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Starch based bioplastics were prepared and characterized with fillers carboxy methyl cellulose (CMC), chitosan (CS) and nanochitosan (NCS); plasticizer sorbitol and cross‐linking agent citric acid (CA) at different loading levels. Structural, water resistance, water vapor permeability, solubility, mechanical, antimicrobial and biodegradation properties of the bioplastics were investigated. FTIR confirmed bonding of starch with cross‐linking agent, fillers and plasticizer. The water uptake of the CMC bioplastics was decreased up to 70 % with 20 % CA addition. Bioplastics with CS and NCS showed lesser water uptake, only 12.5 % for CS bioplastic. The water vapour permeability (WVP) of all bioplastics was low in the range 2.16×10−7–6.29×10−7 gday−1 m−1 Pa−1. The CA addition increased water resistance and lowered WVP of the bioplastics by restricting the hydrophilic functional groups and forming more tight structures. The fillers CS and NCS additions enhanced the mechanical strength attributing to more hydrogen bonding between NH3+ of chitosan and OH− of starch. All bioplastics demonstrated good antimicrobial activities. These bioplastics offer an attractive alternative to non‐biodegradable plastics used in food packaging due to its enhanced water resistance, antibacterial properties and biodegradability. [ABSTRACT FROM AUTHOR]

The synthesis of conventional plastics has increased tremendously in the last decades due to rapid industrialization, population growth, and advancement in the use of modern technologies. However, overuse of these fossil fuel-based plastics has resulted in serious environmental and health hazards by causing pollution, global warming, etc. Therefore, the use of microalgae as a feedstock is a promising, green, and sustainable approach for the production of biobased plastics. Various biopolymers, such as polyhydroxybutyrate, polyurethane, polylactic acid, cellulose-based polymers, starch-based polymers, and protein-based polymers, can be produced from different strains of microalgae under varying culture conditions. Different techniques, including genetic engineering, metabolic engineering, the use of photobioreactors, response surface methodology, and artificial intelligence, are used to alter and improve microalgae stocks for the commercial synthesis of bioplastics at lower costs. In comparison to conventional plastics, these biobased plastics are biodegradable, biocompatible, recyclable, non-toxic, eco-friendly, and sustainable, with robust mechanical and thermoplastic properties. In addition, the bioplastics are suitable for a plethora of applications in the agriculture, construction, healthcare, electrical and electronics, and packaging industries. Thus, this review focuses on techniques for the production of biopolymers and bioplastics from microalgae. In addition, it discusses innovative and efficient strategies for large-scale bioplastic production while also providing insights into the life cycle assessment, end-of-life, and applications of bioplastics. Furthermore, some challenges affecting industrial scale bioplastics production and recommendations for future research are provided. [ABSTRACT FROM AUTHOR]

Plastic pollution poses a significant environmental challenge, necessitating the investigation of bioplastics with reduced end-of-life impact. This study systematically characterizes four promising bioplastics—polybutylene adipate terephthalate (PBAT), polybutylene succinate (PBS), poly(3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV), and polylactic acid (PLA). Through a comprehensive analysis of their chemical, thermal, and mechanical properties, we elucidate their structural intricacies, processing behaviors, and potential morphologies. Employing an environmentally friendly process utilizing supercritical carbon dioxide, we successfully produced porous materials with microcellular structures. PBAT, PBS, and PLA exhibit closed-cell morphologies, while PHBV presents open cells, reflecting their distinct overall properties. Notably, PBAT foam demonstrated an average porous area of 1030.86 μm2, PBS showed an average porous area of 673 μm2, PHBV displayed open pores with an average area of 116.6 μm2, and PLA exhibited an average porous area of 620 μm2. Despite the intricacies involved in correlating morphology with material properties, the observed variations in pore area sizes align with the findings from chemical, thermal, and mechanical characterization. This alignment enhances our understanding of the morphological characteristics of each sample. Therefore, here, we report an advancement and comprehensive research in bioplastics, offering deeper insights into their properties and potential morphologies with an easy sustainable foaming process. The alignment of the process with sustainability principles, coupled with the unique features of each polymer, positions them as environmentally conscious and versatile materials for a range of applications. [ABSTRACT FROM AUTHOR]

Within the scope of the current study, the researchers developed activities for middle school students to raise their awareness on the harm of plastics and microplastics, which are detrimental to nature and living things. In addition, through the activities developed, the study aimed to provide students with knowledge of and experience with bioplastics, which have emerged as an alternative to plastic materials and are environmentally friendly. Twelve eighth grade students participated in the current study. The activities developed by the researchers within the framework of the REACT strategy covered a four-week period. The researchers made sure that the activities designed included each step of the REACT strategy (Relating, Experiencing, Applying, Cooperating, Transferring) and the researchers used different tools (mind map, concept map, Vee diagram). The study suggests that activities designed for classroom use should be integrated with tools such as Vee diagram, concept map and mind map in order to increase students' knowledge and awareness about global environmental problems as well as support students' ability to produce solutions to such problems. [ABSTRACT FROM AUTHOR]

Nowadays, rapidly increasing production, use and disposable of plastic products has become one of the utmost environmental issues. Our current circumstances in which the food supply chain is demonstrated as containing plastic particles and other plastic-based impurities, represents a significant health risk to humans, animals, and environmental alike. According to this point of view, biodegradable plastic material aims to produce a more sustainable and greener world with a lower ecological impact. Bioplastics are being investigated as an environmentally friendly candidate to address this problem and hence global bioplastic production has seen significant growth and expansion in recent years. This article focuses on a few critical issues that must be addressed for bioplastic production to become commercially viable. Although the reduction of fruit and vegetable waste biomass has an apparent value in terms of environmental benefits and sustainability, commercial success at industrial scale has remained flat. This is due to various factors, including biomass feedstocks, pretreatment technologies, enzymatic hydrolysis, and scale-up issues in the industry, all of which contribute to high capital and operating costs. This review paper summarizes the global overview of bioplastics derived from fruit and vegetable waste biomass. Furthermore, economic and technical challenges associated with industrialization and diverse applications of bioplastics in biomedical, agricultural, and food-packaging fields due to their excellent biocompatibility properties are reviewed. Review of the diverse types and characteristics of sustainability of biobased plastics Improved pretreatment technologies can develop to enhance greater yield Enzyme hydrolysis process used for bioplastic extraction & hasten industrial scale-up Focus on technical challenges facing commercialized the bioplastics Detailed discussion on the application for sustainability of biodegradable plastics [ABSTRACT FROM AUTHOR]

Polybutylene succinate (PBS) is one of the most important biobased plastics, based on the amount produced. Owing to its high melting point and resemblance to petroleum‐based plastics (i. e. PP), PBS becomes one of the emerging bioplastics with an array of applications. PBS is manufactured by polymerization of 1,4‐butanediol and succinic acid. Thus, it is of great importance to ensure the use of renewable resources to produce the PBS precursors. As the second most abundant carbohydrate monomer on Earth, D‐xylose will be a suitable candidate for this purpose. In this work, we combined protein engineering with chemical oxidation by gold catalyst to enable transformation of D‐xylose to 1,4‐butanediol and succinic acid simultaneously. In silico docking studies and semi rational design were employed to create variants of the key enzyme, branched chain α‐keto acid decarboxylase (KdcA) with higher affinity for the intermediates in the production of 1,4‐butanediol and succinic acid. Direct enzymatic biotransformation would result in a production of both monomers with 3:1 ratio, thus not readily suitable for a direct polymerization to PBS. By developing a one‐pot multi‐step chemo‐enzymatic approach with a gold catalyst to perform the first oxidation step, we could achieve a final product ratio of 1:1. Application of an engineered KdcA variant allowed us to achieve >98% yield after four hours transformation. In contrast, after 24 h transformation, >10% intermediate was still observed when the original variant was used. We anticipate this new approach could serve as an alternative route for biotechnological productions of PBS and its precursors. [ABSTRACT FROM AUTHOR]

