6 results on '"Vivek Mariappan"'
Search Results
2. Quantum chemical and experimental studies on the extraction of acid blue 80 and acid red 1 from their aquatic environment using tetrabutylammonium bromide based deep eutectic solvents
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Thamby, Beevi Fathima Mohamed, Santhi, Vivek Mariappan, and Ramalingam, Anantharaj
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Polymers and Plastics ,Physical and Theoretical Chemistry ,Surfaces, Coatings and Films - Abstract
In this study, the highest occupied molecular orbital (HOMO) energy, the lowest unoccupied molecular orbital (LUMO) energy, HOMO–LUMO energy gap, chemical potential (µ), electronegativity (χ), electrophilicity index (ω), global hardness (η), and global softness (s) of dyes; acid blue 80 (AB80), acid red 1 (AR1) and deep eutectic solvents: tetrabutylammonium bromide with glycerol {[TBAB][Gly]}, tetrabutylammonium bromide with decanoic acid {[TBAB][DA]} and tetrabutylammonium bromide with oleic acid {[TBAB][OA]} were predicted and calculated using quantum chemical calculation. The polarity of all the studied molecules also predicted in terms of screening charge density and plotted sigma profile and sigma potential. Further, the extraction experiment was conducted for the extraction of acid blue 80 (AB80) and acid red 1 (AR1) using tetrabutylammonium bromide with decanoic acid {[TBAB][DA]} and tetrabutylammonium bromide with oleic acid {[TBAB][OA]} as the potential solvent. The process was characterized by means of distribution coefficient and efficiency. Finally, the extraction process feasibility was studied and discussed in terms of ΔGT0, ΔHT0, and ΔST0.
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- 2023
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3. Deep eutectic solvents on extraction of bisphenol A from water matrices: COnductor like Screening MOdel for Real Solvents prediction and experimental validation
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Swaanika Lakshmi Narasimhan, Divya Lakshmi Parthasarathy, Anantharaj Ramalingam, Priyadarshini Seshasayee, and Vivek Mariappan Santhi
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chemistry.chemical_compound ,Bisphenol A ,Materials science ,chemistry ,Chemical engineering ,Renewable Energy, Sustainability and the Environment ,General Chemical Engineering ,Extraction (chemistry) ,Experimental validation ,Waste Management and Disposal ,Deep eutectic solvent ,Eutectic system ,Conductor - Published
- 2021
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4. Ammonium based deep eutectic solvents (DESs) on extraction of benzothiophene from iso-octane: experiment and COSMO-RS model
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Chandramohan Ayyavu, Vichitra Malaiyarasan, Deepthi Jayachandran Sreekala, Anantharaj Ramalingam, and Vivek Mariappan Santhi
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Ammonium bromide ,Polymers and Plastics ,Extraction (chemistry) ,Benzothiophene ,02 engineering and technology ,Decanoic acid ,021001 nanoscience & nanotechnology ,Surfaces, Coatings and Films ,Deep eutectic solvent ,COSMO-RS ,chemistry.chemical_compound ,020401 chemical engineering ,chemistry ,0204 chemical engineering ,Physical and Theoretical Chemistry ,0210 nano-technology ,Nuclear chemistry ,Octane ,Eutectic system - Abstract
Densities of pure benzothiophene (BT), iso-octane (ISO), and tetra butyl ammonium bromide decanoic acid {[TBAB][DA]} as deep eutectic solvent and their binary mixtures of [BT] + [ISO], [BT] + {[TBAB][DA]} and {[TBAB][DA]} + [ISO] over the entire mole fractions were measured at different temperatures 303.15 K–353.15 K at 1 atm. From this measured density data, the solution thermodynamic properties such as excess molar volume, partial molar volume, excess partial molar volumes, apparent molar volume, isobaric expansivity, and excess isobaric expansivity were calculated. Further, this calculated excess molar volume data were correlated by Redlich-Kister polynomial fit equation. Subsequently, liquid–liquid extraction (LLE) experiment were conducted for the removal of BT from ISO using {[TBAB + DA]} at 298.15 K and 1 atm. This LLE process was characterized in terms of distribution coefficient and selectivity and thermodynamic consistency test were done by Othmer-Tobias and Hand Equations. Finally, the sigma (σ) profile and sigma (σ) potential of all the studied species were generated and analyzed using COSMO-RS model.
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- 2021
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5. Our Experience with Maxillectomies: A Retrospective Decade Study
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M. K. Rajasekar, Narendrakumar Veerasigamani, and Vivek Mariappan
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Otorhinolaryngology ,business.industry ,Medicine ,business - Abstract
Objective The aim of the study is to evaluate the age, sex, site of lesion, histopathological diagnosis, and recurrence rate of the maxillectomy patients. Materials and methods A retrospective study was done in 42 patients, who underwent maxillectomy for malignant growth of the nose and paranasal sinuses from 2006 to 2015 at our center. Results The most common age group is 55 to 65 years (73.8), with male predominance (66.7%). Among symptoms prevalent is nasal obstruction (47%). Maxillary sinus is the most common site of origin (61.9%). Squamous cell carcinoma is the most common histopathological diagnosis (52.4%) and recurrence rate is 16%. Conclusion Exact clearance, reconstruction, postoperative care, and perfect teamwork play a vital role. Thus, successful outcome of maxillectomy is multifactorial. How to cite this article Rajasekar MK, Mariappan V, Veerasigamani N. Our Experience with Maxillectomies: A Retrospective Decade Study. Clin Rhinol An Int J 2017;10(2):58-61.
