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The objective of this study was to evaluate changes in distribution and quality of organic matter in light and heavy fractions of a medium-texture Red Latosol under different uses and management practices in Capinópolis, Brazil. Soil samples were collected from different layers in the profile (0–5, 5–10, and 10–20 cm). The following treatments were evaluated: NTs, no till (no tillage) for 4 years with maize (silage) / soybean in succession; NTg, no till for 4 years with maize/maize/maize/soybean in succession; NTtf, no till for 3 years with tifton (hay) and soybeans in the last year; CS, about 30 years with conventional cultivation system (maize/soybean) with only soybean in the past 4 years; and NF, native forest. The heavy fraction contributed 75–98% of total carbon and 94–99% of total nitrogen, indicating that most carbon and nitrogen in the soil are associated with the mineral fraction, which is fundamental for the maintenance of their stocks. Tifton grass in no tillage was efficient in increasing the amounts of light fraction (free and occluded). Increases of occluded light fraction in no-till systems were greater than in conventional cultivation system. The light fraction was shown to be sensitive to soil cultivation and can be considered indicative of soil degradation. Light-fraction analysis by Fourier transform infrared spectroscopy (FTIR) allowed the study of changes in the chemical structure of these fractions under different uses and management practices. Occluded light fraction was shown to be more recalcitrant and condensed than the free light fraction. The surface layer in the conventional cultivation system has a more aromatic and condensed free light fraction than in no-tillage system. In general, the upper layers were less aromatic than the deepest ones. [ABSTRACT FROM AUTHOR]

The use of treated pulp mill effluent on eucalyptus plantation appears to be an attractive option for plant nutrition and water supply. It also constitutes a supplementary treatment process and a final disposal option for the mill effluent. This study aimed at the investigation and evaluation of the effects of bleached kraft pulp mill treated effluent on three typical Brazilian soils used for eucalyptus plantation. The effluent was characterized and five different application rates, defined according to the load of sodium, were tested in controlled environment experiments (greenhouse). After effluent application over a six month period an increase in the salinity of the studied soils was observed, although no soil dispersion was detected. The low content of some nutrients in the treated effluent indicated the need for fertilizer complementation. In general, the best biomass productivity and plant growth results were obtained in fine textured soil at a loading rate of 6.49tNa ha-1. The good response of the soil-plant system under different effluent application rates showed the feasibility for the eucalyptus irrigation if adequate management practices and monitoring are carried out. [ABSTRACT FROM AUTHOR]

The effect of the introduction of an agrosylvopasture (SASP) system on the changes in the carbon (C) of the soil and its lability were studied. Since 1993, this system has been annually implanted in Paracatu, MG. It was planted under eucalyptus forest abandoned after three cuts, when the brachiaria grass was established. The eucalyptususes were planted at 10×4 m spacing, and the following crops have been grown between the lines: rice in the first year, soybean in the second, and brachiaria in the third. After the third year, pasture of the meat cattle begins on brachiaria and remains until the end of the system cycle that was foreseen for the 11th year. A savannah area and another one with eucalyptusus under a conventional system were used as references to natural condition and the way the area is used before plantation of the SASP, respectively. Some samples aged 1, 2, 3, 6, and 10 years were collected in SASP. According to the obtained results, the following conclusions were drawn: (i) the C contents and stocks were affected before and during the plantation of the SASP by the use and management of SASP, as they were reduced in the first years of the system establishment but improved at the 10th year; (ii) the C from the particulate free light fraction (CFLLP) that was extracted by potassium permangate (KMnO4) was sensitive to the use and management, and so reflected the changes in total organic C (TOC); (iii) the more labile fractions of C that were extracted at different concentrations of sulfuric acid (H2SO4) satisfactorily reflected the changes in both use and management, whereas the less labile fractions were just slightly affected; and (iv) the C management index (IMC) calculated from CFLLP was the most sensitive to the changes in use and management. However, when calculated from the C fraction 1 extracted by 3M H2SO4 (CF1), it showed better reliability. [ABSTRACT FROM AUTHOR]

Rice husks, coffee bean skins, sugar cane bagasse, maize cobs, saw dust and fine charcoal dust were evaluated as filters for the removal of heavy metals (Cu and Zn) from the waste water of swine raising installations. The specific mass, pH and the sum of bases and removable adds were determined to characterize each of the filter materials. Each filtering material was placed in a 100 mm diameter, 600 mm long, PVC column to a height of 500 mm under 12,500 N m-2 of compression. Chemical and physical analyses were determined on effluent samples collected for each 1.5 l. up to a total of 15 l. The organic materials reduced the concentration of sediment solids (>90%), total solids (up to 33%) and Cu (up to 43.6%) of the inffluent but had little or no effect on Zn concentration. [ABSTRACT FROM AUTHOR]

