Search

Soil properties are crucial in forest ecological management and rare vegetation protection. In this study, Fanjing Mountain, a typical subtropical forest, was used to investigate and analyze the differences in soil properties and climate change characteristics of Fanjing Mountain in 1982 and 2014. Then redundancy analysis was used to analyze the influence of climate factors on soil properties. The results showed that: 1) Compared to 1982, the soil properties of Fanjian Mountain changed significantly in 2014. The soil texture evolved from a silty loam in 1982 to a silty clay loam in 2014. There was a significant increase in soil clay particles. In addition, the soil showed acidification, weakened cation exchange capacity, and relatively stable soil total nitrogen but significant loss of soil organic matter and total phosphorus nutrients. 2) In the past 32 years, the environmental climate of Fanjing Mountain has shown the characteristics of increasing annual average temperature and annual rainfall, frequent extreme temperature, widening the annual temperature range and decreasing annual relative humidity. 3) Soil type and maximum annual temperature have a highly significant effect on the evolution of soil properties, while annual rainfall and slope orientation significantly affect the evolution. Conclusion: The evolution of soil properties in subtropical forests is dominated by their type differences and climate warming. [ABSTRACT FROM AUTHOR]

Although a number of studies have provided information on soil texture, soil classification, and depth to bedrock throughout China, few studies have combined this information, which is the basis for agricultural field management. A total of 81% of China's cultivated lands are distributed among the Middle–Lower Yangtze Plain (18.2%), arid and semiarid North China Plain (18.2%), Northeast Plain (17%), Huang-Huai-Hai Plain (16.1%), and Yunnan–Guizhou Plateau (11.6%). The Huang-Huai-Hai Plain has the highest density of agricultural land (58.5%) and the greatest depth to bedrock of cultivated land (243–402 m). The lowest cultivated depth to bedrock (4–84 m) is concentrated in the Sichuan Basin and its surrounding regions. The main cultivated soil types are Anthrosols, Fluvisols, Cambisols, Phaeozems, Luvisols, Kastanozems, Leptosols, and Acrisols, under the main topsoil texture classes of loam, clay loam, silty clay loam, silt loam, sandy loam, and clay. The Fluvisols had the largest depth to bedrock (156 m) on the Middle–Lower Yangtze Plain and Huang-Huai-Hai Plain, with the highest silt soil distributions but comparable lower sand contents. The Yunnan–Guizhou Plateau had the highest clay soil content. The cultivation under Kastanozems and Leptosols on the Qinghai–Tibet Plateau and in arid and semiarid North China and under Phaeozems on the Northeast Plain should be restricted and managed very cautiously facing erosion risk. The higher percentages of Anthrosols are on the Middle–Lower Yangtze Plain (37%), in Southern China (32%), and on the Yunnan–Guizhou Plateau (26%). The same cultivation aim (i.e., more crop 0production) has produced a similar range of properties over time among the soils developed on agricultural fields, which are classified as Anthrosols. However, various soil types can still be found in agroecosystems because of the variations in climate and topography. Our results highlight that the agriculture-based soil climate and topography shape the interaction of the soil development and not only the pedogenic history of the soil development under variations in the soil depth to bedrock but also the cultivation of distinct pedogenic features. This study provides cultivated soil information on the depth to bedrock, soil classification, and soil texture in China, as well as instructions for field strategies for sustainable agricultural development. [ABSTRACT FROM AUTHOR]

Identifying the impact path of climate and soil factors on soil δ15N is very crucial for better understanding the N turnover in soils and the integrated information about ecosystem N cycling. Many studies have showed that climate and soil variables influence the change of soil δ15N. However, most of the existing studies focused on the overall impact of factor on soil δ15N, without distinguishing between the direct and indirect effect. Although scholars have studied the relationships among temperature, precipitation, soil N, soil pH, and soil δ15N rather than estimating all the causal relationships simultaneously. To answer the above-mentioned questions, a regional-scale soil collection was conducted across a temperate grassland in northern China. Meanwhile, a PLS-PATH analysis was utilized to evaluate the direct and indirect effects of various factors on soil δ15N and to explore the causal relationships among variables. The results showed that along the transect, mean annual precipitation (MAP) and mean annual temperature (MAT) directly and significantly reduced soil δ15N, and indirectly affected soil δ15N through their effects on soil pH, soil clay, soil N and soil C/N. Soil C/N ratio has a significant direct impact on soil δ15N with a negative correlation. Soil clay, soil N content, and soil pH have a total positive effect on soil δ15N, but the total positive impact of soil pH is very weak because it has a negative indirect impact on soil δ15N by affecting soil clay, soil N and soil C/N ratio. The total influence is, in order, MAP > MAT > soil C/N > soil clay > soil N > soil pH (in absolute value). The above results will provide valuable information about ecosystem N cycle in temperate grassland of northern China. [ABSTRACT FROM AUTHOR]

