Search

This study aimed to investigate the impact of as-received biomass fly ashes (BFA) and green liquor dregs obtained from a pulp and paper plant in Brazil as substitutes for metakaolin in geopolymeric formulations. The properties of this type of waste material vary widely between different industrial plants. This study refrains from subjecting the waste materials to any form of pretreatment, taking into account their organic matter and particle size heterogeneity, requiring extensive characterization to evaluate their influence on the compressive strength, apparent open porosity, and water absorption of the geopolymeric samples. The objective was to assess their potential for upcycling purposes as an alternative to energy-intensive materials, such as ordinary Portland cement (OPC) and advanced ceramics. This potential arises from the ability of alkali-activated materials (AAM) to undergo curing at ambient temperatures, coupled with the possibility of compositions primarily derived from waste materials. To improve the sustainability of the products, the amorphous content of the raw material, which is more reactive than crystalline phases, was quantified and used as the base for mixture ratios. This approach aimed to reduce the requirement for alkaline activators, which have significant environmental impacts, while also increasing the waste content in the formulation. The incorporation of waste materials into the geopolymer matrix generally led to a reduction in the compressive strength compared to the benchmark metakaolin sample (19.4 MPa) but did not present a trend. The dregs led to values of 4.1 MPa at 25 wt% and 7.1 MPa at 50 wt%, a behavior that is somewhat counterintuitive, and BFA at 10 wt% presented 5.7 MPa. Nevertheless, the apparent open porosity remained at high levels for all the samples, close to 50%, and the compressive strength of most of them was over the values obtained for the metakaolin-only samples with mixture ratios calculated from the total composition instead of the amorphous composition. The decrease in strength and the increase in porosity were attributed to the specific characteristics of the waste materials, such as their high crystallinity, presence of organic matter, heterogeneous particle composition, and size. Overall, this study provides insight into the variations in geopolymerization based on the bulk and amorphous content of the aluminosilicate sources and how the characteristics of the waste materials influence the geopolymer matrix. It also highlights how calculating mixture ratios based on the amorphous composition improves the possibility of waste valorization through alkali activation. Additionally, it suggests that BFA and dregs might be effectively utilized in applications other than OPC substitution, such as adsorption, filtration, and catalysis. [ABSTRACT FROM AUTHOR]

Copyright of Museologia e Patrimônio is the property of Museologia e Patrimonio and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)

Introduction: Distinguishing and categorizing the origin of garlic are highly significant, considering its widespread use as a flavoring agent. With billions of dollars annually in global trade, garlic is frequently susceptible to fraudulent practices. Methodology: Paper spray ionization mass spectrometry (PS‐MS) was employed to quickly analyze garlic samples from distinct geographic origins: China and Brazil. The so‐generated PS‐MS data were treated with metabolomic multivariate approaches, and the garlic samples from these different geographic regions were easily discriminated. Results: Brazilian garlic was characterized to contain higher levels of amino acids, such as arginine, proline, and valine, and organosulfur compounds, such as allicin, alliin, and l‐γ‐glutamil‐S‐allyl‐l‐cysteine, compared to Chinese garlic. The PS‐MS data were treated employing multivariate approaches, typically used in the metabolomics field, and this protocol was promptly able to discern among both types of samples. Conclusion: Hence, this combined strategy holds promise not only as an effective tool for the authentication of the geographical origin of garlic but also as a powerful means for biomarker discovery. [ABSTRACT FROM AUTHOR]

This essay studies the cultural consequences that the spread of paper money had in late nineteenth-century Brazil. First, I examine how these tensions are called into question through the analysis of a political scandal that took place in Rio de Janeiro, in 1900, concerning a two thousand reales banknote. Second, I offer a close reading of Machado de Assis' "Anedota pecuniária", a short-story included in Histórias sem data (1884). My goal is to interrogate the relation between paper money and the economy of credit work, and the narrative devices of literary fiction. [ABSTRACT FROM AUTHOR]

This paper investigates retracted articles indexed in the Scientific Electronic Library Online (SciELO) Brazil, using bibliometric techniques to identify the characteristics of these retractions and relevant citation trends. All records of retracted articles from the first record in October 2004 to April 2022 were included. Sixty-seven retractions and 870 citations pre- and post-retraction were analyzed. Results indicate a change of scenario that began in 2015, with recurrences of retracted articles allegedly produced by paper mills. The prevalence of retractions derived from professional misconduct in health research and the frequency of post-retraction citations in health sciences raise concerns in the chain of stakeholders, public health, and scientific development. [ABSTRACT FROM AUTHOR]

This article discusses Conservation Units in the conservationist perspective, as instruments to protect nature, assuring the maintenance of Brazilian biodiversity and biomes, in order to build an ecologically balanced environment under the terms of the Federal Constitution of 1988. Through deductive method, exploratory, documental, and bibliographic research, and indirect analysis of Environmental Ministry and Environmental, Sustainable Development State Office data, it makes a legal-theoretical appreciation of the issue in Brazil. By looking at the Brazilian scenario, it notices that most part of the Conservation Units were created by the States and were focused, respectively, on Mata Atlântica, Cerrado, and the Amazon, and had sustainability as a legal-political fundament. The conjuncture of Goiás indicates that stating the Conservation Units existence is not enough, since more than half of Conservation Units lack landing regularization. Also, six out of twenty-five Conservation Units still do not have an Administrative Counsel. Twenty Conservation Units do not have a working plan, which, added to financial and staff difficulties may compromise the expected protection of nature. [ABSTRACT FROM AUTHOR]

