121 results on '"Keen DA"'
Search Results
2. Resolving length-scale-dependent transient disorder through an ultrafast phase transition.
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Griffiths J, Suzana AF, Wu L, Marks SD, Esposito V, Boutet S, Evans PG, Mitchell JF, Dean MPM, Keen DA, Robinson I, Billinge SJL, and Bozin ES
- Abstract
Material functionality can be strongly determined by structure extending only over nanoscale distances. The pair distribution function presents an opportunity for structural studies beyond idealized crystal models and to investigate structure over varying length scales. Applying this method with ultrafast time resolution has the potential to similarly disrupt the study of structural dynamics and phase transitions. Here we demonstrate such a measurement of CuIr
2 S4 optically pumped from its low-temperature Ir-dimerized phase. Dimers are optically suppressed without spatial correlation, generating a structure whose level of disorder strongly depends on the length scale. The redevelopment of structural ordering over tens of picoseconds is directly tracked over both space and time as a transient state is approached. This measurement demonstrates the crucial role of local structure and disorder in non-equilibrium processes as well as the feasibility of accessing this information with state-of-the-art XFEL facilities., (© 2024. The Author(s).)- Published
- 2024
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3. Observation of a Reversible Order-Order Transition in a Metal-Organic Framework - Ionic Liquid Nanocomposite Phase-Change Material.
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Nozari V, Azar ANV, Sajzew R, Castillo-Blas C, Kono A, Oschatz M, Keen DA, Chater PA, Robertson GP, Steele JMA, León-Alcaide L, Knebel A, Ashling CW, Bennett TD, and Wondraczek L
- Abstract
Metal-organic framework (MOF) composite materials containing ionic liquids (ILs) have been proposed for a range of potential applications, including gas separation, ion conduction, and hybrid glass formation. Here, an order transition in an IL@MOF composite is discovered using CuBTC (copper benzene-1,3,5-tricarboxylate) and [EMIM][TFSI] (1-ethyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide). This transition - absent for the bare MOF or IL - provides an extended super-cooling range and latent heat at a capacity similar to that of soft paraffins, in the temperature range of ≈220 °C. Structural analysis and in situ monitoring indicate an electrostatic interaction between the IL molecules and the Cu paddle-wheels, leading to a decrease in pore symmetry at low temperature. These interactions are reversibly released above the transition temperature, which reflects in a volume expansion of the MOF-IL composite., (© 2024 The Author(s). Small published by Wiley‐VCH GmbH.)
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- 2024
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4. Loading and thermal behaviour of ZIF-8 metal-organic framework-inorganic glass composites.
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Chester AM, Castillo-Blas C, Sajzew R, Rodrigues BP, Lampronti GI, Sapnik AF, Robertson GP, Mazaj M, Irving DJM, Wondraczek L, Keen DA, and Bennett TD
- Abstract
Here we describe the synthesis of a compositional series of metal-organic framework crystalline-inorganic glass composites (MOF-CIGCs) containing ZIF-8 and an inorganic phosphate glass, 20Na
2 O-10NaCl-70P2 O5 , to expand the library of host matrices for metal-organic frameworks. By careful selection of the inorganic glass component, a relatively high loading of ZIF-8 (70 wt%) was achieved, which is the active component of the composite. A Zn⋯O-P interfacial bond, previously identified in similar composites/hybrid blends, was suggested by analysis of the total scattering pair distribution function data. Additionally, CO2 and N2 sorption and variable-temperature PXRD experiments were performed to assess the composites' properties.- Published
- 2024
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5. Local Structure and Dynamics in MPt(CN) 6 Prussian Blue Analogues.
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Harbourne EA, Barker H, Guéroult Q, Cattermull J, Nagle-Cocco LAV, Roth N, Evans JSO, Keen DA, and Goodwin AL
- Abstract
We use a combination of X-ray pair distribution function (PDF) measurements, lattice dynamical calculations, and ab initio density functional theory (DFT) calculations to study the local structure and dynamics in various MPt(CN)
6 Prussian blue analogues. In order to link directly the local distortions captured by the PDF with the lattice dynamics of this family, we develop and apply a new "interaction-space" PDF refinement approach. This approach yields effective harmonic force constants, from which the (experiment-derived) low-energy phonon dispersion relations can be approximated. Calculation of the corresponding Grüneisen parameters allows us to identify the key modes responsible for negative thermal expansion (NTE) as arising from correlated tilts of coordination octahedra. We compare our results against the phonon dispersion relations determined using DFT calculations, which identify the same NTE mechanism., Competing Interests: The authors declare no competing financial interest., (© 2024 The Authors. Published by American Chemical Society.)- Published
- 2024
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6. Mechanochemically-induced glass formation from two-dimensional hybrid organic-inorganic perovskites.
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Ye C, Lampronti GI, McHugh LN, Castillo-Blas C, Kono A, Chen C, Robertson GP, Nagle-Cocco LAV, Xu W, Stranks SD, Martinez V, Brekalo I, Karadeniz B, Užarević K, Xue W, Kolodzeiski P, Das C, Chater P, Keen DA, Dutton SE, and Bennett TD
- Abstract
Hybrid organic-inorganic perovskites (HOIPs) occupy a prominent position in the field of materials chemistry due to their attractive optoelectronic properties. While extensive work has been done on the crystalline materials over the past decades, the newly reported glasses formed from HOIPs open up a new avenue for perovskite research with their unique structures and functionalities. Melt-quenching is the predominant route to glass formation; however, the absence of a stable liquid state prior to thermal decomposition precludes this method for most HOIPs. In this work, we describe the first mechanochemically-induced crystal-glass transformation of HOIPs as a rapid, green and efficient approach for producing glasses. The amorphous phase was formed from the crystalline phase within 10 minutes of ball-milling, and exhibited glass transition behaviour as evidenced by thermal analysis techniques. Time-resolved in situ ball-milling with synchrotron powder diffraction was employed to study the microstructural evolution of amorphisation, which showed that the crystallite size reaches a comminution limit before the amorphisation process is complete, indicating that energy may be further accumulated as crystal defects. Total scattering experiments revealed the limited short-range order of amorphous HOIPs, and their optical properties were studied by ultraviolet-visible (UV-vis) spectroscopy and photoluminescence (PL) spectroscopy., Competing Interests: There are no conflicts to declare., (This journal is © The Royal Society of Chemistry.)
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- 2024
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7. Thermally activated structural phase transitions and processes in metal-organic frameworks.
- Author
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Castillo-Blas C, Chester AM, Keen DA, and Bennett TD
- Abstract
The structural knowledge of metal-organic frameworks is crucial to the understanding and development of new efficient materials for industrial implementation. This review classifies and discusses recent advanced literature reports on phase transitions that occur during thermal treatments on metal-organic frameworks and their characterisation. Thermally activated phase transitions and procceses are classified according to the temperaturatures at which they occur: high temperature (reversible and non-reversible) and low temperature. In addition, theoretical calculations and modelling approaches employed to better understand these structural phase transitions are also reviewed.
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- 2024
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8. Siliceous zeolite-derived topology of amorphous silica.
