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There has been a growing recognition in recent years that Electrofuels (e-fuels), also known as renewable and sustainable fuels, which are produced from hydrogen and carbon dioxide as the primary feedstocks, have great potential to reduce carbon footprint and address climate change. In the present study, contrary to most previous studies in which the sources of feedstock's preparation were considered as block boxes, two stand-alone processes are taken into account and incorporated into the e-fuels production system. H 2 is obtained by a high-temperature electrolysis system having an overall efficiency nearly twice that of a low-temperature electrolysis system. CO 2 is captured from a power plant flue gas stream with a purity of 99.81%. Investigating heat integration potential in such an integrated plant is an up-to-date and interesting topic and has not yet been well explored. Therefore, a heat integration within the three individual processes is implemented to reduce energy consumption. The design of the process-to-process heat transfer section is carried out using pinch design rules. By integrating individual units, approximately 42% of the required cold utility, traditionally supplied by chilled water and refrigerants, is allocated to generate high and medium-pressure steams. Having used the high-temperature steam electrolysis for H 2 production, a process that requires less external electricity compared to low-temperature water electrolysis, a power-to-liquid efficiency of 70% is achieved. Furthermore, the results reveal a carbon conversion ratio of 98.6%, indicating the effective converting the carbon from the feedstock into liquid hydrocarbons. [Display omitted] • Heat integration between e-fuels unit and its feedstocks supplier units is done. • Shell-and-tube and plate-fin exchangers are used to design heat exchanger network. • Required cold utilities in the processes decreases by 42% by steam generation. • Power-to-liquid efficiency is improved by 70% through the integration. • Effective converting carbon from the feedstock into liquid hydrocarbons by 98.62%. [ABSTRACT FROM AUTHOR]

• Localized socioeconomic and natural narratives are applied on the regional scale. • Propose ecological zoning management in mountainous agglomerations. • POP, GDP, DEM, and Slope have an inverted U-shaped relationship with carbon storage. • Urbanization expands into the western mountainous under the localized SSP5–8.5 narrative. Ecological carbon storage is critical to climate change mitigation by absorbing CO 2 from the atmosphere. Mountainous ecosystems, crucial carbon reservoirs, are experiencing persistent carbon storage declines, yet management mechanisms targeting such complex terrains remain challenging. Focusing on the Sichuan-Chongqing urban agglomeration, interwoven as mountains and basins, we employed the MPI-coupled (Improved Markov-PLUS-InVEST) model and localized "socio-economic-climatic" narratives to simulate the dynamic evolution of carbon storage over extended periods. Diverse impacts and gradient effects of social, economic, and natural (incl. terrain, climate) drivers on carbon storage are further examined. The findings revealed that: (1) The most carbon storage growth projected from 2030 to 2060 reaches 1.53 %, but of which localized SSP5–8.5 narrative the urbanization encroached upon the undeveloped mountainous, severely impairing carbon sequestration by 81.5Tg. (2) In addition to landscape types, carbon storage exhibits complex spatial responses to economic development, population size, and terrain with an inverted U-shaped relationship. The proposed methodology offers more accurate carbon storage estimates and assists policy-makers in similar terrains to effectively manage the spatial heterogeneity of carbon storage. This study facilitates the implementation of tailored ecological conservation through urban zoning, thus contributing to enhanced subregional climate change mitigation efforts globally. [ABSTRACT FROM AUTHOR]

Effective municipal solid waste (MSW) management is a crucial component for sustainable cities, as inefficient waste disposal contributes to the release of about a billion tons of CO 2 -eq in greenhouse gases (GHG) annually. With escalating global waste generation, there is an untapped opportunity to integrate carbon dioxide removal (CDR) technologies into existing MSW management processes. This review explores current research on utilizing MSW for CDR, emphasizing its potential for both energy generation and carbon sequestration. The investigation covers three waste management practices: landfilling, waste-to-energy (WtE), and biochar production, revealing two paths for carbon sequestration. First, MSW serves as a feedstock in bioenergy with carbon capture and storage (BECCS), acting as a carbon-neutral resource that avoids fossil fuel and energy crop use, reducing GHG emissions and generating value through energy production. Second, direct storage of organic MSW and its derivatives, like biochar, in various carbon sinks allows for extended sequestration, offering a comprehensive approach to address the challenges of waste management and climate change mitigation. Moreover, this review advocates for an extended exploration into several subjects including in-depth analysis of waste, research on MSW-derived biochar recalcitrance across different carbon sinks, and understanding the symbiotic connections with GHG-emitting sectors like agriculture and energy. Finally, this review emphasizes the necessity of conducting life-cycle assessment studies to fully discern the benefits and assess the impacts of any future endeavors exploring the role of MSW in carbon sequestration. [Display omitted] • Municipal solid waste (MSW) is an untapped resource for carbon dioxide removal. • Three strategies to utilize MSW for CO 2 removal include landfilling, waste-to-energy, and biochar production. • Carbon sequestration is achieved through MSW-burial and energy recovery with CCS. • Auditing carbon emissions and LCA are necessary to illuminate the impacts of MSW. [ABSTRACT FROM AUTHOR]

CO 2 concentration in the atmosphere has crossed an unprecedented level of 420 ppm, causing catastrophic events like climate change. Climate change mitigation via carbon capture is crucial for reducing CO 2 emissions. Among various CO 2 capture technologies, adsorption is considered one of the most efficient and promising techniques. In recent times, substantial research has been conducted on producing cost-effective and efficient adsorbents for CO 2 capture via the thermal and chemical treatments of biomass. In this review, we discuss key scientific results to give broad insight into the recent progress in biomass conversion to activated porous carbon (APC). The effects of various chemical and thermal treatments on the textural properties and CO 2 adsorption capacity of APC are comprehensively discussed. CO 2 adsorption mechanism based on interaction with the surface functionality is thoroughly explained. The economic aspects of APC synthesis and post-combustion CO 2 capture using APC are systematically reviewed. [Display omitted] • Use of biomass based activate porous carbon (APC) for CO 2 capture is reviewed. • CO 2 adsorption mechanism on APC surface is thoroughly explained. • APC surface functionalization via metal doping and heteroatom doping is discussed. • Economics of APC synthesis & large-scale CO 2 capture on APC is critically reviewed. [ABSTRACT FROM AUTHOR]

This research aims to explore the current evidence on the sustainability of Bioenergy with Carbon Capture and Storage under a life cycle approach and to understand how research on this topic has evolved in the last decade. A systematic literature review was performed, and the main focus was identifying methodological shortcomings and analysing Global Warming Potential results. Forty-seven studies were selected for in-depth revision. Results show that the number of Life Cycle Assessment (LCA) studies on BECCS has increased in the last couple of years and that most of these studies report near-carbon neutral or carbon-negative results for electricity, biofuel energy, and other products. However, in many cases, some aspects have been omitted from the discussion, such as proper accounting of land use impacts, impact allocation procedure, accounting of leakage from storage sites, and impacts related to carbon utilisation. Despite this methodological variability, Global Warming Potential results are mostly carbon-negative and carbon-neutral for both power BECCS and industrial BECCS systems. Consequently, current scientific evidence suggests climate change mitigation benefits from BECCS despite methodological variability. However, it is still insufficient to reach a consensus on the sustainability of this technology as a solution for a global energy transition. It is recommended that further LCA research deals carefully with methodological and product systems variability, which may affect environmental impact results. Moreover, carbon capture approaches with high potential benefits should be further analysed, and the most optimal BECCS typologies should be identified. Finally, additional life cycle impact categories should be reported, along with the assessment of the economic and social dimensions of BECCS. [Display omitted] • Life Cycle Assessment (LCA) of Bioenergy with Carbon Capture and Storage (BECCS) was reviewed. • LCA methodology choices were discussed. • Global Warming Potential ranges between −3.873 and 0.366 kg CO 2 eq per MJ. • Current evidence is insufficient to confirm that BECCS is a sustainable solution for climate change mitigation. [ABSTRACT FROM AUTHOR]

