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Soil respiration (SR) in forests contributes significant carbon dioxide emissions from terrestrial ecosystems and is highly sensitive to environmental changes, including soil temperature, soil moisture, microbial community, surface litter, and vegetation type. Indeed, a small change in SR may have large impacts on the global carbon balance, further influencing feedbacks to climate change. Thus, detailed characterization of SR responses to changes in environmental conditions is needed to accurately estimate carbon dioxide emissions from forest ecosystems. However, data for such analyses are still limited, especially in tropical forests of Southeast Asia where various stages of forest succession exist due to previous land‐use changes. In this study, we measured SR and some environmental factors including soil temperature (ST), soil moisture (SM), and organic matter content (OM) in three successional tropical forests in both wet and dry periods. We also analyzed the relationships between SR and these environmental variables. Results showed that SR was higher in the wet period and in older forests. Although no response of SR to ST was found in younger forest stages, SR of the old‐growth forest significantly responded to ST, plausibly due to the nonuniform forest structure, including gaps, that resulted in a wide range of ST. Across forest stages, SM was the limiting factor for SR in the wet period, whereas SR significantly varied with OM in the dry period. Overall, our results indicated that the responses of SR to environmental factors varied temporally and across forest succession. Nevertheless, these findings are still preliminary and call for detailed investigations on SR and its variations with environmental factors in Southeast Asian tropical forests where patches of successional stages dominate., We measured and analyzed soil respiration (SR) with environmental factors in three successional forests in Thailand. Results showed that SR was generally higher in the wet season and in older forests. Across all forest stages, soil moisture was the main factor contributing to variation in SR in the wet season while organic matter content played significant role in the dry season.

The maritime continent exports an enormous amount of heat and moisture to the rest of the globe via deep atmospheric convection. How this export has changed through time during the last deglacial period and through the Holocene, is hardly known yet critical for the understanding of global climate dynamics. Here we present a continuous paleoclimate record from southern Thailand covering the last 18,000 years, including the first land-based temperature reconstruction of tropical SE Asia. We found evidence for a strongly seasonal climate for most of the deglacial period, causing biomass burning and suppression of rainforest growth, despite rising CO2 levels and increasing mean humidity. Temperatures were ca. 5°C cooler than today during the last cold stadial periods, and ca. 2°C warmer between 7000-2000 yr ago. We also find that tropical wet-season insolation (WSI) is a primary driver of deep atmospheric convection, exerting a strong influence on global climate dynamics.

The seismicity for 35 natural caves in Thailand was investigated probabilistically in order to provide information on their potential earthquake situation. All values representing the earthquake activities within a 300-km radius and the seismic hazard level at each cave were clarified. Seismotectonically, 28 of the 35 caves are situated within previously proposed seismic source zones and most of the seismogenic faults nearby each cave is presently still active, as determined by seismicity and paleoseismological evidence. For the present-day seismicity, the Pla cave in northwest Thailand (situated 0.3[Formula: see text]km from the Mae Hong Son-Tak fault) showed a comparatively high [Formula: see text]-value (4.16) suggesting a high entire seismicity rate, but a relatively high [Formula: see text]-value of 0.82. With respect to the [Formula: see text]-value, which inversely represents the accumulated seismotectonic stress, the caves at Pha Puang, Lom-Wang, Naresuan and Fha Mue Daeng in the Central-North regions had a comparatively low [Formula: see text]-value ([Formula: see text]), indicating a high accumulated stress. Based on the recognized earthquake sources and the utilized strong ground-motion attenuation model, the seismic hazard analyses revealed that the caves at Daowadeung, Phra Thart and Lawa in Western Thailand were in the highest seismic hazard areas. This new study contributes to important information for geotourism (e.g. mitigation planning) and selecting/prioritizing speleoseismological investigation sites.

