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Biochar has been recommended as a soil amendment to improve soil fertility and mitigate methane (CH4) emissions from rice cultivation. Its effects, however, vary depending on soil type, biochar characteristics, and application rate. This study was aimed to evaluate the potential of mangrove biochar on CH4 mitigation, soil properties, and the productivity of rice cultivated in a clay loam soil in Thailand. Biochar was used at a rate equivalent to 10 t ha−1 season−1, both with (biochar + fertilizer: BF) and without (biochar alone: BI) fertilizer, for two cultivation seasons. BI reduced CH4 flux at most stages of rice growth. Relative to control soil (no biochar, no fertilizer: CT), BI significantly decreased cumulative CH4 emissions by 21.1% in the first season and 24.9% in the second season. CH4 emissions from BF soil were also less than those from the use of fertilizer alone (FE). Rice grain yield in BI was 7.85% and 14.4% greater than in CT, and in BF by 1.47% and 3.72% greater than FE, in the first and second seasons, respectively. The decrease in CH4 emissions and increase in rice grain yield decreased CH4 emission intensity under biochar treatments. Soil pH, organic carbon, cation exchange capacity, and available nutrients in the soil increased with biochar addition. The soil organic carbon stock was significantly increased by 32.6% in BI and 27.5% in BF after the first season, and by 43.5% in BI and 39.6% in BF after the second season. [ABSTRACT FROM AUTHOR]

• A paddy field in Thailand contaminated with Cd (41.02 mg kg−1) was restored. • BZVI decreased Cd accumulation in rice grains by 83 %. • BZVI as soil amendment enriched Fe and Zn accumulation in rice grains by 10 %. • ZVI corrosion enhanced by biochar is the key to BZVI success. • This technique is suitable for community-driven soil restoration. Consuming rice grown in contaminated soil that has an elevated level of cadmium (Cd) is a health risk. This study revealed that using a combination of biochar and zerovalent iron (BZVI) reduces the concentration of Cd and enhances that of the essential elements zinc (Zn) and iron (Fe) in rice. The Cd concentration in brown rice grain cultivated in an untreated paddy was 0.84 ± 0.20 mg kg−1, double the acceptable level (0.4 mg kg−1). Soil amendment with BZVI successfully decreased Cd in brown rice by 83 % compared to the untreated field presumably due to the Cd sorption on biochar (BC) and enhanced ZVI corrosion by-products while ZVI and BC alone achieved only 40 % and 74 % reduction, respectively. Moreover, while using ZVI or BC alone decreased Fe in rice grain by 8–14 %, BZVI enhanced the Fe concentrations in rice grain by 11 % because of Fe2+/Fe3+ release from BC-enhanced ZVI corrosion. Similarly, the presence of BC in BZVI enhanced Zn accumulation in rice grain by 8% due to competitive sorption of Cd2+ on BZVI, which may desorb Zn2+, promoting Zn translocation to rice. Using ZVI alone decreased Zn in rice by 19 %. [ABSTRACT FROM AUTHOR]

Organic amendments may improve the quality of acidic tropical agricultural soils with low organic carbon contents under conventional management (mineral fertilization and irrigation) in Southeast Asia. We investigated the effect of biochar, compost and their combination on maize growth and yield, soil physical, biological and chemical properties at harvesting time at four sites in three countries: Thailand, Vietnam and Laos. Treatments consisted of 10 t·ha−1 cow manure compost and 7 t·ha−1 of Bamboo biochar and their combination. Maize biomass production and cop yields were recorded for two seasons. Elemental content, pH and nutrient availability of soils were analyzed after the first growing season. We also characterized macrofauna abundance and water infiltration. Few changes were noted for maize biomass production and maize cop yield. Soil chemical parameters showed contrasting, site-specific results. Compost and biochar amendments increased soil organic carbon, pH, total K and N, P and K availability especially for sandy soils in Thailand. The combination of both amendments could reduce nutrient availability as compared to compost only treatments. Physical and biological parameters showed no treatment response. We conclude that the addition of compost, biochar and their mixture to tropical soils have site-specific short-term effects on chemical soil parameters. Their short-term effect on plants is thus mainly related to nutrient input. The site-dependent results despite similar crops, fertilization and irrigation practices suggest that inherent soil parameters and optimization of organic amendment application to specific pedoclimatic conditions need future attention. [ABSTRACT FROM AUTHOR]