37 results on '"Sundriyal, Shashank"'
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2. Diffusion controlled electrochemical analysis of MoS2 and MOF derived metal oxide–carbon hybrids for high performance supercapacitors
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Shrivastav, Vishal, Mansi, Dubey, Prashant, Shrivastav, Vaishali, Kaur, Ashwinder, Hołdyński, Marcin, Krawczyńska, Agnieszka, Tiwari, Umesh K., Deep, Akash, Nogala, Wojciech, and Sundriyal, Shashank
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- 2023
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3. Evaluation of local oxygen flux produced by photoelectrochemical hydroxide oxidation by scanning electrochemical microscopy
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Gupta, Bhavana, Aziz, Ariba, Sundriyal, Shashank, Shrivastav, Vishal, Melvin, Ambrose A., Holdynski, Marcin, and Nogala, Wojciech
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- 2023
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4. Copper foam supported g-C3N4-metal–organic framework bacteria biohybrid cathode catalyst for CO2 reduction in microbial electrosynthesis.
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Noori, Md Tabish, Mansi, N. A., Sundriyal, Shashank, Shrivastav, Vishal, Giri, Balendu Sekhar, Holdynski, Marcin, Nogala, Wojciech, Tiwari, Umesh K., Gupta, Bhavana, and Min, Booki
- Abstract
Microbial electrosynthesis (MES) presents a versatile approach for efficiently converting carbon dioxide (CO
2 ) into valuable products. However, poor electron uptake by the microorganisms from the cathode severely limits the performance of MES. In this study, a graphitic carbon nitride (g-C3 N4 )-metal–organic framework (MOF) i.e. HKUST-1 composite was newly designed and synthesized as the cathode catalyst for MES operations. The physiochemical analysis such as X-ray diffraction, scanning electron microscopy (SEM), and X-ray fluorescence spectroscopy showed the successful synthesis of g-C3 N4 -HKUST-1, whereas electrochemical assessments revealed its enhanced kinetics for redox reactions. The g-C3 N4 -HKUST-1 composite displayed excellent biocompatibility to develop electroactive biohybrid catalyst for CO2 reduction. The MES with g-C3 N4 -HKUST-1 biohybrid demonstrated an excellent current uptake of 1.7 mA/cm2 , which was noted higher as compared to the MES using g-C3 N4 biohybrid (1.1 mA/cm2 ). Both the MESs could convert CO2 into acetic and isobutyric acid with a significantly higher yield of 0.46 g/L.d and 0.14 g/L.d respectively in MES with g-C3 N4 -HKUST-1 biohybrid and 0.27 g/L.d and 0.06 g/L.d, respectively in MES with g-C3 N4 biohybrid. The findings of this study suggest that g-C3 N4 -HKUST-1 is a highly efficient catalytic material for biocathodes in MESs to significantly enhance the CO2 conversion. [ABSTRACT FROM AUTHOR]- Published
- 2023
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5. Highly Nanoporous Activated Carbon Derived from Poly(aniline-co-pyrrole) for Electrochemical Capacitors.
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Saharan, Pinky, Singh, Mandeep, Kumar, Chandan, Sundriyal, Shashank, and Dhakate, S. R.
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The commercialization of pure carbon-based supercapacitors has faced challenges due to their limited energy density. In order to overcome this challenge, the construction of carbon materials with a hierarchical pore structure has been proposed. Herein, we describe a straightforward template-free method to develop highly nanoporous activated carbon (ACs), via a one-step process where polyaniline (PANI)–polypyrrole (PPy) copolymer is carbonized/activated with KOH in a single step at temperatures ranging from 800 to 1000 °C in N
2 environment to get a highly nanoporous ACs. The AC-900 material comprises a network of linked pores and a higher specific surface area of 3899.88 m2 /g along with a high electrochemical surface area of 722.05 m2 /g, allowing for large amounts of ion storage and quick ion transit. AC-900 has exhibited a very favorable electrochemical performance, in a 1 M H2 SO4 electrolyte, a specific capacitance of 1073.9 F/g was achieved when the current density was set to 0.5 A/g. Symmetrical devices were fabricated out of two AC-900 electrodes of equivalent weight, and the results demonstrate that the AC-900//AC-900 device at a power density of approximately 868 W/kg. The device reaches a noteworthy energy density of ∼72 W h/kg, while also demonstrating very high cyclic stability with an efficiency of approximately 100% even after undergoing 6,000 charge–discharge cycles. The impressive electrochemical performance displayed by AC-900 underscores its significant potential as a polymer-derived carbon nanomaterial for electrodes in supercapacitor applications. [ABSTRACT FROM AUTHOR]- Published
- 2023
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6. Zeolitic Imidazole Framework Derived Cobalt Phosphide/Carbon Composite and Waste Paper Derived Porous Carbon for High‐Performance Supercapattery.
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Sundriyal, Shashank, Dubey, Prashant, Mansi, Gupta, Bhavana, Holdynski, Marcin, Bonarowska, Magdalena, Deep, Akash, Shrivastav, Vishal, and Nogala, Wojciech
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WASTE paper ,COBALT phosphide ,NEGATIVE electrode ,SUPERCAPACITOR electrodes ,HYBRID systems ,ENERGY density - Abstract
Metal–organic frameworks (MOFs) derived nanostructures receive immense research focus due to its high porosity, conductivity, and structural tailrolability features. In this work, porous Zeolitic Imidazole Framework‐67 (ZIF‐67) to synthesize cobalt phosphide/carbon composite (ZCoPC) that serves as a positive electrode is utilized. Furthermore, porous and conductive office paper derived carbon (OPC) are utilized as a negative electrode to make a hybrid system. The metalloid characteristics, high conductivity, and good porosity of ZCoPC material makes it a high‐performance battery like electrode. ZCoPC electrode achieves maximum specific capacity of 192.6 mAh g−1 at 1 A g−1 using 1 m potassium hydroxide (KOH) electrolyte. Furthermore, surface and diffusion charge participation investigation are also undergone for ZCoPC electrode that helps in determining the actual charge dynamics occurring in the electrode. In addition, a supercapattery device is assembled using ZCoPC as battery electrode and OPC as supercapacitor electrode. The as fabricated OPC//ZCoPC hybrid supercapattery device delivers extraordinary energy density of 31.6 Wh kg−1 with a power density of 700 W kg−1 and also a long cycle life of 92.3% even after 10,000 charge–discharge cycles. Hence, these outcomes demonstrate that the synergy of porous MOF derived metal phosphide and OPC electrodes are beneficial for supercapattery devices. [ABSTRACT FROM AUTHOR]
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- 2023
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7. Diffusion controlled electrochemical analysis of MoS2 and MOF derived metal oxide–carbon hybrids for high performance supercapacitors.
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Shrivastav, Vishal, Mansi, Dubey, Prashant, Shrivastav, Vaishali, Kaur, Ashwinder, Hołdyński, Marcin, Krawczyńska, Agnieszka, Tiwari, Umesh K., Deep, Akash, Nogala, Wojciech, and Sundriyal, Shashank
- Abstract
In the context of emerging electric devices, the demand for advanced energy storage materials has intensified. These materials must encompass both surface and diffusion-driven charge storage mechanisms. While diffusion-driven reactions offer high capacitance by utilizing the bulk of the material, their effectiveness diminishes at higher discharge rates. Conversely, surface-controlled reactions provide rapid charge/discharge rates and high power density. To strike a balance between these attributes, we devised a tri-composite material, TiO
2 /Carbon/MoS2 (T10/MoS2 ). This innovative design features a highly porous carbon core for efficient diffusion and redox-active MoS2 nanosheets on the surface. Leveraging these characteristics, the T10/MoS2 composite exhibited impressive specific capacitance (436 F/g at 5 mV/s), with a significant contribution from the diffusion-controlled process (82%). Furthermore, our symmetrical device achieved a notable energy density of ~ 50 Wh/kg at a power density of 1.3 kW/kg. This concept holds promise for extending the approach to other Metal–Organic Framework (MOF) structures, enabling enhanced diffusion-controlled processes in energy storage applications. [ABSTRACT FROM AUTHOR]- Published
- 2023
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8. Improved electrochemical performance of rGO/TiO2 nanosheet composite based electrode for supercapacitor applications
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Sundriyal, Shashank, Sharma, Meenu, Kaur, Ashwinder, Mishra, Sunita, and Deep, Akash
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- 2018
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9. Chemically Oxidized Carbon Paper as a Free‐Standing Electrode for Supercapacitor: An Insight into Surface and Diffusion Contribution.