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Masai H, Kohara S, Wakihara T, Shibazaki Y, Onodera Y, Masuno A, Sukenaga S, Ohara K, Sakai Y, Haines J, Levelut C, Hébert P, Isambert A, Keen DA, and Azuma M
- Abstract
The topology of amorphous materials can be affected by mechanical forces during compression or milling, which can induce material densification. Here, we show that densified amorphous silica (SiO
2 ) fabricated by cold compression of siliceous zeolite (SZ) is permanently densified, unlike densified glassy SiO2 (GS) fabricated by cold compression although the X-ray diffraction data and density of the former are identical to those of the latter. Moreover, the topology of the densified amorphous SiO2 fabricated from SZ retains that of crystalline SZ, whereas the densified GS relaxes to pristine GS after thermal annealing. These results indicate that it is possible to design new functional amorphous materials by tuning the topology of the initial zeolitic crystalline phases., (© 2023. The Author(s).)- Published
- 2023
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9. Superstructure and Correlated Na + Hopping in a Layered Mg-Substituted Sodium Manganate Battery Cathode are Driven by Local Electroneutrality.
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Bassey EN, Seymour ID, Bocarsly JD, Keen DA, Pintacuda G, and Grey CP
- Abstract
In this work, we present a variable-temperature
23 Na NMR and variable-temperature and variable-frequency electron paramagnetic resonance (EPR) analysis of the local structure of a layered P2 Na-ion battery cathode material, Na0.67 [Mg0.28 Mn0.72 ]O2 (NMMO). For the first time, we elucidate the superstructure in this material by using synchrotron X-ray diffraction and total neutron scattering and show that this superstructure is consistent with NMR and EPR spectra. To complement our experimental data, we carry out ab initio calculations of the quadrupolar and hyperfine23 Na NMR shifts, the Na+ ion hopping energy barriers, and the EPR g -tensors. We also describe an in-house simulation script for modeling the effects of ionic mobility on variable-temperature NMR spectra and use our simulations to interpret the experimental spectra, available upon request. We find long-zigzag-type Na ordering with two different types of Na sites, one with high mobility and the other with low mobility, and reconcile the tendency toward Na+ /vacancy ordering to the preservation of local electroneutrality. The combined magnetic resonance methodology for studying local paramagnetic environments from the perspective of electron and nuclear spins will be useful for examining the local structures of materials for devices., Competing Interests: The authors declare no competing financial interest., (© 2023 The Authors. Published by American Chemical Society.)- Published
- 2023
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10. Unravelling the Molecular Structure and Confining Environment of an Organometallic Catalyst Heterogenized within Amorphous Porous Polymers.
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Jabbour R, Ashling CW, Robinson TC, Khan AH, Wisser D, Berruyer P, Ghosh AC, Ranscht A, Keen DA, Brunner E, Canivet J, Bennett TD, Mellot-Draznieks C, Lesage A, and Wisser FM
- Abstract
The catalytic activity of multifunctional, microporous materials is directly linked to the spatial arrangement of their structural building blocks. Despite great achievements in the design and incorporation of isolated catalytically active metal complexes within such materials, a detailed understanding of their atomic-level structure and the local environment of the active species remains a fundamental challenge, especially when these latter are hosted in non-crystalline organic polymers. Here, we show that by combining computational chemistry with pair distribution function analysis,
129 Xe NMR, and Dynamic Nuclear Polarization enhanced NMR spectroscopy, a very accurate description of the molecular structure and confining surroundings of a catalytically active Rh-based organometallic complex incorporated inside the cavity of amorphous bipyridine-based porous polymers is obtained. Small, but significant, differences in the structural properties of the polymers are highlighted depending on their backbone motifs., (© 2023 The Authors. Angewandte Chemie International Edition published by Wiley-VCH GmbH.)- Published
- 2023
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11. Interfacial Bonding between a Crystalline Metal-Organic Framework and an Inorganic Glass.
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Castillo-Blas C, Chester AM, Cosquer RP, Sapnik AF, Corti L, Sajzew R, Poletto-Rodrigues B, Robertson GP, Irving DJM, McHugh LN, Wondraczek L, Blanc F, Keen DA, and Bennett TD
- Abstract
The interface within a composite is critically important for the chemical and physical properties of these materials. However, experimental structural studies of the interfacial regions within metal-organic framework (MOF) composites are extremely challenging. Here, we provide the first example of a new MOF composite family, i.e., using an inorganic glass matrix host in place of the commonly used organic polymers. Crucially, we also decipher atom-atom interactions at the interface. In particular, we dispersed a zeolitic imidazolate framework (ZIF-8) within a phosphate glass matrix and identified interactions at the interface using several different analysis methods of pair distribution function and multinuclear multidimensional magic angle spinning nuclear magnetic resonance spectroscopy. These demonstrated glass-ZIF atom-atom correlations. Additionally, carbon dioxide uptake and stability tests were also performed to check the increment of the surface area and the stability and durability of the material in different media. This opens up possibilities for creating new composites that include the intrinsic chemical properties of the constituent MOFs and inorganic glasses.
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- 2023
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12. Structural insights into hybrid immiscible blends of metal-organic framework and sodium ultraphosphate glasses.
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Chester AM, Castillo-Blas C, Sajzew R, Rodrigues BP, Mas-Balleste R, Moya A, Snelson JE, Collins SM, Sapnik AF, Robertson GP, Irving DJM, Wondraczek L, Keen DA, and Bennett TD
- Abstract
Recently, increased attention has been focused on amorphous metal-organic frameworks (MOFs) and, more specifically, MOF glasses, the first new glass category discovered since the 1970s. In this work, we explore the fabrication of a compositional series of hybrid blends, the first example of blending a MOF and inorganic glass. We combine ZIF-62(Zn) glass and an inorganic glass, 30Na
2 O-70P2 O5 , to combine the chemical versatility of the MOF glass with the mechanical properties of the inorganic glass. We investigate the interfacial interactions between the two components using pair distribution function analysis and solid state NMR spectroscopy, and suggest potential interactions between the two phases. Thermal analysis of the blend samples indicated that they were less thermally stable than the starting materials and had a Tg shifted relative to the pristine materials. Annular dark field scanning transmission electron microscopy tomography, X-ray energy dispersive spectroscopy (EDS), nanoindentation and31 P NMR all indicated close mixing of the two phases, suggesting the formation of immiscible blends., Competing Interests: There are no conflicts to declare., (This journal is © The Royal Society of Chemistry.)- Published
- 2023
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13. Survival of Zirconium-Based Metal-Organic Framework Crystallinity at Extreme Pressures.
- Author
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Robertson GP, Mosca S, Castillo-Blas C, Son FA, Farha OK, Keen DA, Anzellini S, and Bennett TD
- Abstract
Recent research on metal-organic frameworks (MOFs) has shown a shift from considering only the crystalline high-porosity phases to exploring their amorphous counterparts. Applying pressure to a crystalline MOF is a common method of amorphization, as MOFs contain large void spaces that can collapse, reducing the accessible surface area. This can be either a desired change or indeed an unwanted side effect of the application of pressure. In either case, understanding the MOF's pressure response is extremely important. Three such MOFs with varying pore sizes (UiO-66, MOF-808, and NU-1000) were investigated using in situ high-pressure X-ray diffraction and Raman spectroscopy. Partial crystallinity was observed in all three MOFs above 10 GPa, along with some recovery of crystallinity on return to ambient conditions if the frameworks were not compressed above thresholds of 13.3, 14.2, and 12.3 GPa for UiO-66, MOF-808, and NU-1000, respectively. This threshold was marked by an unexpected increase in one or more lattice parameters with pressure in all MOFs. Comparison of compressibility between MOFs suggests penetration of the pressure-transmitting oil into MOF-808 and NU-1000. The survival of some crystallinity above 10 GPa in all of these MOFs despite their differing pore sizes and extents of oil penetration demonstrates the importance of high-pressure characterization of known structures.