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- 2009
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6. The SDSS-IV extended Baryon Oscillation Spectroscopic Survey: final emission line galaxy target selection
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Gong-Bo Zhao, J. A. Newmann, Jean-Paul Kneib, N. Palanque-Delabrouille, Arjun Dey, Timothée Delubac, Eric Jullo, Kyle S. Dawson, Dustin Lang, Ch. Yèche, Guangtun Zhu, John Moustakas, Julian E. Bautista, Will J. Percival, Jeremy L. Tinker, Anand Raichoor, Francisco Prada, Y. Wang, Hee-Jong Seo, Johan Comparat, David J. Schlegel, Ashley J. Ross, Vivek Mariappan, Claudio Gorgoni, Joel R. Brownstein, Département de Physique des Particules (ex SPP) (DPhP), Institut de Recherches sur les lois Fondamentales de l'Univers (IRFU), Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université Paris-Saclay-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université Paris-Saclay, Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université Paris-Saclay, Laboratoire d'Astrophysique de Marseille (LAM), Aix Marseille Université (AMU)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National d'Études Spatiales [Toulouse] (CNES)-Centre National de la Recherche Scientifique (CNRS), EPFL Laboratoire d’astrophysique, Ecole Polytechnique Fédérale de Lausanne (EPFL), Département de Physique des Particules (ex SPP) (DPP), Centre National de la Recherche Scientifique (CNRS)-Institut national des sciences de l'Univers (INSU - CNRS)-Aix Marseille Université (AMU)-Centre National d'Études Spatiales [Toulouse] (CNES), Institut de Recherches sur les lois Fondamentales de l'Univers ( IRFU ), Commissariat à l'énergie atomique et aux énergies alternatives ( CEA ) -Université Paris-Saclay, Laboratoire d'Astrophysique de Marseille ( LAM ), and Aix Marseille Université ( AMU ) -Institut national des sciences de l'Univers ( INSU - CNRS ) -Centre National d'Etudes Spatiales ( CNES ) -Centre National de la Recherche Scientifique ( CNRS )
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Cosmology and Nongalactic Astrophysics (astro-ph.CO) ,Stellar population ,media_common.quotation_subject ,[ PHYS.ASTR ] Physics [physics]/Astrophysics [astro-ph] ,astro-ph.GA ,FOS: Physical sciences ,Astrophysics ,Astrophysics::Cosmology and Extragalactic Astrophysics ,01 natural sciences ,[PHYS.ASTR.CO]Physics [physics]/Astrophysics [astro-ph]/Cosmology and Extra-Galactic Astrophysics [astro-ph.CO] ,0103 physical sciences ,Emission spectrum ,010303 astronomy & astrophysics ,STFC ,Astrophysics::Galaxy Astrophysics ,media_common ,Physics ,ST/N00180X/1 ,010308 nuclear & particles physics ,Oscillation ,Astronomy ,RCUK ,Astronomy and Astrophysics ,Redshift survey ,Astrophysics - Astrophysics of Galaxies ,methods: data analysis ,Galaxy ,Redshift ,Baryon ,galaxies: photometry ,Space and Planetary Science ,Sky ,Astrophysics of Galaxies (astro-ph.GA) ,cosmology: observations ,astro-ph.CO ,galaxies: stellar content ,ST/N000668/1 ,large-scale structure of Universe ,galaxies: distances and redshifts ,[PHYS.ASTR]Physics [physics]/Astrophysics [astro-ph] ,Astrophysics - Cosmology and Nongalactic Astrophysics - Abstract
We describe the algorithm used to select the Emission Line Galaxy (ELG) sample at $z \sim 0.85$ for the extended Baryon Oscillation Spectroscopic Survey of the Sloan Digital Sky Survey IV, using photometric data from the DECam Legacy Survey. Our selection is based on a selection box in the $g-r$ vs. $r-z$ colour-colour space and a cut on the $g$-band magnitude, to favour galaxies in the desired redshift range with strong [OII] emission. It provides a target density of 200 deg$^{-2}$ on the North Galactic Cap (NGC) and of 240 deg$^{-2}$ on the South Galactic Cap (SGC), where we use a larger selection box because of deeper imaging. We demonstrate that this selection passes the eBOSS requirements in terms of homogeneity. About 50,000 ELGs have been observed since the observations have started in 2016, September. These roughly match the expected redshift distribution, though the measured efficiency is slightly lower than expected. The efficiency can be increased by enlarging the redshift range and with incoming pipeline improvement. The cosmological forecast based on these first data predict $\sigma_{D_V}/D_V = 0.023$, in agreement with previous forecasts. Lastly, we present the stellar population properties of the ELG SGC sample. Once observations are completed, this sample will be suited to provide a cosmological analysis at $z \sim 0.85$, and will pave the way for the next decade of massive spectroscopic cosmological surveys, which heavily rely on ELGs. The target catalogue over the SGC will be released along with DR14., Comment: Submitted to MNRAS, 18 pages
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