At present a total of 118 hot springs are distributed throughout Thailand. Several studies with a focus on high-temperature hot springs related to geothermal resources were conducted in the northern and southern parts of the country. Geochemical data, however; especially isotopes of medium-to-low temperature hot springs are still scarce. Geochemical water analyses and isotope studies can provide crucial information for the future economical development of the hot springs, such as reservoir temperature, water source and quality. This study aims to investigate the chemical composition and stable isotopes (δ18O, δD) of three hot spring waters from western Thailand; Hin Dad, Bor Klueng and Ban Samorthong (surface water temperatures of 40-50 °C). The chemical type of the hot spring waters from Ban Samorthong and Bor Klueng are alkaline-carbonate, while Hin Dad hot spring is a calcium-carbonate type with high amount of sulfate, which is related to bedrock. Based on the silica geothermometer, reservoir temperatures are 65-90 °C. The stable isotopes δ18O and δD of all hot spring waters suggest a recharge with meteoric waters. The three hot springs are well-known for public water recreation and health therapy. Bor Klueng, the least developed of the three hot springs is used by locals as a source of drinking water. Regarding toxic elements, Ban Samorthong hot spring has high fluoride (F-) (14.84 mg L-1); while Hin Dad hot spring shows concentrations of lead (Pb2+) (0.07 mg L-1) and Bor Klueng of Pb2+ (0.02 mg L-1), and F- (4.35 mg L-1) which are above drinking water limits and might lead to health problems. In conclusion, the examination of elemental compositions and stable isotopes (δ18O, δD) of the three hot springs contributes to a better understanding of reservoir temperatures and recharge and can be beneficial for the natural resource development of medium-low temperature hot springs in Thailand.

Sedimentary evidence of storms and fluvial floods (FFs) is crucial for a better understanding of such events in coastal zones. In this study, we analyzed the sedimentary characteristics of the coastal storm and FF deposits at the Hoa Duan barrier, Thua Thien Hue, central Vietnam. Analyses of the sedimentary structures and properties (grain size distribution, composition, roundness, and sphericity) and loss on ignition revealed that the storm sediments were comprised of coarser grains with a low organic and carbonated content, and with sedimentary structures, including parallel and inclined landward lamination, multiple sets of normal and reverse grading, mud rip-up clasts, and sharp and erosional contacts (both top and bottom) with finer-grain layers. Conversely, the FF sediments had only fine to very fine grains, with dominant high organic and carbonate contents, and only exhibited sedimentary structures of sharp erosional top and bottom contacts with coarser-grained layers. The clearest differentiation to distinguish coastal storm layers from inland FF layers was obtained by plotting the mean grain size against the sorting. The results of optically stimulated luminescence dating suggested that two storm layers and one FF layer were deposited during the last 130 ± 10 years. Moreover, two layers were deposited by storms and one by a FF prior to that (>130 ± 10 years). The identification of the sedimentary diagnostic key of these two hazards can help to improve the understanding of the geomorphological evolution of the studied site and the other parts of this coastal region in order to remind the coastal community to prepare for future coastal hazards well.

Significance We present a high-resolution, replicated speleothem δ18O record from Klang Cave in southern Thailand that characterizes rainfall variation in NCIP over the past 2,700 y. This record reveals notable dry climate conditions during the current and past warm periods, similar to the observations in SCIP, which resemble enhanced El Niño-like conditions. Using a newly developed ITCZ shift index, we find a southward shifted ITCZ during the early MWP and the CWP. Our results suggest that detecting changes in rainfall due to anthropogenic forcing still remains indistinguishable from natural variability in the northern tropics., Tropical rainfall variability is closely linked to meridional shifts of the Intertropical Convergence Zone (ITCZ) and zonal movements of the Walker circulation. The characteristics and mechanisms of tropical rainfall variations on centennial to decadal scales are, however, still unclear. Here, we reconstruct a replicated stalagmite-based 2,700-y-long, continuous record of rainfall for the deeply convective northern central Indo-Pacific (NCIP) region. Our record reveals decreasing rainfall in the NCIP over the past 2,700 y, similar to other records from the northern tropics. Notable centennial- to decadal-scale dry climate episodes occurred in both the NCIP and the southern central Indo-Pacific (SCIP) during the 20th century [Current Warm Period (CWP)] and the Medieval Warm Period (MWP), resembling enhanced El Niño-like conditions. Further, we developed a 2,000-y-long ITCZ shift index record that supports an overall southward ITCZ shift in the central Indo-Pacific and indicates southward mean ITCZ positions during the early MWP and the CWP. As a result, the drying trend since the 20th century in the northern tropics is similar to that observed during the past warm period, suggesting that a possible anthropogenic forcing of rainfall remains indistinguishable from natural variability.

