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Chronic respiratory symptoms are a health concern in the paper industry. This study evaluates the association between personal inhalable paper dust exposure and chronic respiratory symptoms among workers in this industry. In total, 270 workers from the paper industry and 267 from a water bottling factory participated. Chronic respiratory symptoms were assessed using a standardized questionnaire, modified from the American Thoracic Society. A job exposure matrix, based on cross-sectional personal measurements of inhalable paper dust, was used to estimate the exposure-response relationship between cumulative dust exposure and chronic respiratory symptoms. There was a higher prevalence of chronic coughs (27.4% vs. 7.5%), breathlessness (25.6% vs. 11%), coughs with sputum (21.1% vs. 1.1%), and wheezing (25.6% vs. 5%) among paper workers compared to those in the water bottling industry. A Poisson regression analysis revealed that the prevalence ratios for chronic coughs (APR = 3.3 and 95% CI: 2.0-5.4), breathlessness (APR = 2.2 and 95% CI: 1.4-3.4), and wheezing (APR = 4.3 and 95% CI: 2.3-7.7) were significantly higher in paper workers than in water bottling workers. Among paper workers, a significant exposure-response relationship was observed between cumulative dust exposure and chronic coughs after adjusting for age, sex, history of respiratory illnesses, work in other dusty industries, and use of biofuels. As there were only four ever-smokers, smoking was not included in the regression analysis. The results show a significant association between dust exposure and coughing, highlighting the need for control measures to prevent the development of respiratory symptoms among workers.

Background: Total paper dust exposure has been associated with respiratory problems among workers in the soft tissue paper industry. However, a comprehensive job exposure matrix (JEM) has not been developed for application to this industry. Our study was intended to address this need and to support further studies of mortality and morbidity in a cohort of Swedish workers from this industry., Methods: We evaluated four participating soft tissue paper mills in Sweden. We combined information on process and equipment status from the mills with knowledge of the mills obtained through research efforts and paper dust measurements made at all four mills to develop a semi-quantitative JEM with seven dust exposure levels. The JEM was targeted at workers enrolled into a soft tissue paper mill cohort and working any time between 1960 and 2009., Results: The JEM includes a total of 14 421 cells, with each cell corresponding to the exposure for a job title, department, or work location for a one-year period. Exposure levels in the JEM were estimated to decline at three of the four mills from 1971 to 2009, but overexposures (ie, exceedances of the relevant occupational exposure limits) remained common at the end of the period., Conclusions: The JEM results highlight the need for ongoing exposure control efforts in the soft tissue paper industry, and will inform ongoing epidemiological studies of the health effects of exposure to paper dust in Sweden. It is freely available for use by other researchers., (© 2020 Wiley Periodicals, Inc.)

Purpose: To study respiratory effects of exposure to soft paper dust exposure, a relationship that is rarely studied., Methods: Soft tissue paper mill workers at a Swedish paper mill were investigated using a questionnaire and lung function and atopy screening. Spirometry without bronchodilation was performed with a dry wedge spirometer, and forced vital capacity (FVC) and forced expiratory volume in 1 s (FEV 1 ) were obtained and expressed as percent predicted. Exposure to soft paper dust was assessed from historical stationary and personal measurements of total dust, in addition to historical information about the work, department, and production. The impact of high exposure to soft paper dust (> 5 mg/m 3 ) vs. lower exposure ≤ 5 mg/m 3 , as well as cumulative exposure, was analyzed using multiple linear regression models. Multivariate models were adjusted for smoking, atopy, gender, and body mass index., Results: One hundred ninety-eight current workers (124 male and 74 female) were included. There were significant associations between both cumulative exposure and years of high exposure to soft paper dust and impaired lung function. Each year of high exposure to soft paper dust was associated with a 0.87% decrease in FEV 1 [95% confidence interval (CI) - 1.39 to - 0.35] and decreased FVC (- 0.54%, 95% CI - 1.00 to - 0.08) compared to the lower exposed workers., Conclusions: The present study shows that occupational exposure to soft paper dust (years exceeding 5 mg/m 3 total dust) is associated with lung function impairment and increased prevalence of obstructive lung function impairment.

Objectives: Occupational exposure to soft paper dust is associated with impaired lung function. Whether there is an increased risk for asthma or chronic obstructive pulmonary disease (COPD) is unclear., Methods: We studied 7870 workers from three Swedish soft paper mills, and defined high-exposed workers, as having been exposed to soft paper dust exceeding 5 mg/m 3 for at least 5 years. The remaining workers were classified as 'low exposed'. Person-years at risk were calculated and stratified according to gender, age and calendar-year. The follow-up time was from 1960 to 2013. The expected numbers of deaths were calculated using the Swedish population as reference and standardised mortality ratios (SMRs) with 95% CIs were assessed., Results: There was an increased mortality due to obstructive lung disease (asthma and COPD), among high-exposed workers, SMR 1.89, 95% CI 1.20 to 2.83, based on 23 observed cases. High-exposed workers had an increased mortality from asthma, SMR 4.13, 95% CI 1.78 to 8.14, based on eight observed cases. The increased asthma mortality was also observed among high-exposed men, SMR 4.38, 95% CI 1.42 to 10.2, based on five observed cases. The asthma mortality among low-exposed workers, both men and women, was not increased. The COPD mortality was not clearly increased among high-exposed workers (SMR 1.52, 95% CI 0.85 to 2.50)., Conclusion: High occupational exposure to soft paper dust increases the mortality due to asthma, and the results suggest that soft paper dust levels in workplaces should be below 5 mg/m 3 ., Competing Interests: Competing interests: None declared., (© Author(s) (or their employer(s)) 2020. Re-use permitted under CC BY-NC. No commercial re-use. See rights and permissions. Published by BMJ.)

