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1. Chlorination of Boron on a Ruthenium-Coordinated Hydridotris(pyrazolyl)borate (Tp) Ligand: A Caveat for the Use of TpRu(PPh 3 ) 2 Cl

Author

Foley, Nicholas A, Abernethy, Robyn, Gunnoe, T. Brent, Hill, Anthony, Boyle, Paul D., Sabat, Michal, Foley, Nicholas A, Abernethy, Robyn, Gunnoe, T. Brent, Hill, Anthony, Boyle, Paul D., and Sabat, Michal

Abstract

A side-product that accompanies the synthesis of the widely utilized starting material TpRu(PPh 3) 2Cl (Tp = hydridotris(pyrazolyl)borate) has been identified as the complex clTpRu(PPh 3) 2H ( clTp - chlorotris(pyrazolyl)bo-rate), which provides a rare example of a boron-halogenated pyrazolylborate ligand. The reaction of clTpRu(PPh 3) 2H with dichloromethane or chloroform quantitatively produce clTpRu(PPh 3) 2Cl.

Published
2009

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