The Fine Arts Department of Thailand excavated parts of the city walls in the western part of Songkhla city, Southern Thailand. This excavation found additional brick walls covering the top and sides of a rock wall, which according to historical records was built between AD 1836 and 1842. In this paper, we use optically stimulated luminescence (OSL) to date the brick attachments in order to understand the construction history of Songkhla City Wall. In total, eight brick samples were collected from the top (five samples) and the side (three samples) of the rock wall. All but one sample have excellent OSL properties and the exception is explained by limited burning of this particular brick during the production process, as also indicated by material properties. The major challenge of this study was the correct reconstruction of the dose rate due to the complex situation onside and the limited documentation. Despite these limitations, our results imply that the rock wall and the bricks attached to its side are contemporaneous. The bricks on top of the rock wall date to AD 1853–1865, a time shortly before a royal visit (King Rama V) to Songkhla in AD 1870. Two samples dating to the latest nineteenth century may imply a later restoration phase.

Microplastic pollution is one of the most significant global environmental concerns. This study represents a first attempt to establish connections between the concentration of microplastics and both ocean surface circulation direction and land-based sources along the western Gulf of Thailand. Microplastics at the high-tide line from 25 beaches in 5 provinces were quantified. Observed amounts range from 20 to 273 (max. 5741) pieces/kg. Sheets were the most common shape and black the most common color of microplastics. Our study showed a significant, positive correlation between the number of microplastics and land-based sources (e.g., aquatic industries). While human activities were the dominant factor affecting microplastic concentrations, the newly designed surface circulation direction (SCD) index reflected relative changes in microplastic amounts. Our study identified several locations with substantial microplastic pollution which require a proper management system with appropriate laws and regulations, and a public awareness campaign about effects of microplastics on ecosystems.

Several studies have shown the ubiquitousness of microplastics across ecosystems worldwide including significant amounts in beach sand. In Thailand, however, there is a lack of studies about the microplastic pollution of beaches. This study aimed to quantify microplastics at the high-tide line of 21 beaches along the eastern Gulf of Thailand. Observed amounts ranged from 420 to >200,000 counts/kg. Anthropogenic and environmental factors affect distribution and amount of microplastics. Tide-dominated beaches and beach sections protected by beachrocks exhibit higher microplastic amounts due to lesser hydrodynamics. While human activities have a visible impact, in some cases environmental factors seem to predominate. Despite effective protection efforts led by the government and NGOs, our study shows that the substantial microplastic pollution of beach sand requires a proper management system with appropriate laws and regulations, and a public awareness campaign to reduce effects of microplastics on organisms and their ecosystems.

