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This article presents the spectral parameter maps used in this Surface Composition of Ceres Special Issue. The definition and use of spectral parameters has always played a fundamental role in understanding the properties and composition of a planetary surface. Mapping proper spectral parameters shows the global mineralogical diversity across Ceres. In this work, we discuss the production process of Ceres spectral parameter maps derived by the data of the Visible and Infrared mapping spectrometer (VIR) onboard NASA’s Dawn mission. We describe the data processing of the VIR spectra and the procedure to retrieve the geometries (latitude, longitude and illumination angles) of the acquired data. Spectra and geometries are used to project and mosaic this data to produce Geographic Information System-compatible spectral parameters maps of Ceres. An overview of the variability of the data across the quadrangles is given, addressing the specific analysis to each quadrangle mapping paper included in this special issue.

This paper focuses on the identification and distribution of compositional units and their stratigraphic relationships in the Fejokoo quadrangle of Ceres (Ac-5) located between 21–66°N and 270–360°E and named after one of its prominent and well-preserved impact craters, Fejokoo (centered at 26°N and 312°E). In this quadrangle, we observed that hydroxylated- (OH-rich) and ammoniated- (NH4-rich) phyllosilicates are present everywhere, in various abundances; low abundance is observed on bright terrains and higher abundances are observed on lobate materials associated with craters. Carbonates are mostly correlated with the high-albedo areas surrounding Oxo (359.7°E, 42.2°N) and other major craters, and are mixed with Ceres’ most common surface composition type (i.e. low albedo, phyllosilicate-rich material). There are a few locations where carbonates and phyllosilicates co-exist, indicating a range of geological or chemical processes produced them in co-existence. No correlation between the surface composition and the age of the craters was found. Instead, the composition observed on impact craters depends on the size of the impact and the composition of the different stratigraphic layers excavated. The compositional interpretation inferred from Dawn's visible-infrared spectrometer data of the Fejokoo quadrangle is consistent with the presence of an internal ocean that produced carbonates and phyllosilicates via aqueous alteration of minerals.

Rosetta observes sublimating surface icesComets are “dirty snowballs” made of ice and dust, but they are dark because the ice sublimates away, leaving some of the dust behind on the surface. The Rosetta spacecraft has provided a close-up view of the comet 67P/Churyumov-Gerasimenko as it passes through its closest point to the Sun (see the Perspective by Dello Russo). Filacchioneet al.detected the spectral signature of solid CO2(dry ice) in small patches on the surface of the nucleus as they emerged from local winter. By modeling how the CO2sublimates, they constrain the composition of comets and how ices generate the gaseous coma and tail. Fornasieret al.studied images of the comet and discovered bright patches on the surface where ice was exposed, which disappeared as the ice sublimated. They also saw frost emerging from receding shadows. The surface of the comet was noticeably less red just after local dawn, indicating that icy material is removed by sunlight during the local day.Science, this issue p.1563, p.1566; see also p.1536

On 6 March 2015, Dawn arrived at Ceres to find a dark, desiccated surface punctuated by small, bright areas. Parts of Ceres’ surface are heavily cratered, but the largest expected craters are absent. Ceres appears gravitationally relaxed at only the longest wavelengths, implying a mechanically strong lithosphere with a weaker deep interior. Ceres’ dry exterior displays hydroxylated silicates, including ammoniated clays of endogenous origin. The possibility of abundant volatiles at depth is supported by geomorphologic features such as flat crater floors with pits, lobate flows of materials, and a singular mountain that appears to be an extrusive cryovolcanic dome. On one occasion, Ceres temporarily interacted with the solar wind, producing a bow shock accelerating electrons to energies of tens of kilovolts.

[1] The Framing Camera (FC) on the Dawn spacecraft provided the first view of 4 Vesta at sufficiently high spatial resolution to enable a detailed correlation of the asteroid's spectral properties with geologic features and with the vestoid (V-type) asteroids and the Howardite-Eucrite-Diogenite (HED) class of meteorites, both of which are believed to originate on Vesta. We combine a spectral analysis of the basin with visible and near-IR spectroscopy of vestoids and with archived data over the same spectral range for HED meteorites. The vestoids are only slightly more akin to the Rheasilvia basin than to Vesta as a whole, suggesting that the crustal material ejected is a well-mixed collection of eucritic and diogenitic materials. The basin itself is more diogenitic, implying Vesta is differentiated and the impact that created Rheasilvia uncovered a mineralogically distinct layer. The Rheasilvia basin exhibits a larger range in pyroxene band strengths than Vesta as a whole, further implying that the basin offers a view into a complex, differentiated protoplanet. The discrepancy between the spectral properties of the HED meteorites and Vesta, in particular the meteorites' deeper pyroxene absorption band and the redder color of the vestoids, can be explained by the abundance of smaller particles on Vesta and by the addition of low-albedo exogenous particles to its surface, which in turn are due to its larger gravity and longer exposure time to impact processing. Solar phase effects are slight and do not explain the spectral discrepancies between the HEDs, Vesta, and the vestoids.

The Dawn mission was designed to test our hypothesis about the origin and evolution of the early solar system by visiting the largest differentiated basaltic asteroid, 4 Vesta, believed to be a survivor from the earliest times of rocky body formation. Observations from orbit show that Vesta is the parent body of the Howardite, Eucrite, Diogenite meteorites. Vesta has an iron core and a eucritic–diogenitic crust. Its surface is characterized by abundant impact craters but with no evident volcanic features. It has two ancient impact basins in the southern hemisphere that are associated with circum-planetary troughs. The northern hemisphere is the more heavily cratered and contains the oldest terrains. The surface of Vesta is diverse, with north-south and east-west dichotomies in the eucrite-to-diogenite ratio. Its surface contains both very bright and very dark material, and its color varies strongly from region to region. Both the mineralogical and the elemental compositions agree with that expected for the HED parent body. Significant OH or H may be present in the upper crust and the presence of pits in “fresh” craters is consistent with the devolatilization of the surface after a collision either brought to or tapped a source of water on Vesta. The presence of dark material on the surface of Vesta suggests efficient transport pathways for organic material, and the mixing of the dark material with the more pristine pyroxene explains the varying albedo across the surface. Vesta has proven to be a reliable witness to the formation of the solar system.

