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In regions where drought has become a common occurrence for most of the year and where agriculture is the main economic activity, the development of hydro-agricultural systems has made it possible to improve water management. Despite this, the intensification of agriculture combined with climate change leads to a potential decrease in water quality and water management practices are essential to improve agro-environmental sustainability. The aim of this study was to assess the water quality for irrigation and potential ecological status of the reservoir (using support chemical parameters). The results showed biological oxygen demand values above the maximum stipulated for an excellent ecological potential in all sampling periods except April 2018 and December 2020 (with the highest values of 10 mg L−1 O2 in dry periods). Most of the total nitrogen concentrations (TN) surpassed those stipulated for a good ecological potential (0.96 ≤ TN ≤ 2.44 mg L−1 N). In fact, TN and total suspended solids were the main parameters used for water classification. From the perspective of irrigation and according to FAO guidelines regarding infiltration rate, these waters presented light to moderate levels of restrictions. Thus, the results revealed that the decrease in the water quality status and its possible impact on the soil infiltration rate can be related, in part, to the meteorological conditions and to the intensive agricultural practices developed around the drainage basin. Despite that, as the Lage reservoir is part of Brinches–Enxoé hydraulic circuit, the water recirculation is also an important factor that may have affected the results obtained. Furthermore, the experimental design, integrating ecological status, irrigation parameters, and the impact on soil systems; using the same parameters from different perspectives; allowed us to have a global idea of water contamination and its impact on agroecosystems, improving river basin management processes. [ABSTRACT FROM AUTHOR]

The evaluation of the spatial and temporal variability of soil properties can be valuable to improve crop productivity and soil health. A study of soil properties was carried out in southern Portugal, in three farm fields with irrigated annual crops (layers 0–20 cm and 20–40 cm), over three years. Factor Analysis (FA) and Discriminant Analysis (DA) were used to analyze the data. With FA, the observed variables were grouped into a smaller number of latent variables related to soil attributes. Discriminant Analysis was used to classify and identify the most dominant attributes and indicators for the time and space variability of soil parameters. The FA performed for the surface layer included factors related to texture, water and nutrient retention capacity, chemical composition, and soil fertility. In the sub-surface layer, the factor structure was similar, with four factors related to texture, chemical composition, nutrient availability, and soil fertility. The most influential factors and variables in temporal discrimination (sampling dates) in both layers were those related to chemical composition, with electric conductivity as the preponderant indicator. As for the spatial differentiation (fields), the dominant factor in the surface layer was texture, and in the sub-surface layer, nutrient availability. The most important discriminant indicators of spatial variability were fine sand proportion and available potassium, respectively, for the surface and sub-surface layers. The results obtained showed potential for the multidimensional and integrated assessment of patterns of temporal and spatial variation of soil functions from agricultural practices or soil degradation processes. [ABSTRACT FROM AUTHOR]

This study aimed to evaluate soil physicochemical characteristics (pH, electrical conductivity, organic matter, total N, and extractable P and K), and potentially toxic elements (As, Cu, Pb, and Zn), in non-active mines located in the Portuguese sector of the Iberian Pyrite Belt (IPB). A total of 70 sampling sites were surveyed at Aljustrel and Lousal, in areas already rehabilitated, and at São Domingos, where rehabilitation was only beginning. The soils at São Domingos were very heterogeneous, with extreme values for some properties (e.g., minimum soil pH 2.0 and maximum As concentration, 4382.8 mg kg−1 dry weight basis (DW)). Aljustrel was the site that presented soils with a higher total As, Cu, Pb, and Zn concentration (median values: 441.5, 545.9, 1396.8, and 316.5 mg kg−1 DW, respectively), above the soil quality guidelines values proposed by the Portuguese Environmental Agency (18, 230, 120, and 340 mg kg−1 DW, respectively). A principal component analysis identified the most relevant soil properties to explain the data variance, which were the soil pH and Pb total concentration, followed by Cu and Zn total concentrations, allowing a separation of Aljustrel from the other mines. Pearson correlation coefficients revealed very strong associations between Pb and As, markedly found at higher concentrations in São Domingos, whereas Aljustrel had an elevated concentration of As and Pb, but also of Cu and Zn. It is evident the risk that persists in the Aljustrel mine area, which was not alleviated by the "dig, dump, and cover" techniques that were implemented to rehabilitate the area. [ABSTRACT FROM AUTHOR]

