Search

Ultra-wide band (UWB) radar for short-range human target detection is widely used to find and locate survivors in some rescue missions after a disaster. The results of the application of bistatic UWB radar for detecting multi-stationary human targets have shown that human targets close to the radar antennas are very often visible, while those farther from radar antennas are detected with less reliability. In this paper, on account of the significant difference of frequency content between the echo signal of the human target and that of noise in the shadowing region, an algorithm based on wavelet entropy is proposed to detect multiple targets. Our findings indicate that the entropy value of human targets was much lower than that of noise. Compared with the method of adaptive filtering and the energy spectrum, wavelet entropy can accurately detect the person farther from the radar antennas, and it can be employed as a useful tool in detecting multiple targets by bistatic UWB radar. [ABSTRACT FROM AUTHOR]

The detection of the vibration signal from human vocal folds provides essential information for studying human phonation and diagnosing voice disorders. Doppler radar technology has enabled the noncontact measurement of the human-vocal-fold vibration. However, existing systems must be placed in close proximity to the human throat and detailed information may be lost because of the low operating frequency. In this paper, a long-distance detection method, involving the use of a 94-GHz millimeter-wave radar sensor, is proposed for detecting the vibration signals from human vocal folds. An algorithm that combines empirical mode decomposition (EMD) and the auto-correlation function (ACF) method is proposed for detecting the signal. First, the EMD method is employed to suppress the noise of the radar-detected signal. Further, the ratio of the energy and entropy is used to detect voice activity in the radar-detected signal, following which, a short-time ACF is employed to extract the vibration signal of the human vocal folds from the processed signal. For validating the method and assessing the performance of the radar system, a vibration measurement sensor and microphone system are additionally employed for comparison. The experimental results obtained from the spectrograms, the vibration frequency of the vocal folds, and coherence analysis demonstrate that the proposed method can effectively detect the vibration of human vocal folds from a long detection distance. [ABSTRACT FROM AUTHOR]

Remarkable progress has been achieved in the detection of single stationary human. However, restricted by the mutual interference of multiple humans (e.g., strong sidelobes of the torsos and the shadow effect), detection and localization of the multiple stationary humans remains a huge challenge. In this paper, ultra-wideband (UWB) multiple-input and multiple-output (MIMO) radar is exploited to improve the detection performance of multiple stationary humans for its multiple sight angles and high-resolution two-dimensional imaging capacity. A signal model of the vital sign considering both bi-static angles and attitude angle of the human body is firstly developed, and then a novel detection method is proposed to detect and localize multiple stationary humans. In this method, preprocessing is firstly implemented to improve the signal-to-noise ratio (SNR) of the vital signs, and then a vital-sign-enhanced imaging algorithm is presented to suppress the environmental clutters and mutual affection of multiple humans. Finally, an automatic detection algorithm including constant false alarm rate (CFAR), morphological filtering and clustering is implemented to improve the detection performance of weak human targets affected by heavy clutters and shadow effect. The simulation and experimental results show that the proposed method can get a high-quality image of multiple humans and we can use it to discriminate and localize multiple adjacent human targets behind brick walls. [ABSTRACT FROM AUTHOR]

Ultra-wideband (UWB) radar has been widely used for detecting human physiological signals (respiration, movement, etc.) in the fields of rescue, security, and medicine owing to its high penetrability and range resolution. In these applications, especially in rescue after disaster (earthquake, collapse, mine accident, etc.), the presence, number, and location of the trapped victims to be detected and rescued are the key issues of concern. Ample research has been done on the first issue, whereas the identification and localization of multi-targets remains a challenge. False positive and negative identification results are two common problems associated with the detection of multiple stationary human targets. This is mainly because the energy of the signal reflected from the target close to the receiving antenna is considerably stronger than those of the targets at further range, often leading to missing or false recognition if the identification method is based on the energy of the respiratory signal. Therefore, a novel method based on cross-correlation is proposed in this paper that is based on the relativity and periodicity of the signals, rather than on the energy. The validity of this method is confirmed through experiments using different scenarios; the results indicate a discernible improvement in the detection precision and identification of the multiple stationary targets. [ABSTRACT FROM AUTHOR]