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Waseem, Sadiya, Dubey, Prashant, Singh, Mandeep, Sundriyal, Shashank, and Maheshwari, Priyanka H.
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CARBON paper ,ENERGY density ,SUPERCAPACITOR electrodes ,POTASSIUM dichromate ,POWER density ,RAMAN spectroscopy - Abstract
Carbon paper has been synthesized by paper making process followed by composite formation, and further chemically oxidized by immersing into a mixture of sulphuric acid and potassium dichromate to be used as an electrode for supercapacitor applications. XRD and Raman spectra were used to analyze the structure, and the defects in the samples respectively, in due course of oxidation. FESEM images revealed the morphology of oxidized samples to be rougher, which contributes towards increased active sites for reaction. The sample (COCP‐60) optimized via electrochemical studies, was further tested in various electrolytes to study the electrode/electrolyte interaction. It delivered a highest areal capacitance of 6.02 F/cm2 (231.5 F/g) in acidic electrolyte at a current density of 5 mA/cm2 (0.19 A/g). This findings were further corroborated by surface and diffusion contribution studies wherein it was found that diffusion is more profound with acidic electrolyte. The supercapacitor device fabricated with COCP‐60 electrode delivered an energy density of 0.41 Wh/cm2 at 2.83 W/cm2 power density with coulombic efficiency of 98 %, and cyclic stability of ∼90 % for over 5000 cycles. [ABSTRACT FROM AUTHOR]
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- 2023
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10. Electrolytic Study of Pineapple Peel Derived Porous Carbon for All‐Solid‐State Supercapacitors.
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Dubey, Prashant, Shrivastav, Vishal, Singh, Mandeep, Maheshwari, Priyanka H., Sundriyal, Shashank, and Dhakate, Sanjay R.
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PINEAPPLE ,PORE size distribution ,ENERGY density ,SUPERCAPACITORS ,FRUIT skins ,ELECTRODE performance ,ELECTRIC conductivity - Abstract
Biowaste derived carbon materials are recently gaining attention owing to their high specific surface area (SSA) and decent electrical conductivity. Herein, pineapple peel derived porous carbon nanosheets have been synthesized at different activation temperatures (PP‐600, PP‐700 and PP‐800). This shows that its high SSA along with hierarchal pore size distribution makes it a suitable electrode material for supercapacitors. Further, the electrochemical performance of the as prepared electrode material was carried out in three different electrolytes viz. acidic (1 M H2SO4), basic (6 M KOH) and neutral (1 M Na2SO4) and among them 1 M H2SO4 electrolyte shows superior electrochemical performance. Furthermore, PP‐800 electrode material displayed highest specific capacitance of 368.8 F/g in 1 M H2SO4 electrolyte, which is much higher when tested and compared in 6 M KOH (34 F/g) and 1 M Na2SO4 (102.7 F/g) electrolytes at a constant current density of 1 A/g. Additionally, symmetrical solid‐state supercapacitor was fabricated by utilizing PP‐800 electrodes and PVA gel electrolyte, that rendered remarkable energy density of ∼43 Wh/kg at a high‐power density of ∼1 kW/kg. The as fabricated PP‐800//PP‐800 device displayed an extraordinary cycle life exhibiting capacitance retention of 83 % after 10000 ultra‐long charge‐discharge cycles. [ABSTRACT FROM AUTHOR]
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- 2021
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11. A novel zinc sulfide impregnated carbon composite derived from zeolitic imidazolate framework-8 for sodium-ion hybrid solid-state flexible capacitors.
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Shrivastav, Vishal, Sundriyal, Shashank, Goel, Priyanshu, Saha, Avishek, Tiwari, Umesh K., and Deep, Akash
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- 2021
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12. Enhanced electrochemical performance of nickel intercalated ZIF-67/rGO composite electrode for solid-state supercapacitors.
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Sundriyal, Shashank, Shrivastav, Vishal, Mishra, Sunita, and Deep, Akash
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SUPERCAPACITOR electrodes , *ENERGY density , *POLYMER colloids , *ELECTRIC conductivity , *AQUEOUS electrolytes , *NICKEL , *SUPERCAPACITORS - Abstract
Ni (Nickel) doped zeolitic-imidazolate framework (ZIF-67) has been prepared in presence of reduced graphene oxide (rGO) to realize a ZIF-67/rGO composite. The doping level of Ni and the ratio of rGO (wt%) in the composite have been optimized to attain desirable redox activity and electrical conductivity. A partial incorporation of redox active Ni ions to substitute Co (cobalt) ions in ZIF-67 has resulted in better electrochemical characteristics by inducing additional pseudocapacitance. A finalized composite with 33% Ni and 20% of rGO (i.e, Ni 33 /ZIF-67/rGO 20) has been used as a supercapacitor electrode material to achieve a high specific capacitance of 304 F/g at a current density of 1 A/g in the presence of 1 M H 2 SO 4 as an aqueous electrolyte. The above electrode has also been tested for an all-solid-state symmetric supercapacitor in the presence of a polymer gel electrolyte (PVA/1 M H 2 SO 4). This device delivered high values of power and energy densities, i.e., 1 kW/kg and 21.5 Wh/kg, respectively. The device also exhibited an excellent cyclic stability. About 87% of capacitance could be retained even after 4500 charge-discharge cycles. The device has shown superior results for a working potential window of 0–2 V. The practical usefulness of the device has been demonstrated by preparing a symmetrical supercapacitor, which could energize a white LED for 8 min upon a charging of only 40 s. Image 1 • High surface area and conductive composite of Ni doped ZIF-67/rGO is synthesized. • The as synthesized composite is studied for 2V symmetrical supercapacitor device. • Supercapacitor displays long cycle life of 87% after 4500 charge-discharge cycles. • High values of energy (21.5 W h/kg) and power (1 kW/kg) densities are obtained. [ABSTRACT FROM AUTHOR]
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- 2020
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13. Metal‐organic frameworks‐derived titanium dioxide–carbon nanocomposite for supercapacitor applications.
