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La torrefacción y peletización se han estudiado en la generación de calor a partir de residuos lignocelulósicos, para incrementar las propiedades energéticas del material. El objetivo del presente trabajo fue torrefaccionar aserrín de Gmelina arborea y Dipteryx panamensis a 200 °C en tres tiempos: 0, 15 y 20 minutos. Con las biomasas obtenidas se fabricaron pellets de 6 mm de diámetro y se evaluaron sus propiedades físicas, el poder calórico, la densidad y la propiedad mecánica de resistencia a la compresión. Ambas especies presentaron características físicas similares con respecto al diámetro (0.50 mm), longitud (21.50 mm) y porcentaje de absorción de agua (6.00 %). El poder calórico aumentó de 9,749 kJ·kg-1 en la biomasa sin torrefaccionar a 18,126 kJ·kg-1 en la biomasa torrefaccionada. Los pellets de D. panamesis presentaron mayor densidad y resistencia a la compresión que los de G. arborea. Con base en los resultados, la resistencia a la compresión del pellet disminuye cuando el tiempo de torrefacción aumenta. Existe correlación positiva entre la densidad de los pellets y la resistencia a la compresión. La especie D. panamensis presenta mejor comportamiento a la torrefacción y peletización que la madera de G. arborea.

We evaluated the thermogravimetric and devolatilization rates of hemicellulose and cellulose, and the calorimetric behavior of the torrefied biomass, of five tropical woody species (Cupressus lusitanica, Dipteryx panamensis, Gmelina arborea, Tectona grandis and Vochysia ferruginea), at three temperatures (TT) and three torrefaction times (tT) using a thermogravimetric analyzer. Through a multivariate analysis of principal components (MAPC), the most appropriate torrefaction conditions for the different types of woody biomass were identified. The thermogravimetric analysis-derivative thermogravimetry (TGA-DTG) analysis showed that a higher percentage of the hemicellulose component of the biomass degrades, followed by cellulose, so that the hemicellulose energy of activation (Ea) was less than that of cellulose. With an increase in TT and tT, the Ea for hemicellulose decreased but increased for cellulose. The calorimetric analyses showed that hemicellulose is the least stable component in the torrefied biomass under severe torrefaction conditions, and cellulose is more thermally stable in torrefied biomass. From the MAPC results, the best torrefaction conditions for calorimetric analyses were at 200 and 225 °C after 8, 10, and 12 min, for light and middle torrefaction, respectively, for the five woody species.

Abstract Acetylation of softwoods has been largely investigated to increase the dimensional stability and biological resistance of wood. However, the knowledge of this technology has not been applied to tropical hardwood species up to date. The objective of this work was to study the effect of acetylation on nine tropical hardwood species, from forest plantations in Costa Rica, by applying acetic anhydride in three different treatment times (1 h, 2.5 h, 4 h), as well as to evaluate this by Fourier-Transform Infrared Spectroscopy (FTIR). Results showed that weight percentage gain (WPG) of wood varied from 2.2 to 16.8%, with Vochysia ferruginea species showing the highest WPG, and Gmelina arborea and Tectona grandis species exhibiting the lowest WPGs. Tropical woods such as Enterolobium cyclocarpum, Hieronyma alchorneoides and Samanea saman exhibited statistical differences among treatment times, whereas the rest of the species studied showed no significant differences. In general, the most effective acetylation time was 2.5 h for all the species. The ratio of intensity (RI) from the FTIR spectra was greater at the 1732 cm−1, 1372 cm−1 and 1228 cm−1 peaks for all tropical species, associated with lignin. A good correlation between the RI of those peaks and WPG was found; the same was also found between all RIs and each other. Meanwhile, RI associated to the hemicelluloses and lignin (1592 cm−1 and 1034 cm−1 peaks, respectively) showed no correlation with WPG, nor between each other or with the other RIs. Furthermore, it was suggested that RI at 1732 cm−1 (associated to acetyl groups C=O) can be considered as a reliable indicator of the degree of acetylation for tropical hardwood species. Finally, it was observed that tropical hardwoods having more suitable anatomical features, like larger vessel diameter, higher ray width and frequency, and lesser deposits such as gums and tyloses in the vessels, resulted in significantly higher WPGs.

The purpose of the biomass torrefaction and pelletizing processes is to increase its energy properties, be environmentally friendly, decrease shipping costs, and make handling easier. The objective of the present work is to evaluate the density, internal density variation by X-ray densitometry, moisture content, water absorption, and compression force of torrefied biomass pellets of five wood species (Cupressus lusitanica, Dipterix panamensis, Gmelina arborea, Tectona grandis, and Vochysia ferruginea) under three torrefaction temperature conditions (light, middle, and severe) and three torrefaction times (8, 10, and 12 min). The results showed that the bulk density of the pellets was 0.90–1.30 g/cm3. The density variation of the pellets was higher with torrefaction at 250 °C. The moisture content decreased with increasing torrefaction temperature from 3% to 1%. Water absorption was lower in the pellets torrefied at 250 °C. The compression force was lower in the pellets torrefied at 250 °C with approximate loads of 700 N. Based on the above results, it was concluded that pellets made with biomass torrefied at 200 °C have better energy properties and evaluated properties. According to these results, pellets fabricated with the torrefied biomass of tropical species can be used in stove, gas, and hydrogen production because the pellet presents adequate characteristics.