Whereas space weathering of some airless bodies, such as the Moon, occurs through the accumulation on regolith of nanophase metallic particles, spectroscopic data show that space weathering of the asteroid Vesta occurs through the small-scale mixing of diverse surface components, which gradually generates locally homogenized upper regolith. Between 16 July 2011 and 5 September 2012, NASA's space probe Dawn was orbiting Vesta, a protoplanet thought to have survived virtually intact since an early phase of Solar System formation. In this issue of Nature, two groups report on the encounter. Carle Pieters and co-workers find that space weathering on Vesta has followed a different course from that observed on the Moon and on Itokawa, the asteroid sampled in an Earth-return mission. On Vesta, weathering involved fine-scale regolith (soil) mixing that has removed clear traces of recent impact deposits. There are no signs of the nanophase metallic-particle deposits seen on the Moon and Itokawa. Thomas McCord and co-authors describe two main types of material on Vesta's surface: bright and dark. The bright material may be uncontaminated indigenous Vesta basaltic soil, with the darker material derived from low-albedo impactors. Dawn has now moved on and is due to rendezvous with the protoplanet Ceres in February 2015. The surface of the asteroid Vesta has prominent near-infrared absorption bands characteristic of a range of pyroxenes, confirming a direct link to the basaltic howardite–eucrite–diogenite class of meteorites1,2,3. Processes active in the space environment produce ‘space weathering’ products that substantially weaken or mask such diagnostic absorption on airless bodies observed elsewhere4,5, and it has long been a mystery why Vesta’s absorption bands are so strong. Analyses of soil samples from both the Moon6 and the asteroid Itokawa7 determined that nanophase metallic particles (commonly nanophase iron) accumulate on the rims of regolith grains with time, accounting for an observed optical degradation. These nanophase particles, believed to be related to solar wind and micrometeoroid bombardment processes, leave unique spectroscopic signatures that can be measured remotely8,9,10 but require sufficient spatial resolution to discern the geologic context and history of the surface, which has not been achieved for Vesta until now. Here we report that Vesta shows its own form of space weathering, which is quite different from that of other airless bodies visited. No evidence is detected on Vesta for accumulation of lunar-like nanophase iron on regolith particles, even though distinct material exposed at several fresh craters becomes gradually masked and fades into the background as the craters age. Instead, spectroscopic data reveal that on Vesta a locally homogenized upper regolith is generated with time through small-scale mixing of diverse surface components.

We apply a multivariate statistical method to Titan data acquired by different instruments onboard the Cassini spacecraft. We have searched through Cassini/VIMS hyperspectral cubes, selecting those data with convenient viewing geometry and that overlap with Cassini/RADAR scatterometry footprints with a comparable spatial resolution. We look for correlations between the infrared and microwave ranges the two instruments cover. Where found, the normalized backscatter cross-section obtained from the scatterometer measurement, corrected for incidence angle, and the calibrated antenna temperature measured along with the scatterometry echoes, are combined with the infrared reflectances, with estimated errors, to produce an aggregate data set, that we process using a multivariate classification method to identify homogeneous taxonomic units in the multivariate space of the samples. In medium resolution data (from 20 to 100 km/pixel), sampling relatively large portions of the satellite’s surface, we find regional geophysical units matching both the major dark and bright features seen in the optical mosaic. Given the VIMS cubes and RADAR scatterometer passes considered in this work, the largest homogeneous type is associated with the dark equatorial basins, showing similar characteristics as each other on the basis of all the considered parameters. On the other hand, the major bright features seen in these data generally do not show the same characteristics as each other. Xanadu, the largest continental feature, is as bright as the other equatorial bright features, while showing the highest backscattering coefficient of the entire satellite. Tsegihi is very bright at 5 μm but it shows a low backscattering coefficient, so it could have a low roughness on a regional scale and/or a different composition. Another well-defined region, located southwest of Xanadu beyond the Tui Regio, seems to be detached from the surrounding terrains, being bright at 2.69, 2.78 and 5 μm but having a low radar brightness. In this way, other units can be found that show correlations or anti-correlations between the scatterometric response and the spectrophotometric behavior, not evident from the optical remote sensing data.

