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1. Spin-Crossover Phenomenon in Microcrystals and Nanoparticles of a [Fe(2-mpz)2Ni(CN)4] Two-Dimensional Hofmann-Type Polymer: A Detailed Nano-Topographic Study

Author

Polyzou, Christina D., Malina, Ondřej, Tuček, Jiri, Zbořil, Radek, Panagiotou, Nikos, Tasiopoulos, Anastasios J., Boukos, Nikos, Parthenios, John, Kalarakis, Alexandros N., Tangoulis, Vassilis, Tasiopoulos, Anastasios J. [0000-0002-4804-3822], Boukos, Nikos [0000-0001-7542-0649], Kalarakis, Alexandros N. [0000-0002-9387-6612], and Tangoulis, Vassilis [0000-0002-2039-2182]

Subjects
chemistry.chemical_classification, 010405 organic chemistry, Atomic force microscopy, Nanoparticle, Polymer, 010402 general chemistry, 01 natural sciences, 0104 chemical sciences, Inorganic Chemistry, Crystallography, Microcrystalline, chemistry, Spin crossover, Nano, Diamagnetism, Physical and Theoretical Chemistry, Isostructural
Abstract

The diamagnetic two-dimensional Hofmann-type metal–organic framework [ZnII(2-mpz)2Ni(CN)4] has been successfully synthesized along with its isostructural hysteretic spin-crossover FeII analogue in the form of both bulk microcrystalline powder and nanoparticles. Detailed atomic force microscopy topographic study revealed a nanogrowth relationship between the height and length of the nanoparticle. 58 20 13733 13736

Published
2019
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