1. Decay and Frequency Shift of Inter and Intravalley Phonons in Graphene -Dirac Cone Migration
- Author
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Sasaki, K., Kato, K., Tokura, Y., Suzuki, S., and Sogawa, T.
- Subjects
Condensed Matter - Materials Science ,Condensed Matter - Mesoscale and Nanoscale Physics ,Mesoscale and Nanoscale Physics (cond-mat.mes-hall) ,Materials Science (cond-mat.mtrl-sci) ,FOS: Physical sciences ,Condensed Matter::Strongly Correlated Electrons - Abstract
By considering analytical expressions for the self-energies of intervalley and intravalley phonons in graphene, we describe the behavior of D, 2D, and D$'$ Raman bands with changes in doping ($\mu$) and light excitation energy ($E_L$). Comparing the self-energy with the observed $\mu$ dependence of the 2D bandwidth, we estimate the wavevector $q$ of the constituent intervalley phonon at $\hbar vq\simeq E_L/1.6$ ($v$ is electron's Fermi velocity) and conclude that the self-energy makes a major contribution (60%) to the dispersive behavior of the D and 2D bands. The estimation of $q$ is based on an image of shifted Dirac cones in which the resonance decay of a phonon satisfying $q > \omega/v$ ($\omega$ is the phonon frequency) into an electron-hole pair is suppressed when $\mu < (vq-\omega)/2$. We highlight the fact that the decay of an intervalley (and intravalley longitudinal optical) phonon with $q=\omega/v$ is strongly suppressed by electron-phonon coupling at an arbitrary $\mu$. This feature is in contrast to the divergent behavior of an intravalley transverse optical phonon, which bears a close similarity to the polarization function relevant to plasmons., Comment: 11 pages, 5 figures
- Published
- 2012
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