This study focused on bioplastics and composite bioplastics with incorporated ZnO and TiO2. The ZnO gave a film more transparent than that made with TiO2. The effects of these additives on physical and mechanical properties, biodegradability, surface morphology, and thermal properties of the films were investigated. The functional groups O-H, C-H, C=O, and C-O in the bioplastic and the composites were confirmed by FT-IR. The addition of ZnO and TiO2 could increase thermal stability. The composites exhibited higher tensile strength than the control bioplastic film. The bioplastic film was 100% biodegradable compared to 14.71% and 14.59% for ZnO and TiO2 containing bioplastic films, respectively. [ABSTRACT FROM AUTHOR]

Today, plastic materials are mostly made from fossil resources, and they are characterized by their long lifetime and pronounced persistence in the open environment. These attributes of plastics are one cause of the ubiquitous pollution we see in our environment. When plastics end up in the environment, most of this pollution can be attributed to a lack of infrastructure for appropriately collecting and recycling plastic waste, mainly due to mismanagement. Because of the huge production volumes of plastics, their merits of being cheap to produce and process and their recalcitrance have turned into a huge disadvantage, since plastic waste has become the end point of our linear economic usage model, and massive amounts have started to accumulate in the environment, leading to microplastics pollution and other detrimental effects. A possible solution to this is offered by "bioplastics", which are materials that are either (partly) biobased and/or degradable under defined conditions. With the rise of bioplastics in the marketplace, several standards and test protocols have been developed to assess, certify, and advertise their properties in this respect. This article summarizes and critically discusses different views on bioplastics, mainly related to the properties of biodegradability and biobased carbon content; this shall allow us to find a common ground for clearly addressing and categorizing bioplastic materials, which could become an essential building block in a circular economy. Today, bioplastics account for only 1–2% of all plastics, while technically, they could replace up to 90% of all fossil-based plastics, particularly in short-lived goods and packaging, the single most important area of use for conventional plastics. Their replacement potential not only applies to thermoplastics but also to thermosets and elastomers. Bioplastics can be recycled through different means, and they can be made from renewable sources, with (bio)degradability being an option for the mismanaged fraction and special applications with an intended end of life in nature (such as in seed coatings and bite protection for trees). Bioplastics can be used in composites and differ in their properties, similarly to conventional plastics. Clear definitions for "biobased" and "biodegradable" are needed to allow stakeholders of (bio)plastics to make fact-based decisions regarding material selection, application, and end-of-life options; the same level of clarity is needed for terms like "renewable carbon" and "bio-attributed" carbon, definitions of which are summarized and discussed in this paper. [ABSTRACT FROM AUTHOR]

This review presents a comprehensive update of the biopolymer poly(3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV), emphasizing its production, properties, and applications. The overall biosynthesis pathway of PHBV is explored in detail, highlighting recent advances in production techniques. The inherent physicochemical properties of PHBV, along with its degradation behavior, are discussed in detail. This review also explores various blends and composites of PHBV, demonstrating their potential for a range of applications. Finally, the versatility of PHBV-based materials in multiple sectors is examined, emphasizing their increasing importance in the field of biodegradable polymers. [ABSTRACT FROM AUTHOR]

Plastic waste generation in India was around 9.4 million tonnes.year−1 in 2019 as compared to the global generation rate of more than 380 million tonnes.year−1 in 2019. Thus, India's contribution was around 3.1% of the global plastic waste generation. Globally, 42% of overall plastics produced are consumed by packaging sector and 17% by the construction sector. Whereas in India 35% is consumed by the packaging sector and 23% by construction sector. Bioplastic production is 1% out of 300 million tonnes of conventional plastics produced annually. This review attempts to analyse the plastic waste management rules, legislations, policies and practices in India during the period 1992–2020. The worldwide trend of bioplastic projects is reflected in studies in India, indicating a changed perception of bioplastics as an alternative source to conventional plastics. However, facilitating the implementation of conventional waste plastic processing plant and production of bioplastics in India involves challenges in terms of technology, developing a standardised framework and financial incentives. A legislative framework for the production of bioplastics in India should be developed alongwith an action plan for energy recovery from plastic waste. Markets for conventional plastic waste processing and production of bioplastic projects are not mature in India. This paper addresses the need for developing a roadmap towards efficient planning and sustainable solutions for both conventional plastics and bioplastics. [ABSTRACT FROM AUTHOR]

Cellulose diacetate (CDA) is a bio-based plastic widely used in consumer products. CDA is a promising alternative to conventional thermoplastics due to its susceptibility to biodegradation in various environments. Despite widespread evidence for the degradation of CDA, relatively little is known about the microorganisms that drive degradation, particularly in the ocean. Recently, we documented the biodegradation of CDA-based materials (i.e., fabric, film, and foam) in a continuous-flow natural seawater mesocosm on the timescales of months, as indicated by mass loss, enzyme activity, and respiration to carbon dioxide. These findings paved the way for the present study aimed at identifying key microbial taxa implicated in CDA degradation. Analysis based on 16S rRNA gene amplicon sequencing of bacteria and archaea revealed that material type, incubation time, material morphology (e.g., fabric vs film), and plasticizer content significantly influenced the microbial community structure. Differential abundance analysis revealed that bacterial taxa affiliated with the families of Arenicellaceae, Cellvibrionaceae, Methyloligellaceae, Micavibrionaceae, Puniceicoccaceae, Spirosomaceae, and Thermoanaerobaculaceae, and the order of Pseudomonadales potentially initiated the degradation (i.e., deacetylation) of CDA fabric and film. These taxa were notably distinct from CDA-degrading microbes reported in non-seawater environments. Collectively, the findings lend further support for CDA as a promising next-generation, high-utility, and low-environmental persistence bioplastic material. IMPORTANCE Cellulose diacetate (CDA) is a promising alternative to conventional plastics due to its versatility in manufacturing and low environmental persistence. Previously, our group demonstrated that CDA is susceptible to biodegradation in the ocean on timescales of months. In this study, we report the composition of microorganisms driving CDA degradation in the coastal ocean. We found that the coastal ocean harbors distinct bacterial taxa implicated in CDA degradation and these taxa have not been previously identified in prior CDA degradation studies, indicating an unexplored diversity of CDA-degrading bacteria in the ocean. Moreover, the shape of the plastic article (e.g., a fabric, film, or foam) and plasticizer in the plastic matrix selected for different microbial communities. Our findings pave the way for future studies to identify the specific species and enzymes that drive CDA degradation in the marine environment, ultimately yielding a more predictive understanding of CDA biodegradation across space and time. [ABSTRACT FROM AUTHOR]