- Published
- 2023
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14. Meltable, Glass-Forming, Iron Zeolitic Imidazolate Frameworks.
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León-Alcaide L, Christensen RS, Keen DA, Jordá JL, Brotons-Alcázar I, Forment-Aliaga A, and Mínguez Espallargas G
- Abstract
We describe the first meltable iron-based zeolitic imidazolate framework (ZIF), denoted MUV-24 . This material, elusive from direct synthesis, is obtained from the thermal treatment of [Fe
3 (im)6 (Him)2 ], which yields Fe(im)2 upon loss of the neutral imidazole molecules. Different crystalline phase transformations are observed upon further heating, until the material melts at 482 °C. Vitrification upon cooling of the liquid phase gives rise to the first Fe-metal-organic framework glass. X-ray total scattering experiments show that the tetrahedral environment of the crystalline solids is maintained in the glass, whereas nanoindentation measurements reveal an increase in Young's modulus, in agreement with stiffening upon vitrification.- Published
- 2023
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15. Formation of a meltable purinate metal-organic framework and its glass analogue.
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Bumstead AM, Castillo-Blas C, Pakamorė I, Thorne MF, Sapnik AF, Chester AM, Robertson G, Irving DJM, Chater PA, Keen DA, Forgan RS, and Bennett TD
- Abstract
The chemistries that can be incorporated within melt-quenched zeolitic imidazolate framework (ZIF) glasses are currently limited. Here we describe the preparation of a previously unknown purine-containing ZIF which we name ZIF-UC-7. We find that it melts and forms a glass at one of the lowest temperatures reported for 3D hybrid frameworks.
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- 2023
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16. Mapping short-range order at the nanoscale in metal-organic framework and inorganic glass composites.
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Laulainen JEM, Johnstone DN, Bogachev I, Longley L, Calahoo C, Wondraczek L, Keen DA, Bennett TD, Collins SM, and Midgley PA
- Abstract
Characterization of nanoscale changes in the atomic structure of amorphous materials is a profound challenge. Established X-ray and neutron total scattering methods typically provide sufficient signal quality only over macroscopic volumes. Pair distribution function analysis using electron scattering (ePDF) in the scanning transmission electron microscope (STEM) has emerged as a method of probing nanovolumes of these materials, but inorganic glasses as well as metal-organic frameworks (MOFs) and many other materials containing organic components are characteristically prone to irreversible changes after limited electron beam exposures. This beam sensitivity requires 'low-dose' data acquisition to probe inorganic glasses, amorphous and glassy MOFs, and MOF composites. Here, we use STEM-ePDF applied at low electron fluences (10 e
- Å-2 ) combined with unsupervised machine learning methods to map changes in the short-range order with ca. 5 nm spatial resolution in a composite material consisting of a zeolitic imidazolate framework glass ag ZIF-62 and a 0.67([Na2 O]0.9 [P2 O5 ])-0.33([AlO3/2 ][AlF3 ]1.5 ) inorganic glass. STEM-ePDF enables separation of MOF and inorganic glass domains from atomic structure differences alone, showing abrupt changes in atomic structure at interfaces with interatomic correlation distances seen in X-ray PDF preserved at the nanoscale. These findings underline that the average bulk amorphous structure is retained at the nanoscale in the growing family of MOF glasses and composites, a previously untested assumption in PDF analyses crucial for future non-crystalline nanostructure engineering.- Published
- 2022
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17. Modeling the Effect of Defects and Disorder in Amorphous Metal-Organic Frameworks.
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Bechis I, Sapnik AF, Tarzia A, Wolpert EH, Addicoat MA, Keen DA, Bennett TD, and Jelfs KE
- Abstract
Amorphous metal-organic frameworks ( a MOFs) are a class of disordered framework materials with a defined local order given by the connectivity between inorganic nodes and organic linkers, but absent long-range order. The rational development of function for a MOFs is hindered by our limited understanding of the underlying structure-property relationships in these systems, a consequence of the absence of long-range order, which makes experimental characterization particularly challenging. Here, we use a versatile modeling approach to generate in silico structural models for an a MOF based on Fe trimers and 1,3,5-benzenetricarboxylate (BTC) linkers, Fe-BTC. We build a phase space for this material that includes nine amorphous phases with different degrees of defects and local order. These models are analyzed through a combination of structural analysis, pore analysis, and pair distribution functions. Therefore, we are able to systematically explore the effects of the variation of each of these features, both in isolation and combined, for a disordered MOF system, something that would not be possible through experiment alone. We find that the degree of local order has a greater impact on structure and properties than the degree of defects. The approach presented here is versatile and allows for the study of different structural features and MOF chemistries, enabling the derivation of design rules for the rational development of a MOFs., Competing Interests: The authors declare no competing financial interest., (© 2022 The Authors. Published by American Chemical Society.)
- Published
- 2022
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18. Formation of new crystalline qtz-[Zn(mIm)2] polymorph from amorphous ZIF-8.
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Thorne MF, Castillo-Blas C, McHugh LN, Bumstead AM, Robertson G, Sapnik AF, Coates CS, Sayed FN, Grey CP, Keen DA, Etter M, da Silva I, Užarević K, and Bennett TD
- Abstract
The structure of a new ZIF-8 polymorph with quartz topology (qtz) is reported. This qtz-[Zn(mIm)2] phase was obtained by mechanically amorphising crystalline ZIF-8, before heating the resultant amorphous phase to between 282 and 316 °C. The high-temperature phase structure was obtained from powder X-ray diffraction, and its thermal behaviour, CO
2 gas sorption properties and dye adsorption ability were investigated.- Published
- 2022
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19. An N⋯H⋯N low-barrier hydrogen bond preorganizes the catalytic site of aspartate aminotransferase to facilitate the second half-reaction.
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Drago VN, Dajnowicz S, Parks JM, Blakeley MP, Keen DA, Coquelle N, Weiss KL, Gerlits O, Kovalevsky A, and Mueser TC
- Abstract
Pyridoxal 5'-phosphate (PLP)-dependent enzymes have been extensively studied for their ability to fine-tune PLP cofactor electronics to promote a wide array of chemistries. Neutron crystallography offers a straightforward approach to studying the electronic states of PLP and the electrostatics of enzyme active sites, responsible for the reaction specificities, by enabling direct visualization of hydrogen atom positions. Here we report a room-temperature joint X-ray/neutron structure of aspartate aminotransferase (AAT) with pyridoxamine 5'-phosphate (PMP), the cofactor product of the first half reaction catalyzed by the enzyme. Between PMP N
SB and catalytic Lys258 Nζ amino groups an equally shared deuterium is observed in an apparent low-barrier hydrogen bond (LBHB). Density functional theory calculations were performed to provide further evidence of this LBHB interaction. The structural arrangement and the juxtaposition of PMP and Lys258, facilitated by the LBHB, suggests active site preorganization for the incoming ketoacid substrate that initiates the second half-reaction., Competing Interests: There are no conflicts of interest to declare., (This journal is © The Royal Society of Chemistry.)- Published
- 2022
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20. Materials Formed by Combining Inorganic Glasses and Metal-Organic Frameworks.