Mainland Southeast Asia is located on the moisture transport route of the Indian summer monsoon (ISM) where hydroclimate records from speleothems have rarely been investigated. Here, we present a new multi-proxy (δ18O and δ13C values, trace element concentrations, and grayscale values) data set of stalagmite KPC1 from Khao Prae cave in western Thailand spanning the last 1400 years (500–1900 CE; the Common Era). These multi-proxy data reveal a high variability between the wet and dry periods during 500–850 CE and 1150–1300 CE, stable climate conditions during 850–1150 CE, and overall dry conditions since 1300 CE. The δ13C values, trace elements concentrations, and grayscale values show centennial-scale fluctuations, which were probably driven by local hydrological processes. In contrast, variations in the stalagmite δ18O values reflect integrated changes in rainfall amount from the ISM. The KPC1 record agrees with other speleothem δ18O records of Southeast Asian summer monsoon from the last millennium, as well as the lake multi-proxy and tree-ring PDSI data from Mainland Southeast Asia, but diverges from records from the Indo-Pacific equatorial regions and the western Pacific. We conclude that hydroclimate variability at the western side of Mainland Southeast Asia is mainly driven by changes in moisture transport of the ISM. On socially relevant timescales, the KPC1 data set shows that a period of stable rainfall (850–1150 CE) coincides with the early success of the early empires (e.g., Pagan, Angkor, and Dai Viet) in Mainland Southeast Asia. In line with previous studies in the region, we speculate that the high variability in rainfall between 1150 and 1300 CE and droughts during 1300–1550 CE played a significant role in the demise of ancient societies in Southeast Asia. National Research Foundation (NRF) Accepted version S. Chawchai wishes to express appreciation for the financial support provided by the Development and Promotion of Science Technology (DPST) Research grant 042/2558 and DAAD faculty research grant 2016. X. Wang is supported by Singapore National Research Foundation grants (2017NRF-NSFC001-047 and NRFF2011-08). D. Scholz is thankful to the German Research Foundation (DFG SCHO 1274/9-1 and SCHO 1274/11-1). The authors also thank Dr. S. Tonongto, his family and PANDA CAMP for accommodation and assistance during the field survey, and Prof. M. Choowong as a mentorship for SC. In addition, the authors thank officials at Ban Rai district, Uthai Thani province for their help and hospitality. We also thank S. Mischel for his help with TERMITE and A. Budsky for cutting the sample for LA-ICP-MS analysis, W. Suwansukho and P. Rattanasrimongkol for polishing the samples and discussion, and the Research Clinic Unit, Office of Research Affairs at Chulalongkorn University for assistance during manuscript preparation.

Concerns about heavy metal and metalloid contamination from mine dumps is one of the most intensively discussed issues in society, politics, and academia, because of the levels of pollution, and its toxic properties. During the Middle Ages the Black Forest was one of the most successful mining areas in Southwestern Germany. Historical records show that Sulzburg was a mining town in the Black Forest since the 10th century, but was abandoned in the 19th century. Nowadays this town is considered as an important recreation area in the country. Therefore, soil and water quality and any contamination are of great concern. The purpose of this research was to understand the weathering process and environmental impact of heavy metals and metalloids from the old antimony (Sb) mine sites in Sulzburg. In this study, we examined the mineralogy and whole-rock chemistry and per-formed soil sequential extraction and water chemical analysis around mine sites. The results show that the Sb deposits in Sulzburg contain mixtures of antimony-lead-bearing sulfides and sulfosalts in hydrothermal quartz veins. The primary ore stibnite (Sb2S3) and boulangerite (Pb5Sb4S11) occur associated with pyrite, arsenopyrite, and sphalerite. The whole-rock chemistry of Sb-Mine Sulzburg is characterized by considerable Sb2O3 (4-25 %) and PbO contents (2-7 %). This agrees with the che-mical composition of Sb minerals. Based on soil sequential extraction, toxic elements (Sb, Pb, As) mostly remain in the residual fraction. Comparing the water analysis at and around Sb-mine Sulzburg, Sb concentrations are lower than those of As and Pb for all water samples. This is possible due to the strong affinity of Sb to Fe-oxides-hydroxides and amorphous material and a lower mobi-lity, from the source into water. Based on these findings, we argue that sources of toxic elements and weathering process in Sulzburg are important from the ecotoxicity perspective. Changes in oxidizing or reducing conditions can lead to release and mobilization of Sb, As, and Pb into the environment.

The Cenomanian (Upper Cretaceous) Maha Sarakham Formation of the Khorat Basin, northeastern Thailand consists of three evaporite units (Lower, Middle and Upper Salt) interbedded with clastic sediments and exhibits abundant deposits of potash. Although numerous studies have been carried out on the Khorat potash deposit, results are still equivocal with regard to the origin of the rock salt, whether it was marine or non-marine (hydrothermal and/or mixed fluids). The purpose of this study is to examine the origin of rock salt based on elemental compositions and boron isotope analyses in the southwestern part of the Khorat Basin. A stratigraphic correlation of five boreholes (K-201– 205) located in Bamnet Narong and Chaturat districts, Chaiyaphum province, Thailand, revealed a salt dome structure. The elemental composition and δ11B values in the longest borehole K-203 indicate a precipitation of halite and carnallite from seawater. Rare earth elements (REE) of claystone and siltstone from five boreholes (K-201– 205) are comparable to the REE of sandstone from the Simao Basin in China, which suggest a similar provenance. Stratigraphic comparisons and geochemical signatures are important for a better understanding of the recharge models of paleoseawater. In agreement with some previous studies, we conclude that the Cenomanian evaporites within the Khorat Basin are marine deposits.