This paper is aimed to develop a hybrid model (PCA-ANN) to predict the extractive content in eucalyptus wood clones. The input variables to the virtual analyzer are planting parameters available from the forest inventory, therefore the prediction does not rely on laboratory analysis of the wood samples, affording a quick estimate of the extractive contents. This study further bridges the literature gap on the investigation of the cause of variability of extractive content in eucalyptus wood. The PCA-ANN was identified from experimental data to predict and monitor the extractive content, since laboratory measurements can take several days and become available only after wood processing. The experimental data contained information on ten species of eucalyptus clones from five regions in the extreme south of Bahia, Brazil. Principal Component Analysis (PCA) firstly assessed the impact of planting variables on the extractives content. The variability of the data was represented by eight principal components and the variables that mostly contribute to the extractive content are: potential acidity, iron, saturation of aluminum, magnesium, pH, base saturation, remaining phosphorus, zinc, manganese and copper. The artificial neural network (ANN) with the 8 principal components in the input layer showed that the PCA could effectively reduce the dimensionality of the data. For practical purposes, though, the ANN with 10 input variables and 16 neurons in the hidden layer, presenting an average relative deviation of 1.5%, is recommended. The prediction of the extractive content is essential to allow preventive management practices toward the improvement of yield and quality of the cellulosic pulp. [ABSTRACT FROM AUTHOR]

This article describes how The Language Center at the Espirito Santo Federal University changed from using traditional pencil-andpaper tests to performance testing, based on authentic tasks. The change was prompted because people thought that their testing did not reflect a communicative approach to language teaching. The Assessment Project lasted for two years; the author discusses its participants, goals, stages (including pilot testing), and results. Content and construct validity improved, leading to positive washback. Learning objectives and criteria for passing were clarified.

Silicon (Si) is a chemical element that is not yet considered essential for plants. However, over the past few decades, an increasing number of scientifi c studies have focused on the role of Si in soil-plant interactions. At the same time, many countries are leading the development and use of silicon-based fertilizers. Si can be taken up by plants predominantly in a mobile form (H4SiO4) in the soil through both passive and active uptake mechanisms. Therefore, Scopus data from 2012 to 2022 were used to understand the implementation and current status of research on the benefi cial effects of silicon fertilizers on soil and plants and the role of soil forms of silicon in improving soil quality. A bibliometric study of articles published in the database on the role of Si in soil and silicon fertilizers was carried out. Various tools, such as Microsoft Offi ce Excel 2021, VOS Viewer and Mapchart.net were used in this study. The fi nal literature includes 440 articles, 82% of which are scientifi c. Over the past decade, the number of published articles has increased signifi cantly. For example, in the years 2021–2022, a total of 91 articles were published, which is six times higher than the number of articles published in 2012–2013 (15 articles). This signifi cant increase in publications highlights the growing interest in the role Si and Si fertilizer research. It was found around 32.04% of China, 13.2% of the USA and 9.8% of Brazil the reviewed publications focused on the role of Si and Si fertilizers studies. Among the authors who published the most articles on this topic during the selected period are Wang X. (with 12 articles), Liang Yu., Rizwan M. and Ali S. (each with 8 articles). [ABSTRACT FROM AUTHOR]

Recycled paper has the potential to be used as a mulch for vegetable production and can be adopted for the cultivation of Italian zucchini. However, there have been no studies about the water savings or crop coefficient values used in irrigation management in this system; therefore, there is a need for more research. In view of the above, this study aimed to evaluate the effects of recycled paper mulch on evaporation and evapotranspiration in Italian zucchini and to determine the crop coefficients in its developmental stages. The study was carried out in two cultivation cycles conducted at the Lysimetric Station in Viçosa, MG, Brazil. The experiments were installed in a randomized block design with four replicates. Four lysimeter cultivation treatments were applied: without mulch (C); with recycled paper as mulch (CP); with only recycled paper (P); and with Bahia grass (G). Irrigation and drainage measurements were performed daily to calculate the crop and reference evapotranspiration, and thus the crop coefficient (Kc) values. The following characteristics were evaluated: fruit yield, NDVI and water productivity. For the cultivation of Italian zucchini using paper as mulch, Kc values of 0.54, 0.77 and 0.44 and Kcb values of 0.15, 0.45 and 0.18 are recommended for the initial, intermediate and final stages, respectively. NDVI can be used to estimate the Kc values for Italian zucchini. The use of recycled paper as mulch reduces the water consumption of Italian zucchini. [ABSTRACT FROM AUTHOR]

There is an urgent need for energy sources with lower environmental impacts to dispose of waste generated by human activities. In this context, a holistic analysis of energy use of waste from agricultural and forestry activities, animal excreta, urban solid waste and sewage, waste from the pulp and paper industry and charcoal in Brazil is presented. Based on a bibliographic review, the current Brazilian panorama is presented in figures giving, a vision of national potential for harnessing bioenergy from this theoretical and technical potential. The QGIS3.24.2 Tisler geoprocessing tool was used to generate potentiality maps from census data of microregions and municipalities available in the IBGE database (2022) and in the Geocentric Reference System for the Americas (SIRGAS 2000). The results of map analysis by micro‐regions of the primary energy from agricultural residues highlight sugar cane, corn and soybeans crops, followed by wastewater and animal excreta. They stood out amont the studied sources of biomass with technical potentials of 53.17, 15.23 and 6.81 GW, respectively. With these results, it is concluded that Brazil could enable around 75 GW installed power, reusing all biomass, potentially 12.5 PJ, without considering the 16 GW already installed from sugarcane and paper black liquor plants. [ABSTRACT FROM AUTHOR]

In the 21st century, there is a growing Brazilian academic interest from professors and students in researching realities from Asia, especially in postgraduate courses in Language Arts, Philosophy and Human Science. The paper aims not only to point to a broader panorama of Centers, Nuclei, Programs, Research, Study and Work Groups, Thematic Sessions and Events with Asian themes in the aforementioned academic areas in Brazil, but also to make a brief analysis of the papers carried out in Work Groups and Thematic Sessions of the ANPTECRE and PPCIR (CONACIR) national congresses dedicated to realities of Asian origin, taking into account three criteria, i.e. Religious Studies methodologies used, the genres of authorship, and the religious traditions that were approached by these papers. [ABSTRACT FROM AUTHOR]