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Chester AM, Castillo-Blas C, Wondraczek L, Keen DA, and Bennett TD
- Abstract
Here, we propose the combination of glassy or crystalline metal-organic frameworks (MOFs) with inorganic glasses to create novel hybrid composites and blends.The motivation behind this new composite approach is to improve the processability issues and mechanical performance of MOFs, whilst maintaining their ubiquitous properties. Herein, the precepts of successful composite formation and pairing of MOF and glass MOFs with inorganic glasses are presented. Focus is also given to the synthetic routes to such materials and the challenges anticipated in both their production and characterisation. Depending on their chemical nature, materials are classified as crystalline MOF-glass composites and blends. Additionally, the potential properties and applications of these two classes of materials are considered, the key aim being the retention of beneficial properties of both components, whilst circumventing their respective drawbacks., (© 2022 The Authors. Chemistry - A European Journal published by Wiley-VCH GmbH.)
- Published
- 2022
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21. Orientational disorder in sulfur hexafluoride: a neutron total scattering and reverse Monte Carlo study.
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Zhang S, Qin Y, Zhang S, Gao M, Tucker MG, Keen DA, Cai G, Phillips AE, and Dove MT
- Abstract
The orientational disorder in crystalline sulfur hexafluoride, SF
6 , has been studied using a combination of neutron total scattering and the reverse Monte Carlo method. Analysis of the atomic configurations has shown the extent of the disorder through the evaluation of the S-F bond orientational distribution function, consistent with, but improving upon, the results of earlier neutron powder diffraction data. The correlations between orientations of neighbouring molecules have been studied through analysis of the distributions of F-F distances, showing that nearest-neighbour F-F close contacts are avoided, consistent with previous molecular dynamics simulation results. The results present a new case study of the application of neutron total scattering and the reverse Monte Carlo methods for the study of orientational disorder, where in this instance the disorder arises from orientational frustration rather than from a mismatch of molecular and site symmetries., (Creative Commons Attribution license.)- Published
- 2022
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22. Correction to "From n- to p-Type Material: Effect of Metal Ion on Charge Transport in Metal-Organic Materials".
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Yoon S, Talin AA, Stavila V, Mroz AM, Bennett TD, He Y, Keen DA, Hendon CH, Allendorf MD, and So MC
- Published
- 2022
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23. Multivariate analysis of disorder in metal-organic frameworks.
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Sapnik AF, Bechis I, Bumstead AM, Johnson T, Chater PA, Keen DA, Jelfs KE, and Bennett TD
- Abstract
The rational design of disordered frameworks is an appealing route to target functional materials. However, intentional realisation of such materials relies on our ability to readily characterise and quantify structural disorder. Here, we use multivariate analysis of pair distribution functions to fingerprint and quantify the disorder within a series of compositionally identical metal-organic frameworks, possessing different crystalline, disordered, and amorphous structures. We find this approach can provide powerful insight into the kinetics and mechanism of structural collapse that links these materials. Our methodology is also extended to a very different system, namely the melting of a zeolitic imidazolate framework, to demonstrate the potential generality of this approach across many areas of disordered structural chemistry., (© 2022. The Author(s).)
- Published
- 2022
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24. Post-Synthetic Modification of a Metal-Organic Framework Glass.
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Bumstead AM, Pakamorė I, Richards KD, Thorne MF, Boyadjieva SS, Castillo-Blas C, McHugh LN, Sapnik AF, Keeble DS, Keen DA, Evans RC, Forgan RS, and Bennett TD
- Abstract
Melt-quenched metal-organic framework (MOF) glasses have gained significant interest as the first new category of glass reported in 50 years. In this work, an amine-functionalized zeolitic imidazolate framework (ZIF), denoted ZIF-UC-6, was prepared and demonstrated to undergo both melting and glass formation. The presence of an amine group resulted in a lower melting temperature compared to other ZIFs, while also allowing material properties to be tuned by post-synthetic modification (PSM). As a prototypical example, the ZIF glass surface was functionalized with octyl isocyanate, changing its behavior from hydrophilic to hydrophobic. PSM therefore provides a promising strategy for tuning the surface properties of MOF glasses., Competing Interests: The authors declare no competing financial interest., (© 2022 American Chemical Society.)
- Published
- 2022
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25. Neutron powder diffraction study of the phase transitions in deuterated methylammonium lead iodide.
- Author
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Liu J, Du J, Phillips AE, Wyatt PB, Keen DA, and Dove MT
- Abstract
We report the results of a neutron powder diffraction study of the phase transitions in deuterated methylammonium lead iodide, with a focus on the system of orientational distortions of the framework of PbI
6 octahedra. The results are analysed in terms of symmetry-adapted lattice strains and normal mode distortions. The higher-temperature cubic-tetragonal phase transition at 327 K is weakly discontinuous and nearly tricritical. The variations of rotation angles and spontaneous strains with temperature are consistent with a standard Landau theory treatment. The lower-temperature transition to the orthorhombic phase at 165 K is discontinuous, with two systems of octahedral rotations and internal distortions that together can be described by 5 order parameters of different symmetry. In this paper we quantify the various symmetry-breaking distortions and their variation with temperature, together with their relationship to the spontaneous strains, within the formalism of Landau theory. A number of curious results in the low-temperature phase are identified, particularly regarding distortion amplitudes that decrease rather than increase with lowering temperature., (Creative Commons Attribution license.)- Published
- 2022
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26. Principles of melting in hybrid organic-inorganic perovskite and polymorphic ABX 3 structures.
- Author
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Shaw BK, Castillo-Blas C, Thorne MF, Ríos Gómez ML, Forrest T, Lopez MD, Chater PA, McHugh LN, Keen DA, and Bennett TD
- Abstract
Four novel dicyanamide-containing hybrid organic-inorganic ABX
3 structures are reported, and the thermal behaviour of a series of nine perovskite and non-perovskite [AB(N(CN)2 )3 ] (A = (C3 H7 )4 N, (C4 H9 )4 N, (C5 H11 )4 N; B = Co, Fe, Mn) is analyzed. Structure-property relationships are investigated by varying both A-site organic and B-site transition metal cations. In particular, increasing the size of the A-site cation from (C3 H7 )4 N → (C4 H9 )4 N → (C5 H11 )4 N was observed to result in a decrease in Tm through an increase in Δ Sf . Consistent trends in Tm with metal replacement are observed with each A-site cation, with Co < Fe < Mn. The majority of the melts formed were found to recrystallise partially upon cooling, though glasses could be formed through a small degree of organic linker decomposition. Total scattering methods are used to provide a greater understanding of the melting mechanism., Competing Interests: There are no conflicts to declare., (This journal is © The Royal Society of Chemistry.)- Published
- 2022
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27. From n- to p-Type Material: Effect of Metal Ion on Charge Transport in Metal-Organic Materials.
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Yoon S, Talin AA, Stavila V, Mroz AM, Bennett TD, He Y, Keen DA, Hendon CH, Allendorf MD, and So MC
- Abstract
An intriguing new class of two-dimensional (2D) materials based on metal-organic frameworks (MOFs) has recently been developed that displays electrical conductivity, a rarity among these nanoporous materials. The emergence of conducting MOFs raises questions about their fundamental electronic properties, but few studies exist in this regard. Here, we present an integrated theory and experimental investigation to probe the effects of metal substitution on the charge transport properties of M-HITP, where M = Ni or Pt and HITP = 2,3,6,7,10,11-hexaiminotriphenylene. The results show that the identity of the M-HITP majority charge carrier can be changed without intentional introduction of electronically active dopants. We observe that the selection of the metal ion substantially affects charge transport. Using the known structure, Ni-HITP, we synthesized a new amorphous material, a- Pt-HITP, which although amorphous is nevertheless found to be porous upon desolvation. Importantly, this new material exhibits p-type charge transport behavior, unlike Ni-HITP, which displays n-type charge transport. These results demonstrate that both p- and n-type materials can be achieved within the same MOF topology through appropriate choice of the metal ion.