A millimeter wave (MMW) radar sensor is employed in our laboratory to detect human speech because it provides a new non-contact speech acquisition method that is suitable for various applications. However, the speech detected by the radar sensor is often degraded by combined noise. This paper proposes a new perceptual wavelet packet method that is able to enhance the speech acquired using a 94 GHz MMW radar system by suppressing the noise. The process is as follows. First, the radar speech signal is decomposed using a perceptual wavelet packet. Then, an adaptive wavelet threshold and new modified thresholding function are employed to remove the noise from the detected speech. The results obtained from the speech spectrograms, listening tests and objective evaluation show that the new method significantly improves the performance of the detected speech. [ABSTRACT FROM AUTHOR]

The through-wall detection and classification of human activities are critical for anti-terrorism, security, and disaster rescue operations. An effective through-wall detection and classification technology is proposed for finer-grained human activities such as piaffe, picking up an object, waving, jumping, standing with random micro-shakes, and breathing while sitting. A stepped-frequency continuous wave (SFCW) bio-radar sensor is first used to conduct through-wall detection of finer-grained human activities; Then, a comprehensive range accumulation time-frequency transform (CRATFR) based on inverse weight coefficients is proposed, which aims to strengthen the micro-Doppler features of finer activity signals. Finally, in combination with the effective eigenvalues extracted from the CRATFR spectrum, an optimal self-adaption support vector machine (OS-SVM) based on prior human position information is introduced to classify different finer-grained activities. At a fixed position (3 m) behind a wall, the classification accuracies of six activities performed by eight individuals were 98.78% and 93.23%, respectively, for the two scenarios defined in this paper. In the position-changing experiment, an average classification accuracy of 86.67% was obtained for five finer-grained activities (excluding breathing) of eight individuals within 6 m behind the wall for the most practical scenario, a significant improvement over the 79% accuracy of the current method. [ABSTRACT FROM AUTHOR]

In order to improve the speech acquisition ability of a non-contact method, a 94 GHz millimeter wave (MMW) radar sensor was employed to detect speech signals. This novel non-contact speech acquisition method was shown to have high directional sensitivity, and to be immune to strong acoustical disturbance. However, MMW radar speech is often degraded by combined sources of noise, which mainly include harmonic, electrical circuit and channel noise. In this paper, an algorithm combining empirical mode decomposition (EMD) and mutual information entropy (MIE) was proposed for enhancing the perceptibility and intelligibility of radar speech. Firstly, the radar speech signal was adaptively decomposed into oscillatory components called intrinsic mode functions (IMFs) by EMD. Secondly, MIE was used to determine the number of reconstructive components, and then an adaptive threshold was employed to remove the noise from the radar speech. The experimental results show that human speech can be effectively acquired by a 94 GHz MMW radar sensor when the detection distance is 20 m. Moreover, the noise of the radar speech is greatly suppressed and the speech sounds become more pleasant to human listeners after being enhanced by the proposed algorithm, suggesting that this novel speech acquisition and enhancement method will provide a promising alternative for various applications associated with speech detection. [ABSTRACT FROM AUTHOR]

After chemical or nuclear leakage or explosions, finding survivors is a huge challenge. Although human bodies can be found by smart vehicles and drones equipped with cameras, it is difficult to verify if the person is alive or dead this way. This paper describes a continuous wave radar sensor for remotely sensing the vital signs of human subjects. Firstly, a compact and portable 24 GHz Doppler radar system is designed to conduct non-contact detection of respiration signal. Secondly, in order to improve the quality of the respiration signals, the self-correlation and adaptive line enhancer (ALE) methods are proposed to minimize the interferences of any moving objects around the human subject. Finally, the detection capabilities of the radar system and the signal processing method are verified through experiments which show that human respiration signals can be extracted when the subject is 7 m away outdoors. The method provided in this paper will be a promising way to search for human subjects outdoors. [ABSTRACT FROM AUTHOR]