The use of organic wastes as soil amendments can be an important measure to improve soil quality and reduce waste accumulation and landfilling. However, the potential contaminant loads of such wastes, can be a source of environmental concern. Consequently, legislation has been developed to regulate the use of these wastes in agricultural soils. However, the regulations only consider chemical parameters, which are insufficient to establish the level of environmental risk. A possible solution is the use of species sensitivity distributions (SSDs), employing ecotoxicological data from test batteries that could be incorporated into legislation. In the present study, 2 different hazardous concentrations affecting 5 and 50% of the soil community (HC5 and HC50, respectively) were determined using ecotoxicological data (effect concentrations, 10 and 50% [EC10 and EC50, respectively]) for 5 different wastes. The results demonstrate that, as expected, current legislative thresholds do not translate to environmental risk/protection and that SSDs may be an important tool allowing the simple inclusion and interpretation of ecotoxicological data from test batteries in legislation. On the other hand, SSDs must be used with caution because there are still doubts about their actual value in risk prediction and about which estimates provide adequate protection. For instance, the use of HC50EC10 values is not recommended; these values overlap with the more conservative HC5EC50 data, highlighting the fact that the use of lower effect concentrations may not always provide the most protective approach. Also, hazardous concentrations need to be calibrated at the field or semifield level, to verify environmental protection in different soils/environments and the adequacy of standard test organisms. Environ Toxicol Chem 2019;38:1569–1576. © 2019 SETAC [ABSTRACT FROM AUTHOR]

This study aimed to assess the potential impact on soil porewater, surface and groundwater from the beneficial application of organic wastes to soil, using their eluates and acute bioassays with aquatic organisms and plants: luminescence inhibition of Vibrio fischeri (15 and 30 min), Daphnia magna immobilization (48 h), Thamnocephalus platyurus survival (24 h), and seed germination of Lolium perenne (7 d) and Lactuca sativa (5 d). Some organic wastes’ eluates promoted high toxic responses, but that toxicity could not be predicted by their chemical characterization, which is compulsory by regulatory documents. In fact, when organisms were exposed to the water-extractable chemical compounds of the organic wastes, the toxic responses were more connected to the degree of stabilization of the organic wastes, or to the treatment used to achieve that stabilization, than to their contaminant load. That is why the environmental risk assessment of the use of organic wastes as soil amendments should integrate bioassays with eluates, in order to correctly evaluate the effects of the most bioavailable fraction of all the chemical compounds, which can be difficult to predict from the characterization required in regulatory documents. According to our results, some rapid and standardized acute bioassays can be suggested to integrate a Tier 1 ecotoxicological evaluation of organic wastes with potential to be land applied, namely luminescence inhibition of V. fischeri , D. magna immobilization, and the germination of L. perenne and L. sativa . [ABSTRACT FROM AUTHOR]

Nine different samples of sewage sludges, composts and other representative organic wastes, with potential interest to be used as agricultural soil amendments, were characterized: municipal sewage sludge (SS1 and SS2), agro industrial sludge (AIS), municipal slaughterhouse sludge (MSS), mixed municipal solid waste compost (MMSWC), agricultural wastes compost (AWC), compost produced from agricultural wastes and sewage sludge (AWSSC), pig slurry digestate (PSD) and paper mill wastes (PMW). The characterization was made considering their: (i) physicochemical parameters, (ii) total and bioavailable heavy metals (Cd, Cr, Cu, Ni, Pb, Zn and Hg), (iii) organic contaminants, (iv) pathogenic microorganisms and (v) stability and phytotoxicity indicators. All the sludges, municipal or other, comply with the requirements of the legislation regarding the possibility of their application to agricultural soil (with the exception of SS2, due to its pathogenic microorganisms content), with a content of organic matter and nutrients that make them interesting to be applied to soil. The composts presented, in general, some constraints regarding their application to soil, and their impairment was due to the existence of heavy metal concentrations exceeding the proposed limit of the draft European legislation. As a consequence, with the exception of AWSSC, most compost samples were not able to meet these quality criteria, which are more conservative for compost than for sewage sludge. From the results, the composting of sewage sludge is recommended as a way to turn a less stabilized waste into a material that is no longer classified as a waste and, judging by the results of this work, with lower heavy metal content than the other composted materials, and without sanitation problems. [ABSTRACT FROM AUTHOR]