In the engine of heavy trucks, the built-in fuel filter assumes the role of "lungs". The core of the filter, namely the fuel filter paper, acts as a filter for small impurities and separates oil and water. In order to be able to separate minute impurities from the fuel, in this study, we prepared a novel fuel oil filter paper with high efficiency and high dust holding capacity based on wet-laid forming by laminating PBT/PP two-component melt-blown nonwoven material and cellulose nanocrystals (CNC)-doped cellulose wood fiber pulp with the fiber mesh combination forming technology. The effects of the CNC mixing ratio, surface density of melt-blown nonwoven material layer, surface density of cellulose wood pulp paper layer and calendaring pressure on the pore size and filtration performance of the composite samples were investigated, and the filtration efficiency of the composite samples on the tiny impurities in the fuel were also studied. The results showed that the novel composite fuel filter paper material prepared by the combined forming technology of fibrous web had high filtration efficiency and dust holding capacity, and the filtration efficiency of the composite samples could respectively reach 99.90% and 99.52% for particles larger than 14 μm and 4 μm in diameter in the fuel. At the same time, the dust holding capacity of the composite sample can reach up to 27.63 mgcm−2. [ABSTRACT FROM AUTHOR]

Bisphenol A (BPA) is found in polycarbonate plastic and epoxy resins and is used in a variety of commercial and consumer products. The leaching of BPA can result in human exposure via inhalation, ingestion, and dermal routes. As a result, humans have been exposed in their home and work environment to BPA. Conventional methods for BPA exposure assessment rely on cumbersome laboratory instrumentation with high capital and operational expenditures which limit the number of samples that can be analyzed. We report here the design of a compact portable colorimetric paper-based biosensing device with integrated sampling/analysis units for field-based measurements of BPA in indoor dust. The system employs interchangeable low-cost paper-based enzyme sensors as a test zone for BPA detection interfaced with an air-sampling cassette as a sample collection area. The sensor response was concentration-dependent with a detection limit of 0.28 μg/g. The sensor was validated with the conventional gas chromatography method and used to detect BPA exposure in household dust. BPA concentrations ranged from 0.05 to 3.87 μg/g in 57 household dust samples when both methods were used. The potential of this method for field measurements of dust samples is discussed.

Background: The primary aim of the present study was to investigate if exposure to dust from absorbent hygiene products containing superabsorbent polymer is related to symptoms from the airways and from the eyes. The secondary aim was to estimate the current exposure to superabsorbent polymer among production and maintenance workers in a plant producing hygiene products., Methods: The cohort comprised 1043 workers of whom 689 were exposed to super absorbent polymer and 804 were exposed to paper dust (overlapping groups). There was 186 workers not exposed to either superabsorbent polymer or to paper dust They were investigated with a comprehensive questionnaire about exposure, asthma, rhinitis and symptoms from eyes and airways. The results were analyzed with logistic regression models adjusting for sex, age, atopy and smoking habits. An aerosol sampler equipped with a polytetrafluoroethylene filter with 1 μm pore size was used for personal samplings in order to measure inhalable dust and superabsorbent polymer., Results: The prevalence of nasal crusts (OR 1.4, 95% CI 1.01-2.0) and nose-bleeding (OR 1.7, 95% CI 1.2-2.4) was increased among the paper dust exposed workers (adjusted for superabsorbent polymer exposure). There were no significant effects associated with exposure to superabsorbent polymer (adjusted for paper dust exposure). The average exposure to inhalable levels of total dust (paper dust) varied between 0.40 and 1.37 mg/m³. For superabsorbent polymer dust the average exposure varied between 0.02 and 0.81 mg/m³., Conclusions: In conclusion, our study shows that workers manufacturing diapers in the hygiene industry have an increased prevalence of symptoms from the nose, especially nose-bleeding. There was no relation between exposure to superabsorbent polymer and symptoms from eyes, nose or respiratory tract, but exposure to paper dust was associated with nose-bleeding and nasal crusts. This group of workers had also a considerable exposure to superabsorbent polymer dust.

The aliphatic and polycyclic aromatic fractions of dust collected in the vicinity of recycled paper processing operations were analyzed using gas chromatography/mass spectrometry. Total measured dust concentration (up to 8.73+/-2.02 mg/m3) fluctuated substantially in the different steps of paper manufacture. This was attributed to the type of the operation such as, the release of fibers and particles during paper cutting and the use of reactive chemicals and excessive water under high temperature and pressure during the bleaching and the water rinsing/drying step. Particulate polycyclic aromatic hydrocarbons (PAHs) (from fluorene to benzo[ghi]perylene with mean concentrations from 3.8+/-0.5 to 41.4+/-0.4 ng/m3) and the unresolved mixture of branched, cyclic and unsaturated hydrocarbons (UCM) were measured in all samples while, n-alkanes from n-C20 to n-C27, were only observed in cutting and packaging areas (from 180.6+/-18.9 to 4297.9+/-794.9 ng/m3). The profile of occupational PAHs in bleaching and treatment of contaminated recycled raw paper was comparable to that observed for anthropogenic activities. The values of molecular diagnostic ratios indicated the contribution of oil residues and emissions from worklifts and other equipment used for pulp and paper handling. Total benzo[a]pyrene-equivalent (BaP) concentrations of particulate PAHs (varied from 323 up to 1104 pg/m3), provided evidence that workers were exposed to high quantities of PAHs as compared with exposures to urban air and other indoor settings, posing long-term threat to their health.

Objectives: A cohort study of female pulp and paper workers in Norway has shown a significantly increased risk of ovarian cancer. Other than the involvement of hormonal and reproductive factors, little is known of the etiology of ovarian cancer. Asbestos and talc are two agents hypothesized to influence the development of the disease. The present study aimed to investigate the association between ovarian cancer and occupational exposure to asbestos, talc, and total dust among Norwegian pulp and paper workers., Methods: Forty-six cases of ovarian cancer, with four controls each, were included in the study. Occupational exposure was assessed by combining work histories from personnel files, questionnaire information about production processes, and exposure assessments from the mills. To obtain information about possible confounders, cases and controls were invited to participate in a personal interview., Results: The odds ratio for asbestos exposure was 2.02, 95% confidence interval 0.72-5.66. For talc exposure, the odds ratio was 1.10, and for ever exposure to total dust, it was below 1.00. The risk estimates did not essentially differ after adjustment for possible confounding variables., Conclusions: The results do not confirm an association between exposure to asbestos, talc, and total dust and ovarian cancer among Norwegian pulp and paper workers. However, the odds ratio for asbestos exposure was doubled, and control for established nonoccupational risk factors did not change the estimate. Therefore, the possibility that exposure to substances in the work environment contributes to the elevated risk cannot be rejected.

Objectives: To clarify whether occupational exposure to paper-dust is associated with an increased risk of non-infectious rhinitis., Methods: Thirty-seven workers exposed to paper-dust in a soft-paper mill were compared with 36 unexposed controls. The study was performed under normal working conditions during the non-pollen season. Medical and occupational history was taken down in a comprehensive questionnaire and nasal symptoms were scored on a visual analogue scale (VAS). Pulmonary and nasal function was assessed by spirometry, acoustic rhinometry and peak nasal inspiratory flow. Nasal lavage was analysed for interleukin-8 (IL-8) and nasal transit time was monitored with the saccharine test. Concentrations of inhalable dust for each exposed subject during the day of the clinical study were measured with personal sampling devices., Results: There was an increased prevalence of nasal blockage and crust formation among the exposed workers. However, there was no difference with regard to acoustic rhinometry, nasal transit time or nasal peak inspiratory flow. In the whole population, IL-8 in nasal lavage was higher among men than among women, 193 ng/l vs 132 ng/l, P = 0.006. There was also a positive trend (P = 0.01) with increasing nasal IL-8 going from non-smokers (122 ng/l), ex-smokers (126 ng/l) to current smokers (235 ng/l)., Conclusions: We have found that occupational exposure to paper-dust is associated with symptoms of nasal blockage and nasal crusting. We find no objective signs of nasal inflammation, even among the subgroup with the highest current exposure.

