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This study established a residue detection method based on the QuEChERS pre-treatment method and combined it with high-performance liquid chromatography–tandem mass spectrometry to test six herbicides (metamitron, clopyralid, desmedipham, phenmedipham, ethofumesate, and haloxyfop-p-methyl) in sugar beet plants, soil, and roots. The degradation dynamics and terminal residues of each herbicide in sugar beets were analysed. Finally, the dietary risks of various herbicides in sugar beets were evaluated based on the dietary structure of Chinese people, and the risk quotient values were below 100%. Using this detection method, all reagents exhibited good linearity (0.9724 ≤ R2 ≤ 0.9998), The limit of quantification (LOQ) ranged from 0.01 to 0.05 mg/L, the matrix effect ranged from −1.2% to −50%, the addition recovery rate ranged from 77.00% to 103.48%, and the relative standard deviation ranged from 1.61% to 16.17%; therefore, all indicators of this method met the residue detection standards. Under field conditions, the half-lives (t1/2) ranged about 0.65 ∼ 2.96 d and 0.38 ∼ 27.59 d in sugar beet plants and soil, respectively. All herbicides were easily degraded in sugar beet plants and soil (t1/2 < 30 d). The terminal residue amounts in the beet plants, soil, and roots ranged from < LOQ to 0.243 mg/kg. The dietary risk assessment of each pesticide was conducted based on the residual median of the terminal residues and the highest residual values on the edible part of the beetroot. The chronic exposure risk quotient (RQc) and acute exposure risk quotient (RQa) values were < 100%, indicating that the residue of each pesticide in beetroot posed low risks to consumers in China at the recommended dosage.

ABSTRACTTerrestrial plants can influence the growth and health of adjacent plants through interspecific interaction. Here, the mechanisms of interspecific plant interaction on microbial function and nutrient utilization in the plant-soil interface (non-rhizosphere soil, rhizosphere soil, and root) were studied by soybean- and potato-poplar intercropping. First, metagenomics showed that soybean- and potato-poplar intercropping influenced the composition and co-occurrence networks of microbial communities in different ecological niches, with higher stability of the microbial community in soybean intercropping. Second, the gene abundance related to carbon metabolism, nitrogen cycling, phosphorus cycling, and sulfur cycling was increased at the poplar-soil interface in soybean intercropping. Moreover, soybean intercropping increased soil nutrient content and enzymatic activity. It showed higher metabolic potential in nutrient metabolism and transportation. Third, functional microorganisms that influenced nutrient cycling and transportation in different intercropping have been identified, namely Acidobacteria, Sphingomonas, Gemmatimonadaceae, Alphaproteobacteria, and Bradyrhizobium. Therefore, intercropping can construct microbial communities to alter metabolic functions and improve nutrient cycling and absorption. Interspecific plant interactions to influence the microbiome were revealed, opening up a new way for the precise regulation of plant microbiome.IMPORTANCEPoplar has the characteristics of wide distribution, strong adaptability, and fast growth, which is an ideal tree species for timber forest. In this study, metagenomics and elemental analysis were used to comprehensively reveal the effects of interspecific plant interactions on microbial communities and functions in different ecological niches. It can provide a theoretical basis for the development and application of the precise management model in poplar.

Abstract Study design Retrospective study. Objectives To explore the incidence and risk factors for symptomatic adjacent segment disease (ASD) in patients enveloped in degenerative lumbar diseases after minimally invasive transforaminal lumbar interbody fusion (MIS-TLIF). Methods Data were retrospectively analyzed on 744 patients who underwent MIS-TLIF for degenerative lumbar diseases in our hospital from October 2012 to December 2018. The patients were divided into the ASD group and non-ASD (N-ASD) group on the basis of developing ASD at follow-up, and then the incidence of ASD was calculated. Clinical and radiological risk factors were assessed over time to determine their association with ASD by excluding less important factors. Results Data were missing for 26 patients, while a total of 718 patients were successfully monitored after MIS-TLIF. Of the 718 individuals participated in the study, 34 (4.7%) patients plagued by ASD required surgical intervention. The average onset time of ASD was 62.7 ± 15.1 months. Univariate analysis results shows that age, bone mineral density (BMD), body mass index (BMI), preoperative adjacent intervertebral disc height and preoperative adjacent segment disc degeneration were significantly different between the ASD and N-ASD groups (p