Mangroves are under immense anthropogenic pressures globally which are further exacerbated by their accessibility to humans. To minimize human access hence pressures to the ecosystem, establishment of protected areas is often employed. However, the ecological effectiveness of protected areas, which influences their legal durability, is rarely assessed beyond curbing deforestation. Furthermore, little is known about whether protection could still provide a positive ecological impact if the sites are easily accessible, i.e., adjacent to urban areas, near roads, small in area and/or fragmented. To improve our understanding thereon, this study compares anthropogenic disturbance severity, forest structures and ecosystem carbon (C) stocks of protected and unprotected mangroves near Barranquilla, Colombia's largest coastal city. The outcomes suggest that accessible, yet protected mangrove has a mean disturbance index of 5.3, lower than unprotected mangrove (mean 11). Protected mangrove also has higher mean (± SD) tree basal area (26.5 ± 15.6 m2 ha−1), mean densities of tree, sapling and seedling (899 ± 398, 5155 ± 7860, and 68,837 ± 73,899 individual ha−1, respectively) and biomass C stock (mean 89.5 ± 39 Mg ha−1) than those of accessible unprotected mangrove (mean basal area 19.3 ± 5 m2 ha−1; mean tree, sapling and seedling densities 823 ± 215, 749 ± 94, and 33,727 ± 44,882 individual ha−1, respectively; mean biomass C stock 60.2 ± 14.5 Mg ha−1). Results suggest that the current sediment C stocks, that is higher in unprotected than protected mangroves (396.8 ± 552.6 and 142.4 ± 205.7 Mg ha−1, respectively), are not primarily driven by conservation status, but by long-term processes that likely pre-date the protected status designation. Mangrove protection, however, could help maintain carbon stocks in soils and biomass and the potential for further soil carbon sequestration, and thus are pivotal in determining future trajectories of mangrove climate mitigation potential. This study shows that even imperfect protection offers ecological benefits to highly accessible ecosystems. Hence, focus should be placed on optimizing these benefits and minimizing their vulnerability to downgrading, downsizing and degazettement. • influence of protection on mangroves is assessed beyond curbing deforestation. • protection effectively limit anthropogenic disturbance on mangroves. • protection promotes mangrove biomass C and regeneration potential. • mangrove sediment C stocks is largely influenced by sediment properties. • mangrove protection is ecologically beneficial even for highly accessible systems. [ABSTRACT FROM AUTHOR]

Carbon neutrality strategies have a significant role in climate mitigation efforts. As global concerns regarding climate change continue to increase, achieving carbon neutrality has emerged as a paramount objective for reducing greenhouse gas emissions and limiting the adverse impacts of anthropogenic activities on the environment. This research investigates a wide range of scholarly works to conduct an in-depth analysis and synthesis of the relevant information about carbon neutrality strategies. The review introduces carbon neutrality principles and terminologies, highlighting their importance in climate mitigation. It then proceeds to explore the wide range of strategies employed across different sectors and industries, investigating their effectiveness, scalability, and potential challenges. A multidimensional analysis contrasts the United States Nationally Determined Contributions pathway 2023, China's Nationally Determined contributions 2023, and the EU Directive 2023/2413, assessing their economic, environmental, political, and social impacts. The study evaluates strategies' effectiveness, scalability, and innovation for transitioning to a sustainable, low-carbon future. It fills a gap by analyzing global approaches across the US, China, and the EU, which account for about 50% of the world's total GHG emissions. It evaluates the novel application of diverse strategies, from renewable energy transitions to innovative policy measures, highlighting their potential to mitigate climate change effectively. By providing a multidimensional analysis of these strategies' impacts, the research not only enhances understanding of effective carbon neutrality tactics but also underscores the importance of international cooperation in realizing a sustainable, low-carbon future. • Identifies and analyzes carbon neutrality strategies, emphasizing the need for diverse US, Chinese, and EU approaches. • Evaluate renewable energy, carbon capture, and policy tools for carbon reduction effectiveness, scalability, and innovation. • Highlights the study's novelty in synthesizing current knowledge on carbon neutrality, addressing a significant research gap. • Concludes with strategic ideas for international collaboration and policy development for low-carbon futures. [ABSTRACT FROM AUTHOR]

• CO 2 flows by forest dynamics and forest operations in one simulation tool. • Generic meta -model for plugging in any silvicultural concept of interest. • Freely available as an open source R-package on CRAN. Carbon stocks and flows in forest ecosystems play an important role in the context of climate change mitigation. Different aspects of the forest carbon balance, however, are often treated independently, leading to a fragmented, disciplinary knowledge. With the R-package care4cmodel we want to support a consolidated view of forest growth and forest operations with respect to carbon flows. The software is, in essence, a pragmatic simulation tool that allows juxtaposing the CO 2 uptake due to wood increment and the CO 2 emissions due to forest operations for given silvicultural concepts in an arbitrary area, over time. At the core, the approach is a dynamic forest area model where forest development stages are represented in a cyclical sequence, which can be broken by disturbances. The model scales up growth and yield information given per forest development stage and unit area to the dynamically simulated development stage areas. This allows to quantify the total forest area's CO 2 uptake, and to estimate the CO 2 emissions caused by forest operations. The forest operations in our implementation include the maintenance of the forest road network, felling trees, debranching and bucking the stems, and extracting the timber to a landing at a forest road. The transport from there to the industry is beyond the system boundary. For the CO 2 uptake of the forest system, the current model version focuses on the wood increment only. We use a practical example to demonstrate the basic features of the model and its plausible behaviour. Beyond the current focus of the model, we see a broad field of applications as a generic meta model, especially in the context of ecosystem service provision. [ABSTRACT FROM AUTHOR]

Carbon capture and storage (CCS) in basalt is being actively investigated as a scalable climate change mitigation option. Accurate geochemical modeling prediction of the extent and rate of CO 2 mineralization is a critical component in assessing the local and global feasibility and efficacy of this strategy. In this study, we review basalt-CO 2 -water interaction experimental studies conducted during the last two decades to determine whether they provide useable information for geochemical modeling. Most of the cited experiments generate data on the temporal evolution of water composition, and a few provide identification of secondary precipitates and their compositions, offering information about the reactivity of basalts and the likelihood of secondary carbonate mineralization at various temperatures, pHs, and p CO 2 conditions. However, most experiments provide insufficient information on the properties and quantity of secondary minerals formed, prohibiting accurate mass balance calculations and hence more quantitative geochemical modeling studies. Primary Ca, Mg, and Fe-bearing minerals in basalt control the availability of major ions released into aqueous solution for carbonate precipitation, and many secondary minerals, i.e., smectites, Ca-Mg-Fe carbonates, and zeolites, provide sinks for the same major ions, some of which are difficult to quantify experimentally. Thus, we have a "multi-source and multi-sink" inverse mass balance modeling problem with insufficient constraints on the bulk system in which the temporal evolution of major ions does not provide sufficient information on which mineral(s) dissolve or the sequence of dissolution and precipitation reactions. Going forward, this review highlights the need for providing better-constrained experimental data to calibrate basalt-CO 2 -water geochemical models. Hence, we propose that future experimental work should focus on trace elements and multiple isotopic tracers as well as emphasize the need for better characterization of the solid reaction products with modern analytical instruments. [ABSTRACT FROM AUTHOR]

• Willingness to pay for BECCS in Denmark and factors influencing it are investigated. • Willingness to pay is linked to the view of BECCS as necessary for mitigation. • View of BECCS as a necessity reveals either support or reluctant acceptance. • Preference for renewable energies revealed by respondents unwilling to pay. • Age, views on climate change and sustainability of biomass influence WTP. Most climate change mitigation scenarios rely on negative emissions technologies like bioenergy with carbon capture and storage (BECCS). However, little is known about public support for BECCS. This paper gauges Danes' willingness to pay (WTP) for biomass with carbon capture and storage and examines factors influencing it. Denmark is a suitable case study given its reliance on biomass and negative emissions to achieve climate targets. Results from a questionnaire-based survey indicate a mean WTP of 3072 DKK (412 EUR) per household per year. This correspondents to a 12% increase in heat and electricity expenses. The need for negative emissions is the main stated reason for WTP. This may be interpreted as reflecting either support for, or reluctant acceptance of, BECCS. Results show that being younger, being concerned about climate change and believing that it is mainly caused by human activity, and believing in the mitigation potential of biomass and that sustainability is a precondition of its use have a significant effect on WTP. Public views on BECCS are complex but must be acknowledged if discussion of the role of BECCS in the decarbonisation agenda is to move forward. [ABSTRACT FROM AUTHOR]