We report the detailed analysis of the spectrophotometric properties of Saturn’s icy satellites as derived by full-disk observations obtained by visual and infrared mapping spectrometer (VIMS) experiment aboard Cassini. In this paper, we have extended the coverage until the end of the Cassini’s nominal mission (June 1st 2008), while a previous paper ( Filacchione, G., and 28 colleagues [2007]. Icarus 186, 259–290 , hereby referred to as Paper I) reported the preliminary results of this study. During the four years of nominal mission, VIMS has observed the entire population of Saturn’s icy satellites allowing us to make a comparative analysis of the VIS–NIR spectral properties of the major satellites (Mimas, Enceladus, Tethys, Dione, Rhea, Hyperion, Iapetus) and irregular moons (Atlas, Prometheus, Pandora, Janus, Epimetheus, Telesto, Calypso, Phoebe). The results we discuss here are derived from the entire dataset available at June 2008 which consists of 1417 full-disk observations acquired from a variety of distances and inclinations from the equatorial plane, with different phase angles and hemispheric coverage. The most important spectrophotometric indicators (as defined in Paper I: I / F continua at 0.55 μm, 1.822 μm and 3.547 μm, visible spectral slopes, water and carbon dioxide bands depths and positions) are calculated for each observation in order to investigate the disk-integrated composition of the satellites, the distribution of water ice respect to “contaminants” abundances and typical regolith grain properties. These quantities vary from the almost pure water ice surfaces of Enceladus and Calypso to the organic and carbon dioxide rich Hyperion, Iapetus and Phoebe. Janus visible colors are intermediate between these two classes having a slightly positive spectral slope. These results could help to decipher the origins and evolutionary history of the minor moons of the Saturn’s system. We introduce a polar representation of the spectrophotometric parameters as function of the solar phase angle (along radial distance) and of the effective longitude interval illuminated by the Sun and covered by VIMS during the observation (in azimuth) to better investigate the spatial distribution of the spectrophotometric quantities across the regular satellites hemispheres. Finally, we report the observed spectral positions of the 4.26 μm band of the carbon dioxide present in the surface material of three outermost moons Hyperion, Iapetus and Phoebe.

Lunar Water The Moon has been thought to be primarily anhydrous, although there has been some evidence for accumulated ice in permanently shadowed craters near its poles (see the Perspective by Lucey , published online 24 September). By analyzing recent infrared mapping by Chandrayaan-1 and Deep Impact, and reexamining Cassini data obtained during its early flyby of the Moon, Pieters et al. (p. 568 , published online 24 September), Sunshine et al. (p. 565 , published online 24 September), and Clark et al. (p. 562 , published online 24 September) reveal a noticeable absorption signal for H 2 O and OH across much of the surface. Some variability in water abundance is seen over the course of the lunar day. The data imply that solar wind is depositing and/or somehow forming water and OH in minerals near the lunar surface, and that this trapped water is dynamic.

Material of low geometric albedo (pV⩽0.1pV⩽0.1) is found on many objects in the outer Solar System, but its distribution in the saturnian satellite system is of special interest because of its juxtaposition with high-albedo ice. In the absence of clear, diagnostic spectral features, the composition of this low-albedo (or “dark”) material is generally inferred to be carbon-rich, but the form(s) of the carbon is unknown. Near-infrared spectra of the low-albedo hemisphere of Saturn's satellite Iapetus were obtained with the Visible–Infrared Mapping Spectrometer (VIMS) on the Cassini spacecraft at the fly-by of that satellite of 31 December 2004, yielding a maximum spatial resolution on the satellite's surface of ∼65 km. The spectral region 3–3.6 μm reveals a broad absorption band, centered at 3.29 μm, and concentrated in a region comprising about 15% of the low-albedo surface area. This is identified as the CH stretching mode vibration in polycyclic aromatic hydrocarbon (PAH) molecules. Two weaker bands attributed to CH2 stretching modes in aliphatic hydrocarbons are found in association with the aromatic band. The bands most likely arise from aromatic and aliphatic units in complex macromolecular carbonaceous material with a kerogen- or coal-like structure, similar to that in carbonaceous meteorites. VIMS spectra of Phoebe, encountered by Cassini on 11 June 2004, also show the aromatic hydrocarbon band, although somewhat weaker than on Iapetus. The origin of the PAH molecular material on these two satellites is unknown, but PAHs are found in carbonaceous meteorites, cometary dust particles, circumstellar dust, and interstellar dust.

ESA's Mars Express has successfully completed its nominal mission of one Martian year covering about 25% of the surface in stereo and color with resolutions up to 10 m/pixel by its high-resolution stereo camera (HRSC). Mars Express is now in its extended mission phase, during which much of the remaining part of the Martian surface is envisaged to be covered in stereo and color. The HRSC instrument is designed to map the morphology, topography, structure and geologic context of the surface as well as atmospheric phenomena. This paper discusses the measurement principles and operations of the instrument as well as the acquisition, calibration and processing of regional and global data sets. As HRSC is a push-broom scanning instrument with nine CCD line detectors mounted in parallel on a focal plane, its unique feature is the ability to obtain near-simultaneous imaging data at high resolution, with along-track triple stereo, four colors and five different phase angles, avoiding any time-dependent variations of the observing conditions. The HRSC spatial resolution is 10 m/pixel at the nominal periapsis altitude of 250 km, with an image swath of 53 km, and 2.3 m/pixel for an additional framing CCD device, called super resolution channel (SRC), practically working as an additional tenth channel of the HRSC and yielding nested-in black and white images for studies of small-scale geologic features. The sub-pixel accuracy of the three-dimensional point determination allows the derivation of digital terrain models (DTMs) with a grid size of up to 50 m and a height accuracy of a single pixel with up to 10 m, thus enabling us to carry out detailed quantitative analyses of the surface structure. The HRSC (1) bridges the gap between the medium–high-resolution Viking imagery and the very-high-resolution Global Surveyor mission, thus providing geological context, and (2) fills the gaps in the three-dimensional coverage and DTM grid of the MOLA laser altimetry data, and (3) helps characterize landing sites for in-situ measurements. HRSC also builds the basis for extended compositional mapping when combining spectral information with topographic photomaps over large areas. So far the HRSC measurements have made a significant contribution to the study of the evolution of volcanism and the role of water and ice throughout the Martian history.

