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The Quadrilátero Ferrífero (QF) is a globally known region for its world-class metallic deposits. Although its Precambrian units have been vastly studied since the 1960s due to economic importance, the Cenozoic geological record represents an upcoming subject of interest. The occurrence of Cenozoic sedimentary deposits has been noticed since the end of the 19th century, but most of them are not yet fully characterized. This paper brings a complete description, mapping, 3D modeling, and simulations of the sedimentary deposit named Bandeira Basin, Serra do Tamanduá, QF. Based on field data, such as mapping and drill core database analysis, three drill cores were selected for further investigation and detailed description. The Bandeira Basin can be characterized and subdivided into three units: Unit A: found only in the southeast area and shows exclusively sediments from the Nova Lima Group; Unit B: intermediate unit that occurs in central and southeast areas, with Rio das Velhas Supergroup as a possible source of the sedimentary material; and Unit C: occurs at the top, and it is essentially colluvial deposits from Minas Supergroup units. The contacts between units are abrupt or erosive, recording successive deposition stages. The basin is thicker on its central and southwest ends and thinner on the east and north, where part of the basement outcrops. Cenozoic tectonic events were probably active in this area, controlling the sedimentary processes, with the NW-SE and NE-SW lineaments reactivated, triggering sediment deposition and migration to the deepest spot of the basin. These sediments were 3D modeled in Leapfrog Geo, the visualization of any given region of interest, in the modeled scale. This methodology allowed an assertive characterization of sedimentary filling and could be applied to other basins. This comprehension is important because these sediments are used indirectly or directly in civil projects. [ABSTRACT FROM AUTHOR]

A synthesis of the evolution of the Neoproterozoic belts or orogens surrounding the São Francisco craton (SFC) in northeastern and southeastern Brazil is presented. Emphasis is placed on recognizing the superposition of sedimentary basins, from rift to passive margin to retroarc and foreland, as well as identifying three diachronic continental collisions in the formation of the SFC. The Tonian passive margin occurs in the southern Brasília Belt with the Vazante, Canastra, and Araxá Groups. During the Tonian, island magmatic arcs and basins developed in front and behind these arcs (fore- and back-arcs). Subsequently, in the Cryogenian–Ediacaran, a retroarc foreland basin developed with part of the Araxá Group and the Ibiá Group, and finally, a foreland basin developed, which was filled by the Bambuí Group. A tectonic structure of superimposed nappes, with subhorizontal S1–2 foliation, formed between 650 and 610 Ma, is striking. In the northern Brasília Belt, there is the Stenian passive margin of the Paranoá Group, the Tonian intrusion of the Mafic–Ultramafic Complexes, and the Mara Rosa Island magmatic arc, active since the Tonian, with limited volcanic–sedimentary basins associated with the arc. A thrust–fold belt structure is prominent, with S1 foliation and late transcurrent, transpressive tectonics characterized by the Transbrasiliano (TB) lineament. The Cryogenian–Ediacaran collision between the Paranapanema and São Francisco cratons is the first collisional orogenic event to the west. In the Rio Preto belt, on the northwestern margin of the São Francisco craton, the Cryogenian–Ediacaran Canabravinha rift basin is prominent, with gravitational sediments that represent the intracontinental termination of the passive margin that occurs further northeast. The rift basin was intensely deformed at the Ediacaran–Cambrian boundary, as was the Bambuí Group. On the northern and northeastern margins of the São Francisco craton, the Riacho do Pontal and Sergipano orogens stand out, showing a comparable evolution with Tonian and Cryogenian rifts (Brejo Seco, Miaba, and Canindé); Cryogenian–Ediacaran passive margin, where the Monte Orebe ophiolite is located; and Cordilleran magmatic arcs, which developed between 620 and 610 Ma. In the Sergipano fold belt, with a better-preserved outer domain, gravitational sedimentation occurs with glacial influence. A continental collision between the SFC and the PEAL (Pernambuco-Alagoas Massif) occurred between 610 and 540 Ma, with intense deformation of nappes and thrusts, with vergence to the south and accommodation by dextral transcurrent shear zones, such as the Pernambuco Lineament (PE). The Araçuaí belt or orogen was formed at the southeastern limit of the SFC by a Tonian intracontinental rift, later superimposed by a Cryogenian–Ediacaran rift–passive margin of the Macaúbas Group, with gravitational sedimentation and glacial influence, and distally by oceanic crust. It is overlain by a retroarc basin with syn-orogenic sedimentation of the Salinas Formation, partly derived from the Rio Doce cordilleran magmatic arc and associated basins, such as the Rio Doce and Nova Venécia Groups. A third continental collision event (SF and Congo cratons), at the end of the Ediacaran (580–530 Ma), developed a thrust–fold belt that deforms the sediments of the Araçuaí Belt and penetrates the Paramirim Corridor, transitioning to the south to a dextral strike-slip shear zone that characterizes the Ribeira Belt. [ABSTRACT FROM AUTHOR]

