1. Isotope shifts in electron affinities and in binding energies of Pb and hyperfine structure of 207Pb−.
- Author
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Song, C. X., Yan, S. T., Godefroid, M., Bieroń, J., Jönsson, P., Gaigalas, G., Ekman, J., Zhang, X. M., Chen, C. Y., Ning, C. G., and Si, R.
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ISOTOPE shift ,ELECTRON affinity ,BINDING energy ,HYPERFINE structure ,AB-initio calculations - Abstract
The isotope shifts in electron affinities of Pb were measured by Walter et al. [Phys. Rev. A 106, L010801 (2022)] to be −0.002(4) meV for
207–208 Pb and −0.003(4) meV for206–208 Pb by scanning the threshold of the photodetachment channel Pb− ( S 3 / 2 ◦ 4 ) − Pb (3 P0 ), while Chen and Ning reported 0.015(25) and −0.050(22) meV for the isotope shifts on the binding energies measured relative to3 P2 using the SEVI method [J. Chem. Phys. 145, 084303 (2016)]. Here we revisited these isotope shifts by using our second-generation SEVI spectrometer and obtained −0.001(15) meV for207–208 Pb and −0.001(14) meV for206–208 Pb, respectively. In order to aid the experiment by theory, we performed the first ab initio theoretical calculations of isotope shifts in electron affinities and binding energies of Pb, as well as the hyperfine structure of207 Pb− , by using the MCDHF and RCI methods. The isotope shifts in electron affinities of207–208 Pb and206–208 Pb are −0.0023(8) and −0.0037(13) meV for the3 P0 channel, respectively, in good agreement with Walter et al.'s measurements. The isotope shifts in binding energies relative to3 P1,2 , −0.0015(8) and −0.0026(13) meV for207–208 Pb and206–208 Pb, respectively, are compatible with the present measurements. The hyperfine constant for the ground state of207 Pb− obtained by the present calculations, A ( S 3 / 2 ◦ 4 ) = − 1118 MHz, differs by a factor of 3 from the previous estimation by Bresteau et al. [J. Phys. B: At., Mol. Opt. Phys. 52, 065001 (2019)]. The reliability is supported by the good agreement between the theoretical and experimental hyperfine parameters of209 Bi. [ABSTRACT FROM AUTHOR]- Published
- 2024
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