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Microplastics (MPs) contamination is a well-established impact in oceans, but integrated approaches combining simultaneous analyzes of biotic and abiotic components are scarce. This study addresses this gap, demonstrating Atherinella brasiliensis (fish species) ingestion of MPs and comparing with the contaminant presence in water and sediment. Three Ubatuba beaches (exposed, calm and sheltered estuary) were surveyed for fish, water, and sediment components in summer and winter. Environmental data evidenced spatial and seasonal differences (PCA/ANOVA). Presence of synthetic particles (SPs) in fish was high (~38%). Maximum concentrations occurred in the estuary, for water (490 SPs/m³), and in the exposed beach, for sediment (62 SPs/50g). Fibers format predominated in all components. Fish preference for blue color seems to occur. Significant statistical relationships were determined for fish length and SPs size and between SPs concentrations in water and fish. The chemical identities (µ-FTIR spectra) polypropylene, polyethylene, polyamide, polyester, and cardboard/cellulose predominated. Influences of local hydrodynamics (e.g., SPs sizes) and reduction in tourism during Covid-19 epidemic (e.g., less SPs in summer) are discussed. This study confirms environmental contamination by SPs (mostly MPs) in Ubatuba beaches, affecting fish through direct water column ingestion. Urgent actions from authorities and changes in local user's habits are crucial. [ABSTRACT FROM AUTHOR]

In the context of a biorefinery, lignocellulosic materials represent an important source of raw material for the bioconversion of cellulose, hemicellulose, and lignin into value-added products, such as xylose for fermentation, oligosaccharides, and bioplastics for packaging. Among the most abundant lignocellulosic materials in Brazil, sugarcane bagasse biomass stands out, as it is rich in cellulose and hemicellulose. In this context, through an experimental design, this study developed a robust enzyme cocktail containing xylanases and accessory enzymes to complete the hydrolysis of xylan from sugarcane bagasse, obtaining a low xylose yield and concentration (9% and 1.8 g/L, respectively, observed in experiment number 16 from the complete hydrolysis of a xylan assay), a fermentable sugar that is important in the production of second-generation ethanol, and a high xylooligosaccharides (XOS) yield and concentration (93.1% and 19.6 g/L, respectively, obtained from a xylooligosaccharides production assay); in general, xylan has prebiotic activities that favor an improvement in intestinal functions, with immunological and antimicrobial actions and other benefits to human health. In addition to completely hydrolyzing the sugarcane bagasse xylan, this enzymatic cocktail has great potential to be applied in other sources of lignocellulosic biomass for the conversion of xylan into xylose and XOS due to its enzymes content, involving both main chain and pendant groups hydrolysis of hemicelluloses. [ABSTRACT FROM AUTHOR]

• So-called biodegradable plastics and greenwashing are issues of environmental concern. • Cases of false claims of biodegradability in plastic products are becoming frequent. • Appropriate labeling rules for biodegradable products should be implemented. Plastic pollution is a global environmental concern and several approaches have been implemented seeking to reduce and control releases of plastic waste, especially in marine environments. Recently, disclosure of data on occurrence of single-use plastic straws among the litter collected in beach cleaning campaigns unleashed a worldwide movement that resulted on banning of these items in several countries. The market then quickly began to offer sustainable solutions as the professed biodegradable plastic straws. However, cases of greenwashing added to current limitations related to the technical standards used to attest biodegradability of commercial plastic products may lead these measures to be largely ineffective. Herein, a case study assessing the composition of plastic straws marketed in Brazil and United States under false claims of biodegradability was used as background for discussion of this neglected issue, which goes far beyond plastics straws. Thus, although some local regulations have already banned single-use plastic products, additional actions in regional and global scales should be implemented, especially concerning proper labeling of the alleged biodegradable products. Therefore, from a multi-dimensional perspective and considering the resistance of the powerful plastic industry, multiple management strategies focused on educating people – in the matters of deciding purchases based on correct labeling and properly discarding the waste –, are possibly our best chance to drive a positive global environmental change. Additionally, we also suggest the inclusion of this relevant subject among the tasks proposed by the Basel Convention Partnership on Plastic Waste. [ABSTRACT FROM AUTHOR]

Plastics are abundant artificial substrates in aquatic systems that host a wide variety of organisms (the plastisphere), including potential pathogens and invasive species. Plastisphere communities have many complex, but not well-understood ecological interactions. It is pivotal to investigate how these communities are influenced by the natural fluctuations in aquatic ecosystems, especially in transitional environments such as estuaries. Further study is needed in subtropical regions in the Southern Hemisphere, where plastic pollution is ever increasing. Here we applied DNA-metabarcoding (16S, 18S and ITS-2) as well Scanning Electron Microscopy (SEM) to assess the diversity of the plastisphere in the Patos Lagoon estuary (PLE), South Brazil. Through a one-year in situ colonization experiment, polyethylene (PE) and polypropylene (PP) plates were placed in shallow waters, and sampled after 30 and 90 days within each season. Over 50 taxa including bacteria, fungi and other eukaryotes were found through DNA analysis. Overall, the polymer type did not influence the plastisphere community composition. However, seasonality significantly affected community composition for bacteria, fungi and general eukaryotes. Among the microbiota, we found Acinetobacter sp., Bacillus sp., and Wallemia mellicola that are putative pathogens of aquatic organisms, such as algae, shrimp and fish, including commercial species. In addition, we identified organisms within genera that can potentially degrade hydrocarbons (e.g. Pseudomonas and Cladosporium spp). This study is the first to assess the full diversity and variation of the plastisphere on different polymers within a subtropical Southern Hemisphere estuary, significantly expanding knowledge on plastic pollution and the plastisphere in estuarine regions. [Display omitted] • Season had a stronger influence in shaping the plastisphere compared to polymer and incubation time. • We identified 14 bacterial and 6 fungal phyla, as well as 39 groups of eukaryotes. • We found putative plastic biodegraders and pathogens within the plastisphere in the PLE. [ABSTRACT FROM AUTHOR]