High-resolution stratigraphic analysis was carried out on tidal microbial carbonates from the middle part of the Lagoa do Jacaré Formation from the Ediacaran-Cambrian Bambuí Group in the Ubaí area. In a 41 meter-thick section, sixteen lithofacies and three facies associations were interpreted as deposits of supratidal, intertidal, and subtidal settings. The tidal cycles are asymmetric and shallow upward, the high-resolution stratigraphic approach allowed inferences as to short-term and long-term fluctuations of sea level during deposition. The metric tidal ranges here described suggest strong tidal currents, which is incompatible with the giant enclosed sea model as an analog for Bambuí deposition, given that tidal ranges in suc seas are null or less than a few decimeters. Therefore, we suggest that the Ubaí carbonates were deposited in a semi-enclosed epicontinental sea subject to strong tidal forces when the formerly resticted Bambuí Basin reopened probably during deposition of the upper half of the Lagoa do Jacaré Formation, as suggested by previous isotopic data and now reinforced by our sedimentologic and stratigraphic field data. [ABSTRACT FROM AUTHOR]

A section investigated in the region of Paraopeba, Minas Gerais, provided detailed sedimentologic, stratigraphic and chemostratigraphic data from the Ediacaran Lagoa do Jacaré Formation, Bambuí Group, Southeast Brazil. This information allowed interpretation of tempestite facies in transgressive-regressive cycles, reinforcing the previously proposed storm-influenced sedimentation model and clarifying how it is associated with unusually high C-isotope values related to the Middle Bambuí Excursion (MIBE). Facies analysis of nine lithofacies identified at the GMD quarry based on field and petrographic descriptions showed distal tempestite facies grading upwards to a shallower, oncoidal/ooidal carbonate marine environment, then to basinal shales. The entire succession comprises a low-order transgressive hemicycle, recording the transition from a storm-influenced carbonate ramp to a siliciclastic-dominated platform. Chemostratigraphic data yielded high δ13C values ranging between +11.11‰ and +13.94‰. Our data contribute to the revision of the previously proposed interpretation and as well as to the understanding of paleoenvironmental conditions and C isotope signatures across the MIBE, near the Ediacaran-Cambrian boundary in the Bambuí Basin. [ABSTRACT FROM AUTHOR]

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The Serra da Saudade Formation, Ediacaran/Cambrian Bambuí Group, cropping out along the ridge of the same name in Central-Western Minas Gerais, Brazil, contains important deposits of glauconitic siltstones associated with phosphatic rhythmite as well as other siliciclastic, volcaniclastic and carbonate lithofacies. Lithofacies indicate deposition by proximal and distal storm waves on a continental marine shelf. The basal gray siltstone and part of the green siltstone represent a transgressive systems tract. The glauconitic siltstone indicates sea level rise, with the maximum flooding surface located approximately at the interval of highest K2O content. Biogenic carbonate and an upward increase in sandstone beds are interpreted as a highstand systems tract. Gradual lateral facies changes reflect the transition from foredeep (to the west) to forebulge (to the east) deposition in a foreland basin as the final stage of a shallowing-upward second-order sequence. Black organic-rich limestone has d13C values between -8.78 and 9.79‰, negative d18O values from -11.50 to -9.35‰, and 87Sr/86Sr around 0.7075. This isotopic signature, similar to that of other Bambuí carbonates, indicates a probably-restricted depositional environment with organic sedimentation, methanogenesis and high evaporation rates from the Ediacaran through the early Cambrian period. [ABSTRACT FROM AUTHOR]