Both sectors of the Iberian Pyrite Belt, Portuguese and Spanish, have been exploited since ancient times, but more intensively during and after the second half of the 19th century. Large volumes of polymetallic sulfide ore were extracted in open pits or in underground works, processed without environmental concerns, and the generated waste rocks and tailings were simply deposited in the area. Many of these mining sites were abandoned for years under the action of erosive agents, leading to the spread of trace elements and the contamination of soils, waters and sediments. Some of these mine sites have been submitted to rehabilitation actions, mostly using constructive techniques to dig and contain the contaminated tailings and other waste materials, but the remaining soil still needs to be treated with the best available techniques to recover its ecosystem functions. Besides the degraded physical structure and poor nutritional status of these soils, they have common characteristics, as a consequence of the pyrite oxidation and acid drainage produced, such as a high concentration of trace elements and low pH, which must be considered in the remediation plans. This manuscript aims to review the results from studies which have already covered these topics in the Iberian Pyrite Belt, especially in its Portuguese sector, considering: (i) soils' physicochemical characteristics; (ii) potentially toxic trace elements' concentration; and (iii) sustainable remediation technologies to cope with this type of soil contamination. Phytostabilization, after the amelioration of the soil's properties with organic and inorganic amendments, was investigated at the lab and field scale by several authors, and their results were also considered. [ABSTRACT FROM AUTHOR]

Irrigation-induced or secondary salinization can occur when salts are introduced by irrigation water and accumulate within the root zone due to insufficient leaching. Mediterranean regions are especially susceptible, given the predominant climate and the expanding of irrigation areas. In this study, two indices to assess the risk of salinization (RSA) and sodification (RSO), previously applied at a regional scale, were used in a hydro-agricultural area (AHA) in Southern Portugal, in ten crop fields. Information on climate, irrigation water quality, soil characteristics, and land use was obtained from large databases and from local data. The results revealed the feasibility of using the RSA and RSO indices both on large and smaller scales, seeing as most of the area in the monitored crop fields presented the same risk classes (62% in RSA and 78% in RSO). Deviations were due to the reduction in scores for drainage and, in the case of RSO, the assigned irrigation method based on the land occupation class. Considering that different spatial scales of risk assessment are associated with different objectives and management options, a risk management framework was outlined following a multi-scale perspective for mitigation actions in salt-sensitive areas, ranging from territorial planning to the adoption of on-farm practices that can contribute to the sustainability of irrigated agriculture. [ABSTRACT FROM AUTHOR]

Nowadays, the Mediterranean freshwater systems face the threat of water scarcity, along with multiple other stressors (e.g., organic and inorganic contamination, geomorphological alterations, invasive species), leading to the impairment of their ecosystem services. All these stressors have been speeding up, due to climate variability and land cover/land use changes, turning them into a big challenge for the water management plans. The present study analyses the physicochemical and phytoplankton biomass (chlorophyll-a) dynamics of a large reservoir, in the Mediterranean region (Alqueva reservoir, Southern Portugal), under diverse meteorological conditions and land cover/land use real scenarios (2017 and 2018). The most important stressors were identified and the necessary tools and information for a more effective management plan were provided. Changes in these parameters were further related to the observed variations in the meteorological conditions and in the land cover/land use. The increase in nutrients and ions in the water column, and of potentially toxic metals in the sediment, were more obvious in periods of severe drought. Further, the enhancement of nutrients concentrations, potentially caused by the intensification of agricultural activities, may indicate an increased risk of water eutrophication. The results highlight that a holistic approach is essential for a better water resources management strategy. [ABSTRACT FROM AUTHOR]