- Published
- 2021
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28. Orientational order and phase transitions in deuterated methane: a neutron total scattering and reverse Monte Carlo study.
- Author
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Qin Y, Zhang S, Zhang S, Tucker MG, Keen DA, Cai G, Phillips AE, and Dove MT
- Abstract
We report a study of the orientational order and phase transitions in crystalline deuterated methane, carried out using neutron total scattering and the reverse Monte Carlo method. The resultant atomic configurations are consistent with the average structures obtained from Rietveld refinement of the powder diffraction data, but additionally enable us to determine the C-D bond orientational distribution functions (ODF) for the disordered molecules in the high-temperature phase, and for both ordered and disordered molecules in the intermediate-temperature phase. We show that this approach gives more accurate information than can been obtained from fitting a bond ODF to diffraction data. Given the resurgence of interest in orientationally-disordered crystals, we argue that the approach of total scattering with the RMC method provides a unique quantification of orientational order and disorder., (© 2021 IOP Publishing Ltd.)
- Published
- 2021
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29. Ionic liquid facilitated melting of the metal-organic framework ZIF-8.
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Nozari V, Calahoo C, Tuffnell JM, Keen DA, Bennett TD, and Wondraczek L
- Abstract
Hybrid glasses from melt-quenched metal-organic frameworks (MOFs) have been emerging as a new class of materials, which combine the functional properties of crystalline MOFs with the processability of glasses. However, only a handful of the crystalline MOFs are meltable. Porosity and metal-linker interaction strength have both been identified as crucial parameters in the trade-off between thermal decomposition of the organic linker and, more desirably, melting. For example, the inability of the prototypical zeolitic imidazolate framework (ZIF) ZIF-8 to melt, is ascribed to the instability of the organic linker upon dissociation from the metal center. Here, we demonstrate that the incorporation of an ionic liquid (IL) into the porous interior of ZIF-8 provides a means to reduce its melting temperature to below its thermal decomposition temperature. Our structural studies show that the prevention of decomposition, and successful melting, is due to the IL interactions stabilizing the rapidly dissociating ZIF-8 linkers upon heating. This understanding may act as a general guide for extending the range of meltable MOF materials and, hence, the chemical and structural variety of MOF-derived glasses., (© 2021. The Author(s).)
- Published
- 2021
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30. Glassy behaviour of mechanically amorphised ZIF-62 isomorphs.
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Thorne MF, Sapnik AF, McHugh LN, Bumstead AM, Castillo-Blas C, Keeble DS, Diaz Lopez M, Chater PA, Keen DA, and Bennett TD
- Abstract
Zeolitic imidazolate frameworks (ZIFs) can be melt-quenched to form glasses. Here, we present an alternative route to glassy ZIFs via mechanically induced amorphisation. This approach allows various glassy ZIFs to be produced in under 30 minutes at room temperature, without the need for melt-quenching.
- Published
- 2021
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31. Erratum: Illustrated formalisms for total scattering data: a guide for new practitioners. Corrigendum and addendum.
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Peterson PF and Keen DA
- Abstract
[This corrects the article DOI: 10.1107/S1600576720015630.]., (© Peterson and Keen 2021.)
- Published
- 2021
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32. Room temperature crystallography of human acetylcholinesterase bound to a substrate analogue 4K-TMA: Towards a neutron structure.
- Author
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Gerlits O, Blakeley MP, Keen DA, Radić Z, and Kovalevsky A
- Abstract
Acetylcholinesterase (AChE) catalyzes hydrolysis of acetylcholine thereby terminating cholinergic nerve impulses for efficient neurotransmission. Human AChE (hAChE) is a target of nerve agent and pesticide organophosphorus compounds that covalently attach to the catalytic Ser203 residue. Reactivation of inhibited hAChE can be achieved with nucleophilic antidotes, such as oximes. Understanding structural and electrostatic (i.e. protonation states) determinants of the catalytic and reactivation processes is crucial to improve design of oxime reactivators. Here we report X-ray structures of hAChE conjugated with a reversible covalent inhibitor 4K-TMA (4K-TMA:hAChE) at 2.8 Å resolution and of 4K-TMA:hAChE conjugate with oxime reactivator methoxime, MMB4 (4K-TMA:hAChE:MMB4) at 2.6 Å resolution, both at physiologically relevant room temperature, as well as cryo-crystallographic structure of 4K-TMA:hAChE at 2.4 Å resolution. 4K-TMA acts as a substrate analogue reacting with the hydroxyl of Ser203 and generating a reversible tetrahedral hemiketal intermediate that closely resembles the first tetrahedral intermediate state during hAChE-catalyzed acetylcholine hydrolysis. Structural comparisons of room temperature with cryo-crystallographic structures of 4K-TMA:hAChE and published mAChE complexes with 4K-TMA, as well as the effect of MMB4 binding to the peripheral anionic site (PAS) of the 4K-TMA:hAChE complex, revealed only discrete, minor differences. The active center geometry of AChE, already highly evolved for the efficient catalysis, was thus indicative of only minor conformational adjustments to accommodate the tetrahedral intermediate in the hydrolysis of the neurotransmitter acetylcholine (ACh). To map protonation states in the hAChE active site gorge we collected 3.5 Å neutron diffraction data paving the way for obtaining higher resolution datasets that will be needed to determine locations of individual hydrogen atoms., Competing Interests: The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.
- Published
- 2021
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33. Melting of hybrid organic-inorganic perovskites.
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Shaw BK, Hughes AR, Ducamp M, Moss S, Debnath A, Sapnik AF, Thorne MF, McHugh LN, Pugliese A, Keeble DS, Chater P, Bermudez-Garcia JM, Moya X, Saha SK, Keen DA, Coudert FX, Blanc F, and Bennett TD
- Abstract
Several organic-inorganic hybrid materials from the metal-organic framework (MOF) family have been shown to form stable liquids at high temperatures. Quenching then results in the formation of melt-quenched MOF glasses that retain the three-dimensional coordination bonding of the crystalline phase. These hybrid glasses have intriguing properties and could find practical applications, yet the melt-quench phenomenon has so far remained limited to a few MOF structures. Here we turn to hybrid organic-inorganic perovskites-which occupy a prominent position within materials chemistry owing to their functional properties such as ion transport, photoconductivity, ferroelectricity and multiferroicity-and show that a series of dicyanamide-based hybrid organic-inorganic perovskites undergo melting. Our combined experimental-computational approach demonstrates that, on quenching, they form glasses that largely retain their solid-state inorganic-organic connectivity. The resulting materials show very low thermal conductivities (~0.2 W m
-1 K-1 ), moderate electrical conductivities (10-3 -10-5 S m-1 ) and polymer-like thermomechanical properties., (© 2021. The Author(s), under exclusive licence to Springer Nature Limited.)- Published
- 2021
- Full Text
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34. Spin-ice physics in cadmium cyanide.