[Display omitted] • Soil silt/clay and nutrients increased with increasing distance from the shelterbelt. • Downslope deposition lead to an increase in plow pan thickness and a decrease in bulk density. • Erosion rate was primarily affected by shelterbelt distance, followed by elevation. • Sites closer to shelterbelt warrant particular attention due to coarse-texture materials. Soil erosion is the most severe form of land degradation globally. Farmland shelterbelts are important for reducing erosion, especially erosion caused by the co-occurrence of water and wind. However, few studies have focused on how the distance from the shelterbelt associated with farmland topography affects the redistribution of soil quality indicators. The aims of this study is to reveal the relative importance of these two factors to soil quality under typical wind and water erosion conditions concurrent with the Songnen Plain, China. Topsoils (0–10 cm) were sampled at seven distances from the shelterbelt with three replicates, where topography heterogeneity was also considered. We found that the silt/clay content and soil nutrients at sites farther from the shelterbelt were significantly greater than those at sites closer to the shelterbelt (P < 0.05). Similarly, deposition was dominant at sites farther from the shelterbelt and downslope positions, while erosion was dominant at sites closer to the shelterbelt and upslope positions. Moreover, we discovered that the relative influence of distance from the shelterbelt and farmland elevation varied with individual soil quality indicators. Soil nutrients increased through the deposition of more fine-textured soil (silt/clay) positions farther from the shelterbelt. The downslope region responds to soil deposition by enhancing the plough pan thickness and lowering the bulk density and pH. Overall, distance from the shelterbelt and farmland elevation had interactive effects on soil quality, and erosion was primarily affected by distance from the shelterbelt (63.4 %), followed by elevation (22.7 %). Furthermore, the sites closer to the shelterbelt (i.e., 20 to 420 m) warrant particular attention due to the deposition of coarse-texture materials here. This work is crucial for an improved understanding of the synergistic effects of long-term water and wind co-occurrence on soil quality evolution. [ABSTRACT FROM AUTHOR]

[Display omitted] • Stream power and soil clay content were used to model soil erosion rate. • Sediment sorting and transport were controlled by the soil properties. • A linear function was developed to quantify the sediment clay content. • The relative contributions of different transport mechanisms were quantified. Understanding the sediment sorting and transport processes is is crucial for enhancing the understanding of soil erosion mechanisms and improving soil erosion prediction. However, quantitative studies based on the coupling effects of both hydraulic parameters and soil properties are still lacking. In this study, five loessial soils with varying physicochemical properties were collected in the Loess Plateau of China, and simulated rainfall experiments were carried out in a metal box with a slope of 20 degrees under rainfall intensities of 1, 1.5, and 2 mm min−1. Runoff samples were collected to analyze the variation in erosion rates and effective particle size distribution of eroded sediments during the rainfall process. The results showed that the stream power was the optimal parameter to model the erosion rate, and a power function incorporating the clay content and stream power could well predict the erosion rate of different soils. The enrichment ratio indicated the enrichment of fine particles and depletion of coarse particles. And the sediment sorting degree increased with increasing soil clay content. The critical particle size for distinguishing different transport mechanisms varied among soils, with more than 55.46 % of the total sediment transported by suspension/saltation. A linear function and power function including the original soil particle size distribution and stream power were developed to quantify the sediment clay content and the relative contribution of different transport mechanisms. This study could be helpful to improve the soil erosion prediction model and provide basic guidelines for regional soil and water conservation. [ABSTRACT FROM AUTHOR]