Locating suitable caves and stalagmites for palaeoenvironmental and palaeoclimatic studies can be challenging. Isotopic geochemical analyses, albeit commonly performed for palaeoclimatic reconstruction, are also time consuming and costly. Therefore, petrographic and non‐destructive morphological studies on speleothems are desirable to facilitate sample selection for further analysis. In this study, 20 caves were surveyed in Ban Rai district, Uthai Thani province in western Thailand. After external physical observations in the field, three stalagmite samples were collected from Tham Nam Cave to test their potential for palaeoclimatic research. Firstly, the stalagmites were scanned by X‐ray computed tomography (CT scanning) and subsequently the CT images were compared with petrographic inspections. Columnar fabrics show the highest density, whereas closed and open dendritic fabrics have medium and the lowest densities, respectively. Layers near the top and bottom of the three stalagmites were dated by U‐Th mass spectrometric techniques. All three samples were deposited between c. 87 and c. 105 ka ago; therefore, they are probably the oldest stalagmites that have been reported so far from mainland Southeast Asia. However, their physical features indicate that all the samples have suffered from postdepositional dissolution, and are unlikely to be suitable for palaeoclimatic research. The internal dissolution feature of stalagmites, however, cannot be identified by visual inspection of uncut samples. We hereby argue that CT images are useful to characterize stalagmite petrography, in particular fabric, porosity and density. Such features can be used to select the ideal plane of a stalagmite for sectioning, to maximize the chances of robust climatic reconstruction. NRF (Natl Research Foundation, S’pore) Accepted version

Moisture transport pathway effect offsets glacial forcings, likely explaining a lack of G-IG variability in Chinese cave records., While Asian monsoon (AM) changes have been clearly captured in Chinese speleothem oxygen isotope (δ18O) records, the lack of glacial-interglacial variability in the records remains puzzling. Here, we report speleothem δ18O records from three locations along the trajectory of the Indian summer monsoon (ISM), a major branch of the AM, and characterize AM rainfall over the past 180,000 years. We have found that the records close to the monsoon moisture source show large glacial-interglacial variability, which then decreases landward. These changes likely reflect a stronger oxygen isotope fractionation associated with progressive rainout of AM moisture during glacial periods, possibly due to a larger temperature gradient and suppressed plant transpiration. We term this effect, which counteracts the forcing of glacial boundary conditions, the moisture transport pathway effect.

Limited understanding of the complex dynamics of the tropical monsoon exists, partly due to inadequate paleo (hydro)-climate proxy data from monsoonal regions. This study presents a 2000-year long record of hydrogen isotope values of leaf wax (δDwax) from a sedimentary sequence recovered from Lake Pa Kho, Northern Thailand. Evaluation of present day rainfall patterns and water isotope data indicates that δDwax reflects the amount of rainfall and is also influenced by El Nino-Southern Oscillation (ENSO) dynamics. Over the last 2000 years, wettest conditions occurred between ca. 700 AD and ca. 1000 AD, whereas the driest intervals lasted from ca. 50 BCE to ca. 700 AD and from ca. 1300 AD to ca. 1500 AD. Further investigations to establish the spatiotemporal variability of ENSO within the wider tropical Asian-Pacific realm over centennial timescales revealed a low-frequency-tripole pattern between mainland SE Asia (MSEA), the tropical West Pacific, and the central-eastern Pacific, with a wetter than normal MSEA during El Nino-like climate conditions. This pattern stands in contrast to the annual event where El Nino cause drier conditions in MSEA. We hypothesize that on centennial timescales the land-sea contrast, which drives monsoon intensity in MSEA, is modulated by the latitudinal shift of the Walker circulation and associated ENSO dynamics.