Classifying papers according to the fields of knowledge is critical to clearly understand the dynamics of scientific (sub)fields, their leading questions, and trends. Most studies rely on journal categories defined by popular databases such as WoS or Scopus, but some experts find that those categories may not correctly map the existing subfields nor identify the subfield of a specific article. This study addresses the classification problem using data from each paper (Abstract, Title, Keywords, and the KeyWords Plus) and the help of experts to identify the existing subfields and journals exclusive of each subfield. These "exclusive journals" are critical to obtain, through a pattern detection procedure that uses machine learning techniques (from software NVivo), a list of the frequent terms that are specific to each subfield. With that list of terms and with the help of optimization procedures, we can identify to which subfield each paper most likely belongs. This study can contribute to support scientific policy‐makers, funding, and research institutions—via more accurate academic performance evaluations—, to support editors in their tasks to redefine the scopes of journals, and to support popular databases in their processes of refining categories. [ABSTRACT FROM AUTHOR]

Hypericum perforatum L. (St. John's wort) is one of the world's most consumed medicinal plants for treating depression and psychiatric disorders. Counterfeiting can occur in the medicinal plant trade, either due to the lack of active ingredients or the addition of substances not mentioned on the labels, often without therapeutic value or even harmful to health. Hence, 43 samples of St. John's wort commercially acquired in different Brazilian regions and other countries were analyzed by paper spray ionization mass spectrometry (PS‐MS) and modeled by principal component analysis. Hence, samples (plants, capsules, and tablets) were extracted with ethanol in a solid–liquid extraction. For the first time, PS‐MS analysis allowed the detection of counterfeit H. perforatum samples containing active principles typical of other plants, such as Ageratum conyzoides and Senna spectabilis. About 52.3% of the samples were considered adulterated for having at least one of these two species in their composition. Furthermore, out of 35 samples produced in Brazil, only 13 were deemed authentic, having only H. perforatum. Therefore, there is a clear need to improve these drugs' quality control in Brazil. [ABSTRACT FROM AUTHOR]

Although the importance of understanding the social and cultural processes mediating pre-service teachers' expansion of the power to act has been increasingly recognized lately, the way the concept of "agency" is portrayed in most of the studies focuses almost exclusively on the subject of activity and therefore, there is insufficient theoretical attention to the reverse side of agency, the experience of being subject to and subjected to conditions. In this paper, the authors exemplify the process of "conscientização" and agential development in the case study of Jefferson, a new teacher engaged in a school teaching education program. The purpose of this paper is to show how new forms of consciousness, expansion of the power to act, and increasing control over conditions simultaneously emerge for teachers in training during praxis and how agency is played out by the relations between being subject to and subjected to conditions. Implications for teaching education programs are discussed.

Taking as an example the very interesting and motivating paper by Sousa Ribeiro et al. (2021) an attempt is made of providing a couple of insights into the decision making process from the point of view of the potentially helpful aspects of data analysis and OR-related modelling. These are just hints and suggestions, meant primarily to emphasise the multifaceted character of the decision making situations and processes, especially when concerning more complex issues. While the course of the procedure proposed and exemplified in Sousa Ribeiro et al. (2021) is treated as fully correctly and successfully carried out to the end, we wish to show the potential use of information, constituting in a sense a "by-product" of such a procedure, or, actually, of any similar procedure, aimed at supporting decision making. [ABSTRACT FROM AUTHOR]

Copyright of Revista Fronteiras is the property of Universidade do Vale do Rio dos Sinos and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)

In July 2015, China's national legislature brought in prosecutor-led civil environmental public interest litigation ("EPIL") for thirteen selected provincial areas of the country. After a two-year legal experiment, this prosecutor-led civil EPIL system was then established nationwide in July 2017. Yet, can it be said that prosecutorial regulators in China are in fact a paper tiger? Drawing upon content analysis of the 655 prosecutor-led civil EPILs and in-depth interviews with twelve frontline prosecutors and judges, this article examines the dynamics of regulatory practice and the motivation of the Chinese prosecutorial organs to engage in environmental regulation through litigation. Based upon the above two legislative landmarks in the law reform of this area, the regulatory practice of prosecutorial organs can be viewed as having occurred in three stages, with each stage featuring a distinct regulatory model: ad hoc regulation through local innovation before July 2015, forced regulation during the legal experiment from July 2015 to July 2017, and perfunctory regulation after the nationwide establishment of the prosecutor-led civil EPIL system in July 2017. The data shows that the Chinese prosecutorial organs have engaged in a larger number of such lawsuits since the second stage, but they have shown a strong preference for cases with less complicated facts, weak and small defendants, and minor environmental violations. Three factors that influence regulatory motivation are employed to analyse the change in regulatory models: the ambiguity of the law, the top-down political pressure for regulation, and the cost of regulation. This study highlights the very limited effectiveness of vertical political pressure in boosting prosecutorial regulation and the strong impacts of the cost of regulation and the ambiguity of the law. In particular, the high cost of regulation that takes weak regulatory capacity, lack of regulatory autonomy, and the winning rate-oriented performance appraisal system into account have significantly weakened the motivation of prosecutorial organs to pursue civil EPIL. The findings of this study echo the conditions present in the successful prosecutorial regulations in Brazil and contribute to the scholarship about prosecutorial regulations in the field of environmental protection in the Global South. [ABSTRACT FROM AUTHOR]

