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We present the first high spectral resolution mid-infrared survey in the Orion BN/KL region, covering 7.2–28.3 μ m. With SOFIA/EXES, we target the enigmatic source Orion IRc2. While this is in the most prolifically studied massive star-forming region, longer wavelengths and molecular emission lines dominated previous spectral surveys. The mid-infrared observations in this work access different components and molecular species in unprecedented detail. We unambiguously identify two new kinematic components, both chemically rich with multiple molecular absorption lines. The “blue clump” has v _LSR = −7.1 ± 0.7 km s ^−1 , and the “red clump” has 1.4 ± 0.5 km s ^−1 . While the blue and red clumps have similar temperatures and line widths, molecular species in the blue clump have higher column densities. They are both likely linked to pure rotational H _2 emission also covered by this survey. This work provides evidence for the scenario that the blue and red clumps are distinct components unrelated to the classic components in the Orion BN/KL region. Comparison to spectroscopic surveys toward other infrared targets in the region show that the blue clump is clearly extended. We analyze, compare, and present in-depth findings on the physical conditions of C _2 H _2 , ^13 CCH _2 , CH _4 , CS, H _2 O, HCN, ${{\rm{H}}}^{13}\mathrm{CN}$ , HNC, NH _3 , and SO _2 absorption lines and an H _2 emission line associated with the blue and red clumps. We also provide limited analysis of H _2 O and SiO molecular emission lines toward Orion IRc2 and the atomic forbidden transitions [Fe ii ], [S i ], [S iii ], and [Ne ii ].

We present high spectral resolution observations from 12.96 to 13.33 microns toward Orion IRc2 using the mid-infrared spectrograph, Echelon-Cross-Echelle Spectrograph (EXES), at Stratospheric Observatory for Infrared Astronomy (SOFIA). These observations probe the physical and chemical conditions of the Orion hot core, which is sampled by a bright, compact, mid-infrared background continuum source in the region, IRc2. All 10 of the rovibrational C2H2 transitions expected in our spectral coverage are detected with high signal-to-noise ratios (S/Ns), yielding continuous coverage of the R-branch lines from J = 9–8 to J = 18–17, including both ortho and para species. Eight of these rovibrational transitions are newly reported detections. The isotopologue, 13CCH2, is clearly detected with a high S/N. This enabled a direct measurement of the 12C/13C isotopic ratio for the Orion hot core of 14 ± 1 and an estimated maximum value of 21. We also detected several HCN rovibrational lines. The ortho and para C2H2 ladders are clearly separate, and tracing two different temperatures, 226 K and 164 K, respectively, with a non-equilibrium ortho to para ratio (OPR) of 1.7 ± 0.1. Additionally, the ortho and para VLSR values differ by about 1.8 ± 0.2 km s−1, while the mean line widths differ by 0.7 ± 0.2 km s−1, suggesting that these species are not uniformly mixed along the line of sight to IRc2. We propose that the abnormally low C2H2 OPR could be a remnant from an earlier, colder phase, before the density enhancement (now the hot core) was impacted by shocks generated from an explosive event 500 years ago. [ABSTRACT FROM AUTHOR]