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Chemical explosives such as TNT are widely used in special scenarios, such as civil explosives, due to their simple preparation and high energy density. However, the temperature of the fireball produced by the explosion of these explosives is extremely high. Moreover, this approach may cause many casualties and economic losses if not prevented. To accurately measure the temperature of a transient explosion field and study its space-time distribution, a two-dimensional high-speed temperature measurement system was built based on blackbody radiation theory, high-speed photography, image Bayer array and improved interpolation algorithm. The explosive fireball produced in a static explosion test of 10 kg of TNT was measured within the shooting range. TNT was added with an auxiliary blackbody (tungsten). Compared to traditional explosion temperature measurement methods, the experimental results showed that the colorimetric temperature measurement method based on the improved interpolation algorithm and the addition of tungsten powder could more accurately measure the temporal and spatial distributions of the temperature field. This work can aid in the prevention in the accidents during the transportation, storage, and manufacturing of chemicals relevant to process industries. [ABSTRACT FROM AUTHOR]