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Shrivastav, Vishal, Sundriyal, Shashank, Kim, Ki‐Hyun, Sinha, Ravindra K., Tiwari, Umesh K., and Deep, Akash
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NANOCOMPOSITE materials , *POROUS metals , *TITANIUM , *ENERGY density , *METAL clusters - Abstract
Summary: The pyrolysis of metal‐organic frameworks (MOFs) to derive porous nanocarbons and metal oxides has attracted scientific attention due to the advantageous properties of the final products (eg, high surface areas). In the present research, MIL‐125 (MIL = Materials of Institute Lavoisier, a Ti‐based MOF) has been subjected to a single‐step pyrolysis treatment in argon atmosphere. The combination of uniformly linked titanium metal cluster and oxygen‐enriched organic linker has acted as a template to yield a titanium dioxide (TiO2)–carbon nanocomposite. The TiO2 nanoparticles infused in carbon skeleton structure (TiO2/C) has been investigated as an electrode material for supercapacitor applications. TiO2/C electrodes have delivered an excellent electrochemical performance, for example, in terms of charging–discharging efficiency. Two equally weighed TiO2/C electrodes have been used to assemble a solid‐state symmetrical supercapacitor (SC) device, containing a gel electrolyte (poly vinyl alcohol in 1 M H2SO4). The above device has delivered a high value of energy density (43.5 Wh/kg) and an excellent power output of 0.865 kW/kg. The symmetrical SC could retain almost 95% of its initial capacitance even after 2000 charging–discharging cycles. The electrochemical performance of the TiO2/C SC was better than most MOF‐based SCs reported previously. Such performance is attributed to the synergistic combination of electrically conducting MOF‐derived carbon and redox active TiO2 nanocrystals with a large specific surface area. [ABSTRACT FROM AUTHOR]
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- 2020
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14. Metal-organic frameworks (MOFs) and their composites as electrodes for lithium battery applications: Novel means for alternative energy storage.
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Shrivastav, Vishal, Sundriyal, Shashank, Goel, Priyanshu, Kaur, Harmeet, Tuteja, Satish K., Vikrant, Kumar, Kim, Ki-Hyun, Tiwari, Umesh K., and Deep, Akash
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LITHIUM-air batteries , *ALTERNATIVE fuels , *ENERGY storage , *LITHIUM cells , *METAL-organic frameworks , *PORE size distribution - Abstract
• Recent information has been compiled on the application of MOFs for Li-Batteries applications. • MOFs and their composites have been discussed as a cathode/anode material for various Li-batteries. • Performance of MOF-composites is reviewed in terms of specific capacity and cyclic stability. • MOF and their composites are discussed in detail for Li-HEC in separate section. Metal organic frameworks (MOFs) have emerged as a novel class of advanced functional materials due to their many well-known merits (e.g., ultrahigh porosity, favorable pore size distribution, easy functionalization, and structural tailorability). However, their use in various electronics applications is restricted due to their insulating nature. Therefore, a need arises to intercalate MOFs with various functional/conductive materials for synergistic applications like electrode materials (e.g., diverse Li-ion batteries: LIBs). In this review, the recent developments on pristine MOFs and their derived nanostructures (e.g., nanoporous carbons and metal oxides) for electrode applications are discussed in detail. We focused on the recent applications of various MOF-based composites in anodic/cathodic materials (e.g., LIBs, lithium-sulfur batteries (Li-S), lithium-air batteries (Li-O 2), and lithium hybrid electrochemical capacitors (Li-HEC)) along with details associated with their electrochemical performance. This review is expected to help materials scientists to construct a roadmap for the selection of the best possible electrode materials for LIBs. [ABSTRACT FROM AUTHOR]
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- 2019
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15. Significantly enhanced performance of rGO/TiO2 nanosheet composite electrodes based 1.8 V symmetrical supercapacitor with use of redox additive electrolyte.
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Sundriyal, Shashank, Shrivastav, Vishal, Sharma, Meenu, Mishra, Sunita, and Deep, Akash
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SUPERCAPACITOR electrodes , *ELECTROLYTES , *ENERGY density , *ELECTRODES , *AQUEOUS electrolytes , *SUPERCAPACITOR performance - Abstract
Abstract The role of redox additive electrolytes in supercapacitors is gaining an increased significance. The present research work, for the first time, investigates the supercapacitor performance of a rGO/TiO 2 nanosheet composite (prepared via facile one step hydrothermal reaction route) electrode in combination with a redox additive electrolyte, i.e., 0.2 M K 3 [Fe(CN) 6 ] in 1 M Na 2 SO 4. The synergistic effects between the porous rGO/TiO 2 nanosheet electrode and the optimized redox electrolyte have helped to achieve a significantly high specific capacitance of 1565 F/g at a current density of 3 A/g (working potential window = −0.1–0.5 V). This value of specific capacitance is much higher than achievable with the application of a plain aqueous electrolyte (e.g., 1 M Na 2 SO 4). Furthermore, rGO/TiO 2 nanosheet electrodes have been used to fabricate a symmetrical supercapacitor device which has delivered an excellent specific capacitance value of 204.5 F/g at a current density of 1.5 A/g. The device also yielded promising values of energy density (15.5 Wh/kg) and power density (1.1 kW/kg) apart from showing a long-term cyclic stability (∼87%) even after 1000 continuous charge-discharge cycles. Graphical abstract Image 1 Highlights • A composite of rGO/TiO 2 nanosheets has been explored as a supercapacitor electrode. • 0.2 M K 3 [Fe(CN) 6 ] in 1 M Na 2 SO 4 has been used as an optimized electrolyte. • Selection of above electrode and electrolyte yielded high specific capacitance. • A specific capacitance of 1565 F/g has been achieved at a current density of 3 A/g. • High values of energy (15.5 Wh/Kg) and power (1.1 kW/kg) densities were achieved. [ABSTRACT FROM AUTHOR]
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- 2019
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16. Corrigendum to "Perovskite materials as superior and powerful platforms for energy conversion and storage applications", [Nano Energy volume 80 (2021) 105552].
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Goel, Priyanshu, Sundriyal, Shashank, Shrivastav, Vishal, Mishra, Sunita, Dubal, Deepak P., Kim, Ki-Hyun, and Deep, Akash
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- 2023
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17. Redox Additive Electrolyte Study of Mn–MOF Electrode for Supercapacitor Applications.
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Sundriyal, Shashank, Shrivastav, Vishal, Sharma, Meenu, Mishra, Sunita, and Deep, Akash
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MANGANESE compounds , *SUPERCAPACITOR electrodes , *OXIDATION-reduction reaction - Abstract
The selection of appropriate electrode materials and electrolytes in addition to optimization of their combinations is a key to improve the performance of supercapacitors. Among the new electrode materials, metal‐organic frameworks (MOFs) based electrodes are attracting attention in energy storage devices, including supercapacitors and batteries. In recent years, the redox additive electrolytes have been projected as efficient options over simple aqueous electrolytes. The present work reports the synthesis of a layered MOF, i. e. manganese‐1,4‐ benzene dicarboxylate (Mn‐BDC) and explores its utility as a supercapacitor electrode in the presence of an optimized redox additive electrolyte (0.2 M K3[Fe(CN)6] in 1 M Na2SO4 (0.2 M KFCN)). As demonstrated for the first time in this study, the combined use of the porous Mn‐BDC electrode and KFCN electrolyte has provided a synergistic enhancement in the supercapacitor performance. The present Mn‐BDC/KFCN combination has delivered a high specific capacitance of 1590 F/g at a current density of 3 A/g. Furthermore, the Mn‐BDC electrode could retain around 82% of its initial specific capacitance even after 3000 continuous charge‐discharge cycles. In view of its encouraging electrochemical performance parameters, the proposed system can be touted as an efficient supercapacitor assembly. Manganese‐1,4‐benzene dicarboxylate (Mn‐BDC) is a layered MOF synthesized using one‐pot hydrothermal route. An electrode of Mn‐BDC is prepared and employed as a supercapacitor electrode in presence of an optimized redox additive electrolyte. The proposed system has delivered a high specific capacitance of 1590 F/g at a current density of 3 A/g. The Mn‐BDC electrode retains around 82% of its initial specific capacitance even after 3000 continuous charge‐discharge cycles. [ABSTRACT FROM AUTHOR]
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- 2019
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18. Facile synthesis and electrochemical performance of Mg-substituted Ni1-xMgxCo2O4 mesoporous nanoflakes for energy storage applications.