International audience; In this report, we describe the journey Dawn has taken in the recent past, its present status, and its future mission. The overall objective of Dawn is to explore backward in time via its observations of the primitive bodies, Vesta and Ceres. Thus Dawn embarks on three journeys. The first is its tumultuous temporal terrestrial trek during development. The second is its soon-to-be voyage in space to 4 Vesta, the second most massive asteroid in the main belt, and to 1 Ceres, the most massive. The third is its journey backward in time to infer the conditions as the solar system was formed. Finally, we discuss how it is possible to go back even further in time, beyond the horizon of the Dawn mission to obtain "pre Dawn" observations at 10 Hygiea, the fourth most massive asteroid, and one more primitive than Vesta and Ceres.

Absorption bands in the infrared reflectance spectra from the Galileo Near-Infrared Mapping Spectrometer (NIMS) which are attributed to the presence of CO2 and SO2 on the surface of Callisto have been analyzed and mapped in detail. CO2 of varying concentrations appears to exist everywhere on Callisto, except at higher latitudes, where it may be masked by frost. The CO2 concentration on the trailing hemisphere has a longitudinal distribution largely consistent with a sinusoid centered on the equator near 270° longitude. The approximately sinusoidal pattern suggests that exogenic effects related to Jupiter's corotating magnetic field are involved. Closer inspection of both hemispheres reveals that in many cases, visibly bright and ice-rich impact craters have high CO2 concentrations within or near them. The CO2 sometimes appears to be associated more with dark material near the craters than with the water ice. These correlations suggest impact processes may also affect the distribution of CO2 on the surface of Callisto. The center of the absorption band has been refined to be at 4.258±0.004 μm. The presence of a single band shape and band minimum wavelength position in all data sets for the CO2 absorption implies the physical state of CO2 is similar over the surface of Callisto. The distribution of SO2 on the surface is less well defined owing to characteristically shallower band depths, but it appears generally mottled, with some areas of high concentrations correlated with ice-rich impact craters. Large-scale patterns include the depletion of SO2 in the polar regions and a depletion of SO2 on the trailing side relative to the leading side. There is no sinusoidal pattern to this depletion. The center of the SO2 band is determined to be between 4.01 and 4.02 μm.

We present evidence for several non-ice constituents in the surface material of the icy Galilean satellites, using the reflectance spectra returned by the Galileo near infrared mapping spectrometer (NIMS) experiment. Five new absorption features are described at 3.4, 3.88, 4.05, 4.25, and 4.57 μm for Callisto and Ganymede, and some seem to exist for Europa as well. The four absorption bands strong enough to be mapped on Callisto and Ganymede are each spatially distributed in different ways, indicating different materials are responsible for each absorption. The spatial distributions are correlated at the local level in complex ways with surface features and in some cases show global patterns. Suggested candidate spectrally active groups, perhaps within larger molecules, producing the five absorptions include C-H, S-H, SO2, CO2, and C≡N. Organic material like tholins are candidates for the 4.57- and 3.4-μm features. We suggest, based on spectroscopic evidence, that CO2 is present as a form which does not allow rotational modes and that SO2 is present neither as a frost nor a free gas. The CO2, SO2, and perhaps cyanogen (4.57 μm) may be present as very small collections of molecules within the crystal structure, perhaps following models for radiation damage and/or for comet and interstellar grain formation at low temperatures. Some of the dark material on these surfaces may be created by radiation damage of the CO2 and other carbon-bearing species and the formation of graphite. These spectra suggest a complex chemistry within the surface materials and an important role for non-ice materials in the evolution of the satellite surfaces.

The Dawn spacecraft mission has provided extensive new and detailed data on Vesta that confirm and strengthen the Vesta-howardite-eucrite-diogenite (HED) meteorite link and the concept that Vesta is differentiated, as derived from earlier telescopic observations. Here, we present results derived by newly calibrated spectra of Vesta. The comparison between data from the Dawn imaging spectrometer—VIR—and the different class of HED meteorites shows that average spectrum of Vesta resembles howardite spectra. Nevertheless, the Vesta spectra at high spatial resolution reveal variations in the distribution of HED-like mineralogies on the asteroid. The data have been used to derive HED distribution on Vesta, reported in Ammannito et al. (2013), and to compute the average Vestan spectra of the different HED lithologies, reported here. The spectra indicate that, not only are all the different HED lithologies present on Vesta, but also carbonaceous chondritic material, which constitutes the most abundant inclusion type found in howardites, is widespread. However, the hydration feature used to identify carbonaceous chondrite material varies significantly on Vesta, revealing different band shapes. The characteristic of these hydration features cannot be explained solely by infalling of carbonaceous chondrite meteorites and other possible origins must be considered. The relative proportion of HEDs on Vesta's surface is computed, and results show that most of the vestan surface is compatible with eucrite-rich howardites and/or cumulate or polymict eucrites. A very small percentage of surface is covered by diogenite, and basaltic eucrite terrains are relatively few compared with the abundance of basaltic eucrites in the HED suite. The largest abundance of diogenitic material is found in the Rheasilvia region, a deep basin, where it clearly occurs below a basaltic upper crust. However, diogenite is also found elsewhere; although the depth to diogenite is consistent with one magma ocean model, its lateral extent is not well constrained.

International audience

A New Dawn Since 17 July 2011, NASA's spacecraft Dawn has been orbiting the asteroid Vesta—the second most massive and the third largest asteroid in the solar system (see the cover). Russell et al. (p. 684 ) use Dawn's observations to confirm that Vesta is a small differentiated planetary body with an inner core, and represents a surviving proto-planet from the earliest epoch of solar system formation; Vesta is also confirmed as the source of the howardite-eucrite-diogenite (HED) meteorites. Jaumann et al. (p. 687 ) report on the asteroid's overall geometry and topography, based on global surface mapping. Vesta's surface is dominated by numerous impact craters and large troughs around the equatorial region. Marchi et al. (p. 690 ) report on Vesta's complex cratering history and constrain the age of some of its major regions based on crater counts. Schenk et al. (p. 694 ) describe two giant impact basins located at the asteroid's south pole. Both basins are young and excavated enough amounts of material to form the Vestoids—a group of asteroids with a composition similar to that of Vesta—and HED meteorites. De Sanctis et al. (p. 697 ) present the mineralogical characterization of Vesta, based on data obtained by Dawn's visual and infrared spectrometer, revealing that this asteroid underwent a complex magmatic evolution that led to a differentiated crust and mantle. The global color variations detailed by Reddy et al. (p. 700 ) are unlike those of any other asteroid observed so far and are also indicative of a preserved, differentiated proto-planet.