• Analyses CCS technological innovation system dynamics in Norway. • Employs the technological innovation system (TIS) framework. • Overall the CCS innovation system has intermediate-weak performance. • Momentum is however positive, albeit future prospects being uncertain. CO 2 Capture and Storage (CCS) is today seen as a key technology to cut carbon emissions in many hard-to-abate sectors such as energy-intensive processing industries and the waste sector. Although CO 2 capture is technically possible, key challenges for realizing CCS persist. Over the past decade, CCS has taken a new direction with more focus on application in energy-intensive industries rather than the energy sector. For CCS value chains to materialize, innovation and implementation thus needs to occur amongst an array of actors, with different innovation modes, institutions, and policy regimes, and with varying sectoral capacities for adaptation and change. There has so far been limited social science research on CCS innovation dynamics, which we suggest approaching as a socio-technical change process. To better understand this process, we draw on the sustainability transitions research field and employ the Technological Innovation System (TIS) framework to study the CCS innovation system in Norway. We find that, overall, the Norwegian CCS TIS displays systemic weaknesses for example in the form of market formation and resource mobilization, yet recent developments suggest a relatively positive momentum for this technological field which is key to meeting Norwegian and global climate mitigation targets. [ABSTRACT FROM AUTHOR]

Cocoa production is a leading driver of deforestation in the humid-tropics of West Africa. Reconciling climate change mitigation with livelihoods of farmers requires identification of production strategies to concurrently improve yield and profit while curtailing emissions of greenhouse gases (GHG). Using a 2021 plot-survey conducted in Ghana's Eastern region, we evaluated yields, GHG emissions, and value of production (VOP) (a profit indicator) across a typology representing the diversity of systems at plot-level. The typology was constructed by first stratifying plots according to shade levels and variety (hybrid vs. Amazonia) which resulted in three systems: Hybrid sun , hybrid variety under full-sun (little to no shade); Hybrid shade , hybrid and moderate shade (13–25 shade trees ha−1); and Amazonia, Amazonia under predominantly moderate shade. Next, factor analysis and clustering were used to group plots within each system according to cocoa yield, vegetation, management, and (local) climate conditions. Cluster analysis showed that fertiliser, weeding, pruning, hand pollination, cocoa tree density, and shade tree densities of differing heights were most influential for determination across systems. Hybrid shade had the highest net GHG removal rate at −6.8 ± 1.7 (± 95% CI) Mg CO 2 eq ha−1 yr−1: 48% and 127% higher (emissions more negative) respectively over Amazonia and Hybrid sun. Hybrid shade additionally had the highest average and least variable VOP among production systems at 669 ± 564 USD ha−1 yr−1, compared to Hybrid sun and Amazonia at 404 ± 442 and 213 ± 280 USD ha−1 yr−1 respectively. These results point to hybrid cocoa grown under moderate shade of 13–25 shade trees ha−1 as optimal for reconciling climate change mitigation with development in West African cocoa. • Study concurrently evaluates financial profits and GHG balances (N 2 O & CH 4 emissions, CO 2 removals) in West African cocoa. • Plot-level indicators are evaluated across a typology obtained from sample-stratification and clustering. • Hybrid cocoa under moderate shade (13-25 shade trees ha-1) had GHG removal increment of 127% over same variety without shade. • This system too had higher mean profits, thus best reconciling GHG mitigation and economic development for the region. [ABSTRACT FROM AUTHOR]

The synthesis and characterization of amine-impregnated polymer aerogels for CO 2 capture represents a groundbreaking advancement in combating the urgent challenges of carbon dioxide (CO 2) emissions and climate change mitigation. The traditional way of synthesizing aerogels for CO 2 capture is to use a one-step gelation process without functionalizing the aerogel, which, to some extent, has low CO 2 capture capacity and kinetics. This study finds a method of synthesizing the functionalized aerogel, which has high CO 2 adsorption capacity, faster kinetic, and is more stable. The polymer aerogel was developed using an oil-water emulsion polymerization method, followed by freeze-drying. It was impregnated with a mono-ethanolamine (MEA) solution to enhance CO 2 adsorption. The performance of the amine-impregnated poly (AAm-co-AAc) aerogels was tested in a continuous adsorption column filled with aerogel. The adsorption results showed the amine-impregnated aerogels having an amine equilibrium uptake value of 40% had significantly improved CO 2 capture capacity up to 2.34 mmole g−1 at 1 bar pressure, 25 °C reaction temperature, and 10 ml/min flow rate. The polymeric aerogel has a very fast adsorption rate, as it can capture 90% of its maximum capacity within just 10 minutes. Then the kinetic data of the CO 2 adsorption was modelled and found to best fit on both pseudo-1st and 2nd-order kinetic models, proposing that the adsorption mechanism on aerogel was controlled by surface diffusion and chemisorption. Furthermore, the isotherm data were evaluated and observed to be best represented by the Langmuir isotherm model, suggesting monolayer formation on the aerogel. After five adsorption-desorption cycles, the amine impregnated poly (AAm-co-AAc) aerogel was able to preserve the initial capacity without a significant decrease. These findings underscore the immense ability of amine-impregnated poly (AAm-co-AAc) aerogels as highly efficient adsorbents for CO 2 capture, thus offering a speedy adsorption process and showing stable regeneration capacity, thereby exhibiting greater industrial application potential. [Display omitted] • An emulsion polymerization method was used to synthesize aerogels for CO 2 capture capacity. • The morphology of the aerogel is fibrous, contributing to its high amine uptake. • Its CO 2 adsorption capacity is up to 2.34 mmole g−1 at 25°C, and regeneration stability is five cycles. • The aerogel exhibits a rapid adsorption rate, capturing 90% of its capacity within 10 minutes. [ABSTRACT FROM AUTHOR]

The Andalusian olive grove in South Spain is employed as a case study to assess the environmental and economic effects of the green architecture (eco-schemes) of the Common Agricultural Policy in relation to low carbon agriculture under different soil management policy scenarios to support more efficient agri-environmental policy making. To do so, we adopted a multidisciplinary approach in which we used: (i) an integrated modelling framework comprising geographic information systems (GIS); (ii) the RothC model; and (iii) a cost-benefit analysis. Results show that eco-schemes provide a significant increase of soil organic carbon (SOC) relative to cross-compliance. Practices involving vegetation covers are more efficient than using pruning residues as mulching. SOC accumulation increases rapidly in the first five-ten years to slow down afterwards. The cost-benefit ratios of eco-schemes policy implementation are higher than one when only SOC is considered. Nonetheless, the inclusion of additional co-benefits has the potential to invert this scenario and enhance policy efficacy. Various insights on optimizing the design and application of eco-scheme efficiency are provided. • The new eco-schemes CAP instrument proposed for woody crops contribute to increase SOC • Mowing cover crops leads to the highest SOC stocks, whereas pruning debris maintains SOC stocks. • Tillage and no-tillage with bare soil systems lead to a significant depletion of SOC stocks. • The economic benefits of eco-schemes would not off-set the costs borne by public authority • Environmental externalities are key to reach the profitability of the policy instruments. [ABSTRACT FROM AUTHOR]

• CO 2 injection for EOR in shales can be optimized to adapt CO 2 storage simultaneously. • Dual-lateral wells improved oil recovery by 26 % more than Huff-n-Puff and stored an extra 62 % of the injected CO 2. • The optimization design of the dual lateral injection improved NPV. • Well vertical separation showed a high impact on the efficiency of the injection. The dual challenge of enhancing oil recovery while sequestering carbon dioxide (CO 2) in oil reservoirs is a pivotal concern in the energy sector. CO 2 injection is recognized for its ability to decrease oil density and viscosity, thereby improving oil mobility and recovery rates. Traditionally, efforts have been concentrated either on enhancing oil recovery (EOR) or carbon storage, but not many efforts spent to couple EOR and CO 2 sequestration. Hence, novel techniques to optimize engineering designs to synergize EOR with CO 2 sequestration is the best approach to maximize the opportunities of storing emission gas and contribute to the global world decarbonization goals. This study introduces an innovative dual lateral horizontal well design, aimed at simultaneously boosting oil recovery from shale reservoirs and enhancing CO 2 retention. By integrating a conceptual understanding of oil recovery mechanisms with empirical data from the field, this research contrasts the proposed dual lateral design with the conventional Huff-n-Puff gas injection technique, commonly employed in shale oil formations. Our findings demonstrate that the dual lateral horizontal wells significantly outperform other injection methods in both oil recovery and CO 2 storage. Upon optimization, the dual lateral injection design continues to surpass the Huff-n-Puff method in terms of CO 2 storage, oil recovery, and net present value (NPV). This investigation not only presents innovative gas injection strategies in shale reservoirs but also provides insights into optimizing gas injection methods to enhance production efficiency and contribute to climate change mitigation through improved carbon capture and storage capacities. Through comprehensive numerical simulations and empirical data analysis, the study explores the optimization of well spacing, revealing that a dual lateral well with optimized spacing between 20 and 30 feet achieves the best outcomes in terms of oil recovery, CO 2 retention, and net present value (NPV). The research presents a unique coupling of economic and environmental benefits, supported by economic analysis that includes the potential impact of CO 2 tax credits. The novelty of this research is underscored by its integrated approach to CO 2 -EOR, the development of a dual lateral well design, and the optimization of well spacings for maximized efficiency. By providing a scalable solution that is both economically viable and environmentally sustainable, this research contributes a significant paradigm shift in the field of EOR and CO 2 sequestration, with implications for policy and investment strategies in the energy sector. The findings propose a new direction for shale reservoir exploitation, promising to enhance production efficiency while contributing to global efforts in greenhouse gas reduction. [ABSTRACT FROM AUTHOR]