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Sharma, Meenu, Sundriyal, Shashank, Panwar, Amrish K., and Gaur, Anurag
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LITHIUM cells , *HYDROTHERMAL synthesis , *ENERGY storage - Abstract
Abstract The specific surface area and pore size of illustrative electrode material is a promising task to achieve better performance of energy storage devices. In this respect, Mg-substituted Ni 1-x Mg x Co 2 O 4 (x = 0.0, 0.1, 0.2, 0.3, 0.4, 0.5) samples were synthesized by cost-effective and facile hydrothermal method. As-prepared samples were evaluated as the electrode material for a battery application. The structural and electrochemical characterization analysis has been carried out systematically. Among different samples, NMC50 (x = 0.5) exhibit highest BET surface area of 61 m2g-1 with a suitable pore volume of 0.3029 cm3g-1 and narrow pore size distribution of 2–10 nm. It is verified that the special features of the NMC50 including uniformity of the surface texture and porosity bring significant effect on the electrochemical performances. Consequently, the excellent specific capacity of 302 mAhg−1 is observed for NMC50 sample at a current density of 1.1 Ag-1 and a remarkable cyclic stability of ∼95% is maintained over 2000 continuous charge-discharge cycles. The improved electrochemical performance of NMC50, undoubtedly makes it worth as an excellent electrode material for high-performance energy storage applications. Graphical abstract Image [ABSTRACT FROM AUTHOR]
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- 2019
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19. Enhanced supercapacitive performance of Ni0.5Mg0.5Co2O4 flowers and rods as an electrode material for high energy density supercapacitors: Rod morphology holds the key.
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Sharma, Meenu, Sundriyal, Shashank, Panwar, Amrish, and Gaur, Anurag
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SUPERCAPACITORS , *ENERGY density , *HYDROTHERMAL synthesis - Abstract
Abstract In pursuit of high specific capacitance and high energy density; morphology, specific surface area and conductivity of electrode material are key factors. In this context, Ni 1-x Mg x Co 2 O 4 @C (x = 0.0, 0.5) nanostructures are synthesized via facile hydrothermal route using the cotton template. Notably; the morphology altered from flowers to rods with the incorporation of cotton templates. Additionally, Mg dopant ion helps to attain greater electrical conductivity while preventing the morphology. Besides, Influence of Mg doping on the pseudocapacitance of NiCo 2 O 4 electrode was investigated by electrochemical analysis in 6 M KOH electrolyte. This remarkable synergy display superb electrochemical performance for Ni 0.5 Mg 0.5 Co 2 O 4 @C rods, i.e a high specific capacitance of 1340 Fg-1 at a current density of 1 Ag-1 and admirable cyclic stability of ∼97% up to 2000 charge-discharge cycles (at 15 Ag-1). Further, the proposed Ni 0.5 Mg 0.5 Co 2 O 4 @C rods electrode delivered high values of energy (59.5 Wh/Kg) & power (799.2 W/Kg) densities at a current density of 1 Ag-1, which is 2 times more as compared to flowers structured material. This can be attributed to increase in the specific surface area with more porous nature of rods. This work conveys the deeper understanding of the morphology and chemical composition effect on the supercapcitive performance of Ni 0.5 Mg 0.5 Co 2 O 4 @C. Thus, Ni 0.5 Mg 0.5 Co 2 O 4 @C (NMCo@C) rods may be an excellent electrode material for high-performance supercapacitor due to its exceptional electrochemical performances. Graphical abstract Image 1 Highlights • Highly porous rods structure of specific surface area of 51.78 m2g-1 is fabricated. • The specific capacitance of 1340 Fg-1 is obtained for Ni 0.5 Mg 0.5 Co 2 O 4 @C rods. • Ni 0.5 Mg 0.5 Co 2 O 4 @C rods delivers maximum energy density of 59.5 WhKg−1. • The capacitance retention of ∼97% up to 2000 charge-discharge is maintained. [ABSTRACT FROM AUTHOR]
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- 2018
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20. Metal-organic frameworks and their composites as efficient electrodes for supercapacitor applications.
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Sundriyal, Shashank, Kaur, Harmeet, Bhardwaj, Sanjeev Kumar, Mishra, Sunita, Kim, Ki-Hyun, and Deep, Akash
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METAL-organic frameworks , *PROPYLENE carbonate , *COMPOSITE materials , *ELECTRODES , *SUPERCAPACITORS , *PORE size distribution - Abstract
Metal-organic frameworks (MOFs) belong to a novel class of materials with several advantages (e.g., ultrahigh porosity, tunable pore size distribution, convenience of synthesis, and structural tailor-ability). However, the insulating nature of MOFs is often recognized as a limiting factor in the extension of their applications, especially in electronic fields. In light of such limitations, various functional or conductive materials have been mixed/intercalated with MOFs to improve their potential for such applications (e.g., rechargeable batteries, optoelectronics, and supercapacitors). Lately, many of these composite materials have been recognized as next-generation electrodes for the development of efficient supercapacitors. In this review article, we have critically reviewed the recent advancements in supercapacitor applications of MOFs and their derived composite structures. Further, we have also discussed the application of various categories of electrolytes (e.g., aqueous, organic, ionic liquids, solid-state, and redox electrolytes) and their impacts on the development of MOF-based supercapacitors. [ABSTRACT FROM AUTHOR]
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- 2018
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21. Study of Manganese-1,4-Benzenedicarboxylate Metal Organic Framework Electrodes Based Solid State Symmetrical Supercapacitor.
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Sundriyal, Shashank, Mishra, Sunita, and Deep, Akash
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Abstract In this work, manganese MOF is synthesized using one step solvothermal method and utilized as an electrode for supercapacitor applications. The high specific surface area, chemical & thermal stability and pseudocapacitive charge storage mechanism of Mn-BDC MOF facilitates fast electronic and ionic transport. When the Mn-BDC MOF is tested as an electrode for supercapacitor applications, the electrode exhibits remarkable electrochemical performance using 1 M Na 2 SO 4 aqueous electrolyte. The Mn-BDC electrode shows a highest specific capacitance of 177.9 F/g at a current density of 0.5 A/g and 166.4 F/g at a scan rate of 1 mV/s. Further, an all-solid-state symmetrical supercapacitor is assembled using two equally weighted Mn MOF electrodes using PVA-1 M Na 2 SO 4 polymer gel electrolyte. The solid state symmetrical supercapacitor device shows a highest specific capacitance of 64.5 F/g at a current density of 0.25 A/g within an operating potential window of 0-1.5 V. Also, the device delivers an energy density and power density of 4.3 Wh/kg and 171.6 W/kg respectively along with a very high capacity retention of 98 % even after 2000 charge-discharge cycles. Therefore, the excellent electrochemical performance of Mn MOF electrodes and symmetrical device proves its superiority for practical supercapacitor applications. [ABSTRACT FROM AUTHOR]
- Published
- 2019
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22. Improved electrochemical performance of rGO/TiO2 nanosheet composite based electrode for supercapacitor applications.