• Aspects related to water consumption of P. peruviana were evaluated under different managements. • P. peruviana vegetative growth is favored by high temperatures. • Mulching reduced Kc values of P. peruviana in all phenological stages. • The Kc of P. peruviana can be estimated by means of NDVI. • Recycled paper mulch reduced soil evaporation and water consumption by the P. peruviana crop by 30.6%. The application of soil mulching has been widely used to increase crop production; however, few research studies have comprehensively evaluated the use of recycled paper as soil mulch and its effects in relation to water savings and crop coefficients. The objective was to evaluate the effects of mulching with recycled paper on evaporation and evapotranspiration of Physalis peruviana and to determine the crop coefficients in its development stages. The study was carried out in two cultivation cycles at the Lysimetric Station of Viçosa, MG, Brazil. The experiments were set up in a randomized block design with four replicates, where four lysimeter treatments were applied: P. peruviana cultivation without recycled paper mulch (C); P. peruviana cultivation with recycled paper mulch (CP); lysimeter with only recycled paper mulch (P); and lysimeter cultivated with Bahiagrass (G). Irrigation and drainage volumes in each lysimeter were measured daily to calculate crop evapotranspiration (ETc), reference evapotranspiration (ETo) and, therefore, the crop coefficients (Kc). In addition, crop phenology, fruit characteristics, gas exchange, yield and normalized difference vegetation index (NDVI) were also evaluated. For the first cultivation cycle, over 218 days, the values of water consumption in the lysimeters C, CP, P and G were 405, 291, 88 and 444 mm, respectively. For the second cycle, over 206 days, the values of water consumption were 416, 279, 94 and 331 mm, respectively. Recycled paper significantly reduced water consumption, especially in the initial and late-season stages, also reducing Kc values. The Kc values for P. peruviana were 0.25, 0.55, 1.05 and 0.46 in cultivation with mulch and 0.45, 0.85, 1.35 and 0.48 in cultivation without mulch for the initial, development, mid-season and late-season stages, respectively. NDVI can be used to estimate the Kc values of P. peruviana. Recycled paper mulch reduced water consumption by 30.6% and increased gas exchange and yield of P. peruviana in cycles 1 and 2, respectively. [ABSTRACT FROM AUTHOR]

Copyright of Revista NERA is the property of Revista NERA and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)

The production of handmade paper is a sustainable process that has a relevant social and economic function, especially in developing countries. In the search for alternative, renewable and low-cost sources for cellulose and handmade paper production, we evaluated the morphological characteristics and chemical composition of fibers of leaves and culms from Arundo donax, a fast-growing invasive grass that was introduced in several countries, including Brazil. The fibers of A. donax are long (leaf = 1.73 mm; culm = 1.26 mm), with thick cell walls (leaf = 4.97 μm; culm = 5.36 μm), which provide folding endurance and result in a rougher and more voluminous paper. Additionally, the high values of cell wall fraction (leaf = 78%; culm = 82%) indicate great fiber stiffness. The relatively high values of cellulose (leaf = 38.9%; culm = 39.4%) and low values of lignin (leaf = 12.1%; culm = 13.0%) in the fibers make its use in paper production advantageous, as it reduces costs with chemical products in pulping. Fibers from A. donax are a viable alternative material to produce cellulose and handmade paper or can be mixed with other raw materials to produce different types of paper. [ABSTRACT FROM AUTHOR]

A method for determining thallium in water samples via solid sampling high-resolution continuum source graphite furnace atomic absorption spectrometry (SS HR-CS GF AAS) after preconcentration using chromatographic filter paper as a solid support was proposed. The effects of pH, stirring time, and sample volume in the analyte preconcentration step were studied. The presence of potential interferences in the sample and the type of masking agent were also examined. In the proposed procedure, the sample was placed in contact with the solid phase in a polypropylene tube, and after stirring for 3 min, thallium determination was performed via HR-CS GF AAS directly on chromatographic filter paper. A preconcentration factor of 55, a precision of 9.4% (n = 10; 10 μg L−1), a limit of detection of 0.018 μg L−1, and a limit of quantification of 0.059 μg L−1 were achieved. Analyte addition and recovery tests were performed, and the results ranged from 91% to 110%. The accuracy of the method was evaluated by analyzing a water reference material. The procedure was used to determine thallium in water samples collected in Barreiras, Bahia, Brazil. The results were compared with those obtained using inductively coupled plasma‒mass spectrometry (ICP‒MS). Thallium concentrations in the analyzed samples ranged from <0.059 to 0.80 μg L−1. [Display omitted] • A method for Tl determination in water samples using SS HR-CS GF AAS is presented. • Thallium preconcentration using chromatographic filter paper as a solid phase was performed. • Thallium determination was carried out via HR-CS GF AAS directly on chromatographic paper. • This method was used to analyze river water samples. [ABSTRACT FROM AUTHOR]

Long term annual electricity consumption forecasting is very important for country's energy planning. These forecasts are influenced by several factors (political, technological, social, environmental and economic), and brings with itself a high uncertainty degree in its results and difficulties in the evaluation of such factors over them. A methodology that eases to take into account these factors aiming improve the results and help understanding the electricity consumption annual trajectory till the forecast horizon is, therefore, very much useful and desired. So, we propose a modelling structure using the bottom-up approach to cope with these matters and to evaluate the trajectory of long term annual electricity consumption of a sector of the Brazilian industry up to 2050 considering energy efficiency (EE) scenarios. It is important to emphasize that Brazil is a developing country, and to build a bottom-up approach was a challenge, mainly due to the fact that this model is data intensive. In particular, this modelling was applied in the pulp and paper sector. The main goal was to consider technological diffusion scenarios in EE measures, and show the energy savings achieved. The results point an energy savings in the order of 25% when an actual scenario is considered. [ABSTRACT FROM AUTHOR]

Visceral leishmaniasis remains a serious public health issue, and Brazil was among the seven countries with the highest prevalence of this disease worldwide. The measures to control this disease are not easily developed, and the improvement of its diagnosis, surveillance, and control is still needed. This study aimed to carry out the polymerase chain reaction (PCR) diagnosis of Leishmania infantum in vector samples in some municipalities of the State of São Paulo, which included two municipalities with human disease transmission and two with dog transmission only. Vectors were collected in traps with luminous bait. Next, they were killed at −4 °C and kept in 70% alcohol. Groups of ten female insects (pools) were mashed on cation exchange paper (fine cellulose phosphate with 18 µEq/cm² ionic exchange capacity) for DNA extraction. The PCR was carried out to identify the natural infection of the Leishmania genus in female Lutzomyia longipalpis (Lu. Longipalpis). Out of the 3,880 Lu. longipalpis phlebotomines, 1060 were female and 2820 were male (3:1). The method used to extract the DNA in pools of ten phlebotomines and the PCR resulted in sensitivity, specificity, practicality, and faster analyses when compared to the individual analysis method. The procedure described can be used on a large scale in the leishmaniasis epidemiological surveillance, enabling a higher number of analyses and the optimization of human resources because the traditional diagnostic method is carried out via desiccation of the insect digestive system and microscopic examination, which is time-demanding and there is the need of manual skills. [ABSTRACT FROM AUTHOR]

