates, which are found globally on Mars. The water loss from gypsum possibly explains the coexisting types of Ca‐sulfates found in Gale Crater., This work was supported by ISAS/JAXA as a collaborative program with its Hypervelocity Impact Facility.