Exposure to organic dusts may cause airways inflammation in a large proportion of exposed persons. Most studies have relied on questionnaires and spirometry for diagnosis. To assess the possibility of determining the presence of inflammation using clinical diagnostic procedures, a study was undertaken among workers in a paper industry. Participants were 83 workers and 44 controls. Airborne endotoxin and (1-->3)-beta-D-glucan levels at the worksites were determined. The effects of this exposure were evaluated using a questionnaire, spirometry and measurements of airway responsiveness (methacholine) and levels of eosinophil cationic protein (ECP), myeloperoxidase (MPO), and C-reactive protein (CRP) in serum. The workers had a decreased baseline forced expiratory volume in one second (FEV1) and an increased airway responsiveness compared with controls. The concentrations of ECP and MPO were elevated compared with controls. There was a relation between exposure to endotoxin and (1-->3)-beta-D-glucan and airway responsiveness as well as ECP levels, when controlling for age, sex, smoking habits, atopy and asthma. The results suggest an increased prevalence of subjective respiratory symptoms, and an increased airway responsiveness among exposed workers. There was also a relationship between the serum concentration of eosinophil cationic protein and airway responsiveness. Taken together, the results suggest the presence of airways inflammation in the workers.

The effects of recycling paper dust extract on isolated nonsensitized guinea pig tracheal smooth muscle were studied in vitro. Dust extract was prepared as a 1:10 w/v aqueous solution. Dose related contractions of guinea pig tracheal rings were elicited with paper dust extract. Pharmacologic studies were performed with atropine (10(-6) M), indomethacine (10(-6) M), pyrilamine (10(-6) M), Ly 171883 (10(-5) M), NDGA (10(-5) M) and TMB8 (10(-5) M). The effects of extract were almost totally inhibited by the anticholinergic agent atropine, suggesting that a principal pathway mediating this response may involve the parasympathetic nervous system. The intracellular calcium blocking agent TMB8 also induced a reduction of the contractile response to paper dust extract, which is consistent with intracellular calcium's well established role in smooth muscle constriction. We suggest that paper dust extract causes dose related airway smooth muscle constriction, possibly associated with the release of cholinergic as well as other mediators. The constrictor effect does not require tissue presensitization.

The effect of paper dust collected at two different locations in a paper recycling plant (PD1 and PD2) on isolated nonsensitized guinea pig tracheal smooth muscle was studied in vitro. Dust extracts were prepared as a 1:10 w/v aqueous solution. Dose-related contractions of guinea pig tracheal rings were elicited with both PD1 and PD2. Pharmacologic studies were performed with atropine (10(-6) M), indometacin (10(-6) M), pyrilamine (10(-6) M), LY171883 (10(-5) M), nordihydroguaiaretic acid (10(-5) M), and TMB8 (10(-5) M). The possible role of endogenous neuropeptides in this constrictor process was studied by depleting neural mediators with capsaicin (5 x 10(-6) M) before challenge with dust extracts. Constrictor effects were partially inhibited by a wide variety of the mediator blocking agents. The effects of both extracts were almost totally inhibited by the anticholinergic agent atropine, suggesting that a principal pathway mediating this response may involve the parasympathetic nervous system. The intracellular calcium-blocking agent TMB8 also induced a reduction of the contractile responses to PD1 and PD2 consistent with the well established role of intracellular calcium in smooth muscle constriction. Pretreatment with capsaicin significantly increased the contractile activity of paper dust extracts but only at the higher doses of these extracts. This suggests that the effect of paper dust is not initiated by the release of mediators stored in sensory nerves but that the prerelease of these mediators may enhance the constrictor effects of these dusts. We suggest that paper dust extracts cause dose-related airway smooth muscle constriction possibly associated with the release of cholinergic as well as other mediators. The constrictor effect does not require tissue presensitization or the release of neuropeptides from sensory nerves.

Objective: To elucidate whether occupational noise exposure increases the mortality from ischemic heart disease (IHD) and stroke, and if exposure to paper dust modified the risks. Methods: We studied 6686 workers from soft paper mills, with occupational noise exposure, < 85 dBA, 85–90 dBA and > 90 dBA, and high (> 5 mg/m3) exposure to paper dust. Person-years 1960–2019 were stratified according to gender, age, and calendar-year. Expected numbers of deaths were calculated using the Swedish population as the reference and standardized mortality ratios (SMR) with 95% confidence intervals (95% CI) were assessed. Results: SMR for IHD was 1.12 (95% CI 0.88–1.41) for noise < 85 dBA, 1.18 (95% CI 0.90–1.55) for 85–90 dBA, and 1.27 (95% CI 1.10–1.47) among workers exposed > 90 dBA. Joint exposure to high noise exposure and high exposure to paper dust resulted in slightly higher IHD mortality (SMR 1.39, 95% CI 1.15–1.67). SMR for ischemic stroke was 0.90 (95% CI 0.37–2.15) for noise < 85 dBA, 1.08 (95% CI 0.45–2.59) for 85–90 dBA, and 1.48 (95% CI 0.99–2.00) among workers exposed > 90 dBA. High noise exposure and high exposure to paper dust resulted in higher ischemic stroke mortality (SMR 1.83, 95% CI 1.12–2.98). Conclusion: Noise levels > 90 dBA was associated with increased IHD mortality. Combined exposures of noise and paper dust may further increase the risks. Our results do not provide support for a causal relationship for ischemic stroke. Residual confounding from smoking has to be considered. Workers need to be protected from occupational noise levels exceeding 90 dBA. [ABSTRACT FROM AUTHOR]

The aim of the present cohort study was to investigate whether exposure to paper dust causes increased risk for respiratory symptoms or asthma. The cohort included all workers at a soft paper mill who had worked there for more than 1 year 1960-1986 (n = 1,697). Randomly selected inhabitants of the mill town (n = 781) were used as unexposed referents. Both groups were investigated using a postal questionnaire. From the paper mill cohort, workers with high cumulative exposure (n = 313), with medium cumulative exposure (n = 321), and with low cumulative exposure (n = 338) to paper dust were selected. In the 1960s and 1970s, the dust levels were between 5 and 10 mg/m3. After adjustment for smoking and gender, paper dust exposure resulted in elevated prevalence ratios for chronic cough, chronic phlegm, wheeze, and breathlessness. The prevalence ratios ranged from 1.3 to 2.5. No significantly increased risk of asthma was found among the exposed, incidence rate ratio 1.4 (95% confidence interval 0.93-1.8). Among the exposed, there was an insignificantly increasing incidence rate ratio, 1.0, 1.4, 2.1, with increasing cumulative exposure. In conclusion, an increased risk for respiratory symptoms was observed among workers exposed to paper dust, but the study does not permit any definite conclusions regarding asthma and paper dust exposure.