Metal-organic frameworks (MOFs) are one of the most promising functional materials for CO 2 adsorption and transformation owing to their abundant active sites, easily functionalized surface, and highly adjustable pore structure, among others. This review discussed the recent research outputs in the synthesis and catalytic applications of MOFs – based nanocatalysts for CO 2 capture and conversion. The focus was on papers published in the last five years. The different synthetic methods of MOFs and MOF-based nanocomposites were elaborated. More so, the performance of MOFs as adsorbents in CO 2 capture and the proven performance enhancement strategies which include functionalization and compounding with other materials as nanocomposites were discussed in detail. Special emphasis was given to the different transformation routes of CO 2 viz. hydrogenation, photocatalysis, electrocatalysis, photoelectrocatalysis, and chemical fixation. As against what is obtainable in most similar reviews, the review provides insight into the application of MOF-based materials in integrated CO 2 capture and transformation. The work further provides an elaborate discussion of the current challenges and future perspectives. The reported works indicated that these MOF-based materials possessed the required competence for the adsorption and transformation of CO 2 into valuable products, making them excellent choices for practical applications. [Display omitted] • The uncontrolled release of CO2 into the atmosphere is a threat to human survival. • CO2 capture and transformation are one of the significant climate change mitigation options. • MOFs are one of the most promising functional materials for CO2 adsorption and transformation. • MOF synthesis methods are solvothermal, microwave-assisted, mechanochemical, electrochemical, and sonochemical. • CO2 transformation techniques are hydrogenation, photocatalysis, electrocatalysis, photoelectrocatalysis, and chemical fixation. [ABSTRACT FROM AUTHOR]

Residential green spaces are an integral part of urban green infrastructure and its role in climate change adaptation and mitigation. Various urban typologies and changing planning practices affect the amount and structure of residential greenery, which has a direct impact on climate benefits. While urban green and its climate benefits have received increasing attention, there is still limited knowledge on how changing planning practices and related urban typologies impact residential vegetation and its capacity to deliver climate benefits. This paper aims to address this gap by determining the impact of planning practices on residential vegetation, focussing specifically on climate mitigation and adaptation. With the case study of Helsinki, characterized by a high share of green areas, the paper first examines how construction year and urban density affect the amount and structure of vegetation on residential properties. Second, it estimates the carbon sequestration and summer temperatures in the present-day climate. The paper applies spatial modelling and regression analysis to estimate the impact of construction year on the studied dependent variables, while controlling density via gross floor area of buildings. The study demonstrates that the average amount of residential vegetation, as measured using canopy and vegetation cover, has declined 15 percentage points from the 1970 s to early 2010 s and the canopy to low vegetation ratio has decreased constantly over the periods studied. The decline of the canopy cover in particular has reduced the climate benefits of residential vegetation. The paper highlights the significant impact of gross floor area and planning practices on urban vegetation cover and the climate benefits it provides. It also stresses the importance of ensuring sufficient tree cover and permeable surfaces in cities with progressive climate mitigation agenda throughout the chain of urban planning, construction, and subsequent property management stages. [Display omitted] • Residential areas are a vital but understudied part of urban green infrastructure. • The amount of residential vegetation has diminished since the late 1970 s • The decline in canopy cover has reduced the climate benefits of residential areas. • Density and spatial patterns affect the climate benefits of residential vegetation. • Climate-wise, residential areas require sufficient vegetated and permeable surfaces. [ABSTRACT FROM AUTHOR]

Achieving a precise assessment of the aboveground biomass (AGB) in mangroves is a critical foundation for sustainable management and carbon sequestration assessment within climate change mitigation strategies. Conserving existing mangrove forests can maintain and enhance AGB over time. This study used a support vector regression (SVR) model, and vegetation indices derived from Sentinel-2 data for a comparative analysis of mangrove AGB within conservation and restoration projects in Madagascar and Abu Dhabi Emirate. The results confirmed that the SVR model based on vegetation indices, once calibrated against the field inventory data, was effective for estimating mangrove AGB at project scale. For the Madagascar project, the model achieved an R2 of 0.81 and RMSE of 27.99 Mg ha−1 for the 2015 timepoint, and an R2 of 0.79 and RMSE of 32.82 Mg ha−1 for 2019. In Abu Dhabi, an R2 of 0.76 and RMSE of 20.51 Mg ha−1 in 2015 and R2 of 0.75 and RMSE of 22.29 Mg ha−1 in 2020 were obtained. The SVR model estimated a decline in AGB from 116.78 Mg ha−1 to 109.63 Mg ha−1 during 2015–2019 in Madagascar, representing a decrease of 7.15 Mg ha−1 (6.13%). While in Abu Dhabi, the average AGB was estimated at 37.51 Mg ha−1 in 2015 and 42.69 Mg ha−1 in 2020, indicating an increase of 5.18 Mg ha−1 (13.76%) which can be attributed to conservation efforts in this region. This study suggested that Sentinel-2 can facilitate the comparison of AGB changes before and after conservation efforts, enabling the quantification of long-term shifts in mangrove AGB. • The SVR model and vegetation indices obtained from Sentinel-2 was used for monitoring mangrove AGB changes. • Red, NIR, red-edge bands and SWIR2 demonstrated higher correlation with AGB. • The deforestation is major driver of the decrease in AGB in Madagascar Bay of Assassins. • Monitoring AGB is crucial for mangrove sustainable management and conservation. [ABSTRACT FROM AUTHOR]

Existing assessments of climate mitigation technologies, like carbon capture utilisation and storage (CCUS), often rely on life cycle assessments (LCA), which are helpful for quantification but may not always be the most complete tools for decision-making. The novel contribution of this study is to provide the first application of a consequential carbon accounting approach, presented as a time-series analysis, to measure the system-wide change in emissions from CCUS linked to CO 2 -enhanced oil recovery. This method includes emissions from marginal oil production, a variable typically excluded in other LCA methods. The method was applied to a hypothetical CCUS project in Mexico to understand critical factors determining whether such an intervention can effectively contribute to emissions reduction in alignment with net-zero goals. Four intervention scenarios were assessed, comparing two distinct CO 2 injection strategies in oil reservoirs (water alternating gas and continuous gas injection) and two energy policy scenarios (current and sustainability). The findings suggest that the energy grid's role in overall emissions is relatively minor, with only a ∼2% difference between the compared scenarios, in contrast, the injection strategy has a significant impact on emissions. Scenarios 1 and 3 report a total change in emissions of −28.39 and −29.87MtCO 2 e, and scenarios 2 and 4 account for −19.63 and −21.22MtCO 2 e, respectively. The results highlight the importance of conducting system-wide analysis and comparing different scenarios to identify the critical components that drive changes in emissions and, therefore, support decision-making and project planning. • Consequential carbon accounting quantifies the system-wide change caused by CCUS. • A time-series provides decision-relevant information on climate change mitigation. • Market-mediated effects are highly relevant for CCUS projects. • CCUS is not consistent with net zero due to as remaining emissions. [ABSTRACT FROM AUTHOR]