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Sundriyal, Shashank, Sharma, Meenu, Kaur, Ashwinder, Mishra, Sunita, and Deep, Akash
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NANOCOMPOSITE materials ,GRAPHENE oxide ,SUPERCAPACITORS ,HYDROTHERMAL deposits ,ELECTRODES - Abstract
The present work reports the synthesis of a composite of TiO
2 nanosheets (NS) with reduced graphene oxide (rGO) for supercapacitor applications. The formation of composite has been achieved via a simple one-pot hydrothermal method. The rGO/TiO2 NS composite was used to fabricate a flexible electrode which, in presence of 1 M H2 SO4 as an electrolyte, has shown a high specific capacitance of 233.67 F/g at a current density of 1 A/g within a potential window of 0-1 V. This enhanced supercapacitance of the rGO/TiO2 NS electrode is attributed to the synergistic effects from TiO2 and rGO NS which help in to attain a low equivalent series resistance and enhanced ion diffusion. Furthermore, the fabricated composite electrode has displayed a long-term cyclic stability, retaining a specific capacitance of 98.2% even after 2000 charge-discharge cycles. The proposed rGO/TiO2 NS electrode has delivered high values of energy (32.454 Wh/kg) and power (716.779 W/kg) densities. Interestingly, it is possible to retrieve a sufficiently high energy density of 24.576 Wh/kg which could generate a power density value of as high as 2142.84 W/kg. The above results reveal that the herein proposed thin film composite of rGO/TiO2 NS can offer extraordinary performance as a supercapacitor electrode compared to its nanotubes or nanoparticles. [ABSTRACT FROM AUTHOR]- Published
- 2018
- Full Text
- View/download PDF
23. Metal-organic framework derived zirconium oxide/carbon composite as an improved supercapacitor electrode.
- Author
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Shrivastav, Vishal, Sundriyal, Shashank, Tiwari, Umesh K., Kim, Ki-Hyun, and Deep, Akash
- Subjects
- *
SUPERCAPACITOR electrodes , *SUPERCAPACITORS , *ZIRCONIUM oxide , *CARBON composites , *METAL-organic frameworks , *ENERGY density , *ENERGY storage , *SUPERABSORBENT polymers - Abstract
The pyrolysis of metal-organic frameworks (MOFs) is an effective strategy for the synthesis of novel nanoporous structures for energy storage applications. In this work, the preparation of a zirconium oxide/carbon (ZrO 2 /C) nanocomposite via the pyrolysis of UiO-66 (a zirconium-based MOF) is reported for the first time. These MOF-derived metal oxide/carbon (ZrO 2 /C) materials have a great advantage in the case of supercapacitor applications over other MOFs or their derivatives as they do not need any external conductive agent. The ZrO 2 /C electrode exhibits an excellent electrochemical performance, delivering a specific capacitance of 241.5 F/g at 1 A/g current density. A 2 V symmetrical supercapacitor device is also prepared by employing a solid-state polymer gel electrolyte. The assembled device of ZrO 2 /C electrode has delivered a high energy density of around 29 Wh/kg (at a high power density of 1.5 kW/kg) while retaining almost 97% of the specific capacitance even after 2000 continuous charge/discharge cycles. • The development of efficient supercapacitor is a viable strategy to achieve energy storage devices. • Uniformly distributed oxides/carbon/oxide-carbon structures are prepared by the pyrolysis of MOF. • ZrO 2 /C composite is prepared via one-step pyrolysis of UiO-66 (zirconium-based MOF). • Superiority of a MOF-derived ZrO 2 /C composite is demonstrated in supercapacitor applications. [ABSTRACT FROM AUTHOR]
- Published
- 2021
- Full Text
- View/download PDF
24. Pencil peel derived mixed phase activated carbon and metal-organic framework derived cobalt-tungsten oxide for high-performance hybrid supercapacitors.
- Author
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Sundriyal, Shashank, Shrivastav, Vishal, Gupta, Ashish, Shrivastav, Vaishali, Deep, Akash, and Dhakate, Sanjay R.
- Subjects
- *
ACTIVATED carbon , *METAL-organic frameworks , *SUPERCAPACITOR electrodes , *SUPERCAPACITORS , *ENERGY density , *NEGATIVE electrode , *COBALT - Abstract
[Display omitted] • Pencil peels is used to derive mixed phase activated carbon of high porosity and conductivity. • Asymmetrical supercapacitor is assembled using MOF derived Co 3 O 4 /WO 3 and Pencil derived activated carbon. • Asymmetrical Supercapacitor device retains long cycle life of 92.1 % after 5000 charge-discharge cycles. • The supercapacitor device shows high energy density of 50 Wh/kg at a power density of 90 W/kg. In this work, pencil peel is used to derive the mix phase activated carbon at different temperatures viz 700, 800, and 900 °C for hybrid supercapacitor applications. The derived carbon is showing the highest specific surface area for P-800 (Pencil peel@ 800 °C) sample and exhibits the graphitic and amorphous phase whose fraction can be controlled with pyrolysis temperature. Therefore, the as-prepared P-800 electrode shows the high specific capacitance of 553 F/g at a current density of 1 A/g. On the other hand, metal-organic framework (MOF) derived Cobalt-Tungsten oxide composites (Co 3 O 4 /WO 3) has been synthesized which shows a much higher specific capacitance value (544 F/g at 2 A/g) in the negative potential window. Therefore, an asymmetrical supercapacitor device has been assembled with P-800 as positive and Co 3 O 4 /WO 3 composites as a negative electrode in aqueous 1 M H 2 SO 4 (Sulfuric acid) electrolyte that delivers higher energy and power density in comparison to their symmetrical supercapacitor counterparts. [ABSTRACT FROM AUTHOR]
- Published
- 2021
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- View/download PDF
25. Tetracyanoquinodimethane doped copper-organic framework electrode with excellent electrochemical performance for energy storage applications.
- Author
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Sundriyal, Shashank, Shrivastav, Vishal, Bhardwaj, Sanjeev Kumar, Mishra, Sunita, and Deep, Akash
- Subjects
- *
ENERGY storage , *POLYMER colloids , *COPPER electrodes , *ELECTROCHEMICAL electrodes , *TETRACYANOQUINODIMETHANE , *ENERGY density , *ELECTRODE potential - Abstract
• Tetracyanoquinodimethane doped HKUST-1 has been explored as a battery type material. • A high specific capacity of 208.8 mAh/g (751 C/g) at 2 A/g has been achieved. • Solid-state symmetrical device has delivered high energy and power densities of 70.5 Wh/kg and 0.83 kW/kg respectively. • The energy storage device has yielded an energy efficiency of 58.6% and cyclic stability of 96%. Metal-organic frameworks (MOFs) are emerging as potential electrode materials for next-generation energy storage devices. Cu 3 (BTC) 2 (BTC = benzene tricarboxylate), also known as HKUST-1, is one of the most widely studied MOFs. In the present work, TCNQ (tetracyanoquinodimethane) doped HKUST-1, has been demonstrated as an efficient energy storage electrode material. The infiltration of TCNQ in HKUST-1 has resulted in the synthesis of a high surface area electrode material with significant electrical conductivity. TCNQ@HKUST-1 based electrode has delivered a high specific capacity of 208.8 mAh/g (751 C/g) at a current density of 2 A/g. An all-solid-state symmetrical device has been assembled using a polymer gel electrolyte, which has delivered energy and power densities of 70.5 Wh/kg and 0.83 kW/kg, respectively. Also, the device showed a maximum energy efficiency of 58.6% along with a long cycle life of 96% over 5000 successive charging-discharging cycles. The present system has yielded superior energy storage performance than most of the earlier reported MOF based electrodes. [Display omitted] [ABSTRACT FROM AUTHOR]
- Published
- 2021
- Full Text
- View/download PDF
26. Advances in bio-waste derived activated carbon for supercapacitors: Trends, challenges and prospective.
- Author
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Sundriyal, Shashank, Shrivastav, Vishal, Pham, Hong Duc, Mishra, Sunita, Deep, Akash, and Dubal, Deepak P.