Miscanthus spp. are increasingly cultivated in cropland worldwide due to their bioenergy potential and multiple ecological services. Effects of long‐term cropland‐to‐Miscanthus conversion without N fertilizer on soil microbiome and N cycling largely remain unknown. We aimed to explore the effects of Miscanthus conversion on soil microbiome and N cycling over a 15‐year period. We analyzed diversity, composition, and abundance of bacterial and archaeal communities using 16S rRNA amplicon sequencing, and abundances of N‐cycling‐related genes using quantitative polymerase chain reaction of 0–10 cm soils collected from bare land, cropland, 10‐year Miscanthus × giganteus, and 15‐year Miscanthussacchriflorus land in Beijing. Conversion decreased soil sand and micro‐aggregate proportion, nitrate N (NiN), available phosphorus levels, conductivity, temperature, and pH, while increasing proportion of soil clay and macro‐aggregate (MAA), soil organic C (SOC), available N (AN), exchangeable Mg2+ (EMg2+), and available potassium (AK) contents as well as microbial C/N. Consequently, diversity, composition, and abundance of soil bacterial community exhibited larger changes than those values of archaeal community after conversion. Soil AP, EMg2+, AK, and SOC were key factors in shifting microbiome from the cropland to Miscanthus pattern. Moreover, abundances of bacterial and archaeal communities and the N fixer gene nifH increased, whereas that of the bacterial ammonia monooxygenase gene decreased. The copies of other N‐cycling‐related genes in the two Miscanthus lands seemed similar to those values of cropland. The nifH copies negatively correlated with soil NiN and positively correlated with AN, EMg2+, ECa2+, SOC, AK, and MAA. We conclude that changes in soil microbiome pattern induced by the variation of soil properties enhance microbial N fixation potential, maintaining stable N levels and robust N cycling with lower N leakage risk after conversion. These results should inspire farmers and governments to large‐scale use Miscanthus on marginal cropland in Northern China. [ABSTRACT FROM AUTHOR]

Soil structure is a key factor to determine the different functions of soil, such as water infiltration and retention, soil permeability, and nutrients availability. The dynamic behavior of soil also depends mainly on the tillage, crop roots, and soil organic matter return. Black soil is one of the most important arable soil with high clay content, but hard soil structure is one of the main factors limiting crop growth. It is still lacking on the effect of organic amendment on soil pore structure in the black soil. In this study, a field experiment was carried out in the black soil region located in Hailun City, Heilongjiang Province of China, in order to clarify the effects of organic amendment and depths on soil physical properties and pore structure before maize sowing in 2019. Four treatments were conducted using random block design with four replicates, including shallow tillage with maize straw return in 0-15 cm soil layer (T1), deep tillage with maize straw return (T2), or combined maize straw and organic manure return (T3) in 0-35 cm soil layer, conventional tillage without organic amendment as control. Maize straw and organic manure were also incorporated into the soil layers by shovel using manual work, where the application rates were 10 000 and 30 000 kg/hm2, respectively. CT scanning was adopted to visualize and quantify soil pore structure after maize harvesting. The constant head method was used to measure the saturated hydraulic conductivity. The results demonstrated that the bulk density under T1, T2, and T3 treatments significantly decreased 3.77%-5.66%, compared with CK, while the saturated hydraulic conductivity increased by 2.2-5.00 times, and the field water capacity increased by 6.91%-11.01% within 0-15 cm soil layer (P<0.05). T2 and T3 treatments also improved the bulk density, saturated hydraulic conductivity, and field water capacity within >15-35 cm soil layer after one maize growing season. Furthermore, the number of soil pores and porosity of >500 μm aperture under T1, T2, and T3 treatments significantly increased by 18.1%-180% and 69.2%-256% (P<0.05) in 0-15 cm soil layer, respectively, compared with CK treatment (P<0.05). Specifically, the soil pore number and porosity of >1 000 μm aperture were more 6.06%-150% and 17.4%-196% under T2 treatment than the rest. It infers that the treatments with organic amendment increased the number of soil pores with optimal distribution. In addition, the complexity and connectivity of soil pore also increased significantly, in presence of connected and sender pore. The Euler number values under T1, T2, and T3 treatments were decreased by 21.7%-54.3%, whereas, the fractal dimension under T1 treatment increased by 1.5% in 0-15 cm soil layer (P<0.05), compared with CK treatment. T2 and T3 treatments improved the soil pore structure in >15-35 cm soil layer, as shown in that the Euler decreased by 65.9%-70.5%, anisotropy, fractal dimension, and circularity increased by 50.0%-110%, 12.8%-13.9%, and 12.2%-14.9%, respectively, compared with CK treatment (P<0.05). The Euler and porosity of >1 000 μm aperture presented the largest contribution both for the bulk density and saturated hydraulic conductivity in 0-35 cm soil layer, whereas, the anisotropy and Euler presented the largest contribution for the field capacity in 0-15 cm and >15-35 cm soil layers. Pearson correlation analysis indicated that the extremely significant negative relationship was found between bulk density and saturated hydraulic conductivity, field water capacity, soil porosity within 0-15 cm soil layer (P<0.01), while the extremely significant or significant correlation was found between bulk density and all indicators, excepting for the anisotropy and Euler. Consequently, the improved physical properties of soil were attributed to the fact that the organic amendment regulated soil structure, including optimal distribution of soil pore, complex, and connectivity of pore structure. Correspondingly, the organic amendment can be expected to serve as an effective approach for the pore structure of black soil. It is also necessary to consider the response of soil pore structure in the decomposition of returned organic manure in the future. [ABSTRACT FROM AUTHOR]

