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• Six obsidian sources increased their use in the Late Holocene in north Patagonia. • The closer source to Diamante Valley, is the least used. • The best quality source, Las Cargas, was the most used across the Late Holocene. • Obsidian helped to minimize risk in the occupation of high elevation locations. • Obsidian exchange routes may find a pattern in least cost path analysis results. • Exchange of obsidian followed routes through High elevations villages to sources. In this paper we explore obsidian conveyance in the Diamante Valley, in northwestern Patagonia, Argentina. Obsidian is the third most-common toolstone used in the Diamante Valley after basalts and local cryptocrystallines. Obsidian artifacts are predominantly projectile points and bifaces, with few cores and early-stage reduction debris. To explain these patterns, we conducted XRF sourcing and technological analysis of 177 obsidian artifacts collected there. We also conducted a GIS-based least cost path analysis to assess the costs of conveying obsidian from sources to sites in the Diamante watershed. We found that hunter-gatherers used Las Cargas as the principal obsidian source, followed by Maule 1 and 2, El Peceño, and Coche Quemado. The nearest source, Laguna del Diamante, was the least used. These data, combined with an analysis of the ways cores, formed tools, and debitage types were conveyed and ultimately deposited at sites in the Diamante watershed, suggest a late Holocene pattern of highland-oriented indirect access, implying highland village sites likely served as nodes in a regional and extraregional exchange network focused not only on obsidian but also on other goods, information, and social obligations. [ABSTRACT FROM AUTHOR]