Bioplastics hold significant promise in replacing conventional plastic materials, linked to various serious issues such as fossil resource consumption, microplastic formation, non-degradability, and limited end-of-life options. Among bioplastics, polyhydroxyalkanoates (PHA) emerge as an intriguing class, with poly(3-hydroxybutyrate) (P3HB) being the most utilized. The extensive application of P3HB encounters a challenge due to its high production costs, prompting the investigation of sustainable alternatives, including the utilization of waste and new production routes involving CO2 and CH4. This study provides a valuable comparison of two P3HBs synthesized through distinct routes: one via cyanobacteria (Synechocystis sp. PCC 6714) for photoautotrophic production and the other via methanotrophic bacteria (Methylocystis sp. GB 25) for chemoautotrophic growth. This research evaluates the thermal and mechanical properties, including the aging effect over 21 days, demonstrating that both P3HBs are comparable, exhibiting physical properties similar to standard P3HBs. The results highlight the promising potential of P3HBs obtained through alternative routes as biomaterials, thereby contributing to the transition toward more sustainable alternatives to fossil polymers. [ABSTRACT FROM AUTHOR]

Plastics have changed human lives, finding a broad range of applications from packaging to medical devices. However, plastics can degrade into microscopic forms known as micro- and nanoplastics, which have raised concerns about their accumulation in the environment but mainly about the potential risk to human health. Recently, biodegradable plastic materials have been introduced on the market. These polymers are biodegradable but also bioresorbable and, indeed, are fundamental tools for drug formulations, thanks to their transient ability to pass through biological barriers and concentrate in specific tissues. However, this "other side" of bioplastics raises concerns about their toxic potential, in the form of micro- and nanoparticles, due to easier and faster tissue accumulation, with unknown long-term biological effects. This review aims to provide an update on bioplastic-based particles by analyzing the advantages and drawbacks of their potential use as components of innovative formulations for brain diseases. However, a critical analysis of the literature indicates the need for further studies to assess the safety of bioplastic micro- and nanoparticles despite they appear as promising tools for several nanomedicine applications. [ABSTRACT FROM AUTHOR]

Glucoamylases (GAs) are one of the principal groups of enzymes involved in starch hydrolysis and belong to the glycosylhydrolase family. They are classified as exo-amylases due to their ability to hydrolyze α-1,4 glycosidic bonds from the non-reducing end of starch, maltooligosaccharides, and related substrates, releasing β-D-glucose. Structurally, GAs possess a characteristic catalytic domain (CD) with an (α/α)6 fold and exhibit five conserved regions within this domain. The CD may or may not be linked to a non-catalytic domain with variable functions depending on its origin. GAs are versatile enzymes with diverse applications in food, biofuel, bioplastic and other chemical industries. Although fungal GAs are commonly employed for these purposes, they have limitations such as their low thermostability and an acidic pH requirement. Alternatively, GAs derived from prokaryotic organisms are a good option to save costs as they exhibit greater thermostability compared to fungal GAs. Moreover, a group of cold-adapted GAs from psychrophilic organisms demonstrates intriguing properties that make them suitable for application in various industries. This review provides a comprehensive overview of the structural and sequential properties as well as biotechnological applications of GAs in different industrial processes. [ABSTRACT FROM AUTHOR]

Since the 1950s, 8.3 billion tonnes (Bt) of virgin plastics have been produced, of which around 5 Bt have accumulated as waste in oceans and other natural environments, posing severe threats to entire ecosystems. The need for sustainable bio‐based alternatives to traditional petroleum‐derived plastics is evident. Bioplastics produced from unprocessed biological materials have thus far suffered from heterogeneous and non‐cohesive morphologies, which lead to weak mechanical properties and lack of processability, hindering their industrial integration. Here, a fast, simple, and scalable process is presented to transform raw microalgae into a self‐bonded, recyclable, and backyard‐compostable bioplastic with attractive mechanical properties surpassing those of other biobased plastics such as thermoplastic starch. Upon hot‐pressing, the abundant and photosynthetic algae spirulina forms cohesive bioplastics with flexural modulus and strength in the range 3–5 GPa and 25.5–57 MPa, respectively, depending on pre‐processing conditions and the addition of nanofillers. The machinability of these bioplastics, along with self‐extinguishing properties, make them promising candidates for consumer plastics. Mechanical recycling and fast biodegradation in soil are demonstrated as end‐of‐life options. Finally, the environmental impacts are discussed in terms of global warming potential, highlighting the benefits of using a carbon‐negative feedstock such as spirulina to fabricate plastics. [ABSTRACT FROM AUTHOR]

It is crucial to find an effective, environmentally acceptable solution, such as bioplastics or biodegradable plastics, to the world's rising plastics demand and the resulting ecological destruction. This study has focused on the environmentally friendly production of bioplastic samples derived from corn starch, rice starch, and tapioca starch, with various calcium carbonate filler concentrations as binders. Two different plasticizers, glycerol and sorbitol, were employed singly and in a rich blend. To test the differences in the physical and chemical properties (water content, absorption of moisture, water solubility, dissolution rate in alcohol, biodegradation in soil, tensile strength, elastic modulus, and FT-IR) of the produced samples, nine samples from each of the three types of bioplastics were produced using various ratios and blends of the fillers and plasticizers. The produced bioplastic samples have a multitude of features that make them appropriate for a variety of applications. The test results show that the starch-based bioplastics that have been suggested would be a better alternative material to be used in the packaging sectors. [ABSTRACT FROM AUTHOR]

Background: Bioplastics are attracting considerable attention, owing to the increase in non-degradable waste. Using microorganisms to degrade bioplastics is a promising strategy for reducing non-degradable plastic waste. However, maintaining bacterial viability and activity during culture and storage remains challenging. With the use of conventional methods, cell viability and activity was lost; therefore, these conditions need to be optimized for the practical application of microorganisms in bioplastic degradation. Therefore, we aimed to optimize the feasibility of the lyophilization method for convenient storage and direct use. In addition, we incoporated protective reagents to increase the viability and activity of lyophilized microorganisms. By selecting and applying the best protective reagents for the lyophilization process and the effects of additives on the growth and PHB-degrading activity of strains were analyzed after lyophilization. For developing the lyophilization method for protecting degradation activity, it may promote practical applications of bioplastic-degrading bacteria. Results: In this study, the polyhydroxybutyrate (PHB)-degrading strain, Bacillus sp. JY14 was lyophilized with the use of various sugars as protective reagents. Among the carbon sources tested, raffinose was associated with the highest cell survival rate (12.1%). Moreover, 7% of raffionose showed the highest PHB degradation yield (92.1%). Therefore, raffinose was selected as the most effective protective reagent. Also, bacterial activity was successfully maintained, with raffinose, under different storage temperatures and period. Conclusions: This study highlights lyophilization as an efficient microorganism storage method to enhance the applicability of bioplastic-degrading bacterial strains. The approach developed herein can be further studied and used to promote the application of microorganisms in bioplastic degradation. [ABSTRACT FROM AUTHOR]