[Display omitted] • Hedgerows and adjacent croplands at 23 sites across Germany were sampled. • Under hedgerows, 36 ± 49 % more soil organic carbon (SOC) was stored compared to cropland. • 41 % of absolute SOC stock increase was found in subsoil below 30 cm soil depth. • SOC stocks were also increased along the transect from the hedgerow to the cropland. • Planting hedgerows on 3 % of German cropland could increase SOC stocks by 13 Tg C. Carbon dioxide removal strategies are becoming increasingly important as a fundamental component of comprehensive climate policies. One strategy to increase carbon (C) sinks is the integration of hedgerows into agricultural landscapes. Besides additional C storage in above-ground and below-ground hedgerow biomass, the establishment of hedgerows has the potential to increase soil organic carbon (SOC) stocks. However, empirical data regarding the magnitude of SOC accrual with hedgerow establishment are still limited. We sampled 23 sites across Germany in a paired-plot approach with the aim of estimating SOC stock change with hedgerow establishment on cropland. At 21 sites, SOC stocks were higher beneath hedgerows than in the reference cropland. On average, SOC stock accrual was 29 ± 22 Mg ha−1 (36 ± 49 %) in 0–100 cm soil depth. SOC stocks were significantly different in both topsoil and subsoil. Subsoils below 30 cm depth contributed 41 % (12 ± 17 Mg C ha−1) of the total SOC stock change, stressing the importance of subsoil SOC for the total SOC stocks of hedgerow systems. The positive effect of hedgerows on SOC stocks extended laterally beyond the hedgerow area itself. SOC stock in the grassy hedgerow edge also increased significantly by 22 ± 22 Mg C ha−1 (28 ± 30 %) and SOC stock in the cropland directly adjacent to the hedgerow were 9 ± 19 Mg C ha−1 (12 ± 25 %) higher than in the reference cropland. Particularly high C stock differences between hedgerows and reference cropland soils were found in old hedgerows (>200 years) planted on hedgebanks, which are typically found in northern Germany. Our study confirmed that SOC stocks increase with hedgerow establishment on cropland throughout the whole soil profile. If hedgerows were to be established on 3 % of Germany's cropland area, SOC stocks would increase by 13 Tg C equivalent 48 Mio. t CO 2 , highlighting that hedgerows are a promising and multi-functional climate change mitigation option. [ABSTRACT FROM AUTHOR]

• The 57.00% of the Yangtze River Economic Belt area exhibited a significant increase in annual NPP. • The response of NPP on climate factors was nonlinear, with greater sensitivity to temperature. • The impact of topographic factors on NPP changes had a threshold effect. Net primary productivity (NPP) of terrestrial ecosystems serves as a crucial carbon sink, playing a significant role in mitigating climate change. This study, focusing on the Yangtze River Economic Belt (YREB), a key area for both economic development and ecological conservation in China, evaluates the temporal and spatial changes in regional NPP and its responses to climatic factors against the backdrop of global change. Utilizing long-term NPP and meteorological grid data from 1981 to 2017, we analyzed the annual change patterns of NPP and its linear and nonlinear responses to climatic factors using copula functions. Our findings indicate that 57.00 % of the YREB has experienced a significant increase in NPP, with the most substantial decreases observed in Shanghai and its surrounding areas (P < 0.05). Temperature emerged as the primary climatic driver, positively correlating with NPP changes in over half of the study area (P < 0.05). Moreover, the nonlinear response of NPP to temperature and precipitation underscores the complex interactions between these factors, revealing a sensitivity to temperature variations that surpasses that to precipitation. The study also highlights the influence of solar radiation and topographic factors, with a significant positive correlation between NPP and solar radiation observed in 15.85 % of the area (P < 0.05). The practical significance of these findings lies in their implications for regional ecological management and climate resilience strategies. The positive correlation between temperature and NPP underscores the potential for targeted temperature management to optimize carbon sequestration across the YREB. Furthermore, the identified nonlinear responses and the role of solar radiation and topography in influencing NPP offer valuable insights for the formulation of adaptive strategies that enhance ecosystem productivity and contribute to achieving carbon neutrality goals. By elucidating the dynamics of NPP in response to a range of environmental factors, this study provides a foundation for informed decision-making in ecological conservation and climate change mitigation efforts within the YREB and similar regions globally. [ABSTRACT FROM AUTHOR]

Boreal forests are often managed to maximize wood production, but other goals, among which climate change mitigation, are increasingly important. Hence, it is necessary to examine synergies and trade-offs between forest production and its potential for carbon sequestration and climate change mitigation in forest stands. To this aim, we develop a novel mass-balanced process-based compartmental model that allows following the carbon path from its photosynthetic fixation until its return to the atmosphere by autotrophic or heterotrophic respiration, or by being burnt as wood product. Following carbon in the system allows to account for how long forest ecosystems and wood products retain carbon away from the atmosphere (i.e., the carbon transit time). As example, we apply the model to four management scenarios, i.e., mixed-aged pine, even-aged pine, even-aged spruce, and even-aged mixed forest, and contrast metrics of performance relative to wood production, carbon sequestration, and climate change mitigation potential. While at the end of an 80 yr rotation the even-aged forests held up to 31% more carbon than the mixed-aged forest, the mixed-aged forest was superior during almost the entire rotation when factoring in the carbon retention time away from the atmosphere, i.e., in terms of climate change mitigation potential. Importantly, scenarios that maximize production or amount of carbon stored in the ecosystems are not necessarily the most beneficial for carbon retention away from the atmosphere. These results underline the importance of considering carbon transit time when evaluating forest management options for potential climate change mitigation. [Display omitted] • We evaluate wood production and climate change mitigation potential of boreal forests. • We combine an ecophysiological growth model with forest inventory tree allometries. • Higher carbon sequestration does not ensure higher climate change mitigation potential. • Potential climate change mitigation depends on carbon time away from the atmosphere. [ABSTRACT FROM AUTHOR]

Desertification, the process of land degradation in arid, semi-arid, and dry sub-humid areas, poses significant environmental, social, and economic challenges worldwide. As desertification continues to threaten ecosystems and livelihoods, innovative strategies for its management are urgently needed. The article begins by elucidating the causes and consequences of desertification, emphasizing its complex interplay with human activities and natural factors. It highlights the growing recognition of soil microbes as a critical component in combatting desertification. Soil microbes, encompassing a diverse community of bacteria, fungi, archaea, and other microorganisms, play multifaceted roles in soil health, ecosystem function, and sustainable land management. This review delves into the mechanisms through which soil microbes can contribute to desertification management. It discusses their roles in nutrient cycling, soil fertility enhancement, carbon sequestration, soil stabilization, erosion control, and biodiversity conservation. Drawing on case studies and real-world examples, it offers insights into successful applications of soil microbe-based strategies across different geographical regions and ecosystems. Challenges and limitations in implementing these strategies are also examined, including factors such as environmental variability, scale of application, and potential risks. Furthermore, research gaps and areas for improvement in understanding the intricate relationships between soil microbes and desertification management are identified. The review explores prospects and research directions in soil microbe-based desertification management. It highlights innovative approaches, emerging technologies, and the importance of interdisciplinary collaboration. Additionally, it discusses policy implications and the potential of these strategies to contribute to sustainable land use practices. [ABSTRACT FROM AUTHOR]

• A CGE model elaborately depicting six CCS technologies was developed. • Impacts of four CCS incentive scenarios on decarbonization pathways were simulated. • CCS can sequester 960 ∼ 1,604 MtCO 2 annually in China by 2060 with policy incentives. • CCS incentives can reduce China's future primary energy demand by 7.7 ∼ 17.4 %. • CCS incentives can increase GDP by 5.64 ∼ 6.59 % compared to no policy scenario. Carbon capture and storage (CCS) technology, considered as a pivotal tool in mitigating climate change within the fossil energy system, particularly in China, has experienced slower development than expected. The exploration of direct incentive policies to facilitate its growth remains relatively underdeveloped. This study developed a hybrid dynamic computable general equilibrium (CGE) model to simulate the substantial impacts of CCS incentive policies on China within the context of carbon neutrality target. Two potential incentive policies, carbon emission trading system (ETS) and 45Q tax credit, were simulated, with different sectoral coverage. The results indicate that CCS technologies can reduce carbon emissions by 960 ∼ 1,604 MtCO 2 annually by 2060 through the strategic implementation of these incentive policies. The 45Q tax credit demonstrates its effectiveness in promoting early-stage research and development (R&D) and demonstration of CCS, while the ETS policy facilitates the commercial development of CCS in the later stage of development. By 2060, the implementation of CCS incentive policies could potentially result in 7.7 ∼ 17.4 % reduction in China's primary energy consumption, 71.2 ∼ 82.7 % decrease in the carbon price of ETS and 5.64 ∼ 6.59 % increase in the GDP compared with the no-policy scenario. In addition, the sectoral output in various sectors and the welfare of urban and rural households also increase. This paper provides an important reference for the realization of China's carbon neutrality goal and the model framework can be applied to other countries. [ABSTRACT FROM AUTHOR]