Calcic vertisol is a typical kind of low-yield field with a total area of about 4 million hm2 in China. Calcareous concretion with particle size larger than 2 mm has been one of the representative characteristics of calcic vertisol. The limitation of soil available water is an important reason for crop failure in this region. Therefore, the curve of soil water retention dominates the estimation of available water content. However, most studies focused on the effects of calcareous concretion on soil water retention of calcic vertisol mainly under laboratory conditions. It is lacking that under field conditions. In this study, both field surveys and laboratory experiments were conducted to explore the effect of calcareous concretion distribution in 0-1 m soil profile on soil water retention. Firstly, the spatial distribution of calcareous concretion was investigated in the study plot with 150 m length, 50 m width, and 1 m depth. After then, soil profiles (0-1 m soil depth) were chosen to divide into 5 layers with a 20 cm interval. Disturbed and undisturbed soil samples were collected in each layer. Physicochemical properties were evaluated to measure the distribution of soil particle size, size and content of calcareous concretion, bulk densities of soil, and calcareous concretions. Meanwhile, the curves of soil water retention were determined using high speed centrifuge. A pressure plate method was conducted to measure water retention curves in calcareous concretion. The results showed that the mass contents of clay, silt, and sand were 30.56%-39.75%, 39.88%-45.34%, and 18.67%-24.45%, respectively, which belonged to silty clay soil in the classification standard of the United States Department of Agriculture (USDA). Clayey particles decreased, but sandy particles increased significantly with the increase of soil depth. Calcareous concretion was mainly distributed in the soil depth of >20-100 cm, where the content and size increased as soil depth increased. Calcareous concretions content in the surface soil (0-20 cm) was very low (with mass content 0.02%), where only a few calcareous concretions of 2-5 mm were discovered. The maximum content of calcareous concretion was detected at > 80-100 cm (up to 11.42%), where the calcareous concretion content was 8.04% in the size of >8-30 mm. Soil bulk density ranged from 1.23-1.61 g cm-3. The densities of calcareous concretions were 2.01, 2.21, and 2.23 g cm-3 with the size of 2-5 mm, >5-8 mm, and >8-30 mm, respectively. Soil bulk density increased along with the calcareous concretion content increasing. Water retention curves of soil and calcareous concretion were well fitted by the van Genuchten model, with the determination coefficient larger than 0.95. The saturated water content of surface soil (0-20 cm) was significantly higher than that of 20-100 cm soil. Nevertheless, the Gravitational-water content in the surface soil (0-20 cm) was much larger than that in the soil of > 20-100 cm, which was related to macropores formed during tillage. In the subsurface (>20-100 cm), soil gravitational-water content and available water-holding capacity increased with the increase of soil depth, but the field capacity and wilting point decreased. Calcareous concretion maintained a non-negligible amount of water, 0.25, 0.22, and 0.20 cm3 /cm3 in the particles with the size of 2-5 mm, >5-8 mm, and >8-30 mm, respectively. But the water-holding capacities of calcareous concretion were significantly lower than that of soil. The effects of calcareous concretion on water-holding capacity mainly occurred in the subsurface soil. Soil saturated water content, field capacity, and wilting point decreased with increasing calcareous concretion. Interestingly, calcareous concretion content was positively correlated with the soil sand content, but negatively correlated with the soil clay content. Calcareous concretion can bind soil particles together to prevent sand weathering, and thereby effectively improve soil texture. More calcareous concretion led to higher sand contents, and thus increased the available water-holding capacity in soil. This finding can provide a theoretical basis to accurately assess the soil water-holding capacity in calcic vertisol for precision irrigation and high crop productivity. [ABSTRACT FROM AUTHOR]