Background: Workers in pulp and paper factories are continuously exposed to paper dust. Excessive exposure to paper dust can cause respiratory disease. Information about the prevalence of chronic respiratory symptoms and dust exposure levels among workers in pulp and paper factories is not available in Ethiopia. The aim of this study was, therefore, to assess personal total dust exposure levels, the prevalence of chronic respiratory symptoms and their associated risk factors among workers in Ethiopian pulp and paper factories. Methods: A comparative cross-sectional study was conducted. A total of 40 dust measurements were carried out on 20 randomly selected workers. To assess chronic respiratory symptoms and associated factors, 434 workers from two paper factories and controls were interviewed using a standard questionnaire adapted from the American Thoracic Society (ATS). Gravimetric analyses of the filters were undertaken using a standard microbalance. Poisson regression was performed for comparing the prevalence of symptoms and risk factors for the two groups. Multivariable analyses were conducted to identify factors associated with chronic respiratory symptoms. Result: The arithmetic mean (AM) and geometric mean (GM) of dust exposure levels among the paper factories workers were 11.3 (± 7.7) and 10.2 (± 1.4) mg/m3 respectively. This exposure level exceeded the threshold limit value recommended for total dust (10 mg/m3). The prevalence of having at least one chronic respiratory symptom was about 51% among the workers in paper factories. The prevalence ratio of having chronic respiratory symptoms among paper factory workers was 5.6 times higher (PR = 6, 95% CI 3.5–10.3) than in the controls. Chronic respiratory symptoms were significantly associated with factors such as an educational status of less than grade 9, being employed in the work sections of the factories, having work experience of 5 years and above, working more than 8 h per day and having a past history of occupation and respiratory illnesses. Conclusion: The dust concentration in the paper factories exceeded the acceptable recommended limit value of 10 mg/m3. The prevalence of chronic respiratory symptoms among paper factory workers was higher than among controls. The main determining factors for chronic respiratory symptoms among the workers were the specific work section such as production section, low income, having past history of respiratory illnesses, the number of years of working and low educational status. This finding indicated the need for improving the working conditions in paper factories in Ethiopia. [ABSTRACT FROM AUTHOR]

Lung function deterioration has been reported among workers exposed to heavy exposure to paper dust (greater than 5 mg/m3). This pilot study was undertaken in order to evaluate the health effects of low exposure to paper dust (less than or equal to 1 mg/m3) in bookbinders. The study population consisted of 20 exposed subjects and 18 local office subjects. They were studied during identical conditions by means of dynamic and static spirometry, single breath wash-out with nitrogen (N2) and carbon monoxide (CO). The 90th percentile for daily average values of total dust was 0.6 mg/m3. Non-smoking exposed subjects had on the average an increase in FEV% (forced expiratory volume in one second in percentage of vital capacity) when compared to non-smoking local control subjects. We found a weak correlation between the increase in FEV% and daily average values of total dust (probably reflecting a higher exposure in the past). The results suggest that a low exposure to paper dust in bookbinders with a time of employment more than 10 years might cause a slight lung function deterioration without a clinical relevance.

The contributors used the sensibilization threshold to establish MACs for the dust of the fodder yeast produced as a result of pulp and paper waste products' recycling. The product belongs to the group of substances with low toxicity. It does not produce local irritation and exhibits sensibilization properties in case of both epi- and intracutaneous introduction. The sensibilization threshold in repeated introductions of protein-containing dusts was registered at 4.1 mg/m3. In industrial conditions, the fodder yeast concentrations at the level of about 4 mg/m3 caused increased morbidity with temporary disability.

The characteristics of airborne dust in a soft paper production plant have been characterized by scanning and transmission electron microscopy. A combination of X-ray diffraction, electron diffraction and energy-dispersive X-ray flouresence spectroscopy (EDX) was used to determine the structure and composition of the different components. Size distribution determination and phase identification were carried out. Besides the cellulose fibres, fibres of kaolinite, wollastonite, talc and other silicates were also identified. Gravimetric analysis and fibre counting by optical phase contrast microscopy were used to determine total dust and fibre concentrations. Total dust exposure at the plant was generally below 3 mg m-3. The respirable fraction of the total dust concentrations varied from 15 to 70%. The inorganic dust was 36 +/- 15% of the total dust. The ratio of inorganic fibres to total fibre concentration at the plant varied between 10 and 15%.

Purpose: To study cancer mortality among Swedish pulp and paper mill workers by main mill pulping process and department, and to present the Swedish part of an international exposure measurements database., Methods: A cohort of 18,163 male and 2,290 female workers at four sulfate and four sulfite mills, enrolled from 1939 to 1999, was followed up for mortality during 1952-2001. Standardized mortality ratios (SMRs) relative to the general Swedish population were calculated., Results: There were 1,340 malignant cases out of 5,898 deaths. Total cancer mortality was not increased in either sulfate or sulfite mill workers, or by gender. Lung cancer mortality was increased among female workers (SMR 1.70, 95% CI 1.04-2.63), especially in paper production, but not among male workers (SMR 0.91, 95% CI 0.79-1.04). Exposure to wood dust and sulfur dioxide frequently exceeded occupational exposure limits., Conclusions: Female paper production workers had an increased mortality from lung cancer.

