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1. Ni(II) 10-Boracorrole: An Antiaromatic Porphyrinoid Containing a Boron Atom at the -Position

Author

Omori, Hiroto and Shinokubo, Hiroshi

Subjects
1h nmr spectroscopy, 010405 organic chemistry, Chemistry, Organic Chemistry, 010402 general chemistry, Boron atom, 01 natural sciences, 0104 chemical sciences, Inorganic Chemistry, Crystallography, Transmetalation, Position (vector), Physical and Theoretical Chemistry, Antiaromaticity
Abstract

A Ni(II) 10-boracorrole (2) was obtained from the transmetalation of the corresponding 10-silacorrole with BBr3. The antiaromaticity of 2 was examined by 1H NMR spectroscopy and theoretical calcula...

Published
2019
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