This paper reports the use of paper spray mass spectrometry (PS‐MS) combined with chemometric models to analyze seized samples of anabolic steroids. Because many forensic laboratories typically demand high‐throughput analysis for this type of sample, we developed a quicker and simpler alternative analytical method for routine analysis with minimal sample preparation. Oily samples (n = 39) resulting from seizures carried out by Brazilian Federal and State Police units were selected for this study. These samples were analyzed by PS‐MS in the positive ion mode and full scan (50–1000 m/z), providing spectra containing patterns of the respective active ingredients present in each product. A principal component analysis (PCA) model was built, which discriminated samples mainly according to their active ingredients and allowed to detect and characterize some cases of product counterfeiting. The variable selection method ordered predictors selection was employed jointly with PCA to improve sample cluster separation and to provide model simplification. The final PCA model was built with three principal components and using only 28 spectral variables. This model accounted for 69.82% of the variance and discriminated samples according to their specific active ingredients. [ABSTRACT FROM AUTHOR]

This paper aims to understand how violent deaths suffered by common people and their media coverage are approached in the field of Communication, focusing on the sense-making processes about violence and its structural nature. In order to do so, we analysed papers about the media coverage around murders, published in 26 journals in the field of Communication, classified as A2 and B1 in the Brazilian "Qualis Capes" ranking. Based on the ways of identifying the victims and the circumstances of their deaths, in interaction with the ways of naming such violence, presented in the papers' empirical and analytical dimensions, we designed an overview of the silences and absences in the epistemic constructions about violence in media and academia in Brazil. [ABSTRACT FROM AUTHOR]

The Museu de Zoologia da Universidade de São Paulo (MZUSP), São Paulo, Brazil houses the largest and most representative Brazilian collection of Diptera. In the present study, following a recommendation of the International Code of Zoological Nomenclature, it is presented a catalogue of the type specimens of Diadocidiidae and Ditomyiidae (Diptera: Bibionomorpha) held in the collection of the MZUSP. Label data and the condition of preservation of 27 type specimens (nine holotypes, two paralectotypes, and 16 paratypes) of 14 Neotropical species are provided. [ABSTRACT FROM AUTHOR]

The subsector of pulp and paper presented in 2013 an electric power consumption of 9.3% of electricity consumption in the industrial sector in Brazil. It experienced a significant growth of production in the last 20 years, exceeding 160%, and their consumption of electricity increased by 130%, reaching the level of 19,594GWh. Due to its characteristics, with a known structure and production processes, and its importance in the country's industrial sector, this subsector was selected for study in this paper, to evaluate the behavior of its long-term annual electricity demand, at the horizon of 20 years ahead, in energy efficiency scenarios through bottom-up approach. This approach is data intensive and requires data with good quality; it consists of a hierarchical structure that enables to check how specific actions can affect the results at each level and its effect on higher levels. [ABSTRACT FROM AUTHOR]

Copyright of Revista de Administração e Inovação (RAI) is the property of Revista de Administracao e Inovacao- RAI and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)

Calls from policymakers to assimilate immigrants through English literacy have grown urgent. Yet the 2007 U.S. Census has reported that one in five U.S. residents speaks a language other than English at home. What's more, new immigrants often settle in long-standing immigrant communities in which these non-English languages are the lingua franca. These demographic trends call for a reconceptualization of the problematic relationship of literacy to immigrant assimilation. To whom, precisely, are immigrants assimilating, especially in multi-ethnic communities? And how exactly does literacy, especially biliteracy, shape this process? Through an ethnographic investigation of how two different immigrant groups form biliterate partnerships in the quest for legal immigration papers, this essay examines how literacy and assimilation function in light of the changing writing demands of contemporary immigrant life. (Contains 8 notes.)

This study analyzes the production of knowledge in the field of eco-innovation, checking its state of the art in order to discuss topics of future research. Specifically, it assesses the pulp, paper, and paper products industry in Brazil in order to examine the drivers of the adoption of eco-innovation strategies. The study is essentially a review of the literature, with a methodology based on exploratory research, and using the documental and bibliographical qualitative method. The empirical research was based on a quantitative approach using the strategy of a cross-sectional survey by means of a self-administered online questionnaire. It was verified that the studies related to eco-innovation are still preliminary and that the subject lacks specific research with empirical data from survey and in-depth case studies. The following topics were checked for studies on innovation in environmental issues on conceptual and theoretical discussion; models and indicators for evaluating the eco-innovation; types; and political arguments for their development, with the proposition of research lines within this context. The results of the empirical research allow us to conclude that factors such as environmental regulation, the use of environmental incentives and innovation, reputation effects, top management support, technological expertise, and environmental formalization in the context of domestic enterprises are crucial to the adoption of eco-innovation. Further, the higher the extent to which companies embrace an environmental and innovative culture, the greater the internalization of eco-innovative practices. [ABSTRACT FROM PUBLISHER]