Abstract Local topography and elevation gradients can exert important influences on soil formation processes such as elemental migration, mineral weathering, and soil organic matter (SOM) accumulation, yet these influences remain insufficiently investigated to date, particularly in surface soils of subtropical monsoonal regions. Here, we report on an investigation of a series of surface soils collected from four different topographic locations across the subalpine Dajiuhu Critical Zone Observatory (CZO), representing hillslope (planar), swale and river channel (convergent), and bulge (divergent) microtopographic sites. Evidence provided by rare-earth element (REE) patterns, immobile element ratios, clay-mineral compositions, and particle-size distributions suggests that these soils have rather uniform parent materials. X-ray diffraction (XRD) analysis revealed that secondary clay minerals in these soils are complex, being dominated by various interstratified clays. Diffuse reflectance infrared Fourier transform (DRIFT) spectroscopy shows similar patterns among the swale, bulge, and river-channel soils that differ from those of the hillslope soils. Most soils at convergent sites with poor drainage contain more smectitic clays (interstratified illite/smectite and chlorite/smectite) and less vermiculitic clays (hydroxyl-interlayered vermiculite and interstratified illite/hydroxyl-interlayered vermiculite), and exhibit weaker chemical weathering and fewer elemental losses than those from non-convergent sites. The diversity of clay types can be ascribed to the complexity and heterogeneity, in particular of pH and hydrology, in these soil environments. Across the range of microtopographic sites investigated here, elemental migration and chemical weathering are generally coupled, with greater elemental losses associated with more intense chemical weathering. Soil organic carbon (SOC) content generally increases at higher elevations, which is attributable to lower temperatures and a consequent reduction of microbial remineralization, and under more reducing soil water conditions. Though influenced by eolian dust, variations in Fe/Mn, Ce anomaly, and C org /P can reflect redox conditions of different soils. SOC retention is also closely associated with soil redox status, with more reducing conditions being more conducive to SOC preservation. Highlights • Surface soils in a subalpine CZO of subtropical monsoonal China were studied. • Local topography strongly influences soil hydrology and soil formation processes. • The diversity of clay types ascribed to the heterogeneity of soil pH and hydrology. • Chemical weathering intensity generally increases with increasing elevation. • SOC storage in soils influenced by elevation gradients and soil redox conditions. [ABSTRACT FROM AUTHOR]

In order to obtain the interaction parameters which can be used for discrete element simulation between the soil-engaging components and clayey black soil in northeast China, the Hertz-Mindlin with JKR Cohesion contact model in EDEM2.7 was used to simulate the clayey black soil. Aiming at the actual working environment with moisture content of 10%-20%, 2 kinds of clayey black soil with moisture content of 12.46%±1% and 17.15%±1% were prepared respectively. The rolling friction coefficient, recovery coefficient, JKR surface energy parameter and the static friction coefficient between the soil particles were used as the model calibrated parameters. The soil repose angle simulated under the simulation parameters was set as the response value. The regression model of the soil repose angle was established based on the Box-Behnken response surface method, and the regression model was optimized by using the soil repose angles under 2 moisture contents obtained by physical experiments. The optimal solution of the contact model parameters of the clayey black soil particles with 2 moisture contents was obtained. The parameter range of the discrete element contact model of clayey black soil with moisture content between 10%-20% were given. The soil repose angle and stacked shape obtained by the simulation experiment with the optimized solution had a high similarity with that of the physical test. At the same time, the static friction coefficients of 3 kinds of soil contact materials such as 65Mn plate, UHMW-PE plate and PTFE plate were tested under the conditions of 4 kinds of moisture content, which were 0, 12.46%, 17.15% and 23.5% respectively. Then for the 2 typical soil contact materials such as 65Mn and PTFE, the slope physical test bench were constructed for the clayey black soil with moisture content of 17.15%±1%. The slope simulation models of 65Mn and PTFE materials were established under the EDEM2.7 software platform. Based on the critical simulation parameters such as JKR surface energy parameter, static friction coefficient, rolling friction coefficient and recovery coefficient between soil particle and soil contact material, the simulated rolling distance of the soil ball on different soil contact materials was set as the response value. The excellent fit regression model of rolling distance for the 2 kinds of typical soil contact materials were established based on the response surface optimization method of Box-Behnkende. The 2 regression models were optimized by the sliding distance obtained by the physical experiment. Then the optimized solution of the contact model parameters of different materials was obtained. The simulation results showed that when the surface energy of JKR between soil and 65Mn was 5.5 J/m2, the recovery coefficient was 0.61, the static friction coefficient was 0.57 and the rolling friction coefficient was 0.056, the rolling distance simulation result was 153.56 mm, which was close to the average rolling distance obtained from physical experiments of 155.93 mm, and the relative error was 1.52%; When the surface energy of JKR between soil and PTFE was 4.08 J/m2, the recovery coefficient was 0.6, the static friction coefficient was 0.52 and the rolling friction coefficient was 0.045, the simulation result of rolling distance was 269.35 mm, which was close to the average rolling distance of 269.55 mm obtained from physical experiment, and the relative error was 0.07%. And the optimized parameters can be used to simulate the discrete parameters between the clayey black soil and the soil-engaging components. The study provides credible basic data for the design and simulation of agricultural machinery under clayey black soil conditions. [ABSTRACT FROM AUTHOR]