In east‐central Brazil, the Ediacaran‐Cambrian Bambuí Basin has the potential to provide a record of unique geochemical responses of Earth's ocean and atmosphere evolution during this key time interval. From this perspective, we studied an interval of the upper Bambuí Basin using sedimentologic, stratigraphic, and chemostratigraphic tools. The lower Cambrian Jaíba Member of the uppermost Serra da Saudade Formation is an interval of up to 60 m‐thick of carbonate rocks disposed into two shallowing upward trends. Inner to outer ramp and high‐energy shoal deposits are described, in which laminated microbialites are the prevailing sedimentary facies. REE + Y data suggest contamination by iron (oxy)hydroxides that are dissociated from the riverine detritic flux. Sedimentary iron enrichment may be related to the settling of iron nanoparticles in coastal environments, diagenetic iron mobilization, or both. MREE enrichment is caused by microbial degradation of organic matter in the iron reduction zone during the anoxic early‐diagenetic stage. Chromium isotopes yielded negatively fractionated values (δ53Cr = −0.69 to −0.27‰), probably resulting from biotic and abiotic reduction of dissolved Cr(VI) to light and less toxic Cr(III) within pores of microbial mats. The δ53Cr data of the Jaíba microbialite are thus a product of metabolic reactions in microbial mats and do not reflect seawater signal. The isotopic offset from seawater is feasible from molecular diffusion of Cr into pore water and reduction reactions occurring deep inside the mat, although the exact mechanism and consequences are not yet fully understood due to the poor preservation of metabolic reactions in the geological record. Our study suggests that Cr isotopes can be used to reconstruct Cr and other metals cycling within ancient microbial mats, and that caution should be taken when using past microbialites to infer seawater Cr records and redox state of the atmosphere and ocean. [ABSTRACT FROM AUTHOR]

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Copyright of Brazilian Journal of Geology is the property of Sociedade Brasileira de Geologia and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)

A central tenet of the Neoproterozoic snowball Earth hypothesis is that glaciations ended synchronously. Although this condition is borne out by U-Pb and Re-Os geochronology, the time scale of deglaciation is much less than the intrinsic error of the highest resolution dating techniques, and consequently calibrating the pace and synchronicity of biogeochemical recovery from Cryogenian glaciations remains a challenge. Given the importance of obtaining a globally synoptic view of paleoenvironmental conditions and biological evolution during these extraordinary transitions, robust correlations and chronologies are imperative. Here we extend the negative triple oxygen isotope (Δ17O) anomaly previously documented in ca. 635 Ma postglacial cap carbonates to two new paleocontinents, Brazil and Norway. The global footprint of this geochemical signal coupled to its short duration provides a unique time datum that can be used to cross-correlate Marinoan postglacial cap carbonate sequences and track the geochemical evolution of the oceans during deglaciation. [ABSTRACT FROM AUTHOR]

The Chapada Diamantina region in the São Francisco craton of eastern Brazil is composed of sedimentary successions containing both Mesoproterozoic and Neoproterozoic carbonate levels, making it a key natural laboratory for understanding the fluctuations of Earth's biogeochemical cycles during its middle age. The ca. 1.4--1.2 Ga Caboclo Formation stromatolites yielded unfractionated δ53Crauth (authigenic) (-0.54‰ to +0.08‰). Ediacaran cap carbonates and phosphatic stromatolites of the Salitre Formation, on the other hand, yielded fractionated δ53Crauth reaching as high as +0.51‰, suggesting the input of 53Cr-rich Cr(VI), first delivered through meltwater-induced post-snowball Earth fluctuating redox conditions and then through weathering and mobilization under a fully oxygenated environment. The acquired data set highlights the very distinct redox conditions throughout the Proterozoic and reinforces the suggestion that after the Cryogenian global glaciations, Earth's atmosphere and hydrosphere became progressively oxygenated during the Ediacaran-Cambrian transition. [ABSTRACT FROM AUTHOR]