Purpose: Excessive paper dust during paper production may harm the workers’ respiratory health. We wanted to assess the inhalable paper dust levels and its determinants among paper industry workers.A study was conducted in Ethiopia to assess the level of personal inhalable paper dust exposure among four paper mills. A total of 150 samples were collected using the IOM sampler attached to Side Kick Casella pumps at a flow rate of 2 L/min. The samples were analyzed in Nemko Norlab, Norway. Linear mixed-effect models were applied to identify determinants of inhalable paper dust.The geometric mean of personal inhalable paper dust was 3.3 mg/m3 with 80% of the measurements exceeding the Swedish occupational exposure limit (OEL) of 2 mg/m3. The linear mixed-effects model showed that the level of dust was 28% higher when using high-speed than when using low-speed rewinding machines, while paper mills with an average of more than four machines per job group had 22% higher exposure than paper mills with a lower number of machines. Furthermore, working in packing and preparation was associated with higher dust exposure than in other areas.The dust exposure levels were above the Swedish OEL for 80% of the samples. This indicates that preventive measures should be established in the industry. The exposure model identified high-speed rewinding machines, a high number of machines, and work in preparation and packing as associated with high levels of paper dust exposure.Methods: Excessive paper dust during paper production may harm the workers’ respiratory health. We wanted to assess the inhalable paper dust levels and its determinants among paper industry workers.A study was conducted in Ethiopia to assess the level of personal inhalable paper dust exposure among four paper mills. A total of 150 samples were collected using the IOM sampler attached to Side Kick Casella pumps at a flow rate of 2 L/min. The samples were analyzed in Nemko Norlab, Norway. Linear mixed-effect models were applied to identify determinants of inhalable paper dust.The geometric mean of personal inhalable paper dust was 3.3 mg/m3 with 80% of the measurements exceeding the Swedish occupational exposure limit (OEL) of 2 mg/m3. The linear mixed-effects model showed that the level of dust was 28% higher when using high-speed than when using low-speed rewinding machines, while paper mills with an average of more than four machines per job group had 22% higher exposure than paper mills with a lower number of machines. Furthermore, working in packing and preparation was associated with higher dust exposure than in other areas.The dust exposure levels were above the Swedish OEL for 80% of the samples. This indicates that preventive measures should be established in the industry. The exposure model identified high-speed rewinding machines, a high number of machines, and work in preparation and packing as associated with high levels of paper dust exposure.Results: Excessive paper dust during paper production may harm the workers’ respiratory health. We wanted to assess the inhalable paper dust levels and its determinants among paper industry workers.A study was conducted in Ethiopia to assess the level of personal inhalable paper dust exposure among four paper mills. A total of 150 samples were collected using the IOM sampler attached to Side Kick Casella pumps at a flow rate of 2 L/min. The samples were analyzed in Nemko Norlab, Norway. Linear mixed-effect models were applied to identify determinants of inhalable paper dust.The geometric mean of personal inhalable paper dust was 3.3 mg/m3 with 80% of the measurements exceeding the Swedish occupational exposure limit (OEL) of 2 mg/m3. The linear mixed-effects model showed that the level of dust was 28% higher when using high-speed than when using low-speed rewinding machines, while paper mills with an average of more than four machines per job group had 22% higher exposure than paper mills with a lower number of machines. Furthermore, working in packing and preparation was associated with higher dust exposure than in other areas.The dust exposure levels were above the Swedish OEL for 80% of the samples. This indicates that preventive measures should be established in the industry. The exposure model identified high-speed rewinding machines, a high number of machines, and work in preparation and packing as associated with high levels of paper dust exposure.Conclusions: Excessive paper dust during paper production may harm the workers’ respiratory health. We wanted to assess the inhalable paper dust levels and its determinants among paper industry workers.A study was conducted in Ethiopia to assess the level of personal inhalable paper dust exposure among four paper mills. A total of 150 samples were collected using the IOM sampler attached to Side Kick Casella pumps at a flow rate of 2 L/min. The samples were analyzed in Nemko Norlab, Norway. Linear mixed-effect models were applied to identify determinants of inhalable paper dust.The geometric mean of personal inhalable paper dust was 3.3 mg/m3 with 80% of the measurements exceeding the Swedish occupational exposure limit (OEL) of 2 mg/m3. The linear mixed-effects model showed that the level of dust was 28% higher when using high-speed than when using low-speed rewinding machines, while paper mills with an average of more than four machines per job group had 22% higher exposure than paper mills with a lower number of machines. Furthermore, working in packing and preparation was associated with higher dust exposure than in other areas.The dust exposure levels were above the Swedish OEL for 80% of the samples. This indicates that preventive measures should be established in the industry. The exposure model identified high-speed rewinding machines, a high number of machines, and work in preparation and packing as associated with high levels of paper dust exposure. [ABSTRACT FROM AUTHOR]

Over the past two decades the Global South is witnessing unprecedented economic transformation and Asian Cities in particular have a remarkable upsurge. Coimbatore, an industrial city in Southern India with an estimated population of 2 million (in 2022) is witnessing a rapid transition in terms of infrastructure development. In this context, the present study attempts to assess the particulate matter (PM 10 and PM 2.5 ) emissions at road network construction sites and the heavy metal fractionation in the road dust/sediment samples with a core focus to quantify the bioavailable fraction of metals (Fe, Cu, Cr, Cd, Pb and Ni) and its source apportionment in the road side dust/sediment samples. About 60 composite road dust/sediment samples were collected for heavy metal fractionation analysis in the six arterial roads that undergo core developments like construction of road over bridges, additional road incorporation and street expansions. PM monitoring revealed that 24 h average PM 2.5 (47 µg/m 3 ) and PM 10 (69 µg/m 3 ) concentrations at many construction sites exceeded 24 h average recommended by WHO guidelines [PM 2.5 (15 µg/m 3 ) and PM 10 (45 µg/m 3 ), respectively]. The bioavailable fractions of Fe, Cu, Cr and Cd are notably higher in the roadside sediment samples at road construction sites. Health Risk assessment, such as carcinogenic risks (Children-4.41 × 10 -2 , Adult-3.598 × 10 -6 ) and non-carcinogenic risks, inferred substantial risks at high intensity construction sites with statistical analyses, including PCA and cluster analysis, indicating considerable anthropogenic influences in the heavy metal fractions., (© 2024. The Author(s), under exclusive licence to Springer Nature B.V.)

Addressing solid waste recycling, this study aims to develop biodegradable kraft paper from buffing dust (BD) and post‐consumed jute fiber (JF). Employing a simple solution casting method with a polyurethane binder, the kraft paper was fabricated and characterized using UV–Vis spectroscopy, FTIR, XRD, SEM, TGA, OTR, biodegradability, and tensile tests. The findings revealed covalent and hydrogen bonding between BD and JF, forming a uniform surface. Notably, the composite exhibited improved thermal stability, enhanced gas barrier properties, and biodegradability compared to individual components. Furthermore, the composite also showed 57% higher tensile strength, 38% greater elongation, 20% increased hardness, and 9% higher density compared to buffing dust. Compared to jute fiber, the increases were 125%, 91%, 30%, and 19% respectively. Moreover, the composite excelled in gas barrier performance, surpassing BD and JF by a remarkable 61% and 73% increase respectively. These significant findings underscore the vast potential of the composite kraft paper as a versatile material suitable for various applications, including packaging, interior furnishing industries, and reinforcing elements in the footwear industry. By addressing waste management and promoting sustainability, this research contributes to the development of eco‐friendly materials that align with contemporary environmental concerns. Highlights: Covalent and hydrogen bonding enhance uniformity.Biodegradable kraft paper with improved properties.Impressive tensile strength, elongation, and hardness.Versatile material for eco‐friendly applications.Promotes sustainability and waste management. [ABSTRACT FROM AUTHOR]