[Display omitted] • We studied the effects of moisture content, slope angle, and clay contents on mass failure. • A self-designed hollow model was used. • Indoor hollow-flume experiments were conducted under the condition of surface runoff. • Soils with 5%, 7.5%, and 10% initial water content generate fatal mass failure. • Soil mass failure occurs when critical water and clay contents are reached. Soil mass failure disasters are among the most destructive disasters in mountainous areas worldwide, and they continue to receive significant attention in the literature. However, factors that influence soil mass failure in hollows have not been explored via experimental approaches. In this study, we conducted a series of indoor hollow–flume experiments to exhibit how the three factors, namely, initial moisture content, slope angle, and clay content, influence the collapse of soil mass under surface runoff conditions. Our findings revealed that the major processes causing soil mass failure were internal seepage erosion resulting from subsurface runoff, migration of fine particles, development of tension cracks, increase in pore water pressure, and decrease in cohesion. Fluctuations in pore water pressure were characterized by two main trends: (1) an abrupt rise under static liquefaction and (2) a decrease before failure due to dilatancy. The time required for soil mass failure first decreased and then increased with the increase in moisture content. The soil mass with an initial moisture content of ∼12.5% was more critical to the failure. In addition, the time required for soil mass failure decreased with increasing slope angle, revealing a slope angle of 40° to be more prone to failure. The buildup of pore water pressure was found to increase with clay content; soil with a clay content of ∼7.5% required the shortest amount of time to initiate slides. Thus, our results provide a thorough insight into the processes and factors involved in the initiation and development of soil mass failure in hollow areas, which can be used by public agencies to improve monitoring, early warning, and forecasting systems. Notably, our study can help identify risk-prone source areas, and sensors can be installed to monitor potential mass failure locations. [ABSTRACT FROM AUTHOR]

• The contents of (heavy) metals in ML soils were higher than those in YB and DX soils. • ML soils contained more chlorite in clay minerals/soils than YB and DX soils. • The hydroxyl groups with hydrogen bonds were mainly existed in ML soils. • Molecular soil chemistry could affect the accumulation of heavy metals in karst area. Heavy metals with high average background values in soils from karst regions of China have been reported previously. However, the accumulation mechanism of heavy metals in karst soils derived from different parent materials related to the molecular soil chemistry is still unclear. In this study, six soil cores (0–100 cm) from three locations were collected from Hengxian County, a typical karst basin of Guangxi, among which soils of Maling (ML1 and ML2) were derived from the weathering and leaching residues of carbonate rocks, and soils of Yunbiao (YB1 and YB2) and Dengxu (DX1 and DX2) were mainly developed from deposits of Quaternary formations. Soil heavy metal quantification, X-ray diffraction (XRD) analysis, synchrotron radiation-based Fourier transform infrared (SR-FTIR) spectroscopy, and two-dimensional correlation spectroscopy (2DCOS) analysis were combined to study the contents of heavy metals, mineral compositions, and functional assignments in the karst soils. The results showed that the total concentrations of As, Cr, Cd, Cu, Ni, Pb, and Zn in the soils from ML exceeded the risk screening values from the agricultural soil quality standard in China (GB15618-2018), while the contents in the soils from YB and DX were below the risk screening values. The mineral components were significantly different in soils and their clay minerals. ML soils contained more Fe and Mn oxides than YB and DX soils. Furthermore, it was interesting to find extensive existence of chlorite in ML soils (36.73%-39.07%) and their clay minerals (90.49%-90.97%). While illite was the dominant mineral in YB and DX clay fractions (75.08%-100%) and its percentages decreased to 6.06%-35.23% in the soil samples. In addition, ML soils contained the hydroxyl groups with hydrogen bonds (v O-H: 3523, 3450, and 3378 cm−1) and the hydroxyl groups without hydrogen bonds (v O-H: 3698, 3623 cm−1), while YB and DX soils only had the hydroxyl groups without hydrogen bonds (v O-H: 3695, 3622 cm−1). Our study indicated that the accumulation of heavy metals in karst soils from different parent materials was significantly attributed to their molecular soil chemistry. For instance, the higher contents of Fe-Mn oxides and more reactive v O-H (3523, 3450, and 3378 cm−1) and v Si-O (1000 cm−1) assignments could contribute to the higher contents of heavy metals in ML soils compared to the soils from YB and DX. [ABSTRACT FROM AUTHOR]