More than 390 million tons of fossil fuel plastics have been produced in 2022, and plastic pollution has become a major health issue for humans and ecosytems. Fossil fuel plastics are commonly recalcitrant, thus accumulating in the environment. Fossil fuel plastics also contains toxic chemicals that leach out to waters and are ingested by living organisms. Morevover, recent research has revealed that plastic fragmentation has led to an unprecedented global contamination by microplastics and nanoplastics, with yet poorly adverse impacts on life. In this context, bioplastics, that we will refer to as biobased plastics in this contribution, appear as a promising alternative because bioplastics are carbon neutral and most of them are biodegradable. As a consequence, the world bioplastic production has increased from 1.8 million tons in 2021 to 2.22 million tons in 2022. However, the complete degradation of most bioplastics in the environment remains difficult. Here we compare bioplastics with fossil fuel plastics with focus on life cycle assessment, biodegradability and compostability, end-of-life options, fragmentation into microplastics, and microplastic pollution of soil and aquatic systems. Overall, we observe that bioplastics are not necessarily more ecofriendly than fossil fuel plastics. Technical and cost limitations still prevent bioplastics from fully substituting fossil fuel plastics. For instance, there is still no widely accepted methodology to compare the potential environmental footprint between fossil fuel plastics and bioplastics. Some microorganisms can degrade plastics under laboratory conditions, but both fossil fuel plastics and bioplastics degradation can be limited under environmental conditions. End-of-life options for both fossil fuel and bioplastics are similar, except for composting. Both fossil fuel plastics and bioplastics contribute to environmental pollution by forming microplastics and acting as vectors for environmental pollutants. Overall, the study found that bioplastics and fossil fuel plastics have similar negative effects and both are comparable in terms of their vector role, formation of microplastics, and toxicity to biota. To conclude, the common belief that bioplastics have less or no negative impact on the environment may not be entirely accurate. [ABSTRACT FROM AUTHOR]

[Display omitted] • Management of organic fraction of MSW (OFMSW) and excess sludge is difficult. • Anaerobic codigestion of these two substrates in presence of bioplastic is analyzed. • Influence of bioplastics on methane production has not been evidenced. • Bioplastic biodegradation is very limited and the presence of fragments is evident. • A possible increase in phytotoxicity has been also signalized. Co-digestion of the organic fraction of municipal solid waste (OFMSW) and excess sludge has several benefits especially related to improved methane production and better process stability. In recent years, the presence of biodegradable plastics is increasingly common in OFMSW especially since, as in Italy, biodegradable bags are used for its collection. In this paper, the influence and the fate of biodegradable bags during anaerobic co-digestion of excess sludge and OFMSW are assessed. The best results in terms of methane yield (about 180 NmL/g VS) have been obtained with the 50:50 (VS basis) co-digestion of excess sludge and OFMSW with an organic loading rate of 2 kg VS /m3·d. Bioplastic degradation is very limited during the co-digestion but it does not influence methane production or digestate chemical characteristics. However, the feeding of bioplastic bags seems to induce a higher phytotoxicity and the presence of undigested fragments is anyway a problem for further treatment or direct utilization of digestate. [ABSTRACT FROM AUTHOR]

The formulation of eco-friendly biodegradable packaging has received great attention during the last decades as an alternative to traditional widespread petroleum-based food packaging. With this aim, we designed and tested the properties of polyhydroxyalkanoates (PHA)-based bioplastics functionalized with phloretin as far as antioxidant, antimicrobial, and morpho-mechanic features are concerned. Mechanical and hydrophilicity features investigations revealed a mild influence of phloretin on the novel materials as a function of the concentration utilized (5, 7.5, 10, and 20 mg) with variation in FTIR e RAMAN spectra as well as in mechanical properties. Functionalization of PHA-based polymers resulted in the acquisition of the antioxidant activity (in a dose-dependent manner) tested by DPPH, TEAC, FRAR, and chelating assays, and in a decrease in the growth of food-borne pathogens (Listeria monocytogenes ATCC 13932). Finally, apple samples were packed in the functionalized PHA films for 24, 48, and 72 h, observing remarkable effects on the stabilization of apple samples. The results open the possibility to utilize phloretin as a functionalizing agent for bioplastic formulation, especially in relation to food packaging. [ABSTRACT FROM AUTHOR]

In the current system, the disposal of plastic materials causes serious environmental pollution such as the generation of carbon dioxide and destruction of the ecosystem by micro-plastics. To solve this problem, bioplastics, biomass and biodegradable plastics have been developed. As part of our research, we have developed novel bioplastics called "cell-plastics", in which a unicellular green algal cell serves as a fundamental resource. The production of the cell-plastics would be expected to reduce environmental impact due to the usage of a natural product. Herein, to overcome the mechanical strength of cell-plastics, we used thermosetting epoxy and urethane resins containing Chlorella sp. as the green algae. We successfully fabricated thermosetting resins with a Chlorella sp. content of approximately 70 wt% or more. IR measurements revealed that the chemical structure of an epoxide or isocyanate monomer mixed with Chlorella sp. was modified, which suggests that the resins were hardened by the chemical reaction. In addition, we investigated the effect of thermosetting conditions such as temperature and compression for curing both resins. It was revealed that the Young's moduli and tensile strengths were controlled by thermosetting temperature and compression, whereas the elongation ratios of the resins were constant at low values regardless of the conditions. [ABSTRACT FROM AUTHOR]

One of the main limitations in the creation of bioplastics is their large-scale development, referred to as the industrial-scale processing of plastics. For this reason, bioplastic engineering emerges as one of the main objectives of researchers, who are attempting to create not only more environmentally friendly but also sustainable, low-cost, and less polluting materials. This review presents the advances in the development of biodegradable and compostable films/containers using eco-friendly components of by-products of the coffee industry, such as coffee flour (CF), coffee mucilage (CM), coffee husks (CH), coffee silverskin (CS), and spent coffee grounds (SCGs), and a brief review of the common industrial processing techniques for the production of food packaging, including extrusion, compression molding, injection molding, and laboratory-scale techniques such as solvent casting. Finally, this review presents various advances in the area that can be scalable or applicable to different products using by-products generated from the coffee industry, taking into account the limitations and drawbacks of using a biomaterial. [ABSTRACT FROM AUTHOR]

The development of biodegradable plastics and eco-friendly biomaterials derived from renewable resources is crucial for reducing environmental damage. Agro-industrial waste and rejected food can be polymerized into bioplastics, offering a sustainable solution. Bioplastics find use in various industries, including for food, cosmetics, and the biomedical sector. This research investigated the fabrication and characterization of bioplastics using three types of Honduran agro-wastes: taro, yucca, and banana. The agro-wastes were stabilized and characterized (physicochemically and thermically). Taro flour presented the highest protein content (around 4.7%) and banana flour showed the highest moisture content (around 2%). Furthermore, bioplastics were produced and characterized (mechanically and functionally). Banana bioplastics had the best mechanical properties, with a Young's modulus around 300 MPa, while taro bioplastics had the highest water-uptake capacity (200%). In general, the results showed the potential of these Honduran agro-wastes for producing bioplastics with different characteristics that could add value to these wastes, promoting the circular economy. [ABSTRACT FROM AUTHOR]

Many industries are coming under increasing pressure to replace their petrochemical plastics in products and packaging with biopolymers. Retailers have a key role here because they determine the products to be marketed, but there is little research on how change processes differ between sectors. To guide wholesalers with broad product portfolio on how to effectively plan a plastics transition, this study interviewed 48 experts from the food, pharmaceutical, automotive and technics retailing. From the answers, sector-independent context factors were derived and finally their individual transition strategy for bioplastics was compared. Packaging is the main object for transition and the food and automotive sectors prefer the greatest possible standardisation of the plastics change. Largest group differences are in the recovery method of bioplastics products and in the assessment of the innovation potential. The results guide wholesalers and policy makers for an effective technology change. [ABSTRACT FROM AUTHOR]