Bamboo scrimber is a new type of biomass fiber-based composite material with broad application. In this study, self-developed bio-oil phenolic resin (BPF) was used to prepare bamboo scrimber. The effects of hot-pressing temperature, hot-pressing time, and BPF resin solid content on the modulus of rupture (MOR) and modulus of elasticity (MOE) were systematically investigated through single-factor experiments and response surface methodology (RSM). According to the Box-Behnken design (BBD) experiment of the RSM, the effects of all three factors on MOR and MOE are significant. The effects of the main factors affecting the MOR and MOE decreased in the order of resin solid content, hot-pressing temperature, and hot-pressing time. Based on BBD, the optimal conditions for the preparation of bamboo scrimber were determined as follows: a hot-pressing temperature of 150 °C, a hot-pressing time of 27.5 min, and a resin solid content of 29%. Under these conditions, the MOR is 150.05 MPa and the MOE is 12,802 MPa, which are close to the theoretical values, indicating that the optimization results are credible. This study helps to promote the full utilization of bamboo components and provides a reference for the development of high-quality bamboo scrimber. [ABSTRACT FROM AUTHOR]

Bamboo is a fast-growing plant with properties such as low cost, abundant resources, and good carbon sequestration effect. However, the swift growth of bamboo resources generates an immense quantity of processing waste, which is necessary to effectively utilize bamboo processing waste. The leftovers from bamboo processing can be reutilized by fast pyrolysis to prepare renewable bio-oil. In this study, bamboo bio-oil was partially substituted for phenol to synthesize phenolic resin with different substitution rates under the action of an alkaline catalyst, and then to serve as the adhesive to produce bamboo scrimber. Bamboo bundles were impregnated with synthetic bio-oil phenolic resin to create bamboo scrimber, which was subsequently hot-pressed. The research shows that modified phenolic resins with a bio-oil substitution rate of under 30% have good physical and chemical properties, while the free aldehyde content of phenolic resin with 40% bio-oil substitution exceeds the limit value (0.3%) specified in the Chinese National Standard. The thermal stability of phenolic resins was also increased after bio-oil modification, indicated by the movement of the TG curve to higher temperature ranges. It was found that the bamboo scrimber prepared with 20% BPF resin adhesive had the best comprehensive properties of a good mechanical strength, hydrophobicity, and mildew resistance, particularly with an elastic modulus of 9269 MPa and a static bending strength of 143 MPa. The microscopic morphology showed that the BPF resin was well impregnated into the interior of the bamboo bundle and had a compact bonding structure within the bamboo scrimber. The anti-mold performance experiment found that the bio-oil-modified resin increased the anti-mold level of the bamboo scrimber from slightly corrosion-resistant to strong corrosion-resistant. The conclusions obtained from this study have a good reference value for achieving the comprehensive utilization of bamboo, helping to promote the use of all components, reduce the production cost of bamboo scrimber, and improve its mildew resistance performance. This provides new ideas for the development of low-cost mildew resistant bamboo scrimber novel materials. [ABSTRACT FROM AUTHOR]

The cyclic loading performance of bamboo double-jointed components of different column base connection types was investigated through reversed cyclic loading tests and finite element analysis. Test results indicated that the types of column base connections played an important role in the failure modes of the engineered bamboo double-jointed columns: for an encased steel plate column base connection, the main failure mode was tensile fracture failure of the bamboo scrimber section at the bottom of the cladding plate; for a slotted-in steel plate column base connection, the main failure mode was splitting failure of the bamboo scrimber cross-grain at the bolt connection line at the bottom of the sheathing plate. The initial stiffness of the encased steel plate column base connection specimen was 41.8% higher than that of the slotted-in steel plate column base connection specimen, with the two specimens having similar average bearing capacities. The ductility ratio of the two specimens was below 3.0 due to the brittle failure nature of the engineered bamboo connections. The finite element model accurately predicted the ultimate bearing capacity of the double-jointed bamboo column members. The modeling error was within 12%, which was sufficient to satisfy the accuracy requirements for engineering purposes. [ABSTRACT FROM AUTHOR]