A New Dawn Since 17 July 2011, NASA's spacecraft Dawn has been orbiting the asteroid Vesta—the second most massive and the third largest asteroid in the solar system (see the cover). Russell et al. (p. 684 ) use Dawn's observations to confirm that Vesta is a small differentiated planetary body with an inner core, and represents a surviving proto-planet from the earliest epoch of solar system formation; Vesta is also confirmed as the source of the howardite-eucrite-diogenite (HED) meteorites. Jaumann et al. (p. 687 ) report on the asteroid's overall geometry and topography, based on global surface mapping. Vesta's surface is dominated by numerous impact craters and large troughs around the equatorial region. Marchi et al. (p. 690 ) report on Vesta's complex cratering history and constrain the age of some of its major regions based on crater counts. Schenk et al. (p. 694 ) describe two giant impact basins located at the asteroid's south pole. Both basins are young and excavated enough amounts of material to form the Vestoids—a group of asteroids with a composition similar to that of Vesta—and HED meteorites. De Sanctis et al. (p. 697 ) present the mineralogical characterization of Vesta, based on data obtained by Dawn's visual and infrared spectrometer, revealing that this asteroid underwent a complex magmatic evolution that led to a differentiated crust and mantle. The global color variations detailed by Reddy et al. (p. 700 ) are unlike those of any other asteroid observed so far and are also indicative of a preserved, differentiated proto-planet.

In the last few years Cassini-VIMS, the Visible and Infared Mapping Spectrometer, returned to us a comprehensive view of the Saturn's icy satellites and rings. After having analyzed the satellites' spectral properties (Filacchione et al. (2007a)) and their distribution across the satellites' hemispheres (Filacchione et al. (2010)), we proceed in this paper to investigate the radial variability of icy satellites (principal and minor) and main rings average spectral properties. This analysis is done by using 2,264 disk-integrated observations of the satellites and a 12x700 pixels-wide rings radial mosaic acquired with a spatial resolution of about 125 km/pixel. The comparative analysis of these data allows us to retrieve the amount of both water ice and red contaminant materials distributed across Saturn's system and the typical surface regolith grain sizes. These measurements highlight very striking differences in the population here analyzed, which vary from the almost uncontaminated and water ice-rich surfaces of Enceladus and Calypso to the metal/organic-rich and red surfaces of Iapetus' leading hemisphere and Phoebe. Rings spectra appear more red than the icy satellites in the visible range but show more intense 1.5-2.0 micron band depths. The correlations among spectral slopes, band depths, visual albedo and phase permit us to cluster the saturnian population in different spectral classes which are detected not only among the principal satellites and rings but among co-orbital minor moons as well. Finally, we have applied Hapke's theory to retrieve the best spectral fits to Saturn's inner regular satellites using the same methodology applied previously for Rhea data discussed in Ciarniello et al. (2011)., Comment: 44 pages, 27 figures, 7 tables. Submitted to Icarus

[1] The NASA Discovery Moon Mineralogy Mapper imaging spectrometer was selected to pursue a wide range of science objectives requiring measurement of composition at fine spatial scales over the full lunar surface. To pursue these objectives, a broad spectral range imaging spectrometer with high uniformity and high signal-to-noise ratio capable of measuring compositionally diagnostic spectral absorption features from a wide variety of known and possible lunar materials was required. For this purpose the Moon Mineralogy Mapper imaging spectrometer was designed and developed that measures the spectral range from 430 to 3000 nm with 10 nm spectral sampling through a 24 degree field of view with 0.7 milliradian spatial sampling. The instrument has a signal-to-noise ratio of greater than 400 for the specified equatorial reference radiance and greater than 100 for the polar reference radiance. The spectral cross-track uniformity is >90% and spectral instantaneous field-of-view uniformity is >90%. The Moon Mineralogy Mapper was launched on Chandrayaan-1 on the 22nd of October. On the 18th of November 2008 the Moon Mineralogy Mapper was turned on and collected a first light data set within 24 h. During this early checkout period and throughout the mission the spacecraft thermal environment and orbital parameters varied more than expected and placed operational and data quality constraints on the measurements. On the 29th of August 2009, spacecraft communication was lost. Over the course of the flight mission 1542 downlinked data sets were acquired that provide coverage of more than 95% of the lunar surface. An end-to-end science data calibration system was developed and all measurements have been passed through this system and delivered to the Planetary Data System (PDS.NASA.GOV). An extensive effort has been undertaken by the science team to validate the Moon Mineralogy Mapper science measurements in the context of the mission objectives. A focused spectral, radiometric, spatial, and uniformity validation effort has been pursued with selected data sets including an Earth-view data set. With this effort an initial validation of the on-orbit performance of the imaging spectrometer has been achieved, including validation of the cross-track spectral uniformity and spectral instantaneous field of view uniformity. The Moon Mineralogy Mapper is the first imaging spectrometer to measure a data set of this kind at the Moon. These calibrated science measurements are being used to address the full set of science goals and objectives for this mission.

