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Abstract The catalytic valorisation of biomass to afford synthetically useful small molecules is essential for sustainable biorefinery processes. Herein, we present a mild cascaded electrochemical protocol for converting furoic acid, a common biomass-derived feedstock, into a versatile platform chemical, gamma-butyrolactone. In the platinum(+)|nickel(−) electrode paired undivided cell, furoic acid is electrochemically oxidised with 84.2% selectivity to 2(5H)-furanone, the olefin of which is then hydrogenated to yield gamma-butyrolactone with 98.5% selectivity. The final gamma-butyrolactone yield is 69.1% with 38.3% Faradaic efficiency and 80.1% carbon balance when the reaction is performed with 100 mM furoic acid at 80 °C at +2.0 VAg/AgCl. Mechanistic investigation revealed the critical temperature and electrolyte pH conditions that maximise the production and protection of the key intermediate, furan radical, promoting its transition to 2(5H)-furanone rather than self-polymerising. The reaction is scalable, as 2.1 g of 98.1% pure gamma-butyrolactone is isolated through a simple solvent extraction.

The rapid growth of personal electronics has promoted a surge of e-waste worldwide. Among the e-waste stream, waste printed circuit boards (WPCBs) contain a lot of recyclable valuable metals that can incentivize the recycling operation when recovered. This pedagogical exercise demonstrates a simple electrocatalytic metal recovery strategy that works at room temperature and atmospheric pressure. Students can complete the exercise within 1.5-2 h and get to learn about electrocatalytic reactions and their parameters. The reaction can be powered by a couple of 1.5 V AA batteries and an electrolyte chemically similar to automobile antifreeze. Using quotidian objects can help students connect their laboratory learning with their daily lives. In addition to teaching electrochemistry concepts, we hope this exercise can raise awareness of the substantial increase of e-waste in recent years.