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2. Di- and Oligonucleotide Synthesis Using H-Phosphonate Chemistry.

Author

Walker, John M., Herdewijn, Piet, Stawinski, Jacek, and Ströberg, Roger

Abstract

In this chapter, a concise account of the synthesis of oligonucleotides using the H-phosphonate methodology is given. It includes various methods for the preparation of the starting material, nucleoside 3′-H-phosphonate monoesters, their conversion into dinucleoside H-phosphonate diesters, oxidative transformations of dinucleoside H-phosphonates into the corresponding phosphate and phosphorothioate derivatives, and protocols for the synthesis of oligonucleotides and their phosphorothio analogs. [ABSTRACT FROM AUTHOR]

Published
2005
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