Four streams in the Guadiana watershed were followed up to assess hydrogeomorphological and physicochemical characteristics, and to analyze its correlation with land use/land cover (LULC), analyzing their possible influence in reservoir water quality and possible influence in the reservoir water quality. The highest amounts of organic descriptors and nutrients were quantified in streams with the major percentage of olive groves and vineyards and urban land cover classes. Streams more influenced by agro-silvo-pastoral class presented better water quality, as this type of LULC acts as a buffer of the contamination runoff. The results highlighted that the hydrogeomorphology of the streams may influence the transfer of pollutants loads to reservoirs. Hence, in intermittent streams characterized by coarse particles in the sediment, high amounts of pollutants are accumulated when the flow ceases, and are further transported to the reservoirs when the flow retakes. On the contrary, streams with sediments characterized by a great percentage of fine particles and organic matter do not induce so much stress in reservoirs, since these allow the adsorption of nutrients and trace elements, without their transfer to reservoirs. [ABSTRACT FROM AUTHOR]

Fly ash (FA) from biomass combustion and biological sludge (S), both wastes from the pulp and paper industry, were granulated in different proportions (90% FA + 10% S, and 70% FA + 30% S w/w, dry weight basis, dw) and used to recover the functionality of soils affected by mining activities (Aljustrel, Iberian Pyrite Belt), with and without the application of municipal solid waste compost (MSWC). Application doses of both mixtures were 2.5, 5.0 and 10% (w/w, dw). These materials corrected soil acidity to circumneutral values and increased extractable P and K concentrations. A significant increase in soil organic matter (from 0.6 to 0.8–1.5% w/w, dw) and N content (from 0.04 to 0.09–0.12% w/w, dw) was also observed, but only when MSWC was applied. The soil was already heavily contaminated with Cu, Pb and Zn and the application of amendments did not increase their pseudo-total concentrations. The CaCl 2 extractable fractions of both Cu and Zn decreased to very low values. The improvement in soil quality, compared to fertilizer only treatment, was further evidenced by the increase in some soil enzymatic activities (dehydrogenase, β-glucosidase and cellulase), with a better response for the granules with the higher proportion of biological sludge, as well as by the decrease in the soil-water extract toxicity towards different organisms (Daphnia magna , Thamnocephalus platyurus , and Pseudokirchneriella subcapitata). Agrostis tenuis germinated and grew during the first month only in the amended pots, but, after that, a considerable phytotoxic effect was evident. This was mainly attributed to salt stress or to some specific ionic toxicity. In conclusion, to establish a long-term plant cover in mining soils amended with biomass ash-based materials, the selection of plants with higher resistance to salinity and/or the stabilization of the amendments, to reduce their soluble salt content, is recommended. Unlabelled Image • Biomass ash and biological sludge from a paper mill were used to amend mine soils. • Soil pH increased to neutral values and Cu and Zn CaCl 2 extractability decreased. • Compost application was essential to increase soil organic matter, N and P content. • Some soil enzymatic activities increased, and soil-water extract toxicity decreased. • However, high salinity promoted phytotoxicity to Agrostis tenuis Sibth. [ABSTRACT FROM AUTHOR]