[Display omitted] • Coarse-textured soil surface morphology evolution is studied by simulated rainfall. • Surface enriched coarse grains are quantified by photography and binarization. • Soil loss in inter-rill areas is controlled by surface coarse-grain coverage. • Soil clay content and stream power is shown to fit erosion prediction. The evolution of slope surface morphology directly affects the hydrological process and forms a dynamic feedback loop with the runoff and sediment production. However, the unique erosion processes and feedback mechanism for the surface morphological changes of coarse-textured granite soils have been rarely studied previously. Here, a series of rainfall simulation experiments (intensity of 90 mm h−1) were conducted under continual intermittent rainfall conditions (duration of 20 h) on a 0.8 m by 3.0 m soil flume packed with the four coarse-textured granite soils (sieved soils from the counties of Tongcheng, Ganxian, Changting, and Wuhua, China, defined as TCA, GXA, CTA and WHA, respectively) to measure the surface roughness, coarse grain coverage, soil erosion rate, stream power and sediment sorting. The results showed: 1) the coarse grain coverage of the four soils gradually increased with rainfall duration, with the final maximum (74.89%) for CTA soil, which corresponded to the enrichment of fine particles in the sediments; 2) the mean soil erosion rate of the four soils ranged from 0.090 to 0.76 kg m−2 min−1 with the decrease of clay content from 24.19% to 13.60% in the original soils, coinciding with the surface roughness controlled by rill erosion around the coarse grains; 3) the coarse grain cover provided a protective layer to reduce further soil loss in inter-rill areas; 4) the model of soil clay content and stream power was shown to be suitable for soil erosion prediction of coarse-textured soils (R2 = 0.93). The results highlighted soil mechanical composition and coarse grain coverage on the surface as the key factors affecting the coarse-textured soil erosion. This study facilitates our understanding of the unique erosion processes and the erosion feedback mechanism of coarse-textured soils. [ABSTRACT FROM AUTHOR]

The evolution of sliding zone soil originating from a muddy interlayer in the Three Gorges Reservoir (TGR) in China is accompanied by an increase in clay content, and the subsequent changes in its mechanical properties control the initiation or reactivation of large-scale bedrock landslides. In this paper, using sliding zone soil samples from the Xingfusi landslide in the Wanzhou area, two groups of remolded saturated specimens were prepared with clay contents of 25.0% and 12.5%. Direct shear creep tests and a series of ring shear tests were carried out to investigate the shear behaviors of the specimens with different clay contents. On this basis, the effect of clay content on the evolution of landslides was discussed. The results show that (1) during the long-term creep process before landslide initiation, the shear creep modulus of sliding zone soil in steady creep state significantly decreases with an increase in clay content, which results in the increase in cumulative creep displacement. (2) The increase in clay content in sliding zone soil will lead to a reduction in peak shear strength and residual frictional resistance. In the drained shearing on saturated sliding zone soil with a high clay content, the excess pore-water pressure on the sliding surface cannot dissipate as rapidly due to the small permeability of sliding zone soil with a high clay content, which may favor postfailure movement. (3) With an increase in shear displacement rate, the residual strength first shows a weak "negative shear rate effect" and then shows a significant "positive shear rate effect". However, with an increase in clay content, the initial shear rate for the residual strength showing a "positive rate effect" will decrease. (4) Sliding zone soil with a high clay content generally does not exhibit strength recovery, while sliding zone soil with a low clay content clearly recovers its peak residual strength due to volume change of the shear zone caused by secondary compression after a long period of reconsolidation. In this case, a greater external load or reduction in effective normal stress needs to be applied to reactivate the landslide. • An increase in clay content of sliding zone soil results in the increase in cumulative creep displacement. • High clay content decreases the initial shear rate for the residual strength showing a "positive rate effect". • The effect of clay content on the strength recovery of sliding zone soil was revealed. • The effect of clay content on the whole evolution of landslides was explained. [ABSTRACT FROM AUTHOR]

• Soil hydrological properties (HPs) were determined using borehole nuclear magnetic resonance technique. • Fractal and multifractal dimensions are effective parameters for estimating soil HPs. • Capillary water dominates soil total water in alpine soils. • Alpine vegetation alters the relationship between soil PSD and HPs. The soil hydrological properties (HPs) in active layers regulate soil water migration and affect the evolution of permafrost and biogeochemical cycles. There is relatively little understanding of the changes in soil HPs as a result of soil particle-size distribution (PSD) in the permafrost regions of the Qinghai–Tibet Plateau. In this study, different land-cover types, namely alpine wet meadow (AWM), extremely degraded wet meadow (EDWM), alpine meadow (AM), degraded alpine meadow (DAM), alpine steppe (AS), and alpine desert (AD), were used to determine the relationships between soil PSD and HPs. Soil HPs were determined using borehole nuclear magnetic resonance, and soil PSD (0–2 mm) was analyzed using fractal and multifractal theory. The results showed that vegetation degradation caused coarse soil particle accumulation in the root zone, reflected by the soil single-fractal dimension (D v : 2.12–2.50). The D v values showed significant positive correlations with soil clay and silt content as well as a negative correlation with sand content. Results from the generalized fractal and singularity spectra suggested an even distribution of soil particles in the root zone of the AWM, AM, and AD sites. Vegetation degradation increased the soil PSD capacity dimension (D 0), information dimension (D 1), correlation dimension, D 1 / D 0 ratio, and Hölder exponent of order zero. This was indicative of a narrow soil PSD range and non-uniform soil texture in the root zone. Although capillary water dominated the total soil water content in the alpine soils, soil water composition was also dependent on the vegetation type and soil stratigraphic distribution. Soil particle composition and multifractal dimensions were found to be effective parameters for forecasting soil HPs in the non-root zone of alpine soils. However, the presence of vegetation weakens the relationship between soil PSD and HPs. This study contributes to the accurate evaluation of hydrological and biogeochemical cycles in permafrost regions. [ABSTRACT FROM AUTHOR]

