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Education acts as an important catalyst for socioeconomic and democratic evolution in society and is a critical tool for building an equitable system. In our paper, we have historicized one of the most important educational policies, viz. Samagra Shiksha Abhiyan (SAMSA) in India that carries large expectations to minimize the educational divide. We have studied the policy through the lens of Political Economy and have further critiqued it through the framework of Critical Discourse Analysis. We find in our paper that the budget allocated to SAMSA was revised in 2022, from its preceding years with a 28 per cent slash. We critically reflect on the principles mentioned in the policy and find that although there has been an attempt to mitigate the hazards of banking education the 'Public-Private Partnership' initiative reinforces struggles for equitable education, and further, the privatization sets the government free from any accountability. Moreover, a constitutional right like the Right to Education (RTE) is not sufficient enough to meet the goals of universalisation of education. Besides, we analyse the principles such as 'Education for All', 'Equity', 'Equal Opportunity', 'Access', 'Gender Concern', 'Centrality of teacher', 'Moral Compulsion', and 'Convergent and integrated system of education management', and argue that although some of the facets of societal structural inequalities are addressed, however, there exists hardly a proper roadmap that could be monitoring the process of creating an inclusive educational paradigm.

The current study has investigated the thunderstorm induced atmospheric gravity waves (AGWs) over Indian region based on the perturbation signatures in ionospheric total electron content (TEC) measurement. Robust traveling ionospheric disturbance (TID) signature has been identified along the east side of the thunderstorm affected area. Neutral wind was found to have a favorable impact in this aspect for a certain time duration of the day by modulating the vertical wavelength. The role of temperature was analyzed in terms of kinematic viscosity which is a crucial component, especially over tropical region, for wave dissipation and reflection along its propagation path. Ray tracing algorithm is also applied with varying kinematic viscosity and thermal diffusivity for retrieval of possible ray paths and source location of observed waves. A statistical investigation has been carried out to identify the dissipation altitude of observed waves along the ray paths. It has been found that all waves dissipated at almost a constant altitude for a specific kinematic viscosity and above this altitude vertical wavelength was found to decrease. The ray paths interacted at a common point which was located at about 125 km altitude and was very close to the region of maximum lightning activity. It can also be noted that the observed phase velocities can't be achieved by a wave below the turbopause. It indicates that the observed waves were excited from a secondary source and not directly connected to convective system. The study provides an in‐depth analysis of mesoscale system induced gravity wave propagation and dissipation over tropical region. Plain Language Summary: Mesoscale convective systems in tropical regions are key sources of low‐frequency atmospheric gravity waves (GWs). GWs usually generates above thunderstorm altitudes and propagates to ionospheric heights through dissipation and atmospheric filtering. This is one of the first study about the propagation mechanism of thunderstorm‐generated GWs at thermospheric altitude over the Indian region. The concentric source of the wave was evidenced by concentric rings in traveling ionospheric disturbance and phase velocity Vp $\left({V}_{p}\right)$ trends which coincides with high lightning location. It is also observed that wave with Vp ${V}_{p}$ above 250 m/s were unable to propagate below 100 Km and indicate the secondary source of the gravity wave at thermospheric altitudes which was not directly related with the thunderstorm activity. The effect of background temperature on the propagation mechanism was tested by examining the role of kinematic viscosity on wave dissipation. The maximum momentum fluxes were found around 260 km altitude for a specific kinematic viscosity profile. Interestingly, the ray‐tracing validation fails one scale height above this altitude, aligning with theories of wave dissipation or reflection. Additionally, it was also observed that all waves interacted at a common point in both horizontal and temporal domains. This is one of the key finding of this investigation. Key Points: The study presents signature of thunderstorm induced gravity wave above lower thermospheric altitudePhase velocity and intrinsic period increased linearly from thunderstorm locationAn almost unique wave dissipation altitude found for all waves for a specific kinematic viscosity [ABSTRACT FROM AUTHOR]

Nationalism calls for one’s loyalty and affiliation towards their chosen nation. Various versions of nationalism emphasise that one must prioritise said nation above themselves and their personal ethics, hence, allowing the nation to overpower the nationalist’s individuality. In this article, we use Critical Discourse Analysis to deconstruct the narratives of nationalism as portrayed in two popular films, viz. The Kashmir Files and Uri: The Surgical Strike, which are based on real historical events – the exodus of Kashmiri Hindus and the surgical strike by the Indian Army in retaliation to the Uri attack. Both films use narrative strategies to frame key historical events into certain ideological contexts, and hence they serve the populist purpose of swaying viewers’ opinion in favour of the dominant socio-political class. [ABSTRACT FROM AUTHOR]

