Facing the global freshwater resource crisis, using solar energy to produce fresh water resources in an environmentally friendly way, sorption-based atmospheric water harvesting driven by solar technology has attracted increasingly more attention. In the current research, the adsorbent MOF-801 has the advantages of a high adsorption capacity and is suitable for fields with a wide range of humidity. However, the strong interaction between the adsorbent and water molecules is conducive to rapid moisture absorption, but at the same time, the adsorbent needs higher heat to achieve regeneration, which restricts the practical application of the adsorbent. Based on the principle that carbon materials can improve the photothermal conversion performance of adsorbent, this paper prepared three composite adsorbents with MOF-801 and three different carbon materials, characterized the structure and morphology of each adsorbent, and compared the effects of different carbon materials on the performance of MOF-801 adsorbent. Among them, the photothermal characteristics of MOF-801/CNT adsorbent proposed in this paper are most significantly improved. The experiment shows that compared with MOF-801/G, the adsorption capacity is increased by 30%, and the desorption speed is increased by 50%. It maximizes water withdrawals over a period of time in arid environments. [ABSTRACT FROM AUTHOR]