Plant root exposure to soil aluminum (Al) depends on the soil solution Al concentration and transport to the root by diffusion. Changes in Al diffusive flux for two Oxisols was measured under laboratory conditions as a function of pH, water matric potential, and applications of gypsum, potassium chloride, and calcium phosphate. Double‐faced cation exchange resin sheets served as sinks for Al transported during 10‐day incubations through chambers containing 314 cm3 of soil. Across a range of soil pH values from 4.5 to 5.5, maximum diffusive flux of Al occurred at pH values of 4.7–4.8 in both soils and corresponded to increases of 2.2–3.0% relative to the unlimed treatment. Between pH values of 4.7–4.8 and 5.4, diffusive flux of Al decreased by 38 and 46% in the two Oxisols. Diffusive flux of Al decreased by 16–20% for the two Oxisols as soil water potentials decreased from ‐10 to ‐200 kPa. Magnitude of the reductions in diffusive flux of Al with decreasing soil water potential were less than those reported for diffusive flux of phosphorus (P) in prior investigations. Diffusive flux of Al increased by as much as 4‐fold with additions of CaSO4 and KCl, which increased the soil solution Al concentration. Additions of 400 mg P dm‐3 of soil had no effect on Al diffusion in either Oxisol. [ABSTRACT FROM PUBLISHER]

The removal of Cu, Ni and Zn from electroplating effluents by adsorption in cattle manure vermicompost has been discussed. A glass column 38 cm long and 7 cm i.d. was loaded with cattle manure vermicompost and effluents were passed through it. The metal concentrations were measured in the elutant. The experiments on adding effluent aliquots into the columns were continued until the metal concentrations in the elutant reached the maximum values established for effluent discharges in water courses by the Brazilian quality criteria, i.e., Cu=1.0 mg L(-1), Ni=2.0 mg L(-1), and Zn=5.0 mg L(-1). The amount of Cu retention by the vermicompost was determined at the natural effluent pH (2.0). The Zn and Ni retentions were evaluated at the natural effluent pH (6.9 and 7.4, respectively) as well pH 2.0. Vermicompost residues obtained from this process were used for lettuce cultivation. The vermicompost was found to be efficient in removing metals from the electroplating wastes, as well as in the increase of its pH values. Metal retention values were close to 100%. The Cu concentrations in lettuce leaves from the treatment with vermicompost enriched with this metal were below the range of critical toxicity level to plants, i.e., from 20 to 100 mg L(-1). However, the estimated Cu concentrations in the roots from the treatment with vermicompost enriched with Cu were much larger than that of the treatment with the natural vermicompost, reaching 246.3 mg L(-1). The Ni and Zn concentrations in lettuce leaves from the treatments, with vermicomposts enriched with the respective metals, were above the range of critical toxicity levels to plants, i.e., from 10 to 50 mg kg(-1) and from 15 to 30 mg kg(-1), respectively. However, no symptom of toxicity was found visually. Larger accumulations of Cu, Ni and Zn were found in the lettuce leaves than in the roots after the treatments with the uncontaminated vermicompost. A greater absorption of Cu and Ni by roots was found in treatments with vermicompost enriched with these elements, whereas Zn was found preferentially in the leaves. The statistical analysis was done by analyses of variance and regression.

Aluminum (Al) tolerance mechanisms in crop plants have been extensively researched, but our understanding of the physiological mechanisms underlying Al tolerance in trees is still limited. To investigate Al tolerance in eucalypts, seedlings of six species (Eucalyptus globulus Labill., Eucalyptus urophylla S.T. Blake, Eucalyptus dunnii Maiden, Eucalyptus saligna Sm., Eucalyptus cloeziana F. J. Muell. and Eucalyptus grandis w. Hill ex Maiden) and seedlings of six clones of Eucalyptus species were grown for 10 days in nutrient solutions containing Al concentrations varying from 0 to 2.5 microM (0 to 648 microM Al3+ activities). Root elongation of most species was inhibited only by high Al3+ activities. Low to intermediate Al3+ activities were beneficial to root elongation of all species and clones. Among the species tested, E. globulus and E. urophylla were more tolerant to Al toxicity, whereas E. grandis and E. cloeziana were more susceptible to Al-induced damage. Although E. globulus seedlings were tolerant to Al toxicity, they were highly sensitive to lanthanum (La), indicating that the tolerance mechanism is specific for Al. Fine roots accumulated more Al and their elongation was inhibited more than that of thick roots. In E. globulus, accumulation of Al in root tips increased linearly with increasing Al concentration in the nutrient solution. The majority of Al taken up was retained in the root system, and the small amounts of Al translocated to the shoot system were found mainly in older leaves. No more than 60% of the Al in the thick root tip was in an exchangeable form in the apoplast that could be removed by sequential citrate rinses. Gas chromatography/mass spectrometry and ion chromatography analyses indicated that root exposure to Al led to a greater than 200% increase in malic acid concentration in the root tips of all eucalypt species. The increase in malate concentration in response to Al treatment correlated with the degree of Al tolerance of the species. A small increase in citric acid concentration was also observed in all species, but there were no consistent changes in the concentrations of other organic acids in response to Al treatment. In all eucalypt species, Al treatment induced the secretion of citric and malic acid in root exudates, but no trend with respect to Al tolerance was observed. Thus, although malate and citrate exudation by roots may partially account for the overall high Al tolerance of these eucalypt species, it appears that tolerance is mainly derived from the internal detoxification of Al by complexation with malic acid.