The role of friction in the functional performance of biomaterial interfaces is widely reckoned to be critical and complicated but poorly understood. To better understand friction forces, we investigated the natural adaptation of the holdfast or byssus of mussels that live in high-energy surf habitats. As the outermost covering of the byssus, the cuticle deserves particular attention for its adaptations to frictional wear under shear. In this study, we coacervated one of three variants of a key cuticular component, mussel foot protein 1, mfp-1 [(1) Mytilus californianus mcfp-1, (2) rmfp-1, and (3) rmfp-1-Dopa], with hyaluronic acid (HA) and investigated the wear protection capabilities of these coacervates to surfaces (mica) during shear. Native mcfp-1/HA coacervates had an intermediate coefficient of friction (μ ∼0.3) but conferred excellent wear protection to mica with no damage from applied loads, F⊥, as high as 300 mN (pressure, P, > 2 MPa). Recombinant rmfp-1/HA coacervates exhibited a comparable coefficient of friction (μ ∼0.3); however, wear protection was significantly inferior (damage at F⊥ > 60 mN) compared with that of native protein coacervates. Wear protection of rmfp-1/HA coacervates increased 5-fold upon addition of the surface adhesive group 3,4-dihydroxyphenylalanine, (Dopa). We propose a Dopa-dependent wear protection mechanism to explain the differences in wear protection between coacervates. Our results reveal a significant untapped potential for coacervates in applications that require adhesion, lubrication, and wear protection. These applications include artificial joints, contact lenses, dental sealants, and hair and skin conditioners.

Mussel adhesion to mineral surfaces is widely attributed to 3,4-dihydroxyphenylalanine (Dopa) functionalities in the mussel foot proteins (mfps). Several mfps, however, show a broad range (30-100%) of Tyrosine (Tyr) to Dopa conversion suggesting that Dopa is not the only desirable outcome for adhesion. Here, we used a partial recombinant construct of mussel foot protein-1 (rmfp-1) and short decapeptide dimers with and without Dopa and assessed both their cohesive and adhesive properties on mica using a surface forces apparatus (SFA). Our results demonstrate that at low pH, both the unmodified and Dopa-containing rmfp-1s show similar energies for adhesion to mica and self-self interaction. Cohesion between two Dopa-containing rmfp-1 surfaces can be doubled by Fe3+ chelation, but remains unchanged with unmodified rmfp-1. At the same low pH, the Dopa modified short decapeptide dimer did not show any change in cohesive interactions even with Fe3+. Our results suggest that the most probable intermolecular interactions are those arising from electrostatic (i.e., cation-π) and hydrophobic interactions. We also show that Dopa in a peptide sequence does not by itself mediate Fe3+ bridging interactions between peptide films: peptide length is a crucial enabling factor.

Numerous attempts have been made to translate mussel adhesion to diverse synthetic platforms. However, the translation remains largely limited to the Dopa (3,4-dihydroxyphenylalanine) or catechol functionality, which continues to raise concerns about Dopa's inherent susceptibility to oxidation. Mussels have evolved adaptations to stabilize Dopa against oxidation. For example, in mussel foot protein 3 slow (mfp-3s, one of two electrophoretically distinct interfacial adhesive proteins in mussel plaques), the high proportion of hydrophobic amino acid residues in the flanking sequence around Dopa increases Dopa's oxidation potential. In this study, copolyampholytes, which combine the catechol functionality with amphiphilic and ionic features of mfp-3s, were synthesized and formulated as coacervates for adhesive deposition on surfaces. The ratio of hydrophilic/hydrophobic as well as cationic/anionic units was varied in order to enhance coacervate formation and wet adhesion properties. Aqueous solutions of two of the four mfp-3s-inspired copolymers showed coacervate-like spherical microdroplets (ϕ ≈ 1-5 μm at pH ∼4 (salt concentration ∼15 mM). The mfp-3s-mimetic copolymer was stable to oxidation, formed coacervates that spread evenly over mica, and strongly bonded to mica surfaces (pull-off strength: ∼17.0 mJ/m(2)). Increasing pH to 7 after coacervate deposition at pH 4 doubled the bonding strength to ∼32.9 mJ/m(2) without oxidative cross-linking and is about 9 times higher than native mfp-3s cohesion. This study expands the scope of translating mussel adhesion from simple Dopa-functionalization to mimicking the context of the local environment around Dopa.