Soil-based carbon farming has been identified in previous research as a win-win for farm productivity and the mitigation of climate change through carbon sequestration. However, it faces numerous barriers to adoption, including low carbon prices, high transaction costs, information barriers and high uncertainty around future outcomes, markets and policy conditions. Collaboration between landholders and other stakeholders has been proposed as a potential means of overcoming some of these barriers, while maximising the benefits of soil-based carbon farming. In this article, we present the results of a two-stage process investigating collaborative soil-based carbon farming in Australia, involving national-scale key informant interviews and a regional-scale Participatory Rural Appraisal. Fifty-three interviews were undertaken with key carbon farming stakeholders, including landholders, landholder groups, carbon service providers, government, researchers and the financial sector. Collaboration was seen to offer the greatest advantages in relation to knowledge-sharing and social support, followed by its potential to increase carbon income through enhanced bargaining power and the optimisation of co-benefits. The advantages of collaboration were less clear in relation to reducing costs or maximising farm productivity and collaboration also presents new challenges around risk and complexity. Under current conditions, informal collaboration models were seen to offer the best balance between the benefits and risks, with existing cooperatives also well-placed to diversify into carbon. Alternative conditions in the future or in other locations would be needed to facilitate models involving joint projects, pooled credits, shared land management and/or the creation of new carbon-specific cooperatives. • Soil-based carbon farming benefits both carbon sequestration and farm productivity. • Advantages of collaboration are greatest for knowledge-sharing and social support. • Collaboration less beneficial in relation to cost-reduction and farm productivity. • Informal models for collaboration preferred by study participants. • Existing agricultural cooperatives are well-placed to diversify into carbon farming. [ABSTRACT FROM AUTHOR]

Article 6 of the Paris Agreement establishes the foundation for international carbon markets by allowing Parties to cooperate to achieve their nationally determined contributions (NDCs). The Paris Agreement also embeds the concept of 'net zero' by calling for a balance between anthropogenic emissions of GHGs and removals of GHGs by sinks to be reached in the latter part of this century. All signatory Parties therefore tacitly acknowledge that meeting the Agreement's ambitious climate change mitigation goals relies not only on deep cuts in anthropogenic GHG emissions, but also on the offsetting of residual, hard-to-abate, GHG emission sources through significant increases in carbon removal from the active climate system and the storage of CO 2 in enhanced sinks and reservoirs. In these respects, Article 6 potentially offers a variety of routes to incentivize CO 2 capture and storage (CCS) including through emissions trading but also more novel means of cooperation that focus more specifically on carbon storage and which could potentially address some of the challenges posed for CCS over the past 15 years or so. In order to assess the status and outlook for Article 6 with a focus on CCS activities, we define three potential models for cooperation and undertake a comparative evaluation against the key criteria of effectiveness, environmental integrity, commercial and financial viability, progression and policy performance. We conclude with some observations regarding the factors that may influence the likelihood of these different market models evolving over coming years. [ABSTRACT FROM AUTHOR]

• Substitution factors for forest products for the Canadian context were developed. • Substitution factors ranging from 0.51 to 0.91 tC/tC were found. • They will lead to more accurate assessments of the forest GHG mitigation potential. • These factors will help governments to manage forest and fight climate change. Evaluating the climate change mitigation potential of the forest sector requires a holistic approach based on forest carbon (C) sequestration, C storage in harvested wood products (HWP) and substitution on markets. High uncertainty is associated with substitution factors, that express avoided fossil greenhouse gas (GHG) emissions from the use of forest-based products in replacement of GHG-intensive materials and fossil fuels. Few studies have focused on the development of substitution factors in Canada, resulting in the use of unrepresentative generic data. Here, we provide a framework to reduce uncertainties related to substitution factors for primary wood products in a Canadian context. A life cycle assessment framework is used to quantify fossil GHG emissions for a baseline and a wood-intensive scenario. For solid product substitution, we focused on the construction sector and analyzed a range of innovative wood buildings with steel and reinforced concrete as alternative materials. We found non-weighted averages of 0.80 tC/tC for sawnwood and 0.81 tC/tC for panels. For energy substitution, we analyzed cases with different specifications on biomass product, facility type and alternative fossil fuel source in non-residential heat production and biofuel transportation sectors. We found a non-weighted average of 0.80 tC/tC for non-residential heat production and 0.51 tC/tC for biofuel transportation, that can be interpreted as 0.91 tC/tC for heavy fuel oil, 0.69 tC/tC for light fuel oil and 0.68 tC/tC for natural gas substitution. These results provide a benchmark for substitution factors in Canada, to help guide forest management strategies for climate change mitigation. [ABSTRACT FROM AUTHOR]

The bioeconomic potential of monopodial and sympodial bamboos is not well understood. Therefore, Net primary productivity (NPP), total biomass, carbon (C) stock, soil organic carbon (SOC), CO 2 sequestration, and bioenergy potential were studied in a sympodial Chimonocalamus griffithianus and a monopodial Phyllostachys mannii bamboo in Meghalaya, north-eastern India. P. mannii stand with mean culm density 16,877 ha−1, height 14.8 m and diameter 4.4 cm, accumulated 107.56 Mg ha−1 biomass with a total NPP of 18.83 t ha−1yr−1. It stored 50.67 Mg C ha−1 in biomass, 77.28 Mg C ha−1 in soil, and had sequestration potential of 469.58 t CO 2 ha−1. C. griffithianus stand with mean clump density 1065 ha−1, mean culm density 52,185 ha−1, height 7.19 m and diameter 3.04 cm, accumulated 67.08 Mg ha−1 biomass with a total NPP of 15.30 t ha−1 yr−1. It stored 31.30 Mg C ha−1 in biomass, 83.25 Mg C ha−1 in soil, and had sequestration potential of 420.40 t CO 2 ha−1. Matured culms (>2–3 years old) of P. manni and C. griffithianus produced 143.08–166.65 MW h and 87.13–101.48 MW h of energy per ha, respectively. Although landuse history and site characteristics of the two stands were not 100 % identical, significantly greater (p < 0.05) standing biomass, NPP, growth rate, carbon sequestration potential, and energy values of P. mannii than C. griffithianus makes the monopodial bamboo a better choice for energy plantation and climate change mitigation tool than the sympodial. • Monopodial bamboo, Phyllostachys mannii , surpasses sympodial Chimonocalamus griffithianus in bioeconomic potential. • P. mannii exhibits higher biomass, NPP, carbon sequestration, and energy values. • Comparative analysis reveals the superior suitability of monopodial bamboo for energy plantations. • Results provide valuable insights for sustainable development in India's biobased economy. • Study contributes to understanding the role of bamboos in mitigating climate change. [ABSTRACT FROM AUTHOR]

• Solutions to the climate crisis are not ahistorical. • Both social and technical processes explain their rise (or fall) on the agenda. • Thinking about ocean CDR closely co-evolved with scientific understandings of global climate change. • Ocean CDR methods have followed cycles of hype, controversy and disappointment. • Key sociotechnical configurations and narrative changes explain the new hype around ocean CDR. While the ocean has long been portrayed as a victim of climate change, threatened by ocean warming and acidification, it is now increasingly framed as a key solution to the climate crisis. In particular, the promising carbon sequestration potential of the ocean is being emphasised. In this paper, we seek to historicise the practices, discourses and actors that have constructed the ocean as a climate change solution space. We conceptualise the debate about the mitigation potential of the ocean as a contested site of governance, where varying actors form alliances and different sociotechnical narratives about climate action play out. Using an innovative quali-quantitative methodology which combines scientometrics with document analysis, observational fieldwork, and interviews, we outline three historical phases in the history of ocean carbon sequestration that follow recurring cycles of hype, controversy and disappointment. We argue that the most recent hype around ocean carbon sequestration was not triggered by a technological breakthrough or a reduction in scientific uncertainty, but by new socio-technical configurations and coalitions. We conclude by showing that how climate change solutions are put on the agenda and become legitimised is both a scientific and political process, linked to how science frames the climate crisis, and ultimately, its governance. [ABSTRACT FROM AUTHOR]

