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[Display omitted] • WTE assessment of biomass residue valorization pathway. • Optimization of WTE via multi-criteria decision method. • Pequi seed without extractives reported improved biochar properties. • Optimal gasification condition was obtained with O 2 /H 2 O/N 2 carrier gas. • WTE could be optimized by the seed fat extraction previously to pyrolysis. The waste-to-energy (WTE) valorization pathway of Caryocar brasiliense (pequi) seeds was investigated via pyrolysis, gasification, and transesterification to understand its potential as biochar, syngas, and biodiesel. First, the pyrolysis (300–700 °C) was conducted in N 2 atmosphere for pequi seeds (PS) and pequi seeds without its extractives (PSWE), characterizing its biochar properties. The PSWE was then gasified at 1000 °C under O 2 /N 2 , O 2 /CO 2 /N 2 and O 2 /H 2 O/N 2 atmospheres to evaluate the characteristics of the producer gas. The PS extractives were then transesterified and characterized for biodiesel production. Finally, a multiple-criteria decision analysis assessed the PS products' potential within the thermochemical routes. The results evidenced better biochar (up to 22.29% HHV enhancement, higher mass and energy yield, up to 75.9 and 85.5% reduction of O/C and H/C, respectively, and enriched N content) via PSWE pyrolysis than PS considering biofuel application and optimistic perceptions for soil amendment. This indicates that the preceding extraction of vegetal fat from PS strengthens the WTE by including further processing of extracted oil. The produced syngas under O 2 /H 2 O/N 2 gasification atmosphere showed better applicability as a biofuel (16.37 MJ·kg−1 lower heating value, 107.33% cold gas efficiency, and 113.55% carbon conversion efficiency) with up to 24% higher success rate. The transesterification of the extractives revealed its potential (98% conversion rate) for use as feedstock for in situ power generation, or blended for biodiesel production. The results provide insights into the circular economy in agro-extractivist communities that may support Brazil's small and medium agro-food industries with their energy demands. [ABSTRACT FROM AUTHOR]

Production of biofuels via biomass pyrolysis has received a strong emphasis since it may produce a wide variety of renewable fuels in liquid (bio-oil), solid (biochar), and gas (syngas) forms. Sugarcane bagasse, waste from the sugar-alcohol industry, is largely produced in Brazil, India, and Thailand and appears as a great biomass option for pyrolysis due to its properties, abundance, and current underutilization. However, sugarcane bagasse properties and pyrolysis operating conditions may directly affect the product properties, distribution, and further application as fuels and chemicals. Thus, it is necessary a thorough study of these subjects. This review brings an overview of biomass and pyrolysis concepts, as well as a collection of improvements in the production of products (bio-oil, biochar, and gas) via sugarcane bagasse pyrolysis. In addition, this review discusses the interaction between process operating conditions and this biomass type to address how the products' properties and yields are affected. • Fast Pyrolysis: an efficient thermochemical process for bio-oil, biochar, and gas production. • Fast Pyrolysis concepts, operational conditions, and reactor configurations were reviewed. • Bio-oil, biochar, and gas production as an alternative for renewable energy world matrix. • Focus on sugarcane bagasse as a raw material for bio-oil, biochar, and gas production. • Upgrading methods for bio-oil, challenges, and future works in the pyrolysis field. [ABSTRACT FROM AUTHOR]