- Author
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Coates CS, Baise M, Schmutzler A, Simonov A, Makepeace JW, Seel AG, Smith RI, Playford HY, Keen DA, Siegel R, Senker J, Slater B, and Goodwin AL
- Abstract
Spin-ices are frustrated magnets that support a particularly rich variety of emergent physics. Typically, it is the interplay of magnetic dipole interactions, spin anisotropy, and geometric frustration on the pyrochlore lattice that drives spin-ice formation. The relevant physics occurs at temperatures commensurate with the magnetic interaction strength, which for most systems is 1-5 K. Here, we show that non-magnetic cadmium cyanide, Cd(CN)
2 , exhibits analogous behaviour to magnetic spin-ices, but does so on a temperature scale that is nearly two orders of magnitude greater. The electric dipole moments of cyanide ions in Cd(CN)2 assume the role of magnetic pseudospins, with the difference in energy scale reflecting the increased strength of electric vs magnetic dipolar interactions. As a result, spin-ice physics influences the structural behaviour of Cd(CN)2 even at room temperature.- Published
- 2021
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- View/download PDF
35. Stepwise collapse of a giant pore metal-organic framework.
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Sapnik AF, Johnstone DN, Collins SM, Divitini G, Bumstead AM, Ashling CW, Chater PA, Keeble DS, Johnson T, Keen DA, and Bennett TD
- Abstract
Defect engineering is a powerful tool that can be used to tailor the properties of metal-organic frameworks (MOFs). Here, we incorporate defects through ball milling to systematically vary the porosity of the giant pore MOF, MIL-100 (Fe). We show that milling leads to the breaking of metal-linker bonds, generating additional coordinatively unsaturated metal sites, and ultimately causes amorphisation. Pair distribution function analysis shows the hierarchical local structure is partially retained, even in the amorphised material. We find that solvents can be used to stabilise the MIL-100 (Fe) framework against collapse, which leads to a substantial retention of porosity over the non-stabilised material.
- Published
- 2021
- Full Text
- View/download PDF
36. Mixed hierarchical local structure in a disordered metal-organic framework.
- Author
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Sapnik AF, Bechis I, Collins SM, Johnstone DN, Divitini G, Smith AJ, Chater PA, Addicoat MA, Johnson T, Keen DA, Jelfs KE, and Bennett TD
- Abstract
Amorphous metal-organic frameworks (MOFs) are an emerging class of materials. However, their structural characterisation represents a significant challenge. Fe-BTC, and the commercial equivalent Basolite® F300, are MOFs with incredibly diverse catalytic ability, yet their disordered structures remain poorly understood. Here, we use advanced electron microscopy to identify a nanocomposite structure of Fe-BTC where nanocrystalline domains are embedded within an amorphous matrix, whilst synchrotron total scattering measurements reveal the extent of local atomic order within Fe-BTC. We use a polymerisation-based algorithm to generate an atomistic structure for Fe-BTC, the first example of this methodology applied to the amorphous MOF field outside the well-studied zeolitic imidazolate framework family. This demonstrates the applicability of this computational approach towards the modelling of other amorphous MOF systems with potential generality towards all MOF chemistries and connectivities. We find that the structures of Fe-BTC and Basolite® F300 can be represented by models containing a mixture of short- and medium-range order with a greater proportion of medium-range order in Basolite® F300 than in Fe-BTC. We conclude by discussing how our approach may allow for high-throughput computational discovery of functional, amorphous MOFs.
- Published
- 2021
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- View/download PDF
37. Advantages of a curved image plate for rapid laboratory-based x-ray total scattering measurements: Application to pair distribution function analysis.
- Author
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Irving DJM, Keen DA, and Light ME
- Abstract
The analysis and interpretation of the pair distribution function (PDF), as derived from total scattering measurements, is still seen by many as a technique confined to central synchrotron and neutron facilities. This situation has begun to change with a rising visibility of total scattering experiments reported in mainstream scientific journals and the modification of an increasing number of laboratory diffractometers. However, the rigor required during data reduction and the complexities of data interpretation mean the technique is still very far from being routine. Herein, we report the first application of a large area curved image plate system based on a Rigaku SPIDER (R-AXIS RAPID II) equipped with an Ag tube for collecting data amenable to high quality PDF refinement/modeling of crystalline, amorphous, and liquid samples. The advantages of such a system are the large Q range available without scanning (routinely in excess of 20 Å
-1 ) and the inherent properties of an image plate detector (single photon sensitivity, large dynamic range [1.05 × 106 ], and effectively zero noise). Data are collected and structural models refined for a number of standard materials including NIST 640f silicon for which a Rwp ≤ 0.12 value was obtained with data collected in 60 min (excluding background measurements). These and other data are discussed and compared to similar examples in the literature.- Published
- 2021
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38. Sample Dependence of Magnetism in the Next-Generation Cathode Material LiNi 0.8 Mn 0.1 Co 0.1 O 2 .
- Author
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Mukherjee P, Paddison JAM, Xu C, Ruff Z, Wildes AR, Keen DA, Smith RI, Grey CP, and Dutton SE
- Abstract
We present a structural and magnetic study of two batches of polycrystalline LiNi
0.8 Mn0.1 Co0.1 O2 (commonly known as Li NMC 811), a Ni-rich Li ion battery cathode material, using elemental analysis, X-ray and neutron diffraction, magnetometry, and polarized neutron scattering measurements. We find that the samples, labeled S1 and S2, have the composition Li1- x Ni0.9+ x - y Mny Co0.1 O2 , with x = 0.025(2), y = 0.120(2) for S1 and x = 0.002(2), y = 0.094(2) for S2, corresponding to different concentrations of magnetic ions and excess Ni2+ in the Li+ layers. Both samples show a peak in the zero-field-cooled (ZFC) dc susceptibility at 8.0(2) K, but the temperature at which the ZFC and FC (field-cooled) curves deviate is substantially different: 64(2) K for S1 and 122(2) K for S2. The ac susceptibility measurements show that the transition for S1 shifts with frequency whereas no such shift is observed for S2 within the resolution of our measurements. Our results demonstrate the sample dependence of magnetic properties in Li NMC 811, consistent with previous reports on the parent material LiNiO2 . We further establish that a combination of experimental techniques is necessary to accurately determine the chemical composition of next-generation battery materials with multiple cations.- Published
- 2021
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- View/download PDF
39. Metal-organic framework and inorganic glass composites.
- Author
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Longley L, Calahoo C, Limbach R, Xia Y, Tuffnell JM, Sapnik AF, Thorne MF, Keeble DS, Keen DA, Wondraczek L, and Bennett TD
- Abstract
Metal-organic framework (MOF) glasses have become a subject of interest as a distinct category of melt quenched glass, and have potential applications in areas such as ion transport and sensing. In this paper we show how MOF glasses can be combined with inorganic glasses in order to fabricate a new family of materials composed of both MOF and inorganic glass domains. We use an array of experimental techniques to propose the bonding between inorganic and MOF domains, and show that the composites produced are more mechanically pliant than the inorganic glass itself.