[1] High-resolution compositional data from Moon Mineralogy Mapper (M3) for the Moscoviense region on the lunar farside reveal three unusual, but distinctive, rock types along the inner basin ring. These are designated “OOS” since they are dominated by high concentrations of orthopyroxene, olivine, and Mg-rich spinel, respectively. The OOS occur as small areas, each a few kilometers in size, that are widely separated within the highly feldspathic setting of the basin rim. Although the abundance of plagioclase is not well constrained within the OOS, the mafic mineral content is exceptionally high, and two of the rock types could approach pyroxenite and harzburgite in composition. The third is a new rock type identified on the Moon that is dominated by Mg-rich spinel with no other mafic minerals detectable (

[1] Analysis of two absorption features near 3 μm in the lunar reflectance spectrum, observed by the orbiting M3 spectrometer and interpreted as being due to OH and H2O, is presented, and the results are used to discuss the processes producing these molecules. This analysis focuses on the dependence of the absorptions on lunar physical properties, including composition, illumination, latitude, and temperature. Solar wind proton-induced hydroxylation is proposed as the creation process, and its products could be a source for other reported types of hydrogen-rich material and water. The irregular and damaged fine-grained lunar soil seems especially adapted for trapping solar wind protons and forming OH owing to abundant dangling oxygen bonds. The M3 data reveal that the strengths of the two absorptions are correlated and widespread, and both are correlated with lunar composition but in different ways. Feldspathic material seems richer in OH. These results seem to rule out water from the lunar interior and cometary infall as major sources. There appear to be correlations of apparent band strengths with time of day and lighting conditions. However, thermal emission from the Moon reduces the apparent strengths of the M3 absorptions, and its removal is not yet completely successful. Further, many of the lunar physical properties are themselves intercorrelated, and so separating these dependencies on the absorptions is difficult, due to the incomplete M3 data set. This process should also operate on other airless silicate surfaces, such as Mercury and Vesta, which will be visited by the Dawn spacecraft in mid-2011.

[1] Soils within the impact crater Goldschmidt have been identified as spectrally distinct from the local highland material. High spatial and spectral resolution data from the Moon Mineralogy Mapper (M3) on the Chandrayaan-1 orbiter are used to examine the character of Goldschmidt crater in detail. Spectral parameters applied to a north polar mosaic of M3 data are used to discern large-scale compositional trends at the northern high latitudes, and spectra from three widely separated regions are compared to spectra from Goldschmidt. The results highlight the compositional diversity of the lunar nearside, in particular, where feldspathic soils with a low-Ca pyroxene component are pervasive, but exclusively feldspathic regions and small areas of basaltic composition are also observed. Additionally, we find that the relative strengths of the diagnostic OH/H2O absorption feature near 3000 nm are correlated with the mineralogy of the host material. On both global and local scales, the strongest hydrous absorptions occur on the more feldspathic surfaces. Thus, M3 data suggest that while the feldspathic soils within Goldschmidt crater are enhanced in OH/H2O compared to the relatively mafic nearside polar highlands, their hydration signatures are similar to those observed in the feldspathic highlands on the farside.

The Visible, InfraRed, and Thermal Imaging Spectrometer (VIRTIS) on Rosetta obtained hyperspectral images, spectral reflectance maps, and temperature maps of the asteroid 21 Lutetia. No absorption features, of either silicates or hydrated minerals, have been detected across the observed area in the spectral range from 0.4 to 3.5 micrometers. The surface temperature reaches a maximum value of 245 kelvin and correlates well with topographic features. The thermal inertia is in the range from 20 to 30 joules meter(-2) kelvin(-1) second(-0.5), comparable to a lunarlike powdery regolith. Spectral signatures of surface alteration, resulting from space weathering, seem to be missing. Lutetia is likely a remnant of the primordial planetesimal population, unaltered by differentiation processes and composed of chondritic materials of enstatitic or carbonaceous origin, dominated by iron-poor minerals that have not suffered aqueous alteration.

International audience; The Rosetta spacecraft accomplished a flyby of Mars on its way to 67P/Churyumov-Gerasimenko on 25 February 2007. In this paper we describe the measurements obtained by the M channel of the Visual and Infrared Thermal Imaging Spectrometer (VIRTIS-M) and the first scientific results derived from their analysis. The broad spectral coverage of the VIRTIS-M in the IR permitted the study of various phenomena occurring in the Martian atmosphere; observations were further exploited to achieve accurate absolute radiometric calibration. Nighttime data from the VIRTIS-M constrain the air temperature profile in the lower atmosphere (5-30 km), using variations in CO2 opacity at 4.3 mum. A comparison of this data with the global circulation model (GCM) by Forget et al. (1999) shows a trend of slightly higher air temperature in the VIRTIS-M retrievals; this is accompanied by the presence of moderate decreases (˜5 K) in large sections of the equatorial region. This is potentially related to the occurrence of water ice clouds. Daytime data from the VIRTIS-M reveal CO2 non-local thermodynamic equilibrium emission in the high atmosphere. A mapping of emission intensity confirms its strict dependence on solar zenith angle. Additionally, devoted limb observations allowed the retrieval of vertical emission intensity profiles, indicating a peak around 105 km in southern tropical regions. Ozone content can be effectively monitored by the emission of O2 (a1Deltag) at 1.27 mum. Retrieved emission intensity shows that polar regions are particularly rich in ozone. Aerosol scattering was observed in the 1-2.5 mum region above the night region above the night disk, suggesting the occurrence of very high noctilucent clouds.