• Alkaline coarse-textured soils had larger PFPs' density than acid fine-textured soils. • Longer history of PSVP had significant contribution to the density of soil PFPs. • Soil physical and P sorption properties significantly influenced the occurrence of PFPs. • PFPs had significant impact on leaching of dissolved reactive P from PSVP soils. • Particulate P leaching from PSVP soils mostly occurred through soil matrix. Despite its importance, the contribution of preferential flow pathways (PFPs) to subsurface phosphorus (P) leaching from heavily-fertilized plastic shed vegetable production (PSVP) soils in China has remained unexplored. To investigate this, five acid fine-textured Orthic Anthrosols and six alkaline coarse-textured Ustic Cambosols intact soil columns (20 cm depth and 15 cm diameter), from two typical PSVP systems in Jiangsu Province, Southeast China, were subjected to six leaching experiments with collection of effluents over 24 h. Leachate samples were analyzed for their concentrations of particulate P (PP) and dissolved reactive P (DRP). Finally, soil columns were photographed for their 2D distribution of PFPs both vertically (0−20 cm) and horizontally at 5 cm intervals after the application of dye tracer (Brilliant Blue). Overall, alkaline coarse-textured Ustic Cambosols with longer history of PSVP had larger PFPs' volumes than acid fine-textured Orthic Anthrosols with vertical (0−20 cm) values ranging from 812 to 1260 cm2 and 623 to 1104 cm2, respectively. Of soil properties, pH and sand content had significant positive correlations with PFPs' density (p < 0.05). Whereas, soil contents of clay and oxalate extractable Al and Fe had significant negative correlations with PFPs' density (p < 0.05). In terms of subsurface P mobilization, preferential water flow had significant impact on DRP leaching (p < 0.05). In contrast, leachate PP concentrations had no significant relationships with both vertical and horizontal PFPs, indicating that PP leaching might occur mostly through soil matrix. However, field assays are still essential for better understanding of P leaching in relation to PFPs through taking into account the soil physiochemical properties and agricultural management. [ABSTRACT FROM AUTHOR]

• SEM analyses explained 12.0–46% of the variations in soil K. • Climate acted as the most important factor controlling the variations in soil K. • Topographical conditions were the secondary controls of soil K variations. • Key soil properties and clay mineral showed less effect on soil K variations. • Climate, topography and clay mineral all exhibited indirect effect on soil K variations. Climatic, topographical and soil conditions are the main drivers of soil potassium (K) variations in terrestrial ecosystem. Although theoretical and empirical studies have explored the single effect of these factors on the variations of soil K, the complex interactions and relative importance of these factors is scarce worldwide and virtually absent for China agricultural ecosystem. Here, the complex interactions and the relative contributions of the environmental variables (climate, topography, key soil properties and clay mineralogical composition) to soil K variations were evaluated in China agricultural soil by using method of structural equation model (SEM). The SEM analyses explained 12.0%, 46% and 28.8% of the variations in soil exchangeable K (EK), nonexchangeable K (NEK) and total K (TK), respectively. The results also showed that climate acted as the most important factor controlling soil K variations, followed by topographical conditions, clay mineralogical composition, and key soil properties. High temperature and precipitation (climate) had directly negative effects on soil K concentrations and the negative effects were strengthened by its impacts on key soil properties and clay mineralogical composition. The effects of topography on soil K concentrations were enhanced by its effects on climate, key soil properties and soil clay mineralogical composition. Soil clay mineralogical composition affected soil K concentrations both directly and indirectly through influencing key soil properties. The unexplained variations in soil K concentrations are due to lack of data related to crop species, finer soil particles content, and the quantity and quality of K inputs. These findings advance the understanding of the patterns and mechanisms driving soil K variations, which is critical for predicting changes in soil nutrients in response to soil forming environment at the global scale. [ABSTRACT FROM AUTHOR]