Bamboo engineering materials are green, high-strength, tough, durable, and structurally safe, and have promising application prospects in various modern green and low-carbon buildings. To investigate the vibration behavior of bamboo-bundle laminated veneer lumber (BLVL) for use in floor slabs, this study designed two kinds of full-scale vibration tests under a pedestrian load: an extraction hammer impact test and a static concentrated load test. The results are expected to provide a theoretical foundation and data to support the application of bamboo bundle veneer laminated composite materials in the construction field. The results showed that the self-oscillation frequency and mid-span deflection of the BLVL composite met the requirements of multiple relevant regulations when used as the structural material of floor slabs. The BLVL floor slab had greater flexural stiffness and better vibration-damping performance than the OSB floor slab. The first-order self-oscillation frequency of the BLVL composite floor slab was 13.769 Hz, the damping ratio of the first three orders of modalities was 1.262–2.728%, and the maximum static deflection in the span of the joist was 0.932 mm under a 1 kN concentrated load. The 1 kN static deflection of the BLVL was reduced by 22.33%, and the root mean square (RMS) acceleration of the walking load response was significantly lower than that of the OSB floor slab. The preparation of BLVL composite materials through homogeneous lamination of bamboo bundle veneer and wood veneer may help to improve the vibration behavior of bamboo–wood structures such as floor slabs and walls. [ABSTRACT FROM AUTHOR]

This study aimed to investigate the mechanical property decay that might occur during actual use and soil burial degradation of bamboo fiber lunch boxes. For this, the effects of three accelerated aging methods, namely damp–heat treatment, freeze–thaw cycle, and artificial weathering cycle, on the tensile strength, dynamic viscoelasticity, and chemical composition of bamboo fiber lunch boxes were compared, and a correlation of their mechanical property decay with soil burial degradation was established to obtain an acceleration factor (SAF) with aging time as a reference. The results showed that the mechanical properties of the bamboo fiber lunch box decreased to different degrees under the three accelerated methods, and the tensile strength decreased to less than 50% after 36 h of damp–heat treatment, 5 freeze–thaw cycles, and 11 artificial weathering cycles. However, after 10 days, the mechanical property of lunch box in soil degradation decreased by more than 50%. Infrared spectroscopy demonstrated rapid hemicellulose degradation during damp–heat treatment and freeze–thaw cycle, as well as a minor quantity of lignin, and a significant amount of lignin under artificial weathering cycle. With the freeze–thaw cycle and the artificial weathering cycle, the relative crystallinity dropped quickly, by 32.3% and 21.5%, respectively, but under damp–heat treatment, the crystallinity dropped barely, by 43.5%. The damage caused by the freeze–thaw cycle to the mechanical properties of bamboo fiber lunch boxes was greater than that by the damp–heat treatment and artificial weathering cycle. The fluctuation of SAF under freeze–thaw cycle was also more drastic. Compared to the artificial weathering cycle, the damp–heat treatment was more stable and reliable in predicting the decay law of soil burial degradation tensile strength of bamboo fiber lunch boxes. [ABSTRACT FROM AUTHOR]