Butralin can effectively mitigate the spreading of weeds in ginseng fields, however, the dissipation and residues of butralin in ginseng have not been investigated. In this study, we established a high-performance liquid chromatography tandem mass spectrometry (HPLC-MS/MS) method to determine the butralin residue and its dissipation in ginseng and its dietary intake risk. The mean recoveries of butralin in ginseng (fresh, dried, plants, and soil) ranged from 93.1–107.5% with relative standard deviations of 0.7–6.4%. The half-lives of butralin in ginseng plant and soil were 10.81–18.91 days, and its final residues in ginseng, dried gingeng, gingeng plant, and soil were −4, which suggests that the consumption of butralin-treated ginseng during the harvest period does not affect human health.

Interplay between lattice, orbital, magnetic and nematic degrees of freedom is crucial for the superconductivity in Fe-based materials. Here, the authors demonstrate the subdominant roles of pure lattice distortions and/or orbital ordering in BaFe2As2 by characterizing the in-plane magnetic susceptibility anisotropy.

High-temperature superconductivity in the Fe-based materials emerges when the antiferromagnetism of the parent compounds is suppressed by either doping or pressure. Closely connected to the antiferromagnetic state are entangled orbital, lattice, and nematic degrees of freedom, and one of the major goals in this field has been to determine the hierarchy of these interactions. Here we present the direct measurements and the calculations of the inplane uniform magnetic susceptibility anisotropy of BaFe2As2, which help in determining the above hierarchy. The magnetization measurements are made possible by utilizing a simple method for applying a large symmetry-breaking strain, based on differential thermal expansion. In strong contrast to the large resistivity anisotropy above the antiferromagnetic transition at TN, the anisotropy of the in-plane magnetic susceptibility develops largely below TN. Our results imply that lattice and orbital degrees of freedom play a subdominant role in these materials. [ABSTRACT FROM AUTHOR]

The nature of the hidden-order (HO) state in URu2Si2 remains one of the major unsolved issues in heavy-fermion physics. Recently, torque magnetometry, x-ray diffraction, and elastoresistivity data have suggested that the HO phase transition at THO≈ 17.5 K is driven by electronic nematic effects. Here, we search for thermodynamic signatures of this purported structural instability using anisotropic thermal expansion, Young's modulus, elastoresistivity, and specific-heat measurements. In contrast to the published results, we find no evidence of a rotational symmetry breaking in any of our data. Interestingly, our elastoresistivity measurements, which are in full agreement with published results, exhibit a Curie-Weiss divergence, which we however attribute to a volume and not to a symmetry-breaking effect. Finally, clear evidence for thermal fluctuations is observed in our heat-capacity data, from which we estimate the HO correlation length. [ABSTRACT FROM AUTHOR]

We report on the development of a sensitive dilatometer based upon an atomic force microscope piezocantilever. This dilatometer is designed to measure the elastic properties of bulk materials in extreme conditions, such as temperatures down to 25 mK and magnetic fields up to 16 T. The layered heavy fermion superconductor and its non-magnetic analog are measured to demonstrate their use in detecting phase transitions and quantum oscillations. In addition, using this dilatometer, a simultaneous multi-axis dilation measurement is performed. This compact dilatometer has many advantages, such as its ability to measure very small samples with sub-mm lengths at low temperature and small field dependence, and its ability to rotate, while it works well irrespective of whether it is in a changing liquid or gas environment (i.e. within a flow cryostat or mixing chamber). [ABSTRACT FROM AUTHOR]