For the first time, a cutin-like, highly chemically resistant macropolymer has been isolated from rachises of Karinopteris sp. (lyginopteridalean pteridosperm, Middle Pennsylvanian). Samples are obtained from a cuticular or "paper" coal-shale, i.e., an organic-rich and highly clastic rock associated with the Upper Block Coal Member of the Brazil Formation, Parke County, west-central Indiana, U.S.A. Karinopteris specimens are preserved as naturally oxidized compressions, termed "fossilized cuticles", and possibly represent vegetation of mineral substrate environments. Employing laboratory oxidation reactions, the fossilized cuticle of Karinopteris rachises is used to obtain the cuticle. After additional and long-term oxidation treatment, the cuticle yields the cutin-like macropolymer, here referred to as "cutin" for simplicity. The fossilized cuticle, cuticle, and cutin samples of Karinopteris sp. are chemically analyzed using semi-quantitative Fourier transform infrared (FTIR) spectroscopy. Cutin IR spectra of Karinopteris rachises are characterized by (a) a predominantly aliphatic composition as indicated by intense aliphatic (CH al) C H stretching peaks at 3000–2700 cm−1, which are assigned to methylene (CH 2) and methyl (CH 3) groups; (b) carbonyl (C=O) groups at 1730–1640 cm−1, and aromatic carbon (C=C) absorption bands at 1600–1500 cm−1. A comparison with the cuticle, the cutin stands out due to relatively higher values of CH 2 /CH 3 and C=O/C=C, while displaying notably low values of CH al /C=O and C C contribution. Specifically, the relatively low value of CH al /C=O ratio obtained for the cutin of Karinopteris rachises is consistent with those found in the cutin of extant and fossil leaves. This lower CH al /C=O ratio indicates the important role likely played by C O groups in creating a deformable and flexible structure in both the cutin and the cuticle. Such a reduced rigidity suggests a high level of rachis flexibility of the once-living Karinopteris plant, supporting the interpretation of a climbing or liana habit. Cutin isolation and its chemical characterization shed light on the probable biomechanical (flexibility) properties of Karinopteris rachises, thereby enhancing our understanding of the plant growth habit. [Display omitted] • First-time spectroscopic study of Indiana "paper" coal (Pennsylvanian, U.S.A.). • Cutin polymer is obtained from fossilized cuticles of Karinopteris rachises. • Fourier transform infrared spectroscopy supplies chemical data. • Cutin is mainly aliphatic with highly crossed-linked ester carbonyl (C=O) bonds. • High C O contents suggest a liana-like Karinopteris plant with flexible rachises. [ABSTRACT FROM AUTHOR]

[Display omitted] • Five Brazilian coats of arms paintings are characterized in a microanalytical approach • Artist's palette comprises traditional pigments such as ultramarine blue, indigo, Prussian blue, lead chromate and vermillion • Aluminium and brass are found in silvering and gilding instead of silver and gold, contradicting heraldic guidelines • Differences in the colorant palette and signature raise questions about the authorship of a painting • Crystalline efflorescences in one painting may indicate paint extender migration or past microbiological activity Heraldry in Latin American art of the twentieth century can be considered rare. In this context, the material composition of coat of arms paintings on paper attributed to the Brazilian painter José Wasth Rodrigues is investigated for the first time using a microanalytical approach. Microsamples from 5 municipal coats of arms dated 1932 were analysed using Raman microscopy, Attenuated Total Reflection Fourier Transform Infrared spectroscopy (ATR-FTIR), and Scanning Electron Microscopy with Energy Dispersive Spectroscopy (SEM-EDS). SEM-EDS results revealed the artist's choice of using metallic aluminium and brass in the representation of silver and gold colours, respectively. Raman microscopy analyses showed the use of traditional inorganic pigments, such as ultramarine blue, indigo, Prussian blue, yellow chromates and vermillion. In contrast, the results showed that the painting with an unusual signature attributed to the artist (W. instead of J.W.R, commonly found) contains synthetic organic dyes Orange 5, Red 53, and Yellow 1 (introduced in the 1900s). This discovery raised hypothesis of questioning authorship for this particular painting. ATR-FTIR analysis of a paint fragment from one painting confirmed the use of gum arabic as a binder. ATR-FTIR analyses of efflorescences collected from a blue paint layer of a particular coat of arms suggest protein and lipid content, raising suspicion of either the use of the tempera technique in this particular paint or remains of a past microorganism activity. Robust information was obtained on the chemical characterization of the coat of arms, enhancing comprehension of the painting techniques employed by the artist and providing insight into the production of heraldic art in Brazil at the beginning of the 20th-century. [ABSTRACT FROM AUTHOR]

This paper describes a cradle-to-gate life cycle assessment of offset paper production in Brazil. The production system is classified into two subsystems: a forest production subsystem, which involves seedling production, soil preparation, seedling planting, forest maintenance, and wood harvesting and transport processes; and an industrial production subsystem, involving wood pulp extraction and bleaching, chemical recovery, and offset paper manufacturing processes. The environmental analysis includes the primary energy demand, environmental impact assessment, and land use indicators. The primary energy demand indicated that the largest amount of both renewable and non-renewable primary energy is consumed by the industrial production subsystem, accounting for 91.0% of the total energy demand. The potential environmental impact assessment included eight impact categories: acidification, ecotoxicity, global warming, human toxicity – cancer effects, human toxicity – non-cancer effects, nutrient enrichment, ozone depletion, and photochemical oxidation. Most of the potential impacts are attributed to the processes of pulp extraction and bleaching, and offset paper manufacturing, mainly due to the production of electricity and thermal energy. As for impacts on land use during the forest activities, a recent developed approach was applied for the regionalized assessment of impacts. Land occupation impacts on erosion resistance, physicochemical filtration, and mechanical filtration showed a reduction in the soil ecological functions, whereas groundwater recharge indicated a credit for the performance of the soil function. With a view to reducing the main life cycle impacts of the industrial production subsystem, an evaluation is made of alternative production scenarios. The best scenario was the substitution of biomass and diesel in the energy generation unit by biomass gasification and optimization of the recovery boiler. [ABSTRACT FROM AUTHOR]

Paper aims: This study identifies fundamental characteristics for developing a paper-based thesis (PBT), providing some recommendations to researchers who decide for this academic research report. Originality: This paper contributes to the literature by providing guidance to develop PBTs, which has been attracting researchers' interest because it demonstrates publication capacity and potential as a researcher. Additionally, it is still not entirely clear which issues and countermeasures researchers should address when choosing the paper-based structure. Research method: The authors searched for articles of PBTs already published, institutional documents (e.g., regulations for conducting PBTs in Brazil and abroad) and journal papers concerning this subject. A content and document analysis were conducted in the papers and PBT internal regulations, respectively. Main findings: Results indicate five main factors that impact the success of a PBT approach: (i) the initial planning for this academic model; (ii) alignment between the articles and the thesis/dissertation; (iii) research design construction; (iv) copyrights requirements; and (v) issues regarding co-authorship. Based on that, the study also builds some guidelines to structure a robust PBT. Implications for theory and practice: Our recommendations might be meaningful to scholars and researchers bring more theoretical, empirical, and structural robustness when developing a PBT final document. [ABSTRACT FROM AUTHOR]