The research on the development of lunch boxes made of clean, environment-friendly, and naturally degradable plant fibers has attracted enormous attention. A bamboo fiber lunch box prepared by the clean and efficient steam explosion method has the advantages of good stiffness, water and oil resistance, and easy degradation. The purpose of this study was to investigate the degradation behavior of the environment-friendly bamboo fiber lunch box under indoor soil burial, as represented by the changes in physical properties, mechanical strength, chemical components, morphological structure, and so on. The results showed that: with the extension of the burial time, the weight loss increased rapidly from slowly to quickly; the boxes were completely degraded in the soil on the 70th day; the microorganisms in the soil first decomposed the tapioca starch, hemicellulose, and cellulose in the lunch box, and finally decomposed the lignin; the residual debris in the soil was further decomposed into CO2, H2O, and inorganic salts. In short, the degradation process of the lunch box mainly included the following stages: stage I: the increase in apparent roughness, the generation of microcracks, the rapid increase in weight loss, and the breakdown of starch and hemicellulose; stage II: the slow increase in the weight loss rate of the box fragmentation, the rapid decay of the mechanical strength, and the cellulose decomposition; stage III: the decomposition of lignin, the complete degradation of the debris, and the integration with the soil. [ABSTRACT FROM AUTHOR]

Bamboo musical instruments, such as bamboo flute and Ching-hu (Beijing opera fiddle), can generate a crisp and melodious sound closely related to the delicate multiscale pore structure of bamboo. Bamboo is a natural hydrophilic material, and its acoustic vibration characteristics are highly sensitive to changeable environmental humidity levels. Herein, we investigated the acoustic vibration characteristics of bamboo under three conditions: constant relative humidity (status I), changeable relative humidity (status II), and subjected to water extraction (status III). Three typical parameters were selected as evaluation indicators of bamboo acoustic vibration characteristics, namely, specific dynamic elastic modulus ( E ′ / ρ), loss tangent (tan δ), and acoustical converting efficiency (ACE). The outer bamboos (OB) had higher E ′ / ρ and ACE but lower equilibrium moisture content (EMC) and tan δ than the inner bamboos (IB). Under status I, bamboo showed the maximum E ′ / ρ and ACE and the minimum tan δ at 35% RH (relative humidity) and about 6% MC. Compared with the bamboo under status II, the bamboo under status I retained higher E ′ / ρ and ACE and lower tan δ. However, the bamboo under status (III) reached the maximum E ′ / ρ and ACE and the minimum tan δ. The bamboo musical instrument is made of bamboo with proper removal of water-soluble extractives and high fiber volume fraction and stored in a stable relative humidity environment of 35%, which has suitable acoustic vibration characteristics. [ABSTRACT FROM AUTHOR]

The bamboo–wood composite container floor (BWCCF) has been wildly utilized in transportation in recent years. However, most of the common approaches of mechanics detection are conducted in a time-consuming and resource wasting way. Therefore, this paper aims to provide a frugal and highly efficient method to predict the short-span shear stress, the modulus of rupture (MOR) and the modulus of elasticity (MOE) of the BWCCF. Artificial neural network (ANN) models were developed and support vector machine (SVM) models were constructed for comparative study by taking the characteristic parameters of image processing as input and the mechanical properties as output. The results show that the SVM models can output better values than the ANN models. In a prediction of the three mechanical properties by SVMs, the correlation coefficients (R) were determined as 0.899, 0.926, and 0.949, and the mean absolute percentage errors (MAPE) were obtained, 6.983%, 5.873%, and 4.474%, respectively. The performance measures show the strong generalization of the SVM models. The discoveries in this work provide new perspectives on the study of mechanical properties of the BWCCF combining machine learning and image processing. [ABSTRACT FROM AUTHOR]