International audience; Much of our knowledge of planetary surface composition is derived from remote sensing over the ultraviolet through infrared wavelength ranges. Telescopic observations and, in the past few decades, spacecraft mission observations have led to the discovery of many surface materials, from rock-forming minerals to water ice to exotic volatiles and organic compounds. Identifying surface materials and mapping their distributions allows us to constrain interior processes such as cryovolcanism and aqueous geochemistry. The recent progress in understanding of icy satellite surface composition has been aided by the evolving capabilities of spacecraft missions, advances in detector technology, and laboratory studies of candidate surface compounds. Pioneers 10 and 11, Voyagers I and II, Galileo, Cassini and the New Horizons mission have all made significant contributions. Dalton (Space Sci. Rev., 2010, this issue) summarizes the major constituents found or inferred to exist on the surfaces of the icy satellites (cf. Table 1 from Dalton, Space Sci. Rev., 2010, this issue), and the spectral coverage and resolution of many of the spacecraft instruments that have revolutionized our understanding (cf. Table 2 from Dalton, Space Sci. Rev., 2010, this issue). While much has been gained from these missions, telescopic observations also continue to provide important constraints on surface compositions, especially for those bodies that have not yet been visited by spacecraft, such as Kuiper Belt Objects (KBOs), trans-Neptunian Objects (TNOs), Centaurs, the classical planet Pluto and its moon, Charon. In this chapter, we will discuss the major satellites of the outer solar system, the materials believed to make up their surfaces, and the history of some of these discoveries. Formation scenarios and subsequent evolution will be described, with particular attention to the processes that drive surface chemistry and exchange with interiors. Major similarities and differences between the satellites are discussed, with an eye toward elucidating processes operating throughout the outer solar system. Finally we discuss the outermost satellites and other bodies, and summarize knowledge of their composition. Much of this review is likely to change in the near future with ongoing and planned outer planet missions, adding to the sense of excitement and discovery associated with our exploration of our planetary neighborhood.

The Huygens Probe returned the first in situ data on Titan's surface composition in January 2005. Although Huygens landed on a dry plain, the Gas Chromatograph Mass Spectrometer (GCMS) showed evidence of methane moisture in the near subsurface suggesting methane precipitation at some time in the past. Heavier organic molecules were not found to be abundant in the atmosphere or at the surface, but the GCMS surface results did show ethane to be present and tentatively identified cyanogen, benzene, and carbon dioxide. During descent, aerosol particles were processed with the Aerosol Collector and Pyroliser; results suggested that the aerosols contain both nitriles and hydrocarbons. The Descent Imager/Spectral Radiometer (DISR also carried by the probe) measured the visible and near-infrared spectral reflectance of the dark plain surface at the landing site. Those data suggest a mixture of water ice, tholin-like materials, and dark neutral material with a blue slope in the near infrared; identification of water ice is suggested but inconclusive. Most remarkably DISR did not detect spectral features, beyond those for methane, for a wide range of spectrally active hydrocarbon and nitrile compounds that had been expected to be present on the surface.

[1] The High Resolution Stereo Camera (HRSC) on the Mars Express (MEx) spacecraft in orbit about Mars is delivering images of the Mars surface and atmosphere from its high-inclination, elliptical orbit that are intended to cover most of the Mars surface by the end of the mission. These are acquired in four specific spectral passbands that sample the scene at different parts of the extended visual spectrum from near 0.4 μm to about 1μm and in five additional channels, four used for stereo and one nadir, that use the same fifth spectral passband. These channels view from different angles and can be used for photometric and spectral analysis. The data allow a variety of studies of the surface and atmosphere of Mars, but these require detailed understanding of the data characteristics, as there are several effects, including of the observation geometry and the atmosphere, that need to be treated. This article is a report to the science community on the current understanding of the HRSC color data after an initial analysis and also a demonstration of their capabilities for study of Mars, which, from this study, appear to be considerable. We first discuss the characteristics and calibration of the HRSC spectral data. The atmospheric influence on the photometric appearance of the surface materials is explored, and methods of compensating are considered. Reflectances are calculated for surface units by assuming the dark material is basalt and scaling the entire HRSC scene using a laboratory basalt spectrum for the selected dark material area; the results and the correction factors for different orbits are compared. We present several examples of what could become a large volume of future science results utilizing the HRSC spectrophotometric data in conjunction with photo-interpretation. For example, we find relatively few but very important distinct spectral components at the HRSC resolution, including what we interpret as iron oxide-rich material, unoxidized basalt, and polar ice, consistent with past works. The major spectral components are distributed in ways that suggest compositional mixing and the need to revise the current geologic understanding of major regions.

International audience; Spectra from Cassini's Visual and Infrared Mapping Spectrometer reveal that the horizontal structure, height, and optical depth of Titan's clouds are highly dynamic. Vigorous cloud centers are seen to rise from the middle to the upper troposphere within 30 minutes and dissipate within the next hour. Their development indicates that Titan's clouds evolve convectively; dissipate through rain; and, over the next several hours, waft downwind to achieve their great longitude extents. These and other characteristics suggest that temperate clouds originate from circulation-induced convergence, in addition to a forcing at the surface associated with Saturn's tides, geology, and/or surface composition.