While carbon sequestration is significant to achieve the net zero and plays an important role in climate change mitigation, urbanization-led land use land cover (LULC) changes are causing significant impacts on the carbon stocks of terrestrial ecosystems. Despite rapid urbanization in Pakistan, previous studies focus solely on localized areas without documenting the influence of urbanization on carbon stock. Hence, insights regarding the carbon storage dynamics (CSD) in response to LULC changes become essential to drive informed decisions and policies. In this context, we leverage high-resolution (30 m) remote sensing data to evaluate and map the grid-level spatial-temporal interactions between urbanization and CSD at the national scale in Pakistan during 1990–2020. To do so, multi-sensor earth observation data are retrieved and processed using the Google Earth Engine and the Integrated Valuation of Ecosystem Services and Tradeoffs models. Our findings indicate that urban areas have expanded exponentially (an increase of ∼1040%), resulting in reduced carbon storage (a decrease of ∼ − 5%). Major cities (e.g., Karachi, Lahore, Faisalabad) showed less urban sprawl while emerging cities (e.g., Rawalpindi and Peshawar) demonstrated higher urban sprawl, primarily due to shifting patterns from rangeland (∼47%) and agriculture (∼35%) to built-up class. Though some afforestation projects have increased forest carbon stocks in the northern region, there is a large north-south spatial heterogeneity in carbon storage loss across Pakistan. The presented high-resolution mapping of CSD over the past three decades advances our understanding of where and how much urbanization has influenced carbon sequestration, nationally. Considering the results, this study emphasizes the need for policies and management approaches that support sustainable urbanization, which does not compromise carbon pools in the country. • Grid level impact of LULC transition and its influence on CSD is mapped. • Transition from green cover to built-up areas led to reduced carbon storage. • Sustainable land management is imperative to maintain carbon storage capacity. [ABSTRACT FROM AUTHOR]

Due to the expeditious rise in anthropogenic activities and rapid extractive pressure, protected areas in the Indian Himalayan Region (IHR) are experiencing significant losses in ecological diversity and a substantial decline in the potential for carbon sequestration and climate change mitigation. The quantification of carbon sequestration and the understanding of its corresponding economic gain/loss are crucial for raising strict preservative concerns in protected areas with rich ecological and economic values. Transitions in land use land cover (LULC) trajectories from historical to future scenarios impact the dynamics of carbon storage and sequestration in terrestrial ecosystems. The present study extends a comprehensive 40-year (1995–2035) assessment of carbon mapping (gain/loss) as well as an economic approximation of carbon sequestration in the Askot Wildlife Sanctuary (AWLS), Western Himalaya, using satellite data. This investigation presents a novel hybrid approach by infusing machine learning algorithms and a spatial-temporal technique-based MLPnn-Markov chain model for future LULC simulation with the InVEST model that incorporates carbon mapping and economic valuation. The results show that among all the land use classes, dense forest has the highest carbon density; however, it exhibits a decreasing trend from 1995 (5,695,878.41 Mg/ha) to 2035 (4,378,439.81 Mg/ha). The economic quantification of carbon sequestration was performed by applying sensitivity analysis combined with different carbon prices and discount rates from 2020 to 2035. The observed outcomes reveal significant economic losses due to rapid forest cover decline, as indicated by a negative net present value (NPV) ranging from a minimum of ∼US$ -8 million to a maximum of ∼US$ -53 million. This study develops a valuable database by providing evidence-based decision-making and guidance for the sustainable preservation of ecosystems in the Western Himalayas and similar regions worldwide, where forest carbon sequestration is of paramount importance. The findings of the study suggest sound provisions for the conservation of forested landscapes and the development of efficient voluntary and regulatory carbon trading markets to achieve stability in forest carbon stocks. In doing so, this interdisciplinary approach addresses the growing imperative of integrating ecological and economic aspects in the context of biodiversity conservation and climate change mitigation. • Carbon sequestration in forests and across the landscape is performed and compared. • Remote sensing and machine learning techniques are executed for LULC simulation. • Carbon mapping is carried out in InVEST model. • Both country-level and international carbon prices are used for economic accounting. • Decline in forest cover encounters huge economic losses. [ABSTRACT FROM AUTHOR]

Policies that incentivize the capture and geological storage of CO 2 from large point sources ('CCS'; and more recently, atmospheric removals), have so far tended to reward the resultant avoided CO 2 emissions (or CO 2 removals) achieved by operators at the point of capture. The expectation has been that geological CO 2 storage sites, as well as the connecting infrastructure, will be developed and operated based upon the funding delivered from the single point of incentive (e.g. under an emissions trading system or a carbon tax, only CO 2 capture installation operators are absolved of the obligation to acquire and surrender CO 2 emission rights or to pay the tax). Project-based crediting mechanisms (e.g. in the voluntary carbon market) tend to treat the entire chain of operations as a single entity to be supplied with emission reduction or removal credits. Consequently, there has been minimal explicit financial incentive to store CO 2. Yet a multiple gigaton-per-year scale capture and storage industry requires complex CO 2 networks to evolve, with multiple sources connecting to multiple sinks, with installations owned by different operators with different technical expertise, climate mitigation goals and obligations. This multiplicity of goals and incentives can create agency problems and cross-chain risks, which impact negatively upon investment decisions. In this paper, we review the history, evolution and potential of geological net zero (GNZ) and carbon storage (or takeback) obligation concepts applied to fossil carbon producers and suppliers as a means to address these risks alongside policies aimed at atmospheric net zero (ANZ) and fossil carbon emitters. [ABSTRACT FROM AUTHOR]

The cultivation of deep-rooted vegetation greatly alters the tradeoffs between water and carbon dynamics, yet their impact on microbial carbon sequestration (MCS) remains inadequately documented, particularly in thick vadose zones. This information is crucial for global climate mitigation and ecosystem service enhancement. As such, we collected triplicate samples for each land use type, exploring the abundance and structure of cbbL -harboring microbial communities within 10-m deep profiles under cultivated farmland and two apple orchards of varying ages (n = 72). Our findings indicated a shift from water-dominated (improved water retention at the expense of reduced carbon sequestration) to carbon-dominated benefits (enhanced carbon sequestration at the expense of decreased water retention) in deep soil layers (2–10 m) after the transformation from farmland to apple orchards. Despite the lack of significant differences among the three land use types, the gene abundances and microbial diversity indices reduced with soil depths because of variations in substrates, resources, and microenvironments. The cbbL -harboring microorganisms consisted of 5 phyla, 7 classes, 19 orders, 30 families, and 55 genera, with Proteobacteria as the predominant bacterial phylum. The relative contributions of different genera varied with soil depths, reflecting their distinct survival strategies. The microbial network was positively connected in various soil layers under farmland and apple orchards. Furthermore, the results of correlation, redundancy analysis, and structural equation modeling jointly indicated that plant roots and soil properties, including total nitrogen and organic carbon, governed MCS processes in deep unsaturated zones. Specifically, the low microbial variation between farmland and apple orchards can be attributed to the predominant effects of climatic and pedogenic factors on soil properties, the restricted contribution of plant roots to soil nutrient levels per unit depth, and the adverse effects of plant-induced ecohydrological consequences on root systems and microbial populations. This study offers new insights within thick vadose zones containing deep-rooted plants, thereby contributing to a better understanding of global terrestrial carbon cycle processes. [Display omitted] • Microbial carbon sequestration processes were explored in 10-m deep profiles. • The farmland-to-apple orchards conversion led to water-carbon tradeoffs. • Microbial carbon sequestration differed with depths rather than land use types. • Depth-dependent plant roots and soil nutrients affects carbon sequestration. [ABSTRACT FROM AUTHOR]