The basal units of the Vazante Group, the Santo Antônio do Bonito and Rocinha formations, present different stratigraphic records and younger ages than the rest of the group. These units are characterized by diamictites, sandstones, pelites and rare carbonates originated from subaqueous gravitational sedimentation. U–Pb geochronological data in detrital zircon indicate a Tonian maximum depositional age for both formations. The youngest zircon grains yielded ages ranging from 903 to 935 Ma. The main source for zircon is Paleoproterozoic (mainly Rhyacian and Orosirian) to Mesoproterozoic (Calymmian and Ectasian) areas being probably the São Francisco paleocontinent the main area. Due to the complete absence of ice-rafted debris within fine-grained sediments in the Santo Antônio do Bonito Formation, we interpret a gravitational reworking as the main process of diamictites deposition, probably during a period of ice retreat and sea level rise. The U–Pb data corroborate a lateral correlation between the Santo Antônio do Bonito and Rocinha formations with the glaciogenic Jequitaí Formation (Bambuí Group). From east to west, glacial sediments of the Jequitaí Formation were reworked probably by a slope-apron system during a late-glacial to post-glacial stage on the western margin of the São Francisco paleocontinent. Therefore, the Vazante Group can be divided into two successions: the upper Lagamar-Serra do Garrote formations and the lower Santo Antônio do Bonito-Rocinha formations. The Lagamar-Serra do Garrote sedimentation comprises a late Mesoproterozoic mixed carbonate-siliciclastic deposition in passive margins. The second succession is a gravitational slope-apron resedimentation and probably correlates with the Neoproterozoic glacial rocks of the Jequitaí Formation from the Bambuí Group. Finally, the collisional phase of the Brasília Belt was responsible for stratigraphic inversion, placing the older Lagamar-Serra do Garrote formations over the younger Santo Antônio do Bonito-Rocinha formations. • New regional and local geological mapping of the basal formations of the Vazante Group. • Gravitational sedimentation record in the basal formations of the group, relate to a subaqueous slope-apron system. • New U–Pb data of the Santo Antônio do Bonito and the Rocinha formations and its provenance change during Neoproterozoic. • Lateral correlations between Santo Antônio do Bonito and Jequitaí formations, during final stages of the ice retreatment. [ABSTRACT FROM AUTHOR]

• Extensive new Ba isotopic survey of modern barites. • First Proterozoic Ba isotopic results. • Provides genetic model for enigmatic post-Marinoan barite formation. • Provides evidence for stratified post-Marinoan ocean. • Provides arguments for why barite horizons are confined to Marinoan and not Sturtian or Paleoproterozoic strata. Measurements of triple oxygen isotope ratios in barite horizons within post-Marinoan cap carbonates have provided some of the most compelling evidence that the Marinoan glaciation was a Snowball Earth event. However, the origin of these barite horizons remains unresolved. To constrain the Ba sources, and thus formation mechanisms of these horizons, we analyzed the Ba isotope composition of post-Marinoan barite deposits from Northwest Canada, Northern Norway, Brazil and South China. We augment these analyses with a Ba isotope survey of almost 100 modern and ancient additional barite measurements, including samples from pelagic (or 'marine'), hydrothermal, terrestrial, Proterozoic stratiform and cold seep environments. Unlike modern cold seep or terrestrial barites, we find that globally-distributed post-Marinoan barites exhibit a relatively narrow isotopic range, suggesting a well-mixed, effectively limitless Ba source. Moreover, post-Marinoan deposits exhibit a similar mean Ba isotope composition to modern marine barites, which we interpret as evidence of a marine Ba source. Considered alongside existing geochemical, geological, and new Ba isotope survey data, we conclude that Ba in barite horizons was sourced from a well-mixed, Ba-replete but SO 4 -poor reservoir that accumulated during the Marinoan Snowball Earth interval. This deep Ba reservoir was then transported upward—either by ocean circulation or dolomitization of underlying cap carbonates—and was brought into contact with continental weathering-derived sulfate in a post-glacial meltwater surface layer. Thus, in addition to providing a plausible mechanism for generating globally-synchronous deposition of post-Marinoan barite horizons that reconciles all existing geochemical and geological data, our results demonstrate the utility of Ba isotopes to interrogate the origin of enigmatic barite deposits throughout the sedimentary record. [ABSTRACT FROM AUTHOR]