[1] CO2 is inferred on the surface of Ganymede by the presence of an absorption band at ∼4.26 μm in reflectance spectra returned by the Near Infrared Mapping Spectrometer (NIMS) aboard the Galileo spacecraft. Detailed studies of NIMS observations of Ganymede show that the CO2 absorption band on Ganymede is symmetric about 4.257 μm ± 0.004 μm and is negligibly different from the CO2 absorption band on Callisto. In general, bright terrains (sulci) contain less CO2 than dark terrains (regiones), little or no CO2 is detected at the poles, and, unlike for Callisto, there does not appear to be any leading/trailing hemisphere asymmetry in the distribution of CO2 nor do impact craters tend to be CO2 rich. High spatial resolution observations show that CO2 is occasionally enriched in terrain containing larger-grained ice in comparison with adjacent terrain of similar morphology and ice abundance, that the dark ejecta of Kittu is depleted in CO2 with respect to adjacent terrain, and that only one observed impact crater (Mir) is enriched in CO2. The CO2 that is detected by NIMS is in the nonice material(s) present, not in the fraction that is ice. The ice in all terrain types where CO2 is detected is always sufficiently large-grained that its low reflectance in the region of the CO2 band prevents discrimination of the CO2 absorption band from the continuum. Areas with relatively fine-grained ice that are sufficiently bright at 4 μm for CO2 to be observed, such as the polar regions, do not contain detectable CO2.

Reflectance spectra in the 1- to 2.5-micrometer wavelength region of the surface of Europa obtained by Galileo's Near Infrared Mapping Spectrometer exhibit distorted water absorption bands that indicate the presence of hydrated minerals. The laboratory spectra of hydrated salt minerals such as magnesium sulfates and sodium carbonates and mixtures of these minerals provide a close match to the Europa spectra. The distorted bands are only observed in the optically darker areas of Europa, including the lineaments, and may represent evaporite deposits formed by water, rich in dissolved salts, reaching the surface from a water-rich layer underlying an ice crust.

Water plays a key role in the evolution of terrestrial planets, and notably in the occurrence of Earth's oceans. However, the mechanism by which water has been incorporated into these bodies—including Earth—is still extensively debated. Here we report the detection of widespread 2.8 μm OH absorption bands on the surface of the asteroid Vesta by the VIR imaging spectrometer on board Dawn. These observations are surprising as Vesta is fully differentiated with a basaltic surface. The 2.8 μm OH absorption is distributed across Vesta's surface and shows areas enriched and depleted in hydrated materials. The uneven distribution of hydrated mineral phases is unexpected and indicates ancient processes that differ from those believed to be responsible for OH on other airless bodies, like the Moon. The origin of Vestan OH provides new insight into the delivery of hydrous materials in the main belt and may offer new scenarios on the delivery of hydrous minerals in the inner solar system, suggesting processes that may have played a role in the formation of terrestrial planets.

On December 7, 1995, the Galileo spacecraft will begin observations of the Jovian system with orbit insertion and a satellite tour of 10 orbits. The Galilean satellites will be observed with four remote sensing instruments spanning the ultraviolet, visible, near infrared, and thermal infrared regions of the spectrum. The Galileo near-infrared mapping spectrometer will observe the satellites in the wavelength range 0.7–5.2 μm, a region particularly well suited for analyzing volatile components. Planned observations include mapping most available longitudes at about 100-km resolution per pixel at full wavelength resolution, together with observing limited regions at high spatial resolution. The opportunity to affect the choice and design of observations for the Galileo tour extends until June 1996.

The quality and quantity of asteroidal spectral reflectance data has increased rapidly in recent years. This data can be either (a) classified into spectral, polarization and/or albedo groups (e.g., ‘C’, ‘S’, etc.) which should tend to lump together grossly similar materials, or (b) interpreted utilizing laboratory and theoretical understanding of spectral features (e.g., absorption bands, continuum shape and slope) which are diagnostic of mineralogy or mineral chemistry. Mineral assemblages have been identified on asteroid surfaces which are comparable to most known meteorite types or which have undergone the types of processes (e.g., melting and differentiation) necessary to produce the meteoritic assemblages. The ordinary chondrites, which dominate the meteoritic flux reaching the Earth’s surface, are very rare or absent on Main Belt asteroids but appear common on the small asteroids which approach or cross the orbit of the Earth. The present interpretations of asteroidal spectra are not yet quantitative enough to permit the evaluation of specific asteroids as the sources bodies of particular meteorite specimens in terrestrial collections.

The most recent comprehensive results on spectrophotometric remote sensing of planets and satellites are reviewed. The moon and terrestrial planets are considered in terms of individual surface elements, reflectance spectra being analyzed to show the composition of the soils of these bodies. For more distant, unresolved objects, including the asteroids, the Galilean satellites, the small satellites of Jupiter, the rings and satellites of Saturn and Uranus, as well as Triton and Pluto, the global or hemispheric averages of surface composition are the objects of study. The absorptions due to methane gas and frost are indicated.

Several image processing systems have been developed and used at MIT to calibrate and analyze two dimensional images and spectra of astronomical objects. An interactive system allows creative processing under direct control of the astronomer and a batch system enables the astronomer to process large numbers of images while requiring little of his time. System descriptions and a list of processing routines are given.

Observations of the extinction in the spectral range 0.63 to 2.6 microns are presented for Mauna Kea Observatory. It is shown that high-quality photometric data can be obtained even in the intense 1.4 and 1.9 micron telluric water bands. Extinction coefficients (log intensity change per air mass) are presented with 1% spectral resolution

P/Ashbrook-Jackson has a period of 7.43 years and comes to perihelion at 2.284 AU. It is a low inclination object (12.5 deg) of moderate eccentricity (0.400). In 1963, it made the best possible apparition, coming to perihelion and opposition virtually simultaneously, but no one made physical observations of faint periodic comets in 1963. In 1978 Ashbrook-Jackson came to opposition on Sept. 28, just 40 days after perihelion. It will be just over 100 years before an equally favorable apparition recurs. P/Ashbrook-Jackson was recovered by Pereyra at Cordoba Observatory on April 28, 1977, more than a year and a quarter before perilhelion and already showing a diffuse coma with central condensation. Its helio-centric distance was then 3.7 AU. An extensive program was planned, but equipment problems and weather ultimately limited it to the two nights of data reported here.