Surfactant self-assembly on surfaces is an effective way to tailor the complex forces at and between hydrophobic-water interfaces. Here, the range of structures and forces that are possible at surfactant-adsorbed hydrophobic surfaces are demonstrated: certain long-chain bolaform surfactants-containing a polydimethylsiloxane (PDMS) mid-block domain and two cationic α, ω-quarternary ammonium end-groups-readily adsorb onto thin PDMS films and form dynamically fluctuating nanostructures. Through measurements with the surface forces apparatus (SFA), it is found that these soft protruding nanostructures display polymer-like exploration behavior at the PDMS surface and give rise to a long-ranged, temperature- and rate-dependent attractive bridging force (not due to viscous forces) on approach to a hydrophilic bare mica surface. Coulombic interactions between the cationic surfactant end-groups and negatively-charged mica result in a rate-dependent polymer bridging force during separation as the hydrophobic surfactant mid-blocks are pulled out from the PDMS interface, yielding strong adhesion energies. Thus, (i) the versatile array of surfactant structures that may form at hydrophobic surfaces is highlighted, (ii) the need to consider the interaction dynamics of such self-assembled polymer layers is emphasized, and (iii) it is shown that long-chain surfactants can promote robust adhesion in aqueous solutions.

Understanding the interactions between collagen and adhesive mussel foot proteins (mfps) can lead to improved medical and dental adhesives, particularly for collagen-rich tissues. Here we investigated interactions between collagen type-1, the most abundant load-bearing animal protein, and mussel foot protein-3 (mfp-3) using a quartz crystal microbalance and surface forces apparatus (SFA). Both hydrophilic and hydrophobic variants of mfp-3 were exploited to probe the nature of the interaction between the protein and collagen. Our chief findings are: 1) mfp-3 is an effective chaperone for tropocollagen adsorption to TiO2 and mica surfaces; 2) at pH 3, collagen addition between two mfp-3 films (Wc = 5.4 ± 0.2 mJ/m(2)) increased their cohesion by nearly 35%; 3) oxidation of Dopa in mfp-3 by periodate did not abolish the adhesion between collagen and mfp-3 films, and 4) collagen bridging between both hydrophilic and hydrophobic mfp-3 variant films is equally robust, suggesting that hydrophobic interactions play a minor role. Extensive H-bonding, π-cation and electrostatic interactions are more plausible to explain the reversible bridging of mfp-3 films by collagen.

Understanding the interactions between collagen and adhesive mussel foot proteins (mfps) can lead to improved medical and dental adhesives, particularly for collagen-rich tissues. Here we investigated interactions between collagen type-1, the most abundant load-bearing animal protein, and mussel foot protein-3 (mfp-3) using a quartz crystal microbalance and surface forces apparatus (SFA). Both hydrophilic and hydrophobic variants of mfp-3 were exploited to probe the nature of the interaction between the protein and collagen. Our chief findings are: 1) mfp-3 is an effective chaperone for tropocollagen adsorption to TiO2 and mica surfaces; 2) at pH 3, collagen addition between two mfp-3 films (Wc = 5.4 ± 0.2 mJ/m(2)) increased their cohesion by nearly 35%; 3) oxidation of Dopa in mfp-3 by periodate did not abolish the adhesion between collagen and mfp-3 films, and 4) collagen bridging between both hydrophilic and hydrophobic mfp-3 variant films is equally robust, suggesting that hydrophobic interactions play a minor role. Extensive H-bonding, π-cation and electrostatic interactions are more plausible to explain the reversible bridging of mfp-3 films by collagen.

Mussel foot protein-1 (mfp-1) is an essential constituent of the protective cuticle covering all exposed portions of the byssus (plaque and the thread) that marine mussels use to attach to intertidal rocks. The reversible complexation of Fe(3+) by the 3,4-dihydroxyphenylalanine (Dopa) side chains in mfp-1 in Mytilus californianus cuticle is responsible for its high extensibility (120%) as well as its stiffness (2 GPa) due to the formation of sacrificial bonds that help to dissipate energy and avoid accumulation of stresses in the material. We have investigated the interactions between Fe(3+) and mfp-1 from two mussel species, M. californianus (Mc) and M. edulis (Me), using both surface sensitive and solution phase techniques. Our results show that although mfp-1 homologues from both species bind Fe(3+), mfp-1 (Mc) contains Dopa with two distinct Fe(3+)-binding tendencies and prefers to form intramolecular complexes with Fe(3+). In contrast, mfp-1 (Me) is better adapted to intermolecular Fe(3+) binding by Dopa. Addition of Fe(3+) did not significantly increase the cohesion energy between the mfp-1 (Mc) films at pH 5.5. However, iron appears to stabilize the cohesive bridging of mfp-1 (Mc) films at the physiologically relevant pH of 7.5, where most other mfps lose their ability to adhere reversibly. Understanding the molecular mechanisms underpinning the capacity of M. californianus cuticle to withstand twice the strain of M. edulis cuticle is important for engineering of tunable strain tolerant composite coatings for biomedical applications.