The Borborema Province of northeast Brazil occupies a strategic position in the central portion of West Gondwana, linking three of its major cratonic constituents: the São Francisco- Congo, Amazon, and West Africa cratons. The southern portion of the province, the Riacho do Pontal fold belt, comprises an association of exhalative rocks with metabasalts having transitional mid-oceanic ridge basalt geochemistry (Monte Orebe Complex) that suggests the preservation of remnants of Neoproterozoic oceanic crust. This view is supported by geophysical data: the Riacho do Pontal fold belt corresponds to the inflexion of a paired positive-negative Bouguer anomaly similar to other Precambrian suture zones. Sm-Nd isotope data for the metabasalts yield a whole-rock isochron age of 819 ± 120 Ma with an initial εNd(t) = +4.4, indicating derivation from a depleted mantle source. The onset of subduction within the Borborema Province (ca. 630 Ma) caused the inversion of basins and obduction of slices of oceanic crust. In this scenario, the Riacho do Pontal fold belt represents a complete late Neoproterozoic plate tectonics cycle involving the collision of the São Francisco craton (lower plate) with the Pernambuco-Alagoas block (upper plate). This interpretation challenges current views that the Borborema Province has acted as a coherent block since Paleoproterozoic time (part of the Atlantica supercontinent), suggesting instead a dynamic setting, where multiple plates interacted during the Proterozoic. The Monte Orebe ophiolite provides a link with other Cryogenian oceanic crust occurrences in central Brazil and West Africa, indicating the preservation of a transcontinental Neoproterozoic suture zone in the heart of West Gondwana. [ABSTRACT FROM AUTHOR]

The Serra da Saudade Formation is part of the Bambuí Group, a cratonic cover from the western São Francisco craton. It is composed by siliciclastic sediments deposited in a foreland basin during a transgressive event. The Serra da Saudade Formation is mainly represented by rhythmites, siltstones (locally glauconitic) and rare sandstones. The glauconitic siltstone was deposited during a maximum flooding surface and sediment starvation, which allowed high concentrations of probable volcanic-sourced potassium. The interpretation of the depositional age of the Bambui Group had multiple turnovers in the last decades. Finding and dating synsedimentary volcanic rocks is essential to solve this conundrum. This paper presents the first U-Pb direct dating of the Bambuí Group from zircon grains recovered from a volcaniclastic layer interbedded with glauconitic siltstones from the upper Serra da Saudade Formation. A total of 107 U-Pb ages were obtained by LA-ICP-MS and plotted into a Concordia diagram. The provenance signature comprises a wide range of detrital zircon ages (1.0–2.8 Ga). These data represent inherited zircon grains incorporated into the magma during magmatic activity that produced the volcanic sediment, or to dilution and reworking of volcanic ashes that mixed to fine-grained clastic sediments prior to deposition. A significant amount of 10 highly concordant, prismatic zircon grains clustered into a well constrained age of 520.2 ± 5.3 Ma, which represent the explosive volcanic eruption age, and by extent, the depositional age of the upper Serra da Saudade Formation. Since the currently final thrust stacking ages from the Brasilia Belt and the Araçuaí Belt are dated ca. 600 and 540 Ma, respectively, one must carefully look for the real age of the deformation event that affected the Bambuí Group over the São Francisco craton. Image 1 • Stratigraphy, petrography and geochronology of Serra da Saudade Formation, Bambuí Group. • The glauconitic siltstone was deposited in a foreland basin during low sedimentation rates and related to volcanic processes. • The volcanoclastic layer described in the upper Bambuí Group reveals a sedimentation age of 520.2 ± 5.3 Ma. • The Bambuí Group spanned the Ediacaran-Cambrian boundary and was deformed during the Cambrian Period. [ABSTRACT FROM AUTHOR]