For a sustainable economy, biodegradable biopolymers polyhydroxyalkanoates (PHA) are desirable substitutes to petroleum-based plastics that contaminate our environment. Medium-chain-length (MCL) PHA bioplastics are particularly interesting due to their thermoplastic properties. To hamper the high cost associated to PHA production, the use of bacterial mixed cultures cultivated in open systems and using cheap resources is a promising strategy. Here, we studied the operating conditions favouring direct MCL accumulation by activated sludge, using oleic acid as a model substrate and phosphorus limitation in fed-batch bioreactors. Our results confirm the presence of PHA-accumulating organisms (PHAAO) in activated sludge able to accumulate MCL from oleic acid. A positive correlation between phosphorus (P) limitation and PHA accumulation was demonstrated, allowing up to 26% PHA/total biomass accumulation, and highlighted its negative impact on the MCL/PHA fraction in the polymer. Diversity analysis through 16S rRNA amplicon sequencing revealed a differential selection of PHAAO according to the P-limitation level. A differential behaviour for the orders Pseudomonadales and Burkholderiales at increasing P-limitation levels was revealed, with a higher abundance of the latter at high levels of P-limitation. The PHA accumulation observed in activated sludge open new perspectives for MCL-PHA production system based on P-limitation strategy applied to mixed microbial communities. Key points: • Direct accumulation of MCL-PHA in activated sludge was demonstrated. • MCL-PHA content is negatively correlated with P-limitation. • Burkholderiales members discriminate the highest P-limitation levels. [ABSTRACT FROM AUTHOR]

Polyhydroxybutyrates (PHBs) are macromolecules synthesized by bacteria. PHBs are the most promising type of bioplastic; they are nontoxic, biodegradable and biocompatible and have properties similar to those of conventional plastics. In the present study, an attempt was made to screen of different bacterial isolates accumulating PHB from soil samples collected from Istanbul, Turkey. A total of 86 different bacterial isolates were isolated from soil samples and a total of 32 isolates were suggested to be PHB producer when stained with Sudan Black B, a preliminary screening agent for lipophilic compounds. 13 bacterial isolates were selected as PHB producing isolates by using the Nile blue A dying technique. 16S rRNA gene sequences analysis showed that PHB producing 13 isolates belonged to Pseudomonas, Arthrobacter and Bacillus genera. The PHB from the isolates was extracted using the dispersion method of the hypochlorite and chloroform method. The highest PHB production and percentage productivity were obtained from Pseudomonas plecoglossicida M9 (0.94 PHB g/L; 78.8% PHB) and Pseudomonas baetica Y6 (0.81 PHB g/L; 74.3% PHB) respectively. [ABSTRACT FROM AUTHOR]

The increasing use of synthetic polymers and their disposal has raised concern due to their adverse effects on the environment. Thus, other sustainable alternatives to synthetic plastics have been sought, such as polyhydroxyalkanoates (PHAs), which are promising microbial polyesters, mainly due to their compostable nature, biocompatibility, thermostability, and resilience, making this biopolymer acceptable in several applications in the global market. The large-scale production of PHAs by microorganisms is still limited by the high cost of production compared to conventional plastics. This review reports some strategies mentioned in the literature aimed at production and recovery, paving the way for the bio-based economy. For this, some aspects of PHAs are addressed, such as synthesis, production systems, process control using by-products from industries, and advances and challenges in the downstream. The bioplastics properties made them a prime candidate for food, pharmaceutical, and chemical industrial applications. With this paper, it is possible to see that biodegradable polymers are promising materials, mainly for reducing the pollution produced by polymers derived from petroleum. [ABSTRACT FROM AUTHOR]

Durability and affordability are two main reasons for the widespread consumption of plastic in the world. However, the inability of these materials to undergo degradation has become a significant threat to the environment and human health To address this issue, bioplastics have emerged as a promising alternative. Bioplastics are obtained from renewable and sustainable biomass and have a lower carbon footprint and emit fewer greenhouse gases than petroleum-based plastics. The use of these bioplastics sourced from renewable biomass can also reduce the dependency on fossil fuels, which are limited in availability. This review provides an elaborate comparison of biodegradation rates of potential bioplastics in soil from various sources such as biomass, microorganisms, and monomers. These bioplastics show great potential as a replacement for conventional plastics due to their biodegradable and diverse properties. [ABSTRACT FROM AUTHOR]

The increasing use of synthetic polymers and their disposal has raised concern due to their adverse effects on the environment. Thus, other sustainable alternatives to synthetic plastics have been sought, such as polyhydroxyalkanoates (PHAs), which are promising microbial polyesters, mainly due to their compostable nature, biocompatibility, thermostability, and resilience, making this biopolymer acceptable in several applications in the global market. The large-scale production of PHAs by microorganisms is still limited by the high cost of production compared to conventional plastics. This review reports some strategies mentioned in the literature aimed at production and recovery, paving the way for the bio-based economy. For this, some aspects of PHAs are addressed, such as synthesis, production systems, process control using by-products from industries, and advances and challenges in the downstream. The bioplastics properties made them a prime candidate for food, pharmaceutical, and chemical industrial applications. With this paper, it is possible to see that biodegradable polymers are promising materials, mainly for reducing the pollution produced by polymers derived from petroleum. [ABSTRACT FROM AUTHOR]

There has been a lot of interest in developing and producing biodegradable polymers to address the current environmental problem caused by the continued usage of synthetic polymers derived from petroleum products. Bioplastics have been identified as a possible alternative to the use of conventional plastics since they are biodegradable and/or derived from renewable resources. Additive manufacturing, also referred to as 3D printing, is a field of growing interest and can contribute towards a sustainable and circular economy. The manufacturing technology also provides a wide material selection with design flexibility increasing its usage in the manufacture of parts from bioplastics. With this material flexibility, efforts have been directed towards developing 3D printing filaments from bioplastics such as Poly (lactic acid) to substitute the common fossil- based conventional plastic filaments such as Acrylonitrile butadiene styrene. Plant biomass is now utilized in the development of biocomposite materials. A lot of literature presents work done toward improving the biodegradability of printing filaments. However, additive manufacture of biocomposites from plant biomass is faced with printing challenges such as warping, low agglomeration between layers and poor mechanical properties of the printed parts. The aim of this paper is to review the technology of 3D printing using bioplastics, study the materials that have been utilized in this technology and how challenges of working with biocomposites in additive manufacture have been addressed. [ABSTRACT FROM AUTHOR]

Plastics have become ubiquitous materials essential for modern life and sustaining the global economy. On the other hand, their dependence on dwindling fossil fuel sources and their durability has raised concerns about their sustainability. Biobased plastics, which include biodegradable plastics, appear to be an appealing solution, yet their uptake has been slow. This paper specifically looks at the commercialization challenges for two bioplastics: polyethylene furanoate (PEF) and polyhydroxy alkanoate (PHA), that have been claimed by the industry as potentially disruptive. The superior barrier, mechanical and thermal properties of PEF present a suitable competition to polyethylene terephthalate (PET). The versatility and marine biodegradability of PHAs have attracted interest from several potential adopters. However, the high production costs of both pose a serious commercialization challenge when considering the established production, supply chain and recycling infrastructure for fossil‐based plastics. This study illustrates how firms are mitigating technical and market uncertainties by strategies such as adding value to other products, utilizing existing industrial assets, balancing exploration of more efficient and sustainable production pathways with commercial exploitation, lowering transaction costs by utilizing existing knowledge base, by developing formulation capabilities and forward integrating into end consumer products, or by entering collaborative alliances. These strategies could inevitably overcome inertia posed by the current market structure for fossil‐based plastics. © 2022 The Authors. Biofuels, Bioproducts and Biorefining published by Society of Industrial Chemistry and John Wiley & Sons Ltd. [ABSTRACT FROM AUTHOR]