- Subjects
ACTIVATED carbon ,ENERGY development ,SUPERCAPACITORS ,CLEAN energy ,RENEWABLE energy sources ,CARBONIZATION - Abstract
The ever-increasing demand for green and clean energy urge the development of cheap and efficient electrode materials for supercapacitors (SCs). In this context, several naturally abundant bio-wastes have been explored to develop porous carbons for SCs due to their easy availability, high performances, and simple processing methods. Although various BDCs are utilized for SC, the relation between the bio-waste precursor and resultant carbon materials are not very well understood. Here, we highlight how the different bio-waste precursors affect the surface characteristics of the carbon nanostructures and outlined their subsequent effect on electrochemical performances. Moreover, the surface modification of carbon materials using pre-processing, carbonization and activation methods is provided. The supercapacitive properties of activated carbons (AC) with their unique surface features derived from the different feedstock are systematically summarized. Finally, the challenges and future directions for the development of AC from bio-waste are discussed. Overall, this review provides a guide to understand how best to refine and carbonize this biomass to achieve optimum supercapacitive performance. Schematic of the used biowaste and the methodology of preparing activated carbon. Reproduced with permission from Ref. (Yue et al., 2019) Copyright 2019, Multidisciplinary Digital Publishing Institute, Ref. (Sulyman et al., 2017) Copyright 2018, American Chemical Society [Display omitted]. [ABSTRACT FROM AUTHOR]
- Published
- 2021
- Full Text
- View/download PDF
27. Unveiling the Potential of Covalent Organic Frameworks for Energy Storage: Developments, Challenges, and Future Prospects.
- Author
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Dubey, Prashant, Shrivastav, Vishal, Boruah, Tribani, Zoppellaro, Giorgio, Zbořil, Radek, Bakandritsos, Aristides, and Sundriyal, Shashank
- Abstract
Covalent organic frameworks (COFs) are porous structures emerging as promising electrode materials due to their high structural diversity, controlled and wide pore network, and amenability to chemical modifications. COFs are solely composed of periodically arranged organic molecules, resulting in lightweight materials. Their inherent properties, such as extended surface area and diverse framework topologies, along with their high proclivity to chemical modification, have positioned COFs as sophisticated materials in the realm of electrochemical energy storage (EES). The modular structure of COFs facilitates the integration of key functions such as redox‐active moieties, fast charge diffusion channels, composite formation with conductive counterparts, and highly porous network for accommodating charged energy carriers, which can significantly enhance their electrochemical performance. However, ascribing intricate porosity and redox‐active functionalities to a single COF structure, while maintaining long‐term electrochemical stability, is challenging. Efforts to overcome these hurdles embrace strategies such as the implementation of reversible linkages for structural flexibility, stimuli‐responsive functionalities, and incorporating chemical groups to promote the formation of COF heterostructures. This review focuses on the recent progress of COFs in EES devices, such as batteries and supercapacitors, through a meticulous exploration of the latest strategies aimed at optimizing COFs as advanced electrodes in future EES technologies. [ABSTRACT FROM AUTHOR]
- Published
- 2024
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- View/download PDF
28. Perovskite materials as superior and powerful platforms for energy conversion and storage applications.
- Author
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Goel, Priyanshu, Sundriyal, Shashank, Shrivastav, Vishal, Mishra, Sunita, Dubal, Deepak P., Kim, Ki-Hyun, and Deep, Akash
- Abstract
In order to meet the continuously growing demand for clean energy, a plethora of advanced materials have been exploited for energy storage applications. Among these materials, perovskites belong to a relatively new family of compounds with the structural formula of ABX 3. These compounds exhibit a variety of electrical, optical, and electronic properties to adopt them for a variety of energy conversion and storage applications. The present review highlights the multifaceted nature of perovskite materials by covering a brief background, common crystallographic structures, and the importance of doping with different elements. Our discussion is extended further on the strategic energy applications of perovskites in modern devices such as fuel cells, lithium batteries, supercapacitors, LEDs, and solar cells. ga1 • Arrangement of the atoms in its crystallographic structure of Perovskites is explained. • Effect of doping on perovskite is discussed w.r.t. changes in its physicochemical properties. • The utility of perovskite in various forms of energy storage/harvesting is provided. • Discussion on the future prospects of perovskite and its derivatives is provided. [ABSTRACT FROM AUTHOR]
- Published
- 2021
- Full Text
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29. Conductive and porous ZIF-67/PEDOT hybrid composite as superior electrode for all-solid-state symmetrical supercapacitors.
- Author
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Shrivastav, Vishal, Sundriyal, Shashank, Kaur, Ashwinder, Tiwari, Umesh K., Mishra, Sunita, and Deep, Akash
- Subjects
- *
SUPERCAPACITOR electrodes , *SUPERCAPACITORS , *POROUS materials , *ENERGY storage , *ENERGY density , *COMPOSITE materials , *ELECTRODES - Abstract
The application of porous and conductive composite materials in energy storage devices has received great attention in the recent years. Porous materials, such as metal-organic frameworks (MOFs), possess features like large specific surface area, mesoporous structures, and multiple reaction sites that make them attractive for energy storage devices. Further, the integration of MOFs with suitable conducting agents is a promising strategy to introduce additional conductive pathways in them, which facilitates fast charge transfer. In the present work, we report synthesis and supercapacitor application of a ZIF-67/PEDOT heterostructure composite. The prepared ZIF-67/PEDOT composite, when analyzed for electrochemical performance in three-electrode systems, has delivered a specific capacitance of 106.8 F/g at a current density of 1 A/g. This value is significantly better than that attaintable with only pristine ZIF-67 electrode (34.75 F/g at 1 A/g). Extending the study, two ZIF-67/PEDOT electrodes have been used to assemble an all-solid-state symmetrical supercapacitor, which delivers excellent values of energy density (∼11 Wh/kg) and power density (200 W/kg). Hence, this work paves the way for the potential application of ZIF-67/PEDOT composite in the development of next-generation supercapacitors. Image 1 • Incorporation of PEDOT in ZIF-67 benefits high conductivity and large specific surface area. • ZIF-67/PEDOT has been explored as a supercapacitor electrode material. • The assembled 1.6 V device delivered high energy (11 Wh/kg) and power (200 W/kg) densities. • Supercapacitor device has a long cycle life (93% capacity retention even after 4000 charge-discharge cycles). [ABSTRACT FROM AUTHOR]
- Published
- 2020
- Full Text
- View/download PDF
30. ZIF-67 derived Co3S4 hollow microspheres and WS2 nanorods as a hybrid electrode material for flexible 2V solid-state supercapacitor.