Understanding past climate and environmental conditions depends largely on accurate interpretations of proxy records from a range of environments, including tropical wetlands and lakes. Lipid biomarker analysis can provide important information about the sources of the accumulated organic material, and thus about the environmental information contained therein. Here we use n -alkane distributions and stable carbon isotopes of leaf waxes (δ 13 C wax ) to identify the sources of organic matter (OM) of a 2000-year long sediment/peat record from Lake Pa Kho (LPK) in northeastern Thailand, and to constrain the mechanisms that cause shifts in δ 13 C wax and in δ 13 C of bulk organic matter (δ 13 C bulk ). Our results show three main sources of OM: terrestrial plants, aquatic macrophytes and algae. The δ 13 C values of the long chain n -alkanes, show two distinct groups: C 27 –C 31 and C 33 –C 35 n -alkanes, where the δ 13 C values of C 33 –C 35 n -alkanes reflect that of δ 13 C bulk . Lower moisture availability on the wetland, known from other sedimentary evidence, was characterized by low carbon isotope values typically seen for C3 plants, whereas greater moisture availability corresponded to higher δ 13 C values (around −20‰) of C 33 –C 35 n -alkanes, resembling a typical C4 plant signal. However, various lines of evidence argue against large shifts between C3 and C4 plant input. Instead, we suggest that the high δ 13 C values were indirectly caused by higher aquatic productivity during periods of greater moisture availability, decreasing dissolved CO 2 , but increasing bicarbonate availability caused by higher pH. This caused the dominant macrophytes (e.g., Potamogeton spp.) to shift their carbon source from CO 2 to bicarbonate, which has much higher δ 13 C values. Our results show that the environmental context should be taken into account when interpreting n -alkane δ 13 C variability as a paleo-environmental/climatic signal as this contains several important variables that need to be disentangled and explained.

The evolutionary dynamics of El Nino Southern Oscillation (ENSO) over the last glacial period remains understudied, despite its potential in providing a “cold case” for climate sensitivity studies. Here, we investigate SE Asian-Pacific paleoclimate records to decipher the dominant underlying mechanism that governed tropical Asian-Pacific hydrology during MIS 3. Our results suggest that the glacial emergence of the Sunda Shelf likely altered the atmospheric circulation pattern in Southeast (SE) Asia and led to the realignment of rainfall patterns between Thailand and Indonesia during the last glacial period. We also propose that the long-term hydrological regime change in the tropical Asian-Pacific region during MIS 3 was mainly influenced by an El Nino-like mechanism. An intense El Nino-like condition led to strong aridity in SE Asia during mid MIS 3. By late MIS 3, an enhanced seasonality dampened the intensity of the El Nino-like conditions, thus, leading to muted aridity in SE Asia. The alternating warm and wet summer months and droughts during winter favoured the proliferation of C4 plant types in Northern Thailand from mid MIS 3 to late MIS 3.

In the version of this Analysis originally published, the following affiliation for A. Lohila was missing: ‘Finnish Meteorological Institute, Climate System Research, Helsinki, Finland’. This affiliation has now been added, and subsequent affiliations renumbered accordingly, in the online versions of the Analysis.