Plastics-based materials have a high carbon footprint, and their disposal is a considerable problem for the environment. Biodegradable bioplastics represent an alternative on which most countries have focused their attention to replace of conventional plastics in various sectors, among which food packaging is the most significant one. The evaluation of the optimal end-of-life process for bioplastic waste is of great importance for their sustainable use. In this review, the advantages and limits of different waste management routes—biodegradation, mechanical recycling and thermal degradation processes—are presented for the most common categories of biopolymers on the market, including starch-based bioplastics, PLA and PBAT. The analysis outlines that starch-based bioplastics, unless blended with other biopolymers, exhibit good biodegradation rates and are suitable for disposal by composting, while PLA and PBAT are incompatible with this process and require alternative strategies. The thermal degradation process is very promising for chemical recycling, enabling building blocks and the recovery of valuable chemicals from bioplastic waste, according to the principles of a sustainable and circular economy. Nevertheless, only a few articles have focused on this recycling process, highlighting the need for research to fully exploit the potentiality of this waste management route. [ABSTRACT FROM AUTHOR]

Beer bagasse is a residue produced in large quantities, though it is undervalued in the industry. Its high protein and polysaccharide content make it attractive for use in sectors such as the manufacture of bioplastics. However, its high water content makes it necessary to stabilize it before being considered as a raw material. The main objective of this work was to evaluate the stabilization of beer bagasse and the production of bioplastics from it. In this sense, different drying methods (freeze-drying and heat treatment at 45 and 105 °C) were studied. The bagasse was also characterized physicochemically to evaluate its potential. In addition, bagasse was used in combination with glycerol (plasticizer) to make bioplastics by injection molding, analyzing their mechanical properties, water absorption capacity and biodegradability. The results showed the great potential of bagasse, presenting a high content of proteins (18–20%) and polysaccharides (60–67%) after its stabilization, with freeze-drying being the most suitable method to avoid its denaturation. Bioplastics present appropriate properties for use in applications such as horticulture and agriculture. [ABSTRACT FROM AUTHOR]

The objective of this research was to investigate the mechanical, physical and antibacterial activities and biodegradability properties of bioplastics from polylactic acid (PLA) and corncob fibers (CF). The bioplastics were prepared by mixing PLA and CF at different ratios (100:0, 90:10, 80:20, 70:30, 60:40 and 50:50 % w:w) in the internal mixer and molding was done by using the hot-compressing molding method. The results demonstrated the decrease in tensile strength and elongation at break with increased in CF. Young’s modulus was found to be highest in the 70 %PLA: 30 %CF bioplastic, however, it decreased when the CF was increased. The hardness and water absorption were dependent on CF concentration. SEM analysis revealed the well dispersion of CF in PLA matrix. PLA matrix and increasing of CF induced in CF agglomeration. To develop PLA/CE plastic for antibacterial food packaging application, its antibacterial activity was conducted. The antibacterial determination revealed that 70 %PLA: 30 %CF containing 2 % TiO2 bioplastic exhibited the highest inhibition against E. Coli, S. aureus and B. subtilis. Additionally, the biodegradable character of the bioplastic was dependent on concentration and time, as the bioplastic weight loss was increased when the concentration of CF and biodegradation period were increased. The results obtained from this research indicate that the bioplastics prepared from polylactic acid and corncob fibers is biodegradable bioplastics and can be used as alternate synthetic plastics. The bioplastic with 2 %TiO2 added can be utilized potentially for expected antibacterial food packaging. [ABSTRACT FROM AUTHOR]

The safety of food contact materials is a hot topic since chemicals can migrate from packaging into food, thus raising health concerns about and/or producing changes in the organoleptic properties of foodstuffs. Migration tests are required to demonstrate the compliance with current regulations and to investigate the transferred compounds. In this context, mass spectrometry is the analytical technique of choice for the detection and quantitation of both intentionally added substances, such as antioxidants, stabilizers, processing aids, and non-intentionally added substances (NIAS). Untargeted strategies represent a major analytical challenge, providing a comprehensive fingerprinting of the packaging material and migrating components, allowing for NIAS identification. Hyphenated mass spectrometry-based techniques have been devised for screening the presence of migrating contaminants and for quantitation purposes. Both low-resolution (LRMS) and high-resolution (HRMS) methods were screened, with a special emphasis on the latter because of its capability to directly characterize food contact materials with minimal/no sample preparation, avoiding chromatographic separation, and reducing sample handling, analysis costs, and time. Examples related to the migration of contaminants from existing or newly developed bioplastic materials will be discussed, providing an overview of the most used MS-based methods, covering the state-of-the-art approaches from 2012 up to 2022. [ABSTRACT FROM AUTHOR]

Biofuels and bioplastics are promising replacements for reducing our reliance on fossil fuels and decrease the negative environmental impact of traditional plastics. However, their production efficiency and sustainability need improvement. One solution to address these issues is the use of nanofluids. Nanofluids are suspensions of nanoparticles in a base fluid that can enhance the thermal and transport properties. The use of nanofluids in biofuel and bioplastic production can lead to significant improvements in efficiency, reduced energy consumption, and lower environmental impacts. This paper proposes the use of nanofluids as a way to improve the production of sustainable biofuels and bioplastics. Nanoparticles such as carbon nanotubes, graphene, and metal oxides can be used to improve the properties of biofuels and bioplastics, leading to a more sustainable and environmentally friendly product. By leveraging the unique properties of nanofluids, we can enhance the performance of biofuels and bioplastics, leading to more efficient and sustainable production processes. This paper also provides the advantages of using nanofluids in biofuel and bioplastic production and the potential applications and leading to a more sustainable and environmentally friendly product. [ABSTRACT FROM AUTHOR]

The extensive application of petroleum-based plastics has caused serious environmental pollution and ecological problems. Now, governments in the world are urgently aiming to develop biodegradable and renewable plastic alternatives. Agricultural waste, being widely available and affordable, may provide a resource of natural polymers to replace those from fossil sources for material manufacturing. However, there are still some non-negligible issues needing more attention. Herein, we briefly discuss the issues and challenges in the conversion of agricultural waste into bioplastics to provide a possible way for its further utilization. [ABSTRACT FROM AUTHOR]

Biobased and biodegradable polymers are used in bioplastics as blends or composites of various materials to tune their physical properties but also influence their stability with respect to biodegradation. Biodegradable polymers are often not as biodegradable as they are claimed to be, especially due to different degradation conditions in soil, water, compost, or in vivo. Mixing such polymers with faster degrading polymers (blends) or fillers (composites) is a powerful strategy to adjust degradation rates. This review selects representative examples of bioplastic blends and composites in applications, such as tissue engineering, agriculture, or packaging, with a focus on controlling/accelerating the biodegradation rates. It also focuses on strategies such as hydrolysis enhancement, attraction of microbes for microbial degradation, pore forming fillers, or increase of phase separation in polymer mixtures. A basis for the prevention of microplastic formation or unwanted side effects with too slow degradation rates of biodegradable polymers is set. [ABSTRACT FROM AUTHOR]