Rationale: The effort to make fake documents look real leads to the use of crickets and beverages to produce artificially aged papers, as land titles, based on yellowing caused by the use of these methods. An old practice in Brazil, called "cricketing", has led to the misappropriation of Brazilian land using these documents. We propose a rapid, simple, instantaneous and non‐destructive method to identify artificially aged papers by easy ambient sonic‐spray ionization mass spectrometry (EASI‐MS) analysis. Methods: Three typical aging procedures were used to obtain artificially aged papers using coffee, cola drink, and crickets, with the papers being analyzed by EASI‐MS. Multivariate statistical analyses were performed on the data to find the sample groups and to study the most relevant ions of each ageing procedure. High‐resolution MS (HRMS) was used to obtain the exact masses and attribute formulae to relevant ions present in the samples. Results: The combination of EASI‐MS and multivariate statistical analyses allowed us to identify the most relevant ions to classify the adulteration of documents and HRMS identified most of these relevant ions. TMS fingerprinting in combination with multivariate analysis also demonstrated that this approach can qualitatively differentiate all the examined paper samples. Conclusions: We developed a cheap, fast and easy method that can help to elucidate counterfeit documents that have been artificially aged, helping to identify chemical additives and one that can be used in forensic laboratories. [ABSTRACT FROM AUTHOR]

For five hundred eighty days, between 2018 and 2019, former Brazilian President Luiz Inácio Lula da Silva remained imprisoned in the city of Curitiba, about two hundred miles South of São Paulo. During that period, more than twenty thousand letters were sent to him from all regions of the country—the result of a campaign initiated by the Workers' Party and rapidly disseminated through social media—correspondence now archived at the Lula Institute, in the city of São Paulo, as part of the Lula Presidential Archives. This article surveys the status of private presidential archives in Brazil, probing the nature of "prison letters" and their uses in campaign actions for Lula's release, with special attention to the circulation of documents in digital format on websites and social media. The authors had access to the documentation cited in this piece during the mobilization for the Lula Livre movements. Finally, the article contributes to the study of political correspondence and analyzes the challenges posed to historical research by the digital circulation of documents. [ABSTRACT FROM AUTHOR]

Copyright of Exacta is the property of Exacta - Engenharia de Producao and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)

Copyright of Organizações Rurais & Agroindustriais is the property of Organizacoes Rurais & Agroindustriais and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)

The paper recycling process generates a sludge characterized by a high content of cellulose fiber. To understand the behavior of this fibrous material, this article presents an interpretation of the geotechnical behavior of a waste sludge from a paper recycling plant situated in southern Brazil using data from laboratory tests. Engineering properties of compacted paper mill sludges are similar to those of most fibrous organic soils: low hydraulic conductivity upon compression and high compressibility. The waste studied has a water content of approximately 250%, organic content of 48%, mineral charges, and water. The one-dimensional compressibility parameters are indicative of high compressibility. For the determination of the strength parameters of the material, undrained triaxial tests were carried out. An incredibly high effective friction angle ([lowercase_phi_synonym]′=53°) was found, probably because of the fibrous nature of the paper sludge. In addition, hydraulic conductivity tests were performed on a flexible wall permeameter. The hydraulic conductivity of the fibrous paper sludge reached values near10-9 m/s. The results showed that the paper mill sludge is a ductile material with reduced hydraulic conductivity and elevated shear strength that could have multiple applications, such as in the construction of bottom liners, cover liners, and steep side-slope liners for solid-waste landfills. [ABSTRACT FROM AUTHOR]

This study aims to analyze the relative efficiency of graduate programs in terms of the quality of their scientific publications in journals. To this end, we applied Data Envelopment Analysis to the fields of Public and Business Administration, Accounting, and Tourism, using data from the 2017 Quadrennial Evaluation developed by the Coordenação de Aperfeiçoamento de Pessoal de Nível Superior ["Coordination for the Improvement of Higher Education Personnel", CAPES]. The results suggest that efficient graduate programs are concentrated in the center-south axis of Brazil, in the areas of Administration and Accounting. Despite the overall publishing strategy in journals of various ranks (strata), efficient graduate programs allocate their efficiency primarily to Qualis A1 journals, A1 being the excellence rating in the CAPES scale. We conclude that legitimized research practices pressure graduate programs to improve the quality of their publications while threatening the survival of programs that fail to conform to the assessment rules. [ABSTRACT FROM AUTHOR]

Bisphenol A (BPA) is an endocrine and metabolic disruptor commonly employed as a color developer in thermal papers. Consequently, BPA derived from thermal papers has been considered an important source of exposure for humans, since this chemical may migrate from paper to skin upon contact. Further, due to recent restrictions on BPA use in some countries, it has been replaced by a new analogue, bisphenol S (BPS). The aim of the present study was to determine levels of BPA and BPS in 190 different thermal receipts, randomly collected from different locations in São Paulo State, Brazil, including receipts from supermarkets, general and fast-food restaurants, gas stations, bus and airplane tickets, and credit card and bank accounts. BPA and/or BPS were detected in 98% of samples at concentrations ranging from below the quantification limit to 4.3% (mg/100 mg paper). The obtained values were higher than amounts previously reported in other countries. The estimated daily intake through dermal absorption from handling of thermal receipt papers was estimated on the basis of concentrations and frequencies of handling of papers by humans in both the general population and occupationally exposed individuals. Fifth percentile, median, and 95th percentile daily intakes by the general population were 0.44, 1.42, and 2 μg/d, respectively, whereas the corresponding values for occupationally exposed population are 21.8, 71 and 101 μg/d. The potential adverse consequences of elevated occupational exposure are currently being examined. [ABSTRACT FROM AUTHOR]

