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In recent years, the Southern Ocean has experienced extremely low sea ice cover in multiple summers. These low events were preceded by a multidecadal positive trend that culminated in record high ice coverage in 2014. This abrupt transition has led some authors to suggest that Antarctic sea ice has undergone a regime shift. In this study we analyze the satellite sea ice record and atmospheric reanalyses to assess the evidence for such a shift. We find that the standard deviation of the summer sea ice record has doubled from 0.31 million km2 in 1979–2006 to 0.76 million km2 for 2007–22. This increased variance is accompanied by a longer season-to-season sea ice memory. The atmosphere is the primary driver of Antarctic sea ice variability, but using a linear predictive model we show that sea ice changes cannot be explained by the atmosphere alone. Identifying whether a regime shift has occurred is difficult without a complete understanding of the physical mechanism of change. However, the statistical changes that we demonstrate (i.e., increased variance and autocorrelation, and a changed response to atmospheric forcing), as well as the increased spatial coherence noted by previous research, are indicators based on dynamical systems theory of an abrupt critical transition. Thus, our analysis is further evidence in support of a changed Antarctic sea ice system. Significance Statement: In recent years, there have been several summers with extremely low Antarctic sea ice cover, including consecutive record lows in February 2022 and February 2023. Since then, the 2023 winter has seen a remarkably low sea ice growth with an anomaly far below expected climatology. This has led researchers to question whether there has been a regime shift, and we assess the observational evidence for such a shift. In the last decade or so, the variability of summer sea ice has almost doubled, accompanied by a much longer sea ice memory from season to season. These statistical changes, as well an increased spatial coherence noted by other researchers, are consistent with theoretical indicators of a critical transition, or regime shift. [ABSTRACT FROM AUTHOR]

The oceans play a key role in climate regulation especially in part buffering (neutralising) the effects of increasing levels of greenhouse gases in the atmosphere and rising global temperatures. This chapter examines how the regulatory processes performed by the oceans alter as a response to climate change and assesses the extent to which positive feedbacks from the ocean may exacerbate climate change. There is clear evidence for rapid change in the oceans. As the main heat store for the world there has been an accelerating change in sea temperatures over the last few decades, which has contributed to rising sea-level. The oceans are also the main store of carbon dioxide (CO2), and are estimated to have taken up approximately 40% of anthropogenic-sourced CO2 from the atmosphere since the beginning of the industrial revolution. A proportion of the carbon uptake is exported via the four ocean 'carbon pumps' (Solubility, Biological, Continental Shelf and Carbonate Counter) to the deep ocean reservoir. Increases in sea temperature and changing planktonic systems and ocean currents may lead to a reduction in the uptake of CO2 by the ocean; some evidence suggests a suppression of parts of the marine carbon sink is already underway. While the oceans have buffered climate change through the uptake of CO2 produced by fossil fuel burning this has already had an impact on ocean chemistry through ocean acidification and will continue to do so. Feedbacks to climate change from acidification may result from expected impacts on marine organisms (especially corals and calcareous plankton), ecosystems and biogeochemical cycles. The polar regions of the world are showing the most rapid responses to climate change. As a result of a strong ice-ocean influence, small changes in temperature, salinity and ice cover may trigger large and sudden changes in regional climate with potential downstream feedbacks to the climate of the rest of the world. A warming Arctic Ocean may lead to further releases of the potent greenhouse gas methane from hydrates and permafrost. The Southern Ocean plays a critical role in driving, modifying and regulating global climate change via the carbon cycle and through its impact on adjacent Antarctica. The Antarctic Peninsula has shown some of the most rapid rises in atmospheric and oceanic temperature in the world, with an associated retreat of the majority of glaciers. Parts of the West Antarctic ice sheet are deflating rapidly, very likely due to a change in the flux of oceanic heat to the undersides of the floating ice shelves. The final section on modelling feedbacks from the ocean to climate change identifies limitations and priorities for model development and associated observations. Considering the importance of the oceans to climate change and our limited understanding of climate-related ocean processes, our ability to measure the changes that are taking place are conspicuously inadequate. The chapter highlights the need for a comprehensive, adequately funded and globally extensive ocean observing system to be implemented and sustained as a high priority. Unless feedbacks from the oceans to climate change are adequately included in climate change models, it is possible that the mitigation actions needed to stabilise CO2 and limit temperature rise over the next century will be underestimated.

The investigation of multichromophore-containing electro-optic dendritic material demonstrates that the frequently observed asymptotic dependence of electro-optic activity on chromophore number density might be overcome through rational design.

A femtosecond pump-study of the primary events of nitrosyl chloride (CINO) photochemistry in solution is presented. Following 266 nm photolysis, the resulting evolution in optical density is measured for CINO dissolved in acetonitrile, chloroform, and dichloromethane.

A novel approach is developed to simultaneously achieve high first-order hyperpolarizability [beta] values while providing an adjustable dipole moment by linking a strong neutral-ground-state (NGS) nonlinear optical (NLO) chromophore with positive [beta] to a zwitterionic (ZWI) chromophore with negative [beta] in an antiparallel fashion. The results have shown that an antiparallel-aligned NGS chromophore and a zwitterionic chromophore can simultaneously achieve an increase in [beta] and a decrease of the dipole moment.

A series of nonlinear optical (NLO) chromophores incorporating the ferrocenyl (F) group as an electron donor and 2-dicyanomethylene-3-cyano-4-methyl 1-2,5-dihydrofuran (TCF) derivatives as electron acceptors is discussed. The excellent agreement between the theoretical and experimental beta values demonstrates that a linear relation exists between the hyperpolarizability and the bond length alteration.

Author(s): Grégory Beaugrand (corresponding author) [1, 2]; Keith M. Brander [3]; J. Alistair Lindley [2]; Sami Souissi [1]; Philip C. Reid [2] The Atlantic cod (Gadus morhua L.) has been [...]

A study was conducted to describe the first examination of the early-time photo dissociation dynamics of isopropyl nitrate (IPN) in the condensed phase using absolute resonance Raman intensity analysis (RRIA). Comparison of the results in cyclohexane and acetonitrile revealed that the excited-state structural evolution was solvent dependent.

Sixth-order anharmonic force field of malonaldehyde along the two proton-transfer double-well coordinates and the four O-H and C=O stretching modes were constructed at the MP2/6-31G(d,p) level. The coherent infrared vibrational spectra were predicted using the virbational eigenstates.