This review appraised current research on enzyme-embedded biodegradable agricultural plastics and microbial degradation, given that the increased use of fossil-fuel-based plastics in agriculture involved significant environmental tradeoffs. Over 370 million tons of plastics were produced in 2019, releasing over 400 million tons of greenhouse gases during production, transportation, consumption, burning, and exposure to sunlight biodegradation. Less than 10% of bags are recycled at the end of their life, leading to environmental pollution. Thus, it is imperative to summarize studies that have suggested solutions of this problem. The scoping review approach was preferred, given that it established current practices and uncovered international evidence on bio-based solutions and conflicting outcomes. Bioplastics with low greenhouse warming potential had a small market share (approximately 1%). The accumulation of fossil-fuel-based plastics and poor post-use management releases mercury, dioxins, furans, and polychlorinated biphenyls (PCBs). Enzyme-embedded polymers degrade fast in the environment but lack the desired mechanical properties. Even though polylactic acid (PLA) and other bioplastics are better alternatives to synthetic polymers, they persist in the environment for years. Fast degradation is only practical under special conditions (elevated temperatures and humidity), limiting bioplastics' practical benefits. The research and development of plastics that could degrade under ambient conditions through enzyme-catalyzed reactions and soil-inoculated microbes are ongoing. However, there are no guarantees that the technology would be profitable in commercial agriculture. Other limiting factors include the geographical disparities in agricultural plastic waste management. Future perspectives on the waste management of agricultural plastics require smart technologies, such as artificial intelligence (AI), machine learning (ML), and enzyme-embedded plastics that degrade under ambient conditions. The replacement of synthetic plastics with polylactic acid and polycaprolactone/Amano lipase (PCL/AL) composite films would offset the negative ecological effects. A major drawback was the slow research and development and commercial adoption of bio-based plastics. The transition to bioplastics was resource- and time-intensive. [ABSTRACT FROM AUTHOR]

Bioplastics are one of the possible alternative solutions to the polymers of petrochemical origins. Bioplastics have several advantages over traditional plastics in terms of low carbon footprint, energy efficiency, biodegradability and versatility. Although they have numerous benefits and are revolutionizing many application fields, they also have several weaknesses, such as brittleness, high-water absorption, low crystallization ability and low thermal degradation temperature. These drawbacks can be a limiting factor that prevents their use in many applications. Nonetheless, reinforcements and plasticizers can be added to bioplastic production as a way to overcome such limitations. Bioplastics materials are not yet studied in depth, but it is with great optimism that their industrial use and market scenarios are increasing; such growth can be a positive driver for more research in this field. National and international investments in the bioplastics industry can also promote the green transition. International projects, such as EcoPlast and Animpol, aim to study and develop new polymeric materials made from alternative sources. One of their biggest problems is their waste management; there is no separation process yet to recycle the nonbiodegradable bioplastics, and they are considered contaminants when mixed with other polymers. Some materials use additives, and their impact on the microplastics they leave after breaking apart is subject to debate. For this reason, it is important to consider their life cycle analysis and assess their environmental viability. These are materials that can possibly be processed in various ways, including conventional processes used for petrochemical ones. Those include injection moulding and extrusion, as well as digital manufacturing. This and the possibility to use these materials in several applications is one of their greatest strengths. All these aspects will be discussed in this review. [ABSTRACT FROM AUTHOR]

To diminish the environmental impacts instigated by plastics, investigators recommended bioplastics. In the current work, an attempt is made to develop sustainable bioplastics from waste plants. Cellulose was extracted from the wood of Prosopis juliflora. The Prosopis juliflora wood was cut and ground into powder. The powder was washed with water and subjected to several chemical treatments to extract the cellulose. The bioplastic film samples were produced using it. Six different samples were prepared by varying the composition of cellulose, gelatin, citric acid, and glycerol. Several tests were carried out on samples developed as per ASTM standards, and the results were compared with the existing bioplastics. The test results indicated that sample 1 has a maximum tensile strength of 7.73 MPa. The average bursting strength of the bioplastic film is 12.44 kg/cm2, which is better than the other bioplastics reported in the literature. The average biodegradability of developed bioplastic films is approximately 59.43%. The results revealed that the Prosopis juliflora cellulose-based bioplastics would be a better substitute for conventional plastics. [ABSTRACT FROM AUTHOR]

Biodegradable polymers obtained from renewable resources are urgently needed to help mitigating the environmental burden of plastic pollution. Herein, a green process is developed to obtain protein‐based bioplastics through valorization of rapeseed cake. First, the effects of different protein extraction protocols are investigated, including water extraction at pH values from 1 to 12 and salt extraction with isoelectric point precipitation (IP), on proteins profile and sample composition. It is demonstrated that alkaline extraction at pH 12 results in the highest extraction yields of proteins (≈70%) and total solutes (≈50%). The IP results in lower yields but in highest protein purity of ≈80%. Alkaline extraction at pH 10.5 results in the extraction of 36% total solutes and ≈50% of proteins, with a protein profile similar to that obtained by IP, rich in α and β polypeptides chains of cruciferin. AFM analysis shows that samples containing cruciferin allow self‐assembly into mature amyloid fibrils upon incubation. Rapeseed amyloids are blended with polyvinyl alcohol and glycerol to develop bioplastics films that are characterized by decreased water absorption, higher water contact angle, and elongation at break >600%, more than double compared to films obtained from native monomers. [ABSTRACT FROM AUTHOR]

In this research, the utilisation of used transformer oil (UTO) as carbon feedstock for the production of polyhydroxyalkanoate (PHA) was targeted; with a view to reducing the environmental challenges associated with the disposal of the used oil and provision of an alternative to non-biodegradable synthetic plastic. Acinetobacter sp. strain AAAID-1.5 is a PHA-producing bacterium recently isolated from a soil sample collected in Penang, Malaysia. The PHA-producing capability of this bacterium was assessed through laboratory experiments in a shake flask biosynthesis under controlled culture conditions. The effect of some biosynthesis factors on growth and polyhydroxyalkanoate (PHA) accumulation was also investigated, the structural composition of the PHA produced by the organism was established, and the characteristics of the polymer were determined using standard analytical methods. The results indicated that the bacteria could effectively utilise UTO and produce PHA up to 34% of its cell dry weight. Analysis of the effect of some biosynthesis factors revealed that the concentration of carbon substrate, incubation time, the concentration of yeast extract and utilisation of additional carbon substrates could influence the growth and polymer accumulation in the test organism. Manipulation of culture conditions resulted in an enhanced accumulation of the PHA. The data obtained from GC-MS and NMR analyses indicated that the PHA produced might have been composed of 3-hydroxyoctadecanoate and 3-hydroxyhexadecanoate as the major monomers. The physicochemical analysis of a sample of the polymer revealed an amorphous elastomer with average molecular weight and polydispersity index (PDI) of 110 kDa and 2.01, respectively. The melting and thermal degradation temperatures were 88 °C and 268 °C, respectively. The findings of this work indicated that used transformer oil could be used as an alternative carbon substrate for PHA biosynthesis. Also, Acinetobacter sp. strain AAAID-1.5 could serve as an effective agent in the bioconversion of waste oils, especially UTO, to produce biodegradable plastics. These may undoubtedly provide a foundation for further exploration of UTO as an alternative carbon substrate in the biosynthesis of specific polyhydroxyalkanoates. [ABSTRACT FROM AUTHOR]