Arrays of titania nanotubes (TiO2NTs) were developed by electrochemical anodization and doped with silver on their surface by photodeposition to achieve TiO2NTs/Ag. It is found that only anatase TiO2NTs were formed, with the preferential growth direction perpendicular to the titanium substrate, and with the length and diameter of ~2 µm and 90–120 nm, respectively. The presence of Ag on the surface of TiO2NTs was also confirmed. The TiO2NTs and TiO2NTs/Ag were used as photocatalysts to decolorize the methylene blue (MB) aqueous solution. The photodegradation efficiency (PDE) is as high as 83% for TiO2NTs and 98% for TiO2NTs/Ag photocatalysts. This work focused on the investigation of the stability and recyclability of these photocatalysts in terms of efficiency and its physical origin by surface analysis using X-ray photoelectron spectroscopy (XPS). It is found that PDE diminishes from 83% to 76% in TiO2NTs upon eight recycling runs and from 98% to 80% in TiO2NTs/Ag upon six recycling runs. The XPS analysis revealed that the physical origin of diminishing efficiency is the carbon contamination on the surface of recycled TiO2NTs and a combination of carbon contamination and Ag leaching in recycled TiO2NTs/Ag. [ABSTRACT FROM AUTHOR]

The lack of an effective and practical quality control method for industrialized bamboo bundle veneers is the key restriction in the application of bamboo bundle composite materials in the field of construction. In this work, the density uniformity and mechanical properties of bamboo bundle veneers were systematically evaluated by the combination of light transmittance and mechanical stiffness. It was found that the number of broomings, dippings, and high-temperature heat treatments had different effects on the bamboo bundle veneers. On this basis, the uniformity of the density and mechanical properties of the bamboo scrimber (BS) that underwent hybrid paving, and the bamboo bundle laminated veneer lumber (BLVL), were analyzed. The results showed that the performance stability of bamboo bundle composites could be greatly improved by bamboo bundle veneer laminated paving. A large-scale quality evaluation system for bamboo bundle veneers was established in this work, and it provides conditions for the manufacture of bamboo bundle composites with stable and controllable performance. [ABSTRACT FROM AUTHOR]

Two-dimensional (2D) metal dichalcogenides have attracted considerable attention for use in photoelectric devices due to their unique layer structure and strong light-matter interaction. In this paper, vertically grown SnS2 nanosheets array film was synthesized by a facile chemical bath deposition (CBD). The effects of deposition time and annealing temperature on the quality of SnS2 films was investigated in detail. By optimizing the preparation conditions, the SnS2 array film exhibited efficient photoelectric detection performance under sunlight. Furthermore, in order to improve the performance of the photodetector based on SnS2 nanosheets film, a transparent graphene film was introduced as the hole-transport layer by wet-chemical method directly transferring techniques. Graphene/SnS2 nanosheets array film heterojunction photodetectors exhibit enhanced photoresponsivity. The light on/off ratio of the photodetector based on graphene/SnS2 was 1.53, about 1.4 times higher than that of the pristine SnS2 array films. The improved photoresponse performance suggested that the effective heterojunction between vertical SnS2 nanosheets array film and graphene suppresses the recombination of photogenerated carriers. The results indicate that the graphene/SnS2 heterojunction photodetectors have great potential in photodetection devices. [ABSTRACT FROM AUTHOR]

As one of the most renewable and sustainable resources on Earth, bamboo with its high flexibility has been used in the fabrication of a wide variety of composite structures due to its properties. A bamboo-based winding composite (BWC) is an innovative bamboo product which has revolutionized pipe structures and their applications throughout China as well as improving their impact on the environment. However, as a natural functionally graded composite, the flexibility mechanism of bamboo has not yet been fully understood. Here, the bending stiffness method based on the cantilever beam principle was used to investigate the gradient and directional bending flexibility of bamboo (Phyllostachys edulis) slivers under different loading Types during elastic stages. Results showed that the graded distribution and gradient variation of cell size of the fibers embedded in the parenchyma cells along the thickness of the bamboo culm was mainly responsible for the exhibited gradient bending flexibility of bamboo slivers, whereas the shape and size difference of the vascular bundles from inner to outer layers played a critical role in directional bending flexibility. A validated rule of mixture was used to fit the bending stiffness under different loading Types as a function of fiber volume fraction. This work provides insights to the bionic preparation and optimization of high-performance BWC pipes. [ABSTRACT FROM AUTHOR]