- Author
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Shrivastav, Vishal, Sundriyal, Shashank, Goel, Priyanshu, Shrivastav, Vaishali, Tiwari, Umesh K., and Deep, Akash
- Subjects
- *
SUPERCAPACITOR electrodes , *MICROSPHERES , *POLYMER colloids , *ENERGY density , *COMPOSITE materials , *ELECTRIC conductivity , *ELECTRODES - Abstract
Transition metal dichalcogenides (TMDs) are gaining interest in the energy sector due to its 2D chemistry and heterogeneous characteristics however its stability for the long run and poor electrical conductivity are pushing the researchers to make their hybrid. Herein we synthesized the hybrid WS 2 nanorods and Co 3 S 4 microspheres composite material which attained a high energy density of 47.3 Wh/kg along at a high-power density of 512 W/kg. The hollow Co 3 S 4 microspheres were synthesized using highly porous ZIF-67 as a precursor. Furthermore, these hollow Co 3 S 4 microspheres are in-situ modified by combining with WS 2 nanostructures to enhance its energy density. The electrodes with the synthesized hybrid material deliver the specific capacitance of 412.7 F/g at the current density of 1 A/g, Additionally, two equal weighted Co 3 S 4 /WS 2 composite electrodes are used to fabricate an all-solid-state symmetrical supercapacitor device with PVA-1M H 2 SO 4 polymer gel electrolyte, exhibiting a wide potential window of 2 V with 92% cyclic stability (2000 charge-discharge cycles) demonstrates its potential applicability for the supercapacitor application. The excellent electrochemical performance and splendid cyclic stability are attributed to the synergy of high surface area ZIF-67 derived Co 3 S 4 microsphere for fast charge transfer with 2D networked WS 2 material responsible to provide high energy density. Image 1 • A hybrid Co 3 S 4 /WS 2 composite was prepared using a one-step solvothermal method. • The hybrid composites deliver the highest specific capacitance of 412.7 F/g at the current density of 1 A/g. • A solid-state symmetrical supercapacitor was assembled with PVA-1M H 2 SO 4 gel electrolyte as a separator. • With wide potential window of 2 V, the fabricated device attained a high energy density of 47.3 Wh/kg along at a high-power density of 512 W/kg. [ABSTRACT FROM AUTHOR]
- Published
- 2020
- Full Text
- View/download PDF
31. Luminescent metal-organic frameworks and their composites: Potential future materials for organic light emitting displays.
- Author
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Kaur, Harmeet, Sundriyal, Shashank, Pachauri, Vivek, Ingebrandt, Sven, Kim, Ki-Hyun, Sharma, Amit L, and Deep, Akash
- Subjects
- *
METAL-organic frameworks , *ORGANIC light emitting diodes , *QUANTUM efficiency , *LUMINESCENCE - Abstract
• Luminescent MOFs and their composites showing great promise in OLEDs. • Application of MOFs is useful to obtain enhanced quantum efficiencies and emission lifetimes. • MOFs offer development of efficient white light emitters. • MOFs in OLEDs provide fairly good CCT and CRI values and wider color emission gamuts. Metal-Organic Frameworks (MOFs) are hybrid organic-inorganic materials with enhanced electronic and optical functionalities that can be tailored by the judicious selection of the building units or their combinations. A large-scale diversity of metal-ligand combinations, along with the ability to form composites, have allowed MOFs to realize enhanced luminescence functionality with applicability in the avenues of solid-state lighting, luminescence-based sensors, and organic light emitting diodes (OLEDs). Because of their enhanced fluorescence lifetimes, high quantum efficiencies, and large-scale tunability, the luminescent MOFs and their composites hold great promise for the OLED industry with enhanced potential to resolve low efficiency issues. The present article presents a comprehensive review of emerging applications for luminescent MOFs and their composites in various OLED applications, with a focus on key attributes like quantum efficiencies, emission lifetimes, tunability, Commission internationale de l'éclairage (CIE) color coordinates, etc. At last, the prospects of luminescent MOFs have been addressed with respect to their future roles and applications in the OLED industry. [ABSTRACT FROM AUTHOR]
- Published
- 2019
- Full Text
- View/download PDF
32. Recent advances on core-shell metal-organic frameworks for energy storage applications: Controlled assemblies and design strategies.
- Author
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Mansi, Shrivastav, Vishal, Dubey, Prashant, Sundriyal, Shashank, Tiwari, Umesh K., and Deep, Akash
- Subjects
- *
ENERGY storage , *METAL-organic frameworks , *MATERIALS science , *ENERGY density , *LITHIUM-ion batteries - Abstract
[Display omitted] • State of the art information on core–shell MOF-based supercapacitors and batteries are explored. • CSMOF structures are discussed separately in terms of properties, synthesis and their types. • CSMOF structures for supercapacitors are compared in terms of specific capacitance, capacitance retention, energy density, and self-discharge. • CSMOF structures for batteries are compared in terms of reversible capacity, initial discharge capacity, and cyclic stability. • Besides Li-ion batteries, CSMOFs are also reviewed for Na-ion, K-ion, Li-S, Li-Se, and Li-O 2 batteries. • Critical assessment and future aspects are also explored for CSMOF based energy storage devices. Core-shell metal–organic framework (CSMOF) has attracted the attention of researchers in the material science and nanotechnology research field. The structural properties of CSMOF and their derived material include extortionate specific surface area and porosity, good structural flexibility, high stability, etc. These appealing properties make CSMOF a great alternative for various practical applications. CSMOF has shown great performance as an electrode material for energy storage applications. This review is primarily focused on the factor affecting the assemblies and synthesis of core shell structures, strategy to control the assemblies, synthesis methods, and properties of different CSMOFs for energy storage devices viz. supercapacitors (SC) and batteries. After that, different CSMOF structures are compared in terms of their performance parameters for SC including specific capacitance, capacitance retention, cyclic stability, energy density, and self-discharge.On the other hand, reversible capacity, initial discharge capacity, and cyclic stability are a few performance parameters for Li-ion batteries that are also discussed for different materials.CSMOF's applications for some other batteries like Na-ion, K-ion, Li-S, Li-Se, and Li-O 2 will likewise be discussed in other sections. Eventually, the expansion and future scope of CSMOF and its derivatives are proposed for upcoming energy storage applications. [ABSTRACT FROM AUTHOR]
- Published
- 2024
- Full Text
- View/download PDF
33. Kraft lignin-derived free-standing carbon nanofibers mat for high-performance all-solid-state supercapacitor.
- Author
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Singh, Mandeep, Gupta, Ashish, Sundriyal, Shashank, Jain, Karishma, and Dhakate, S.R.
- Subjects
- *
CARBON nanofibers , *SUPERCAPACITOR electrodes , *EFFECT of heat treatment on microstructure , *HEAT treatment , *ENERGY density , *ENERGY storage , *AQUEOUS electrolytes - Abstract
In the present investigation, renewable kraft lignin-based nanofibers were synthesized by facile electrospinning technique and further converted into carbon nanofibers (CNFs) by heat treatment at different temperatures (600, 800 and 1000 °C). These different heat treated carbon nanofiber mats were characterized using SEM, Raman, FTIR, BET and electrochemical workstation. These CNFs were used as a free-standing electrode and characterized for electrochemical performance using a three-electrode system. Among different electrodes, the 800 °C heat treated CNF electrode shows higher specific capacitance (196.63 F/g @ 1 A/g) as compared to the 600 and 1000 °C heat treated CNF electrodes. Based on the electrochemical performance, 800 °C heat treated CNF electrode is selected to assemble two different types of symmetrical supercapacitor devices i.e., aqueous (using 1 M H 2 SO 4) and solid-state electrolyte using PVA-1M H 2 SO 4 polymer gel. The solid-state electrolyte device operating potential window of 0–2 V which is higher than that of an aqueous electrolyte based device. In addition to this, it delivers higher energy and power density as 62.6 Wh/kg and 1.25 kW/kg respectively with an efficiency of 99.5% after 10,000 cycles. These remarkable results of Kraft lignin-derived ribbon type CNF based solid-state symmetrical supercapacitor device opens new paths for the development of futuristic carbon-based free-standing mat as energy storage devices. • Lignin (90%) based carbon nanofibers synthesized by electrospinning and heat treatment at different temperatures. • Effect of heat treatment on microstructure, surface area and functional groups has been studied extensively. • The assembled symmetrical solid state supercapacitor device operates within a wide potential window of 0–2 V. • It shows superior long cycle life of 99.5% after 10,000 charge-discharge cycles. • The solid-state supercapacitor device shows high values of energy (62.6 Wh/kg) and power (1.25 kW/kg) density. [ABSTRACT FROM AUTHOR]
- Published
- 2021
- Full Text
- View/download PDF
34. Recent advances in biomass derived activated carbon electrodes for hybrid electrochemical capacitor applications: Challenges and opportunities.