Copyright of China Pulp & Paper is the property of China Pulp & Paper Magazines Publisher and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)

The technical properties of three layered cement-bonded boards (CBBs) made from wastepaper and sawdust were investigated. The CBBs were produced at three density levels of 1000, 1200 and 1300 kg/m3 and at four cement/particle ratios of 2.0:1, 2.5:1, 3.0:1 and 3.5:1 on a weight to weight basis. The technical properties evaluated were modulus of rupture (MOR), modulus of elasticity (MOE), water absorption (WA) and thickness swelling (TS). The MOR values ranged from 4.85 to 11.69 MPa and MOE values ranged from 2.80 to 5.57 GPa. The mean values of WA and TS after 24 h of water soaking of the CBBs ranged from 18.18% to 40.49% and 3.55% to 12.13%, respectively. MOR and MOE of the CBBs increased with increase in board density, but MOR decreased with the increase in cement/particle ratio. On the other hand, WA and TS decreased with increase in board density and cement/particle ratio. CBBs produced from wastepaper and sawdust at cement/particle ratios of 3.0:1 and 3.5:1 are suitable for building construction such as paneling, ceiling and partitioning.

The aim of the present cross-sectional study was to investigate whether long-term exposure to soft paper dust causes impairment of lung function. Exposed workers (n = 287) and referents (n = 79) were investigated, using spirometry and questionnaires. Personal samplings of total dust showed that the actual mean concentrations did not exceed 3 mg/m3. The exposed subjects were divided into three categories according to historical and present exposure to paper dust; low exposure, moderate exposure and high exposure. The study did not show any lung function impairment due to exposure to paper dust. However, the exposed subjects had a significantly increased prevalence of symptoms from both the upper and lower airways as well as an increased prevalence of reported asthma. On the basis of our study, we conclude that lung function impairment does not occur among workers exposed to mean levels of soft paper dust below 5 mg/m3.

The objective of this study was to investigate if the dust in a mill producing soft paper tissue caused respiratory symptoms or impaired respiratory function. Using a questionnaire and spirometry, 355 persons were examined. They were divided into three groups according to present exposure to dust; low (less than 1 mg/m3), moderate (1-5 mg/m3) and heavy (greater than 5 mg/m3). There was a dose-dependent increase of symptoms from the upper respiratory tract. However, coughing and coughing with phlegm were not found to be more common among persons with heavy exposure compared to those with low exposure to the dust. There was no difference in FEV1 or FVC during a work shift. Persons with long-term (greater than 10 years) and heavy exposure to dust seemed to have impaired respiratory function compared to those with low and/or short-term exposure to the dust.

In a cross-sectional study, 13 nonsmoking men with heavy exposure to paper dust were compared with 14 unexposed men, mainly office workers, employed at the same paper mill. They were studied using questionnaires, physical examinations, pulmonary function studies, and chest radiographs. Among those exposed there was an increased lung elastic recoil pressure (Pel) compared with controls which was significant (p less than 0.05) at the maximal level of total lung capacity (100% TLC). Furthermore, among the exposed workers there was also a significantly (p less than 0.05) decreased residual volume (RV). Two of the exposed men underwent lung biopsies, one of which showed fibrotic alveolar walls. Among the exposed there was also a significant (p less than 0.05) predominance of symptoms from the lower respiratory tract. We suggest that the observed pulmonary function impairment taken together with the histological examination of the lung biopsies are signs of a nonspecific reaction to high levels of paper dust.

The prevalence of bagassosis was investigated in a Louisiana paper mill, which in the past had considerable numbers of workers with the disease. Based on negative clinical histories and the low number of positive serological reactions of the workers' serum with Thermoactinomyces sacchari antigen, it was concluded that bagassosis was no longer present. This was thought to be due to a different method of storage of bagasse, which retards microbial decay and reduces airborne organic dust, and to the increased awareness of plant management resulting in greater safety measures.

The leather sector is currently under heavy threat to reduce environmental pollution problems associated with the generation of leather waste, especially in terms of public acceptance issues related to environmental welfare requirements. Leather waste must be disposed of in landfills, which has a significant environmental impact. The development of natural polymer/paper mill sludge-based leather replacements for the production of leather goods and footwear products is an alternative solution supported by the recycled leather industry. In this work, a study is carried out to prepare natural polymer leather sheet (NPLS) from leather waste (chrome shavings and buffing dust), paper mill sludge, and natural polymer [natural rubber latex (NRL)] by vacuum-pressure method, for their potential application in leather products industries. The NPLS was characterized by its physicochemical and mechanical properties. Various types of NPLS were produced by comprising different ratios of the NRL. Results portrayed that 300 mL w/v NRL significantly improved the physicochemical and mechanical properties of NPLS. Hence, the research has revealed a revolutionary idea of NPLS developed which is cost-effective, eco-friendly, and energy efficient. [ABSTRACT FROM AUTHOR]

Especially in the field of paper and print post-processing on an industrial scale, continuous cutting operations generate paper dust. Despite preventive measures like dedusting units, a high paper web velocity induces the release of particulate dust. As a result, the particles settle and accumulate on machine components and in the surrounding area. Resuspended particles around a potential ignition source represent a fire hazard. The prevention of such fire incidents requires frequent servicing and maintenance. However, the shutdown time on industrial scale applications remains cost-intensive. In this research, a cutting plotter executes reproducible knife edge cutting sequences to identify significant parameters affecting the paper dust formation on a macro and micro scale. For this purpose, an extraction system collects the exposed particles along the cutting line. The applied methods include gravimetric determination of the dust mass and dynamic image analysis to characterise particle size and shape. Final results indicate a significant influence of the blade wear condition. [ABSTRACT FROM AUTHOR]

Dust poses environmental, geological, health, and economic concerns, and microorganisms can help mitigate these adverse consequences by improving soil properties. Microbial calcium carbonate precipitation (MICP) has been found to be an efficient strategy for increasing soil strength, reducing soil porosity, and preventing erosion; however, severe environmental conditions such as pH and high temperatures may impede this process. To identify the best strain for MICP, 60 bacteria strains were obtained from arid soils using the enrichment culture technique. They were tested for the capacity of calcium carbonate deposition and biocement synthesis in stress environments. Phenotypic characterization indicated that the majority of the bacterial isolates were gram-positive and rod-shaped, with strong catalase and oxidase enzyme activity. Furthermore, MALDI-TOF MS identification revealed that the isolates were from the Bacillus and Pseudomonas genera. Scanning Electron Microscopy (SEM), Energy-dispersive X-ray spectroscopy (EDS), and X-ray diffraction (XRD) were used to analyze the microstructures and composition of bacterial cement. The results represented that B. subtilis isolate S56 has a higher production yield and forms distinctive calcite crystals as a result of fast urease synthesis. B. subtilis isolate S56 can be applied in situ to reduce soil erosion and dust pollution. This study reveals the potential of the B. subtilis S56 strain for soil consolidation and dust prevention in harsh environments and has the prospect of promoting its application in desertification control and ecological restoration., (© 2024. The Author(s).)