Climate change has intensified the demand for better social and environmental conservation efforts, motivating organisations to become more engaged in the development of sustainable technologies. This study analyses the innovation process in the production of green plastic, a process which replaces a non-renewable resource (naphtha) for a renewable one (ethanol from sugarcane), through the lens of sustainable supply-chain management (SSCM). An in-depth case study was conducted with a Brazilian petrochemical company, including interviews with agents of the supply chain. The results show that collaborations between the focal organisation and other agents of the supply chain are important for product development. The focal organisation has created many industry-wide initiatives, such as certification programmes and seal of quality/approval, to support the production of green plastic and reduce the social and environmental impact along the supply chain. [ABSTRACT FROM AUTHOR]

The growing demand for plastics, for packaging and consumption, is a current environmental issue. Although there are many scientific developments concerning material science, knowledge about the public's perception is low, which can delay society's efforts to face this challenge. This study aimed to understand if Brazilians who practice different sustainable actions perceive differently biodegradable, recycled, and common plastics and have different purchase intentions for each specific type of packaging. A total of 1080 Brazilian adults were first classified by their day-to-day attitudes regarding sustainability efforts. Then, their purchase intention and perception about different plastics were assessed. Regardless of sustainability practices, people associate common plastic bags with negative attributes and biodegradable plastic bags with positive attributes. This shows that there is a well-established concept about these types of bags, even if there are some misconceptions (e.g. recyclable) or controversies (e.g. non-polluting). On the other hand, results showed that consumers who adopted more sustainable practices were 3.5 times more willing to pay for biodegradable packages, even though no differences were observed in the accepted price for biodegradable bags between consumer's groups. Finally, the purchase intention comparisons for products packaged in recycled and biodegradable plastics showed the consumers were more interested in those biodegradable plastics and the purchase intention was lower for perishable food (e.g. products that can have higher safety risks). The results are important for understanding environmental policy management in Brazil, highlighting the importance to improve the population's knowledge about different types of plastic, leading to more conscious choices. • Aimed to understand if Brazilians with different sustainable practices. • Importance to improve population's knowledge about different type of plastics. • Understand the management of environmental policy in Brazil. • Consumers are more interested in purchasing products in biodegradable plastics. [ABSTRACT FROM AUTHOR]

There have been numerous discussions about plastic drinking straws and their impacts on the natural environment, reflecting on public policies and companies' operation, while alternatives to substituting plastic-based products have been proposed. However, making decisions without measuring trade-off conditions between the different scenarios may lead to higher impacts elsewhere on the life cycle or even in other areas of protection. To deepen this discussion, this paper aimed to quantify the potential environmental impacts of different drinking straws as well as find possible break-even situations. A comparative life cycle assessment (LCA) was performed to assess six different drinking straws (plastic, stainless steel, glass, paper, bamboo and jute) from cradle-to-grave. A hybrid life cycle impact assessment (LCIA) method was applied following the characterization models recommended by ILCD. Sensitivity analyses included reuse rate, washing condition, the ancillary kits usage, End-of-Life (EoL) strategies and the inclusion of an indicator to account for the marine litter impacts from Life Cycle Inventory (LCI). Results showed that for baseline scenarios, plastic drinking straws have a better environmental performance if compared to reusable straws and has a favourable performance in 10 of 11 categories if compared to paper drinking straws. Water and detergent consumptions during the use phase and the manufacturing of additional elements (bag, brush) are the main drivers for this potentially higher environmental impact. Sensitivity analyses, however, showed that certain consumption patterns may lead to a break-even situation, especially when plastic drinking straws are disposed incorrectly into the natural ecosystem. Accounting for the impacts of marine litter may lead to a change in the decision-making depending on the significance (weight) attributed to the marine litter indicator. These outcomes reinforce the importance of understanding trade-offs during the entire life cycle of products and demonstrate that policies directed to product substitution should be carefully grounded. Recommendations on reusable straws rely on simplifying their "kits", expanding reuse rates and improving the washing process. For single use straws, waste collection and correct disposal are mandatory. The lack of a LCIA methodology to account for the environmental impact of mismanaged plastic waste on ecosystems, especially in the marine compartment represents an important issue to be further developed, from which, more realistic scenarios could be outlined for any product. • The Life Cycle Assessment (LCA) of five different drinking straws was performed. • Plastic drinking straw has better environmental profile in baseline scenario. • Washing process at use phase is one of the main drivers of reusable straws. • Break-even point is possible through sensitive aspects of baseline scenario. • When mismanage plastic flow is considered decision making is affected. [ABSTRACT FROM AUTHOR]