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In this work, we present a packaged whispering gallery mode (WGM) device based on an optical nanoantenna as the coupler and a glass microsphere as the resonator. The microspheres were fabricated from either SiO2 fiber or Er3+-doped fiber, the latter creating a WGM laser with a threshold of 93 µW at 1531 nm. The coupler-resonator WGM device was packaged in a glass capillary. The performance of the packaged microlaser was characterized, with lasing emission both excited in and collected from the WGM cavity via the nanoantenna. The packaged system provides isolation from environmental contamination, a small size, and unidirectional coupling while maintaining a high quality (Q-) factor (∼108)., source:https://www.osapublishing.org/oe/fulltext.cfm?uri=oe-29-11-16879&id=451125

There are extensive studies to date on optical nonlinearities in microcavities at the near and mid-IR wavelengths. Pushing this research into the visible region is equally valuable. Here, we demonstrate a directly pumped, blue band Kerr frequency comb and stimulated Raman scattering (SRS) at 462 nm in a silica nanofiber-coupled whispering gallery microcavity system. Notably, due to the high optical intensities achieved, photodarkening is unavoidable and can quickly degrade the optical quality of both the coupling optical nanofiber and the microcavity, even at very low pump powers. Nonetheless, stable hyperparametric oscillation and SRS are demonstrated in the presence of photodarkening by taking advantage of in-situ thermal bleaching. This work highlights the challenges of silica-based, short wavelength nonlinear optics in high-quality, small mode volume devices and gives an effective method to overcome this apparent limitation, thus providing a baseline for optics research in the blue region for any optical devices fabricated from silica., source:https://opg.optica.org/prj/fulltext.cfm?uri=prj-10-9-2073

There are extensive studies to date on optical nonlinearities in microcavities at the near and mid-IR wavelengths. Pushing this research into the visible region is equally valuable. Here, we demonstrate a directly pumped, blue band Kerr frequency comb and stimulated Raman scattering (SRS) at 462 nm in a silica nanofiber-coupled whispering gallery microcavity system. Notably, due to the high optical intensities achieved, photodarkening is unavoidable and can quickly degrade the optical quality of both the coupling optical nanofiber and the microcavity, even at very low pump powers. Nonetheless, stable hyperparametric oscillation and SRS are demonstrated in the presence of photodarkening by taking advantage of in-situ thermal bleaching. This work highlights the challenges of silica-based, short wavelength nonlinear optics in high-quality, small mode volume devices and gives an effective method to overcome this apparent limitation, thus providing a baseline for optics research in the blue region for any optical devices fabricated from silica., source:https://opg.optica.org/prj/fulltext.cfm?uri=prj-10-9-2073

© 2020, The Author(s). Three-dimensional metal−organic frameworks (MOFs) are cutting-edge materials in the adsorptive removal of trace gases due to the availability of abundant pores with specific chemistry. However, the development of ideal adsorbents combining high adsorption capacity with high selectivity and stability remains challenging. Here we demonstrate a strategy to design adsorbents that utilizes the tunability of interlayer and intralayer space of two-dimensional fluorinated MOFs for capturing acetylene from ethylene. Validated by X-ray diffraction and modeling, a systematic variation of linker atom oxidation state enables fine regulation of layer stacking pattern and linker conformation, which affords a strong interlayer trapping of molecules along with cooperative intralayer binding. The resultant robust materials (ZUL-100 and ZUL-200) exhibit benchmark capacity in the pressure range of 0.001–0.05 bar with high selectivity. Their efficiency in acetylene/ethylene separation is confirmed by breakthrough experiments, giving excellent ethylene productivities (121 mmol/g from 1/99 mixture, 99.9999%), even when cycled under moist conditions.

A novel optical sensor for ammonia concentration in water is demonstrated using up-conversion (UC) fluorescence intensity ratio (FIR). The sensor element consists of (i) an Er3+-Yb3+ co-doped tellurite glass microsphere integrated inside a section of suspended tri-core hollow fiber (STCHF) and (ii) the pH indicator phenol red. When 980 nm pump is coupled into the microsphere, the Er3+ ions produce green and red UC emissions. Exposure to ammonia results in a strong increase in the 560 nm absorption of the phenol red, which acts as a filter for the green emission, while the red emission is unaffected. A simple linear relation between the FIR and the ammonia aqueous concentration has been established., source:https://ieeexplore.ieee.org/document/9535508

Liquid level measurement in microfluidics is challenging, where a sensor with ultra-high sensitivity but miniature in nature is demanded. In this paper, we propose for the first time a microsized fiber sensor structure in both diameter and length for microfluidics applications, which is capable of sub-micrometer scale liquid level measurement. The sensor is simply fabricated by fusion splicing a short section of a hollow core fiber (HCF) between two singlemode fibers (SMFs). HCFs with different air core diameters (10 µm, 20 µm, 30 µm) were investigated and it is found that for a given length of HCF stronger resonant dips were excited in transmission for the HCF with a smaller air core diameter. Thus the HCF structure with an air core diameter of 10 µm (HCF-10) was used for demonstration of high sensitivity liquid level measurement in microfluidics. Simultaneous excitation of both Anti-Resonant Reflecting Optical Waveguide (ARROW) guiding mechanism and Mach-Zehnder interferometer (MZI) in transmission is demonstrated in such an HCF-10 structure when HCF-10 is longer than the critical length. A maximum sensitivity of 0.042 dB/µm (corresponding to a calculated liquid level resolution of ~0.23 µm) was experimentally achieved with an HCF-10 length of ~867 µm, which is three times higher than that of the previous reported to date of the most sensitive fiber optic liquid level sensors based on intensity modulation. In addition, the proposed sensor shows good repeatability of measurement and a very low cross sensitivity to changes in the surrounding refractive index., source:https://www.sciencedirect.com/science/article/pii/S0924424721005999