Air filters are placed upstream of internal combustion engines to remove dust particles in the suction air. In this article, we examine the acoustic characterization of an air-filtering unit in the absence of mean flow. For this purpose, a circular air-filtering unit with an axial inlet and side outlet widely used in the automobile industry is considered. The air-filter element is modeled as an equivalent acoustic fluid with finite flow resistivity. The flow resistivity of the region is estimated from the permeability of the filter paper and the geometrical arrangement of the paper folds (pleats) inside the air-filter element using an electrical analogy. A numerical model based on the finite element method (FEM) and an analytical model using classical one-dimensional plane wave analysis (1-D PWA) was developed. Experiments were carried out using an impedance tube to estimate transmission loss. A good correlation is observed between the FEM model and the experiments. The results obtained from the 1-D PWA are in reasonable agreement with those obtained from the other two methods. [ABSTRACT FROM AUTHOR]

Fluorides are emitted in both gaseous and particle forms in the industrial sector. However, studies usually only report total fluoride content. Therefore, the study aimed to assess the particulate, gaseous fluoride and correlate it with the respirable dust particles in Single Super Phosphate (SSP), Granular Single Super Phosphate (GSSP), and administration divisions of the industry. Respirable dust particles, particulate fluoride, and hydrogen fluoride in the work environment were collected on a filter cassette containing an MCE filter paper (0.8 micron 37-mm) and Na2CO3 impregnated backup pad, respectively, using a personal sampler. The fluoride samples were analyzed using Ion Selective Electrode (ISE) and expressed as milligrams per meter cube (mg.m-3). The respirable dust, particulate, and gaseous fluoride content were found to have statistically significant differences (p<0.001) between the divisions (SSP, GSSP, and administration) in the static monitoring, whereas, in the case of personal monitoring, no significant differences were observed. Average airborne respirable, particulate, and gaseous fluoride levels in static monitoring were 1.37, 1.03, 0.20 mg.m-3, 0.018, 0.008, 0.001 mg.m-3, and 0.808, 0.403, 0.026 ppm in SSP, GSSP and administration respectively, whereas in personal monitoring the average respirable, particulate and gaseous fluoride concentrations were 1.18, 0.85, 0.30 mg.m-3, 0.0013, 0.007, 0.002 mg.m-3 and 0.356, 0.258, 0.011 ppm in SSP, GSSP and administration respectively. The present study observed that the levels of fluoride decreased with an increase in distance from SSP, followed by GSSP and administration. It indicates that the fluoride exposure was inversely proportional to the distance of the source. This study outcome will help to design a policy and intervention to mitigate fluoride exposure among workers. [ABSTRACT FROM AUTHOR]

Copyright of China Pulp & Paper is the property of China Pulp & Paper Magazines Publisher and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)

Leaking manhole covers add inflow to sanitary sewer systems. These are the most accessible components of the sewer system, and so potentially the cheapest to repair or modify, to reduce inflow. There is, however, very little data regarding manhole cover leakage available to evaluate the cost-benefit of such an approach, and there is no field data. So, a multi-year field study of inflow was conducted. Two-hundred and fifty manholes in New York City and surrounding towns were tested. A key field observation in this study was that a dust and grit seal typically built up between the cover and the rim. This seal had a big impact on leakage rates. This made testing in-situ a necessity, and the test method had to preserve this seal. Due to the presence of the dust and grit seal, approximately 80% of the manholes tested showed no leakage. A further 15% had slow leaks. Only 5% had significant leaks., Competing Interests: The authors declare there is no conflict., (© 2024 The Author This is an Open Access article distributed under the terms of the Creative Commons Attribution Licence (CC BY 4.0), which permits copying, adaptation and redistribution, provided the original work is properly cited (http://creativecommons.org/licenses/by/4.0/).)

Endotoxins in grain dust, household dust, and animal bedding may induce respiratory symptoms in rodents and humans. We assayed the endotoxin, coliform, and dust levels in 20 types of rodent bedding. Endotoxin concentrations were measured by using a commercial test kit, coliform counts were determined by using conventional microbiologic procedures, and dust content was evaluated by using a rotating-tapping shaker. Paper bedding types contained significantly less endotoxin than did other bedding types; the highest levels of endotoxin were detected in hardwood and corncob beddings. The range of endotoxin content for each bedding type was: corncob bedding, 1913 to 4504 endotoxin units per gram (EU/g); hardwood bedding, 3121 to 5401 EU/g; corncob-paper mixed bedding, 1586 to 2416 EU/g; and paper bedding, less than 5 to 105 EU/g. Coliform counts varied from less than 10 to 7591 cfu/g in corncob beddings, 90 to 4010 cfu/g in corncob-paper mixed beddings, less than 10 to 137 cfu/g in hardwood beddings, and less than 10 cfu/g in paper beddings. Average dust content was less than 0.15% in all commercial bedding types. We conclude that paper bedding is the optimal bedding type for conducting LPS inhalation studies and that rodent bedding containing high levels of endotoxin may alter the results of respiratory and immunologic studies in rodents.

Solar cells are considered one of the most important and widespread solar applications in the world. However, the performance of the PV modules is significantly affected by the dust in the air. This paper, therefore, presents a comparison of an outdoor experimental study of dust effect on monocrystalline, and polycrystalline photovoltaic (PV) modules. For analysis, four 100 W PVs were installed horizontally in Sohar, Oman. For each pair of PV modules, one was left dusty due to environmental impact, and the second was cleaned daily. PV performance and environmental parameter measurements were conducted every 30 min for 35 days. The effects of dust on current, voltage, power, and energy were discussed in terms of time and normalized values. Also, cleaning methods were tested to determine the optimum one. It is found that power degradation of monocrystalline (20%) is higher compared with polycrystalline (12%) due to dust accumulation. For monocrystalline, the current, voltage, and power losses ranged between 10.0-24.0%, 2.0-3.5%, and 14.0-31.0%, respectively. However, for polycrystalline, the degradation rates were 16.88-27.92%, 0.455-0.455%, and 17.14-28.1% for current, voltage, and power losses after exposure to outdoor conditions for the same period, respectively. The dust accumulation on the PV surface found after 5 weeks is 0.493 mg/cm 2 , which can be considered the lowest accumulation rate compared to other Gulf countries, but which, however, leads to less energy degradation as well. It is found that water is sufficient to clean PV in the study area. However, sodium detergent as a cleaner introduced better results compared to water, especially when there is high pollution in the location., (© 2022. The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature.)

