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1. Synthesis of furoxan derivatives: DABCO-mediated cascade sulfonylation/cyclization reaction of α-nitro-ketoximes.

Author

Zhao, Jian-Qiang, Zhou, Ming-Qiang, Zuo, Jian, Xu, Xiao-Ying, Zhang, Xiao-Mei, and Yuan, Wei-Cheng

Subjects
*CHEMICAL synthesis, *FURAZANS, *CHEMICAL derivatives, *RING formation (Chemistry), *SULFONYL chlorides
Abstract

A convenient and efficient method for the synthesis of furoxan derivatives from α-nitro-ketoximes and sulfonyl chlorides is reported. A wide variety of furoxan derivatives were smoothly obtained in good yields via a DABCO-mediated cascade sulfonylation/cyclization process under mild conditions. The usefulness of this method was also demonstrated by the conversions of the furoxan products into other promising compounds. [ABSTRACT FROM AUTHOR]

Published
2015
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