- Published
- 2020
- Full Text
- View/download PDF
40. A quantum liquid of magnetic octupoles on the pyrochlore lattice.
- Author
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Sibille R, Gauthier N, Lhotel E, Porée V, Pomjakushin V, Ewings RA, Perring TG, Ollivier J, Wildes A, Ritter C, Hansen TC, Keen DA, Nilsen GJ, Keller L, Petit S, and Fennell T
- Abstract
Spin liquids are highly correlated yet disordered states formed by the entanglement of magnetic dipoles
1 . Theories define such states using gauge fields and deconfined quasiparticle excitations that emerge from a local constraint governing the ground state of a frustrated magnet. For example, the '2-in-2-out' ice rule for dipole moments on a tetrahedron can lead to a quantum spin ice2-4 in rare-earth pyrochlores. However, f -electron ions often carry multipole degrees of freedom of higher rank than dipoles, leading to intriguing behaviours and 'hidden' orders5-6 . Here we show that the correlated ground state of a Ce3+ -based pyrochlore, Ce2 Sn2 O7 , is a quantum liquid of magnetic octupoles. Our neutron scattering results are consistent with a fluid-like state where degrees of freedom have a more complex magnetization density than that of magnetic dipoles. The nature and strength of the octupole-octupole couplings, together with the existence of a continuum of excitations attributed to spinons, provides further evidence for a quantum ice of octupoles governed by a '2-plus-2-minus' rule7-8 . Our work identifies Ce2 Sn2 O7 as a unique example of frustrated multipoles forming a 'hidden' topological order, thus generalizing observations on quantum spin liquids to multipolar phases that can support novel types of emergent fields and excitations.- Published
- 2020
- Full Text
- View/download PDF
41. Halogenated Metal-Organic Framework Glasses and Liquids.
- Author
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Hou J, Ríos Gómez ML, Krajnc A, McCaul A, Li S, Bumstead AM, Sapnik AF, Deng Z, Lin R, Chater PA, Keeble DS, Keen DA, Appadoo D, Chan B, Chen V, Mali G, and Bennett TD
- Abstract
The synthesis of four novel crystalline zeolitic imidazolate framework (ZIF) structures using a mixed-ligand approach is reported. The inclusion of both imidazolate and halogenated benzimidazolate-derived linkers leads to glass-forming behavior by all four structures. Melting temperatures are observed to depend on both electronic and steric effects. Solid-state NMR and terahertz (THz)/far-IR demonstrate the presence of a Zn-F bond for fluorinated ZIF glasses. In situ THz/far-IR spectroscopic techniques reveal the dynamic structural properties of crystal, glass, and liquid phases of the halogenated ZIFs, linking the melting behavior of ZIFs to the propensity of the ZnN
4 tetrahedra to undergo thermally induced deformation. The inclusion of halogenated ligands within metal-organic framework (MOF) glasses improves their gas-uptake properties.- Published
- 2020
- Full Text
- View/download PDF
42. Proton transfer and drug binding details revealed in neutron diffraction studies of wild-type and drug resistant HIV-1 protease.
- Author
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Kovalevsky A, Gerlits O, Beltran K, Weiss KL, Keen DA, Blakeley MP, Louis JM, and Weber IT
- Subjects
- Binding Sites, Crystallography, X-Ray, HIV Protease genetics, Hydrogen Bonding, Protons, Neutron Diffraction, Pharmaceutical Preparations
- Abstract
HIV-1 protease is an essential therapeutic target for the design and development of antiviral inhibitors to treat AIDS. We used room temperature neutron crystallography to accurately determine hydrogen atom positions in several protease complexes with clinical drugs, amprenavir and darunavir. Hydrogen bonding interactions were carefully mapped to provide an unprecedented picture of drug binding to the protease target. We demonstrate that hydrogen atom positions within the enzyme catalytic site can be altered by introducing drug resistant mutations and by protonating surface residues that trigger proton transfer reactions between the catalytic Asp residues and the hydroxyl group of darunavir. When protein perdeuteration is not feasible, we validate the use of initial H/D exchange with unfolded protein and partial deuteration in pure D
2 O with hydrogenous glycerol to maximize deuterium incorporation into the protein, with no detrimental effects on the growth of quality crystals suitable for neutron diffraction experiments., (© 2020 Elsevier Inc. All rights reserved.)- Published
- 2020
- Full Text
- View/download PDF
43. Synthesis and Properties of a Compositional Series of MIL-53(Al) Metal-Organic Framework Crystal-Glass Composites.
- Author
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Ashling CW, Johnstone DN, Widmer RN, Hou J, Collins SM, Sapnik AF, Bumstead AM, Midgley PA, Chater PA, Keen DA, and Bennett TD
- Abstract
Metal-organic framework crystal-glass composites (MOF-CGCs) are materials in which a crystalline MOF is dispersed within a MOF glass. In this work, we explore the room-temperature stabilization of the open-pore form of MIL-53(Al), usually observed at high temperature, which occurs upon encapsulation within a ZIF-62(Zn) MOF glass matrix. A series of MOF-CGCs containing different loadings of MIL-53(Al) were synthesized and characterized using X-ray diffraction and nuclear magnetic resonance spectroscopy. An upper limit of MIL-53(Al) that can be stabilized in the composite was determined for the first time. The nanostructure of the composites was probed using pair distribution function analysis and scanning transmission electron microscopy. Notably, the distribution and integrity of the crystalline component in a sample series were determined, and these findings were related to the MOF-CGC gas adsorption capacity in order to identify the optimal loading necessary for maximum CO
2 sorption capacity.- Published
- 2019
- Full Text
- View/download PDF
44. Metal-organic framework crystal-glass composites.
- Author
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Hou J, Ashling CW, Collins SM, Krajnc A, Zhou C, Longley L, Johnstone DN, Chater PA, Li S, Coulet MV, Llewellyn PL, Coudert FX, Keen DA, Midgley PA, Mali G, Chen V, and Bennett TD
- Abstract
The majority of research into metal-organic frameworks (MOFs) focuses on their crystalline nature. Recent research has revealed solid-liquid transitions within the family, which we use here to create a class of functional, stable and porous composite materials. Described herein is the design, synthesis, and characterisation of MOF crystal-glass composites, formed by dispersing crystalline MOFs within a MOF-glass matrix. The coordinative bonding and chemical structure of a MIL-53 crystalline phase are preserved within the ZIF-62 glass matrix. Whilst separated phases, the interfacial interactions between the closely contacted microdomains improve the mechanical properties of the composite glass. More significantly, the high temperature open pore phase of MIL-53, which spontaneously transforms to a narrow pore upon cooling in the presence of water, is stabilised at room temperature in the crystal-glass composite. This leads to a significant improvement of CO