- Author
-
Dubey, Prashant, Shrivastav, Vishal, Maheshwari, Priyanka H., and Sundriyal, Shashank
- Subjects
- *
SUPERCAPACITORS , *CARBON electrodes , *ELECTROCHEMICAL electrodes , *ALTERNATIVE fuels , *PORE size distribution , *ACTIVATED carbon - Abstract
Biomass derived activated carbon (BDAC) materials are recently gaining attention as an active electrode material for alternative energy storage devices. Biomass is a rich source of carbon and blessed with high specific surface area, hierarchical pore size distribution, good conductivity, easy availability and facile synthesis approaches. These characteristics make BDAC a suitable electrode material for next generation clean and green energy applications. The review examines the recent developments in the usage of biomass derived carbon and their composites for various hybrid electrochemical capacitor (HEC) devices claiming high electrochemical performance in terms of energy and power density. It also summarizes the various synthesis strategies which lead to different morphologies that are beneficial for high performance energy storage applications. Additionally, the review also coins the existing challenges and possible solutions towards developing cost-effective and high performance HECs using biomass derived carbon-based electrodes. Finally, we speculate the future prospects of biomass derived carbon materials for energy storage applications. We expect that this review article will help in the evolution of new insights for the practical energy storage applications of biomass derived carbons. Image 1 • Various biowastes are reviewed as a potential resource for the generation of activated carbon (BDAC). • BDAC are used as one of the electrodes for Li-HEC, Na-HEC, Zn-HEC, and K-HEC. • BDAC are reviewed in terms of their need, morphologies, porosity and conductivity. • BDAC are reviewed to attain superior energy density, power density and long cycle life when used in HECs. [ABSTRACT FROM AUTHOR]
- Published
- 2020
- Full Text
- View/download PDF
35. Recent advances on surface mounted metal-organic frameworks for energy storage and conversion applications: Trends, challenges, and opportunities.
- Author
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Shrivastav, Vaishali, Mansi, Gupta, Bhavana, Dubey, Prashant, Deep, Akash, Nogala, Wojciech, Shrivastav, Vishal, and Sundriyal, Shashank
- Subjects
- *
ENERGY conversion , *ENERGY storage , *METAL-organic frameworks , *POWER resources , *CLEAN energy - Abstract
Establishing green and reliable energy resources is very important to counteract the carbon footprints and negative impact of non-renewable energy resources. Metal-organic frameworks (MOFs) are a class of porous material finding numerous applications due to their exceptional qualities, such as high surface area, low density, superior structural flexibility, and stability. Recently, increased attention has been paid to surface mounted MOFs (SURMOFs), which is nothing but thin film of MOF, as a new category in nanotechnology having unique properties compared to bulk MOFs. With the advancement of material growth and synthesis technologies, the fine tunability of film thickness, consistency, size, and geometry with a wide range of MOF complexes is possible. In this review, we recapitulate various synthesis approaches of SURMOFs including epitaxial synthesis approach, direct solvothermal method, Langmuir-Blodgett LBL deposition, Inkjet printing technique and others and then correlated the synthesis-structure-property relationship in terms of energy storage and conversion applications. Further the critical assessment and current problems of SURMOFs have been briefly discussed to explore the future opportunities in SURMOFs for energy storage and conversion applications. [Display omitted] • State of the art information on SURMOF-based energy storage and conversion devices are explored. • SURMOFs are discussed separately in terms of need, preparation and their properties. • SURMOFs as an electrode for energy storage devices are explored in supercapacitors and batteries. • SURMOFs for energy conversion devices are explored in electrocatalysis and Solar cells applications. • Critical assessment and future aspects are also explored for SURMOF based energy storage and conversion devices. [ABSTRACT FROM AUTHOR]
- Published
- 2023
- Full Text
- View/download PDF
36. Diffusion and surface charge studies of waste cow dung derived highly porous carbon as a facile electrode for solid-state supercapacitors.
- Author
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Dubey, Prashant, Shrivastav, Vishal, Gupta, Bhavana, Hołdyński, Marcin, Nogala, Wojciech, and Sundriyal, Shashank
- Subjects
- *
SURFACE charges , *CARBON foams , *SURFACE diffusion , *CARBON electrodes , *SUPERCAPACITORS , *SURFACE charging , *MANURES - Abstract
Carbon-based materials generated from biowaste have recently attracted interest due to their exceptional surface and conductive properties. Cow dung derived porous carbon (CDPC) with a 3D structure and linked pores is synthesized in this study, making it an alternative electrode for supercapacitors (SC). Herein, we studied the diffusion and surface charge contribution and their relationship with the scan rate. Diffusion charge contribution is more prevalent at lower scan rates. Furthermore, a large fraction of surface charge contribution of 69.2 % at a high scan rate of 100 mV/s indicates rapid electrochemical kinetics and hence high-rate performance even at higher current densities. In addition, utilizing a 1 M H 2 SO 4 electrolyte, the CDPC electrode has attained a high specific capacitance value of 210 F/g at 0.5 A/g. Furthermore, symmetrical solid-state SC device displayed high energy density of 36 Wh/kg at good power density of 800 W/kg along with remarkable cyclic stability of 92.6 % after 10,000 charge-discharge cycles. Hence, these findings demonstrate that investigating surface and diffusion charge contributions opens up new avenues for tuning the supercapacitor performance. [Display omitted] • Waste cow dung derived carbon obtained by hydrothermal carbonization and activation • Surface and diffusion charge contribution studies are performed for CDPC electrode. • Solid-state symmetrical SC assembled using two CDPC electrodes and gel electrolyte • Device retains long cycle life of 92.6 % after 10,000 charge-discharge cycles. • Device delivers high energy density of 40 Wh/kg at a power density of 907 W/kg. [ABSTRACT FROM AUTHOR]
- Published
- 2022
- Full Text
- View/download PDF
37. High-Performance Symmetrical Supercapacitor with a Combination of a ZIF-67/rGO Composite Electrode and a Redox Additive Electrolyte.
- Author
-
Sundriyal S, Shrivastav V, Kaur H, Mishra S, and Deep A
- Abstract
The synthesis of a highly porous composite of ZIF-67 and reduced graphene oxide (rGO) using a simple stirring approach is reported. The composite has been investigated as an electrode to be assembled in a supercapacitor. In the presence of an optimized redox additive electrolyte (RAE), that is, 0.2 M K
3 [Fe(CN)6 ] in 1 M Na2 SO4 , the ZIF-67/rGO composite electrode has combined the properties of improved conductivity, high specific surface area, and low resistance. The proposed composite electrode in the three-electrode system shows an ultrahigh specific capacitance of 1453 F g-1 at a current density of 4.5 A g-1 within a potential window of -0.1 to 0.5 V. Further, the ZIF-67/rGO composite electrode was used to fabricate a symmetrical supercapacitor whose operation in the presence of the RAE has delivered high values of specific capacitance (326 F g-1 at a current density of 3 A g-1 ) and energy density (25.5 W h kg-1 at a power density of 2.7 kW kg-1 ). The device could retain about 88% of its initial specific capacitance after 1000 repeated charge-discharge cycles. The practical usefulness of the device was also verified by combining two symmetrical supercapacitors in series and then lighting a white light-emitting diode (illumination for 3 min). This study, for the first time, reports the application of a ZIF-based composite (ZIF-67/rGO) in the presence of an RAE to design an efficient supercapacitor electrode. This proposed design is also scalable to a flexible symmetric device delivering high values of specific capacitance and energy density., Competing Interests: The authors declare no competing financial interest.- Published
- 2018
- Full Text
- View/download PDF
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