The forest sector plays an important role in the circular bioeconomy due to its focus on renewable materials that can substitute fossil or greenhouse gas emissions-intensive materials, store carbon in bio-based products and provide ecosystem services. This study investigates the state of the bioeconomy in Brazil and its forest industry. Specifically, this study presents some examples of novel wood-based products being developed or manufactured in Brazil and discusses possible opportunities for the development of the country's forest sector. The pulp and paper industry plays an important role in the forest sector. It has also been showing advancements in the development of cascading uses of wood invalue-added products, such as nanocrystalline cellulose, wood-based textile fibers, lignin-based products, and chemical derivatives from tall oil. Product and business diversification through the integration of the pulp and paper industry to biorefineries could provide new opportunities. Moreover, biochemicals derived from non-wood forest products, such as resin and tannins could promote diversification and competitiveness of the Brazilian forest industry. Although some engineered wood products are still a novelty in Brazil, the market for such products will likely expand in the future following the global trends in wood construction. [ABSTRACT FROM AUTHOR]

This article explores how the quality of institutions influences the strategic choice of agents in the pulp and paper production system based on the forest plantation sector. In order to proceed with the study, we employ the Economic Analysis of Property Rights (Barzel, 1982, 1989, 2002) as foundation, and test the proposition: in federative states where the institutional environment is fragile and therefore the State has a high cost to enforce property rights, private mechanisms stand out in the protection of property rights. According to Dixit (2009, p. 8), "if the government does not pro tect property rights, at least not as well as owners require, many private arrangements arise to satisfy the owners' needs". The analysis of three business cases of companies with plantations in more than one federative unit revealed the broad range of private mechanisms in place to cope with insecure land rights. In addition to countrywide strategies, in the federative units where government fails to be a good property rights steward, we found geographically specific initiatives being used. Another finding was the identification of variables that are able to evaluate the quality of institutions and employed in the companies' decision-making process for the selection of land rights protection strategies. Findings altogether are empirical evidence of how the quality of institutions influences the strategic choice of land rights protection in the forest plantation sector in Brazil. [ABSTRACT FROM AUTHOR]

Industrial energy efficiency has received increasing attention in many countries because of its importance in the pursuit of energy supply security, increased economic competitiveness and in the mitigation of greenhouse gases emissions. This paper aimed to evaluate the energy consumption development of the Brazilian pulp and paper industry through an energy decomposition analysis and an energy efficiency index approach over a 30 years period. An international comparison with other important paper-producing countries (i.e., Canada, United States of America, Finland and Sweden) was carried out. It was concluded that despite a significant increase in the energy efficiency levels, responsible for 5.6 PJ savings in electricity consumption and for 38.6 PJ savings in fuels consumption between 1979 and 2009, a saving potential of 7.8 PJ and 146.2 PJ related to the annual consumption of electricity and fuels, respectively, could be identified in the Brazilian pulp and paper industry. Among the countries evolved in the international comparison, both the Swedish and Finnish industries were the most efficient, followed by the Brazilian, American and Canadian, the latter being the only one where there was a reduction in the energy efficiency levels from 1979 to 2009. [ABSTRACT FROM AUTHOR]

Dilemma: a discussion between two managers, from different generations, raised the dilemma of evaluating a decision made. This dilemma focuses on analysing how such a decision affects the interests of the company, the partners, as well as other stakeholders. Educational objective: to reflect upon the management process in a family business environment, highlighting issues such as decision-making, leadership, power relations, management styles, human behaviour in organizations and strategic planning. Contextualization: the decision-making process requires transforming data into action; therefore, the quality of the decision is the key for the success of an organization. Paper & Art is a family business, located in Minas Gerais, Brazil, and has seven employees. The teaching case focuses on the story of a father and son who, when running a business in the stationery industry, are faced with challenges that require the need to combine the efforts of those involved, preventing disparities in the objectives of the members from harming the company. Main theme: the case enables discussions on decision-making processes, decision quality and conflicts between generations in family businesses. Audience: the case can be applied to business students and in undergraduate or graduate disciplines that involve decisions, power and conflict. Originality / value: the combination of the efforts of those involved is necessary for the context presented, it could prevent disparities in the members' goals and harm the company. This is the originality of the case. [ABSTRACT FROM AUTHOR]

• The study of plant–plant parasitism has experienced remarkable growth in the scientific literature. • Research on plant parasites has predominantly focused on ecological and physiological aspects in the last 20 yeras. • Aspects of evolution and host-parasite interactions needs further and deeper investigations. • We hope this special issue will serve as a catalyst for further advancements in the investigation of plant-plant parasitism. The study of plant–plant parasitism has experienced remarkable growth in the scientific literature, particularly over the past two decades. Hemi- and holoparasites, in particular, have been recognized as pivotal components within plant communities, capable of upscale effects to the ecosystem. Research on plant parasites has predominantly focused on ecological and physiological aspects of parasites and hosts, with a global distribution pattern. However, some fields remain relatively unexplored, and specific regions of Asia and the Global South (with exception of Australia and Brazil) have yet to receive comprehensive attention. Here, we introduce the theme on plant hemi- and holoparasites and explore publication trends on plant–plant parasitism over the past half-century, with a particular emphasis on papers published within the last two decades. We explore our findings to extend an invitation to researchers from diverse backgrounds and disciplines to contribute their expertise to a forthcoming Virtual Special Issue of Flora – Morphology, Distribution, Functional Ecology of Plants on "Plant Parasitism: Ecology, Evolution and Functional Aspects", with contributions expected from a wide range of topics related to ecology, physiology, morphology, systematics, and reproductive biology. We believe that this special issue will help in advancing our knowledge in plant-plant parasitism, fostering collaboration and facilitating the growth of this exciting area of research. [ABSTRACT FROM AUTHOR]

Copyright of Revista Brasileira de Estudos Urbanos e Regionais is the property of Associacao Nacional de Pos-Graduacao e Pesquisa em Planejamento Urbano e Regional and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)

Copyright of Educação Matemática Pesquisa is the property of Pontificia Universidade Catolica de Sao Paulo, Programa de Estudos Pos-Grad. em Educacao Matematica and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)