Bioplastics are one of the answers to environmental pollution and linear material flows. The most promising bioplastic polylactide (PLA) is already replacing conventional plastics in a number of applications. The properties of PLA, however, do not fit for all potential application areas, but they can be altered by the introduction of comonomers. The copolymerization of lactide (LA) with other lactones like ϵ‐caprolactone (CL) has been established for several years. Nevertheless, controlling copolymerizations remains a challenge due to the high complexity of the system. Copolymerization of LA with other monomer classes is much less investigated, but has the chance to overcome the limitations in material properties that occur when only lactones are used. The crucial factor for all copolymerizations is the catalyst. It dominates the reaction kinetics and determines the resulting microstructure. In this review, copolymerization catalysts for LA are presented divided into catalysts for the synthesis of lactone block copolymers, lactone random copolymers, and multimechanistically synthesized copolymers. The selected catalysts are highlighted either owing to their industrially applicable polymerization conditions or their non‐standard mechanism. [ABSTRACT FROM AUTHOR]

Environmental pollution by synthetic polymers is a global problem and investigating substitutes for synthetic polymers is a major research area. Starch can be used in formulating bioplastic materials, mainly as blends or composites with other polymers. The major drawbacks of using starch in such applications are water sensitivity and poor mechanical properties. Attempts have been made to improve the mechanical properties of starch-based blends and composites, by e.g., starch modification or plasticization, matrix reinforcement, and polymer blending. Polymer blending can bring synergetic benefits to blends and composites, but necessary precautions must be taken to ensure the compatibility of hydrophobic polymers and hydrophilic starch. Genetic engineering offers new possibilities to modify starch inplanta in a manner favorable for bioplastics applications, while the incorporation of antibacterial and/or antioxidant agents into starch-based food packaging materials brings additional advantages. In conclusion, starch is a promising material for bioplastic production, with great potential for further improvements. This review summarizes the recent advances in starch-based blends and composites and highlights the potential strategies for overcoming the major drawbacks of using starch in bioplastics applications. [ABSTRACT FROM AUTHOR]

For the purpose of mechanical recycling for food contact applications, decontamination of polyhydroxybutyrate-co-valerate (PHBV) plastic was performed under different temperatures and time conditions. As expected, increasing the decontamination temperature and duration increased the decontamination efficiency, but also the degradation of the polymer. The combination 160 °C/6 h was selected as the optimal conditions that maximize contaminants removal while minimizing polymer degradation. Then the safety of the recycled PHBV under these conditions was assessed, in accordance with EFSA regulation based on bottle-to-bottle PET recycling. Decontamination of low molecular weight molecules such as toluene, chlorobenzene, and methyl salicylate was nearly complete with residual concentrations below the modeled concentrations allowed in the polymer when the adult scenario is considered. However, the higher molecular weight and lower volatility molecules exhibited acceptable decontamination efficiencies, but their residual concentrations in the polymer exceeded the maximum concentrations of no concern. The presence of these molecules allows the use of nearly 21% recycled PHBV in the new materials to meet safety criteria. It is important to keep in mind that this work, never done before, is a preliminary work on mechanical recycling of PHBV, mainly based on extrapolation of PET conditions and regulations. Much more research needs to be done to improve the decontamination process, the barrier properties of PHBV or to think about a short recycling line for PHBV. [ABSTRACT FROM AUTHOR]

This review article will discuss the ways in which various polymeric materials, such as polyethylene (PE), polypropylene (PP), polystyrene (PS), and poly(ethylene terephthalate) (PET) can potentially be used to produce bioplastics, such as polyhydroxyalkanoates (PHAs) through microbial cultivation. We will present up-to-date information regarding notable microbial strains that are actively used in the biodegradation of polyolefins. We will also review some of the metabolic pathways involved in the process of plastic depolymerization and discuss challenges relevant to the valorization of plastic waste. The aim of this review is also to showcase the importance of methods, including oxidative degradation and microbial-based processes, that are currently being used in the fields of microbiology and biotechnology to limit the environmental burden of waste plastics. It is our hope that this article will contribute to the concept of bio-upcycling plastic waste to value-added products via microbial routes for a more sustainable future. [ABSTRACT FROM AUTHOR]

The automotive industry has used plastics almost since the beginning. The lightness, flexibility, and many qualities of plastics make them ideal for the automotive industry, reducing cars' overall weight and fuel consumption. Engineering plastics in this industry belong to the high-performance segment of non-renewable resources. These plastics exhibit higher properties than commodity plastics. Fortunately, unlike recycled commodity plastics, the super properties and high-performance characteristics make engineering plastics effectively reused after recycling. The substitution of these fossil-fuel-derived plastics adds to the solution of lightweighting, a much-needed solution to waste management, and solves industrial and ecological issues surrounding plastic disposal. All major vehicle manufacturers worldwide use bioplastics and bio-based plastics, including natural-fiber composites and engineering plastics reinforced with natural fibers. Changing the source of plastics to raw materials from renewable resources is the logical approach to sustainability. Thus, high-quality plastics, recycled plastics, bio-based plastics, and biodegradable plastics could be exploited from design, making sustainability an integral concept of mobility development. This review analyzes that switching from fossil-fuel- to renewable-sources-derived plastics is a step toward meeting the current environmental goals for the automotive industry, including electric cars. [ABSTRACT FROM AUTHOR]

Lately, environmentally benign packaging materials with biodegradability, flexibility, and high barrier properties are sought after as a substitute for conventional plastic packaging materials due to increasing plastic pollution and microplastics in the environment. Although natural polymers can be sustainable alternatives to petro‐sourced, non‐biodegradable plastics, they suffer from the poor barrier and mechanical properties. In this study, a mechanically stable, biodegradable film of tree gum kondagogu with remarkable barrier properties is fabricated. The introduction of spray‐coated, waterborne, large‐aspect ratio sodium‐hectorite dispersion on tree‐gum films ensured very high barrier properties even at high relative humidity conditions (oxygen transmission rate (OTR) ≈1.7 cm3 m−2 day−1 bar−1 at 75% relative humidity). The coating not only decreases gas permeability through the films but also minimizes the sensitivity of performance to humidity levels. The clay‐coated nanocomposite films outperformed various commercial polymers and are comparable to high‐performance packaging films in terms of oxygen barrier properties. Further, the coating improved the mechanical properties of the films rendering them a prospective packaging material. These biodegradable, high‐barrier and mechanically robust films are a promising advance in the field of sustainable packaging. [ABSTRACT FROM AUTHOR]

Biopolymers based on starch, cellulose and proteins extracted directly from biomass with or without modification have been widely used as the natural resources to produce biodegradable plastic. Starch has several disadvantages: strong hydrophilic behavior and inferior mechanical properties when compared with synthetic polymers. Starch is also mostly soluble in water and will be decomposed before undergoing the gelatinization process. To provide resistance and mechanical strength of starch, several fillers (reinforcement) in the form of metal and natural materials are usually added to the polymer matrix. Zinc oxide (ZnO) nanoparticle and natural fiber as a lightweight material that is biocompatible, nontoxic, cost-effective and exhibit strong antibacterial activity can be considered as a reinforcement of starch-based bioplastic. The present study, the reinforcing effect of ZnO on the mechanical, antibacterial, and physical properties of bioplastic films in the form of cassava starch/chitosan/pineapple leaf fiber (PALF)/ZnO. The highest value of elongation at break is for 16 % ZnO-bioplastics which could be completely decomposed only 21 days in ordinary soil and only 18 days in seawater. The packaging tests using slice bread showed antimicrobial properties with no fungal growth for 30 days of bioplastic coatings with 10, 13, and 16 % ZnO NPs. The results in this study indicated that, the ZnO and PALF plays an important role in reinforcing the physical, mechanical, and antibacterial properties of starch/chitosan/PALF-based bioplastic. [ABSTRACT FROM AUTHOR]