Organic dust exposure can influence the development and symptoms of immune-related diseases such as atopy and asthma, but has rarely been examined in relation to systemic autoimmunity. The present analyses explore the association of lifetime farm and occupational organic dust exposures with systemic lupus erythematosus (SLE) in recently diagnosed patients (n = 265) compared with controls (n = 355) frequency matched by age, sex and state. Questionnaire data included childhood farm residence, childhood and adult experience with specific crops, and adult work in textiles, hog or poultry processing and paper or furniture manufacture. Adjusted odds ratios (OR) and 95% confidence intervals (CI) were estimated by logistic regression models including age, sex, state, race, education and silica exposure. Overall childhood or adult farm contact and childhood farm residence were not associated with SLE. Farm contact with livestock was inversely associated with SLE (OR = 0.55, 95% CI 0.35, 0.88). This effect was most pronounced among those with childhood farm residence and both childhood and adult livestock exposure (OR = 0.19; 95% CI 0.06, 0.63), but was difficult to separate from adult exposure to grains or corn. Other adult occupational exposures were not associated with SLE risk overall, regardless of childhood farm residence or livestock exposure, although an inverse association was seen among non-smokers (OR = 0.59; 95% CI 0.33, 1.1), particularly for textile work (OR = 0.34; 95% CI 0.19, 0.64). These exploratory findings support the development of studies to specifically investigate the effects of organic dust exposure on SLE risk, with particular attention to exposure assessment and characterization of demographics, smoking and other occupational exposures.

In this work, the performance of residual iron dust (RID) from metallurgic industry was assessed as Fenton catalyst for the treatment of real pulp bleaching wastewater. The focus was on the removal of recalcitrant pollutants AOX (adsorbable organic halides), by a novel, cleaner, and cost-effective circular solution based on a waste-derived catalyst. The behaviour of RID as iron source was firstly assessed by performing leaching tests at different RID:wastewater w/v ratios and contact time. Afterwards, RID-catalysed homogeneous and heterogeneous Fenton processes were conducted to maximise AOX removal from the pulp bleaching wastewater. Reusability of RID was assessed by a simple collect-and-reuse methodology, without any modification. Similar AOX removal under less consumption of chemicals was achieved with the novel heterogeneous Fenton process. Reaction in the bulk solution was the main pathway of AOX removal, given that the low surface area and porosity of the material did not allow for a high contribution of surface reaction to the overall performance. Moreover, AOX removal was similar over two consecutive treatment cycles, with Fenton process being responsible for 56.7–62.1% removal of AOX from the wastewater, and the leaching step adding 11.4–13.2%. At the end of treatment, COD either decreased (1st cycle) or remained unchanged (2nd and 3rd cycle). The operating cost of the optimised heterogeneous Fenton was 3–11% lower than under conventional Fenton process. This work presented a novel, circular solution based on a low-cost waste-derived catalyst, advancing the knowledge needed to foster industrial application of such technologies to increase industrial environmental performance and efficiency. [Display omitted] • Residual iron dust successfully catalysed Fenton process, acting mainly as iron supplier. • Catalyst performance in removing AOX was maintained over consecutive treatment cycles. • The catalyst was successfully reused without any modification or regeneration. • Operating cost of the heterogeneous Fenton was 3–11% lower than conventional Fenton. [ABSTRACT FROM AUTHOR]

• ZIF-67 particles can be evenly distributed and tightly attached to the cellulose paper substrate. • Mild synthesis conditions combined with papermaking processes are suitable for mass production. • The composite filter has a hierarchical porous structure with a large specific surface area. • The optimum sample exhibited removal efficiencies of 98.52% for PM 2.5 and 99.00% for PM 10. • Composite papers possessed excellent mechanical properties and reusability. The combination of functional zeolitic imidazolate frameworks (ZIFs) with suitable substrates is promising for the preparation of advanced filtering materials. In this study, the bleached kraft softwood pulp (NBKP) was composited with ZIF-67 particles via an in situ growth method to fabricate functional paper. Enabled by the traditional papermaking process, ZIF-67 crystals were uniformly and tightly anchored on cellulosic fibers in a facile and economic way. The introduction of ZIF-67 boosted the mechanical performances of the composite paper owing to the presence of electrostatic interactions and hydrogen bonds. Meanwhile, the resultant paper presents hierarchical porous structure with a large specific surface area of 327.07 m2·g−1. The filters with hierarchical pore structure will provide a complex tortuous channel for passing particulates, which can increase the frequency of effective collision between filters and particulates. Air filtering tests demonstrated that the ZIF-67 entrapped paper has superior particle removal efficiency with a low pressure drop and a large dust holding capacity. The optimal ZP-3 sample displayed removal efficiencies of 98.52 % for PM 2.5 and 99.00 % for PM 10. Meanwhile, filtration quality factors were calculated to be 0.15 (PM 2.5) and 0.17 (PM 10), respectively. The filter also has good antibacterial activity. In addition, ZP-x composite paper is easy to regenerate and possesses good reusability. The high-efficient ZP-x filter will have potential applications in fields of air purification. [ABSTRACT FROM AUTHOR]

Objectives Paper dust has previously been linked to adverse health effects. However, a comprehensive dataset of paper dust exposures does not appear to have been published previously. Our study was intended to address this need by describing a large dataset of measurements made in Swedish soft tissue paper mills. Methods We compiled personal and area total dust exposure measurements collected from a range of operations by our research staff at four soft tissue paper mills in Sweden. We also compiled measurements made by the occupational health staff at each mill and the Swedish Work Environment Authority. We analyzed these measurements to describe patterns and trends in exposures and used mixed-effects regression models to identify measurement characteristics that predicted exposure levels. Results We compiled 1578 measurements from 1971 to 2009, of which 1026 (65%) were personal samples. Statistically significant differences were found between measurements made by research, mill, and Swedish Work Environment Authority staff, as well as between personal and area measurements. The measurement data suggest that, beginning in the 1980s, exposures declined at three of the four mills, but that overexposures were still common at the end of the period. Papermaking and converting operations had the highest observed dust exposures. One mill had significantly lower exposures than the others. Type of measurement (personal versus area) and source of measurement (research staff, company, or regulatory agency) were not significant predictors of measured total dust exposure after controlling for mill, operation, and time. Conclusions Our analysis of measured paper dust exposures may be useful for historical and contemporary exposure assessment in our own and other epidemiological studies. We have identified specific characteristics (i.e. papermaking operations and mill) and time trends that are important data features to consider, and documented continuing overexposure situations. Our results highlight the ongoing need for application of exposure controls to reduce paper dust exposures in the soft tissue paper industry. [ABSTRACT FROM AUTHOR]