Direct air capture (DAC) technology plays a crucial role in mitigating the effects of global warming by capturing carbon dioxide (CO 2) directly from the atmosphere. A significant technical challenge for DAC is its high thermal energy consumption, which results in an unacceptable overall cost (600 $ t CO 2 – 1). The combination of a high-temperature heat pump (HTHP) and DAC system offers a substantial reduction in thermal energy consumption, decreased reliance on renewable energy sources, and enhanced DAC system flexibility. This study presents three distinct thermal integration strategies that combine an HTHP with solid adsorbent-based DAC and verifies their effectiveness in reducing energy consumption and CO 2 emissions compared to a traditional DAC system. Among them, the deeply integrated DAC-HTHP system (I-DAC) exploits low-grade adsorption heat and waste heat, providing direct heating and cooling energy to the DAC system via refrigerant condensation and evaporation processes. Simulation results indicate that the I-DAC system achieves an extremely low operating energy consumption of 2.77 GJ t CO 2 – 1 , representing a 69.5% reduction than traditional DAC under the same conditions. Consequently, the I-DAC offers a cost-effective (32.0–46.2 $ t CO 2 – 1) negative emission solution. We also demonstrate that the I-DAC is promising for wide application in cities to recycle waste heat and remove CO 2 from the air. The comprehensive implementation of the I-DAC in 105 cities could yield a net annual productivity of 980 MtCO 2. • Proposed a deeply thermal integrated DAC system (I-DAC) with waste heat recovery heat pump. • I-DAC achieved a 69.5% reduction in specific energy consumption compared to base-DAC. • I-DAC offers a cost-effective and scalable negative emission solution for climate change mitigation. • Successful implementation of I-DAC in 105 cities could yield a net annual capture capacity of 980 MtCO 2 by 2050. • Highlights the potential of I-DAC to recycle waste heat and remove CO 2 from the air, with policy implications [ABSTRACT FROM AUTHOR]

Non-native species are expanding globally and can alter ecosystem functions, including food web dynamics, community structure and carbon storage. Seagrass are foundation species that contribute a variety of ecosystem services in near-shore coastal ecosystems, including a significant sink of carbon. In the Caribbean, the rapidly expanding non-native Halophila stipulacea has unknown impacts on carbon storage. To investigate the impacts on carbon storage, we quantified organic carbon (C org) content in sediment and seagrass tissues from monotypic H. stipulacea beds, mixed native seagrass beds dominated by Thalassia testudinum and Syringodium filiforme, and unvegetated substrate in St. John, USVI. We found native seagrass-vegetated sediment contained 1.3 times more C org than sediment covered by H. stipulacea , and 1.6 times more C org than unvegetated areas on average. Whereas, H. stipulacea -dominated substrate stored 1.2 times more C org than unvegetated substrate. Likewise, native species contained 2.2 times more aboveground biomass and 6.0 times more belowground biomass than H. stipulacea. Since seagrasses are critical sources of carbon sequestration, our results suggest that invading H. stipulacea is associated with lower carbon stocks which has potential implications for conservation activities and climate change mitigation. [Display omitted] • Non-native species are expanding globally and can alter ecosystem functions. • Our results suggest that invading H. stipulacea is associated with lower carbon stocks. • In the Caribbean, rapidly expanding Halophila stipulacea may reduce carbon storage. [ABSTRACT FROM AUTHOR]

• CCUS development among EU countries with the latest progress in the field. • Realization of EGD targets with CCUS technology in EU. • Applicability of benchmarking method to compare environmental profiles. • UK and the Netherlands are among top countries with rapid CCUS development. • Poland and Germany with a high level of difficulty in achieving the EGD targets. Carbon Capture Utilization and Storage (CCUS) is a technology highlighted as one of the tools in climate change mitigation and one of the ways to reach the goal of 1.5℃ set by the Paris Agreement. The European Commission (EC) developed this goal by creating and implementing the European Green Deal (EGD) – the European Union's (EU) environmental policy. This paper provides an analysis of environmental policies and an overview of crucial CCUS projects of selected member states based on a benchmarking analysis of 27+ UK member states. An overall review of a total of 28 countries was undertaken based on economic and environmental factors. Afterward, a benchmarking analysis was performed ranking the countries according to the TOP10 for the selected five categories: total net emissions with international transport, percentage share of the energy sector, percentage share of fossil fuels, percentage share of fossil fuels in the Gross Electricity Production (GEP), and numbers of CCUS projects. Subsequently, a detailed and comprehensive overview of four selected member states was done, with a special focus on the national energy policy towards net-zero emission goals, the role of CCUS in domestic environmental policy, with current projects and facilities development. Finally, this paper outlines how the EGD has reformed the national energy policies of selected member states, and what is the part of CCUS technology in the national efforts towards climate neutrality. [ABSTRACT FROM AUTHOR]

Despite numerous prior studies regarding public acceptance of climate change mitigation technologies, most academic papers focus on individual technologies in their analyses. Little is known about the acceptance of multiple low-carbon energy technologies. This study bridges this research gap and explores the cross-technology acceptance of various energy solutions at different locations. Thus, we provide a comprehensive understanding of public acceptance patterns by analysing a broader range of technologies concurrently, focusing on: (a) nuclear power, (b) district heating, (c) energy-saving technologies, (d) onshore, nearshore, and offshore wind power (WP), (e) photovoltaics (PV) installed on agricultural land, industrial roofs, and private roofs, and (f) carbon capture and storage (CCS) in offshore, nearshore, rural onshore, and urban onshore locations. Based on Danish nationally representative survey data, our results give strong policy indications that PV on industrial rooftops is accepted at the highest level. In contrast, nuclear power, onshore rural and urban CCS, and nearshore CCS are the least accepted technologies to combat climate change among the Danish public. Additionally, we discover that the acceptance of a specific technology is contingent on locations. Specifically, the public acceptance of PV, WP, and CCS depends on the place of living and the potential location of technology placement. Finally, this study explores subgroup analyses to compare acceptance differences according to gender, age, education, income, and location of residence. [Display omitted] [ABSTRACT FROM AUTHOR]

Plants capture atmospheric carbon dioxide (CO 2) for carbon (C) assimilation through photosynthesis, with the photosynthates stored as plant biomass (above- and below-ground plant parts). The C stored as living biomass is a short-term C sequestration strategy, whereas soil organic carbon (SOC) is a long-term C sequestration strategy. In this regard, plant roots are the primary route of C entry into the SOC pool. Through establishing a recalcitrant SOC pool, long-term sequestration can potentially offset the C losses caused by soil degradation in industrial and pre-industrial eras. Over the next 50–100 years, implementing effective agricultural practices could sequester 80–130 GT (109) C as SOC. Carbon, as the primary elemental component of soil organic matter, plays a significant role in shaping the soil's physical, chemical, and biological properties, ultimately influencing soil biomass productivity. By enhancing crop productivity and biomass production, farmers can increase C sequestration, creating a positive feedback loop that contributes to overall C sequestration. Carbon sequestration has numerous co-benefits, including climate change mitigation, ecosystem health, food security, and farm profitability. Adopting conservation agriculture and site-specific practices and developing crop and pasture genotypes with high yields and C sequestration potential should significantly improve crop productivity and C sequestration simultaneously. This opinion article delves into the nexus between photosynthesis and soil C sequestration, highlighting its significance in enhancing farm productivity while mitigating climate change. [Display omitted] • Good agricultural practices could sequester 80–130 GT (109) C as soil organic carbon (SOC). • Engineering of carbon-concentrating mechanisms can enhance carbon assimilation potential of plants. • Afforestation and restoration of degraded lands can improve SOC besides other ecosystem services. [ABSTRACT FROM AUTHOR]

Bioenergy with carbon capture and storage (BECCS) is regarded as a crucial negative emission technology (NET) in many prospective climate change mitigation scenarios that limit global warming below 2 °C. However, there is still insufficient understanding of the overall life cycle environmental performance of different BECCS configurations. Despite the fact that BECCS entails many technological combinations, the technology is still regarded as a single "black box" technology in most climate scenarios. This study presents a critical review of life cycle assessment (LCA) on a wide range of BECCS options: biomass direct-fired power generation, biomass gasification power generation, bio-hydrogen production, biomass application in industry sectors and other biomass conversion processes, such as pyrolysis and fermentation. It is evident from the review that the biomass direct-fired and gasification power plant with a 100% biomass firing ratio and the gasification-based bio-hydrogen processes have a strong potential to achieve negative emissions. However, the net negative life cycle emissions range widely among studies for each configuration due to variations in technology, LCA methodology and assumptions. Additionally, there is an insufficient assessment of comprehensive environmental impacts for BECCS systems other than GWP, making it still unclear about the trade-offs between the benefit from climate change mitigation and potential negative impacts. Main recommendations for improving LCA on BECCS include developing a generalized guideline and standardization for BECCS LCA, conducting LCAs with comprehensive impact categories, focusing on BECCS configurations being overlooked, considering the impact of land use change and the global warming potential of biomass, and extending LCA in both temporal and spatial dimension. [Display omitted] • Systematically review of life cycle assessment on BECCS systems. • Detailed review on various biomass conversion technologies. • Net negative life cycle emissions range widely among studies. • Insufficient studies of some biomass conversion pathways. • Insufficient studies on multi-environmental environment impact categories. [ABSTRACT FROM AUTHOR]