2 adsorption capacity.- Published
- 2019
- Full Text
- View/download PDF
45. Fluid type influences acute hydration and muscle performance recovery in human subjects.
- Author
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Harris PR, Keen DA, Constantopoulos E, Weninger SN, Hines E, Koppinger MP, Khalpey ZI, and Konhilas JP
- Subjects
- Adult, Athletic Performance, Body Temperature, Cross-Over Studies, Female, Heart Rate, Heat-Shock Response, Hot Temperature, Humans, Male, Osmolar Concentration, Water-Electrolyte Balance, Young Adult, Dehydration, Drinking Water, Energy Drinks, Exercise, Fluid Therapy, Mineral Waters therapeutic use
- Abstract
Background: Exercise and heat trigger dehydration and an increase in extracellular fluid osmolality, leading to deficits in exercise performance and thermoregulation. Evidence from previous studies supports the potential for deep-ocean mineral water to improve recovery of exercise performance post-exercise. We therefore wished to determine whether acute rehydration and muscle strength recovery was enhanced by deep-ocean mineral water following a dehydrating exercise, compared to a sports drink or mountain spring water. We hypothesized that muscle strength would decrease as a result of dehydrating exercise, and that recovery of muscle strength and hydration would depend on the type of rehydrating fluid., Methods: Using a counterbalanced, crossover study design, female (n = 8) and male (n = 9) participants performed a dehydrating exercise protocol under heat stress until achieving 3% body mass loss. Participants rehydrated with either deep-ocean mineral water (Deep), mountain spring water (Spring), or a carbohydrate-based sports drink (Sports) at a volume equal to the volume of fluid loss. We measured relative hydration using salivary osmolality (S
osm ) and muscle strength using peak torque from a leg extension maneuver., Results: Sosm significantly increased (p < 0.0001) with loss of body mass during the dehydrating exercise protocol. Males took less time (90.0 ± 18.3 min; P < 0.0034) to reach 3% body mass loss when compared to females (127.1 ± 20.0 min). We used a mono-exponential model to fit the return of Sosm to baseline values during the rehydrating phase. Whether fitting stimulated or unstimulated Sosm , male and female participants receiving Deep as the hydrating fluid exhibited the most rapid return to baseline Sosm (p < 0.0001) regardless of the fit parameter. Males compared to females generated more peak torque (p = 0.0005) at baseline (308.3 ± 56.7 Nm vs 172.8 ± 40.8 Nm, respectively) and immediately following 3% body mass loss (276.3 ± 39.5 Nm vs 153.5 ± 35.9 Nm). Participants experienced a loss. We also identified a significant effect of rehydrating fluid and sex on post-rehydration peak torque (p < 0.0117)., Conclusion: We conclude that deep-ocean mineral water positively affected hydration recovery after dehydrating exercise, and that it may also be beneficial for muscle strength recovery, although this, as well as the influence of sex, needs to be further examined by future research., Trial Registration: clincialtrials.gov PRS, NCT02486224 . Registered 08 June 2015.- Published
- 2019
- Full Text
- View/download PDF
46. Structural evolution in a melt-quenched zeolitic imidazolate framework glass during heat-treatment.
- Author
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Zhang J, Longley L, Liu H, Ashling CW, Chater PA, Beyer KA, Chapman KW, Tao H, Keen DA, Bennett TD, and Yue Y
- Abstract
A pronounced enthalpy release occurs around 1.38Tg in the prototypical metal-organic framework glass formed from ZIF-4 [Zn(C3H3N2)2], but there is no sign for any crystallization (i.e., long-range ordering) taking place. The enthalpy release peak is attributed to pore collapse and structural densification.
- Published
- 2019
- Full Text
- View/download PDF
47. Flux melting of metal-organic frameworks.
- Author
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Longley L, Collins SM, Li S, Smales GJ, Erucar I, Qiao A, Hou J, Doherty CM, Thornton AW, Hill AJ, Yu X, Terrill NJ, Smith AJ, Cohen SM, Midgley PA, Keen DA, Telfer SG, and Bennett TD
- Abstract
Recent demonstrations of melting in the metal-organic framework (MOF) family have created interest in the interfacial domain between inorganic glasses and amorphous organic polymers. The chemical and physical behaviour of porous hybrid liquids and glasses is of particular interest, though opportunities are limited by the inaccessible melting temperatures of many MOFs. Here, we show that the processing technique of flux melting, 'borrowed' from the inorganic domain, may be applied in order to melt ZIF-8, a material which does not possess an accessible liquid state in the pure form. Effectively, we employ the high-temperature liquid state of one MOF as a solvent for a secondary, non-melting MOF component. Differential scanning calorimetry, small- and wide-angle X-ray scattering, electron microscopy and X-ray total scattering techniques are used to show the flux melting of the crystalline component within the liquid. Gas adsorption and positron annihilation lifetime spectroscopy measurements show that this results in enhanced, accessible porosity to a range of guest molecules in the resultant flux melted MOF glass.
- Published
- 2019
- Full Text
- View/download PDF
48. Temperature-Induced Replacement of Phosphate Proton with Metal Ion Captured in Neutron Structures of A-DNA.
- Author
-
Vandavasi VG, Blakeley MP, Keen DA, Hu LR, Huang Z, and Kovalevsky A
- Subjects
- Crystallography, X-Ray, DNA, A-Form metabolism, Hydrogen Bonding, Models, Molecular, Neutron Diffraction, Nucleic Acid Conformation, Protons, Temperature, DNA, A-Form chemistry, Phosphates metabolism
- Abstract
Nucleic acids can fold into well-defined 3D structures that help determine their function. Knowing precise nucleic acid structures can also be used for the design of nucleic acid-based therapeutics. However, locations of hydrogen atoms, which are key players of nucleic acid function, are normally not determined with X-ray crystallography. Accurate determination of hydrogen atom positions can provide indispensable information on protonation states, hydrogen bonding, and water architecture in nucleic acids. Here, we used neutron crystallography in combination with X-ray diffraction to obtain joint X-ray/neutron structures at both room and cryo temperatures of a self-complementary A-DNA oligonucleotide d[GTGG(C
Se )CAC]2 containing 2'-SeCH3 modification on Cyt5 (CSe ) at pH 5.6. We directly observed protonation of a backbone phosphate oxygen of Ade7 at room temperature. The proton is replaced with hydrated Mg2+ upon cooling the crystal to 100 K, indicating that metal binding is favored at low temperature, whereas proton binding is dominant at room temperature., (Published by Elsevier Ltd.)- Published
- 2018
- Full Text
- View/download PDF
49. Metal-organic framework glasses with permanent accessible porosity.
- Author
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Zhou C, Longley L, Krajnc A, Smales GJ, Qiao A, Erucar I, Doherty CM, Thornton AW, Hill AJ, Ashling CW, Qazvini OT, Lee SJ, Chater PA, Terrill NJ, Smith AJ, Yue Y, Mali G, Keen DA, Telfer SG, and Bennett TD
- Abstract
To date, only several microporous, and even fewer nanoporous, glasses have been produced, always via post synthesis acid treatment of phase separated dense materials, e.g. Vycor glass. In contrast, high internal surface areas are readily achieved in crystalline materials, such as metal-organic frameworks (MOFs). It has recently been discovered that a new family of melt quenched glasses can be produced from MOFs, though they have thus far lacked the accessible and intrinsic porosity of their crystalline precursors. Here, we report the first glasses that are permanently and reversibly porous toward incoming gases, without post-synthetic treatment. We characterize the structure of these glasses using a range of experimental techniques, and demonstrate pores in the range of 4 - 8 Å. The discovery of MOF glasses with permanent accessible porosity reveals a new category of porous glass materials that are elevated beyond conventional inorganic and organic porous glasses by their diversity and tunability.
- Published
- 2018
- Full Text
- View/download PDF
50. Publisher Correction: Liquid phase blending of metal-organic frameworks.
- Author
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Longley L, Collins SM, Zhou C, Smales GJ, Norman SE, Brownbill NJ, Ashling CW, Chater PA, Tovey R, Schönlieb CB, Headen TF, Terrill NJ, Yue Y, Smith AJ, Blanc F, Keen DA, Midgley PA, and Bennett TD
- Abstract
The original version of this Article contained an error in Figure 1b, where the blue '(ZIF-4-Zn)
0.5 (ZIF-62)0.5 blend' data curve was omitted from the enthalpy response plot. This has now been corrected in both the PDF and HTML versions of the Article.- Published
- 2018
- Full Text
- View/download PDF
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