Abstract The mine abandonment is generally associated with the release of potentially toxic metals into the environment, which may depend on metals speciation, soil properties and climate conditions. The goal of the present work was to assess the environmental impact of the abandoned Pb-Zn mine "Las Musas" (Spain) using an integrative approach. The impact on soils and surface waters was performed using: chemical parameters, quantification of potentially toxic metals (Cd, Cu, Pb and Zn), and ecotoxicological responses using lethal and sub-lethal bioassays with organisms' representative of different trophic level ((soil: Eisenia fetida (mortality and reproduction test); Latuca sativa and Lollium perenne (seedling emergence); and water: Vibrio fischeri (luminescence inhibition), Daphnia magna (immobility and reproduction test), Thamnocephalus platyurus (mortality), Pseudokirchneriella subcapitata (growth inhibition)). The results showed soils with neutral to slight alkaline pH (7.64–8.18), low electric conductivity (125–953 μS/cm) and low organic matter levels (0.20–1.85%). For most of the soil samples, Pb was the only metal which surpassed the limit proposed by the Canadian soil quality guidelines, with values ranging from 42.2 to 181.4 mg/kg. The ecotoxicological results showed that the soils with the highest levels of Pb induced a decrease on E. fetida reproduction and on L. sativa germination, indicating negative impacts on the habitat function. The analysis of the surface waters showed levels of Zn surpassing the legal limit adopted from the Water Framework Directive (37.0 to 69.0 μg/L). The ecotoxicological results highlight the importance of bioassays that evaluate the behavior of species, when assessing the risk of mining areas with non-acid soils and waters with high nutrients/organic matter concentrations and low concentrations of potentially toxic metals. The results indicated a moderate environmental risk from potentially toxic metals, at the areas analyzed around the Azuaga mine. Graphical abstract Unlabelled Image Highlights • Environmental impact of an old abandoned Pb-Zn mine on soil and water was assessed. • Soils still have high Pb levels and restricted habitat function to soil organisms. • Water pollution with metals is low and mixed with other anthropogenic pollutants. • Environmental risk is limited in the area of the study. • Risk assessment of non-acid mining areas should integrate toxicological behavior responses. [ABSTRACT FROM AUTHOR]

Using organic wastes, as soil amendments, is an important alternative to landfilling with benefits to soil structure, water retention, soil nutrient and organic matter concentrations. However, this practice should be monitored for its environmental risk due to the frequent presence, of noxious substances to soil organisms. To evaluate the potential of eight organic wastes with different origins, as soil amendments, reproduction tests with four soil invertebrate species ( Folsomia candida , Enchytraeus crypticus , Hypoaspis aculeifer , Eisenia fetida ) were performed using gradients of soil–waste mixtures. Results obtained demonstrated that contaminant concentrations required by current legislation might not be a protective measure for the soil ecosystem, as they do not properly translate the potential toxicity of wastes to soil invertebrates. Some wastes with contaminant loadings below thresholds showed higher toxicity than wastes with contaminants concentrations above legal limits. Also, test organism reproduction was differently sensitive to the selected wastes, which highlights the need to account for different organism sensitivities and routes of exposure when evaluating the toxicity of such complex mixtures. Finally this study shows that when combining chemical and ecotoxicological data, it is possible to postulate on potential sources of toxicity, contributing to better waste management practices and safer soil organic amendment products. [ABSTRACT FROM AUTHOR]

The Guadiana Basin is a transnational basin, presenting historical contamination with potentially toxic metals (PTM), which origin can be both natural and anthropogenic. This study explores the use of a set of observational, chemical and ecotoxicological assays with Heterocypris incongruens, Vibrio fischeri, Pseudokirchneriella subcapitata, Thamnocephalus platyurus, identifying the most sensitive to be included in a toolbox to analyze the quality of freshwater sediments related to this type of contamination. The study included the analysis of a reservoir and streams sediments of Guadiana basin, in two consecutive years with different climate conditions 2017 (dry year) and 2018 (normal year). The results showed high chemical variability along the basin, with greater contamination with PTM in the reservoir sediments. The calculated Enrichment Factors (EF) indicated high anthropogenic contamination by Cd, followed by Pb (EF > 1.5). The geoaccumulation index (I geo) revealed that the sediments were severely polluted with Cd, and slightly polluted with Pb and Cu, inducing a higher sublethal toxicity to Heterocypris incongruens. Among the parameters evaluated, and after the use of multivariate statistical techniques, the toolbox for assessing sediments quality, in similar climate and geological conditions, should include the analysis of: meteorology, land use/cover in the area, granulometry, organic matter content, PTM concentrations, contamination indices (e.g., I geo and EF), and sublethal bioassays with H. incongruens (total sediment analysis) and Vibrio fisheri luminescence inhibition (pore water analysis). [Display omitted] • Sediment quality toolbox with observational, analytical and ecotoxicological tests. • CORINE Land use/Land cover essential to management processes. • EF and I geo indices needed to understand historical contamination. • Ecotoxicological assess of sediment, with lethal and sub-lethal endpoints. • H. incongruens should be included in sediment quality studies. [ABSTRACT FROM AUTHOR]