The objective of this study was to investigate the hygroscopic characteristics of three typical bamboo engineering composites (Bamboo scrimber (BS), bamboo bundle/wood laminated veneer lumber (BLVL), and bamboo laminated timber (BLT)) as well as predict their performance changes and service life in hot humid environments. The composites were subjected to three treatment conditions (23 °C, 63 °C, and 100 °C) for this experiment. The hygroscopic thickness swelling model and Fick's second law were used to quantify the characterization and prediction of the water absorption, thickness swelling rate, and water absorption rate of BS, BLVL, and BLT. The results indicated that the order of the hygroscopic thickness swelling coefficient KSR and the diffusion coefficient D was BLT > BLVL > BS (at 23 °C and 63 °C). The optimal dimensional stability was displayed by BS, followed by BLVL and BLT. In addition to the hygroscopic properties, elastic modulus degradation was investigated. It was observed that the elastic modulus (MOR) degradation had a linear relationship with the aging temperature. After 152 h of the hydrothermal aging test (63 °C), the MOE of BS, BLVL, and BLT degraded by 44.33%, 53.89%, and 25.83%, respectively. [ABSTRACT FROM AUTHOR]

We prepared high-performance photoresistors based on CH3NH3PbI3 films with a high PbI2 doping level. The role of PbI2 in CH3NH3PbI3 perovskite thin film was systematically investigated using scanning electron microscopy, X-ray diffraction, time-resolved photoluminescence spectroscopy, and photoconductive atomic force microscope. Laterally-structured photodetectors have been fabricated based on CH3NH3PbI3 perovskite thin films deposited using precursor solution with various CH3NH3I:PbI2 ratios. Remarkably, the introduction of a suitable amount of PbI2 can significantly improve the performance and stability of perovskite-based photoresistors, optoelectronic devices with ultrahigh photo-sensitivity, high current on/off ratio, fast photo response speed, and retarded decay. Specifically, a highest responsivity of 7.8 A/W and a specific detectivity of 2.1 × 1013 Jones with a rise time of 0.86 ms and a decay time of 1.5 ms have been achieved. In addition, the local dependence of photocurrent generation in perovskite thin films was revealed by photoconductive atomic force microscopy, which provides direct evidence that the presence of PbI2 can effectively passivate the grain boundaries of CH3NH3PbI3 and assist the photocurrent transport more effectively. [ABSTRACT FROM AUTHOR]

Three new crystal structures containing [PtCl6]2−, pyridinium and benzimidazole groups have been prepared: [PtCl6]·(H-bzm)2·2(H2O) (1), [PtCl6]·(H-bipy)2·2(H2O) (2), [PtCl6]·(H-dimethyl-bipy)2·2(H2O) (3) [H-bzm: benzimidazole cation, H-bipy: 2,2′-bipyridine cation, H-dimethyl-bipy: 4,4′-bimethyl-2,2′-bipyridine cation]. All compounds have been fully characterized by elemental analyses, single-crystal X-ray analyses, IR spectra, TG analyses, and fluorescence studies. Single-crystal X-ray diffraction analysis suggests that the primary synthon contains +N–H···Cl−, including ionic bonding and hydrogen bonding interactions. The dimensions are enhanced further by secondary O–H ∙∙Cl and N–H ∙∙O hydrogen bonding interactions between donor and acceptor atoms located at the periphery of these synthons. Moreover, coulombic attractions between the ions play an important role in reinforcing the structures of these complexes. In addition, antitumor activity against human lung adenocarcinoma cell line (A549) and human nasopharyngeal carcinoma cell line (CNE-2) was performed. These complexes all showed inhibition to the two cell lines, while complex 3 exhibited higher efficiency than complexes 1–2. [ABSTRACT FROM AUTHOR]