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The reactions of coronene dehydrogenation and fusion upon heat treatment in the temperature range of 500-700 degrees C were studied using XRD, TEM, Raman, IR, and NEXAFS spectroscopy. The formation of a coronene dimer (dicoronylene) was observed at temperatures 530-550 degrees C; dicoronylene can easily be separated using sublimation with a temperature gradient. An insoluble and not sublimable black precipitate was found to form at higher temperatures. Analysis of the data shows that dimerization of coronene is followed at 550-600 degrees C by oligomerization into larger molecules. Above 600 degrees C amorphization of the material and formation of graphitic nanoparticles was observed. Coronene fusion by annealing is proposed as a road to synthesis of larger polycyclic aromatic hydrocarbons and nanographenes.

The reactions of coronene dehydrogenation and fusion upon heat treatment in the temperature range of 500-700 degrees C were studied using XRD, TEM, Raman, IR, and NEXAFS spectroscopy. The formation of a coronene dimer (dicoronylene) was observed at temperatures 530-550 degrees C; dicoronylene can easily be separated using sublimation with a temperature gradient. An insoluble and not sublimable black precipitate was found to form at higher temperatures. Analysis of the data shows that dimerization of coronene is followed at 550-600 degrees C by oligomerization into larger molecules. Above 600 degrees C amorphization of the material and formation of graphitic nanoparticles was observed. Coronene fusion by annealing is proposed as a road to synthesis of larger polycyclic aromatic hydrocarbons and nanographenes., authorCount :10

The reactions of coronene dehydrogenation and fusion upon heat treatment in the temperature range of 500700 C were studied using XRD, TEM, Raman, IR, and NEXAFS spectroscopy. The formation of a coronene dimer (dicoronylene) was observed at temperatures 530-550 C; dicoronylene can easily be separated using sublimation with a temperature gradient. An insoluble and not sublimable black precipitate was found to form at higher temperatures. Analysis of the data shows that dimerization of coronene is followed at 550600 C by oligomerization into larger molecules. Above 600 C amorphization of the material and formation of graphitic nanoparticles was observed. Coronene fusion by annealing is proposed as a road to synthesis of larger polycyclic aromatic hydrocarbons and nanographenes.

Many special problems crop up when evolutionary theory turns, quite naturally, to the question of the adaptive value and causal role of consciousness in human and nonhuman organisms. One problem is that -- unless we are to be dualists, treating it as an independent nonphysical force -- consciousness could not have had an independent adaptive function of its own, over and above whatever behavioral and physiological functions it "supervenes" on, because evolution is completely blind to the difference between a conscious organism and a functionally equivalent (Turing Indistinguishable) nonconscious "Zombie" organism: In other words, the Blind Watchmaker, a functionalist if ever there was one, is no more a mind reader than we are. Hence Turing-Indistinguishability = Darwin-Indistinguishability. It by no means follows from this, however, that human behavior is therefore to be explained only by the push-pull dynamics of Zombie determinism, as dictated by calculations of "inclusive fitness" and "evolutionarily stable strategies." We are conscious, and, more important, that consciousness is piggy-backing somehow on the vast complex of unobservable internal activity -- call it "cognition" -- that is really responsible for generating all of our behavioral capacities. Hence, except in the palpable presence of the irrational (e.g., our sexual urges) where distal Darwinian factors still have some proximal sway, it is as sensible to seek a Darwinian rather than a cognitive explanation for most of our current behavior as it is to seek a cosmological rather than an engineering explanation of an automobile's behavior. Let evolutionary theory explain what shaped our cognitive capacity (Steklis & Harnad 1976; Harnad 1996, but let cognitive theory explain our resulting behavior.

Many special problems crop up when evolutionary theory turns, quite naturally, to the question of the adaptive value and causal role of consciousness in human and nonhuman organisms. One problem is that -- unless we are to be dualists, treating it as an independent nonphysical force -- consciousness could not have had an independent adaptive function of its own, over and above whatever behavioral and physiological functions it "supervenes" on, because evolution is completely blind to the difference between a conscious organism and a functionally equivalent (Turing Indistinguishable) nonconscious "Zombie" organism: In other words, the Blind Watchmaker, a functionalist if ever there was one, is no more a mind reader than we are. Hence Turing-Indistinguishability = Darwin-Indistinguishability. It by no means follows from this, however, that human behavior is therefore to be explained only by the push-pull dynamics of Zombie determinism, as dictated by calculations of "inclusive fitness" and "evolutionarily stable strategies." We are conscious, and, more important, that consciousness is piggy-backing somehow on the vast complex of unobservable internal activity -- call it "cognition" -- that is really responsible for generating all of our behavioral capacities. Hence, except in the palpable presence of the irrational (e.g., our sexual urges) where distal Darwinian factors still have some proximal sway, it is as sensible to seek a Darwinian rather than a cognitive explanation for most of our current behavior as it is to seek a cosmological rather than an engineering explanation of an automobile's behavior. Let evolutionary theory explain what shaped our cognitive capacity (Steklis & Harnad 1976; Harnad 1996, but let cognitive theory explain our resulting behavior.