Caesium-137 (137Cs) has no natural source and is commonly employed in establishing the chronology of recent lake sediments in the Anthropocene epoch. Because of their location in the northern mid-latitude Westerlies circulation region, downwind of the Chernobyl accident and their proximity to the Lop Nur Chinese Nuclear Testing (CNT) site, lake sediments in NW China record a137Cs fallout maximum of global atmospheric thermonuclear weapon tests (GTWT) in 1963–1964 Common Era (CE), with probably local fallout subpeaks due to the Chernobyl accident in 1986 CE and CNT in 1976 CE. This complexity means that the use of 137Cs fallout maximum in lake sediments as a time marker in NW China is thus far not well constrained, impeding assessment of recent and future changes in paleoclimate and human activities. To identify the 137Cs time marker and provide a reliable chronology of surface lake sediments for investigating paleoclimatic changes and for defining the Anthropocene epoch in NW China during the last 50–100 years, here we describe chronologies of 6 near-surface sediment cores from NW China based on 137Cs and 210Pb activities, and review the chronology of 23 lake sediments and 10 ice cores from NW China and central Asia based on 137Cs, 210Pb, 239+240Pu, 3H, 241Am, and beta-activity dating methods, and annual layer counting, as well as 240Pu/239Pu isotopic ratios. Based on the potential influence of radioactivity transport from the Chernobyl accident and CNT, and the comparison with deposition records of 26 European lake sediments and 5 Alpine ice cores, we propose that the 137Cs fallout maximum of lake sediments in NW China and central Asia is primarily attributable to GTWT and that there is no unambiguous evidence to confirm the Chernobyl- and CNT-derived 137Cs local-fallout subpeaks. Taking into account the approximately one-year delay between injection of 137Cs into the atmosphere and its incorporation in lake sediment records, we conclude that the 137Cs fallout maximum in lake sediments of NW China provides a reliable GTWT time marker for 1964 CE.

Hydroclimatic variations in central Asia are widely recognized to be tele-connected with the North Atlantic climate via the mid-latitude Westerlies. However, the long-term hydroclimatic variation and its response to North Atlantic climate changes are not fully understood. Here we report multi-decadal and centennial hydroclimatic variations in central Asia during the late Holocene using high-resolution oxygen and carbon isotopes of bulk carbonate from a remote hydrologically closed alpine lake in Tianshan Mountains, northwestern China. The hydroclimatic variations inferred from the covariance between δ18Ocarb and δ13Ccarb and published multi-proxy in the Lake Sayram together agree well with the records from the central Asia, showing enhanced effective moisture at the intervals of 4000-3780, 3590-3210, 2800-2160, 1700-1370 and 890-280 cal yr BP during the negative phase of North Atlantic Oscillation (NAO). Comparison with European hydroclimatic changes on centennial scale, our records not only provide valuable insight into the hydroclimatic variations in central Asia, but also indicate all broadly contemporaneous changes with that of southern Europe whereas antiphase with that of northern Europe. We then conclude that the observed antiphase hydroclimatic pattern between northern Europe and southern Europe-central Asia on centennial time scale during the late Holocene were persistently controlled by the north-south migration of mid-latitude Westerlies and changes of NAO phase in response to solar irradiance forcing. However, further research is necessary to fully disentangle the natural and anthropogenic forcing mechanisms for enhanced effect moisture and/or precipitation in central Asia.

Kumphawapi, which is Thailand’s largest natural freshwater lake, contains a >10,000-year-long climatic and environmental archive. New data sets (stratigraphy, chronology, hydrogen isotopes, plant macrofossil and charcoal records) for two sedimentary sequences are here combined with earlier multi-proxy studies to provide a comprehensive reconstruction of past climatic and environmental changes for Northeast Thailand. Gradually higher moisture availability due to a strengthening of the summer monsoon led to the formation of a large shallow lake in the Kumphawapi basin between >10,700 and c. 7000 cal. BP. The marked increase in moisture availability and lower evaporation between c. 7000 and 6400 cal. BP favoured the growth and expansion of vegetation in and around the shallow lake. The increase in biomass led to gradual overgrowing and infilling, to an apparent lake level lowering and to the development of a wetland. Multiple hiatuses are apparent in all investigated sequences between c. 6500 and 1400 cal. BP and are explained by periodic desiccation events of the wetland and erosion due to the subsequent lake level rise. The rise in lake level, which started c. 2000 cal. BP and reached shallower parts c. 1400 cal. BP, is attributed to an increase in effective moisture availability. The timing of hydroclimatic conditions during the past 2000 years cannot be resolved because of chronological limitations.

X-ray fluorescence (XRF) core scanning has become widely available for geological studies during the last decade. The data obtained from XRF core scanning, however, may be strongly influenced by the amount of organic matter, water content, density and porosity of the sediment matrix. In this study we discuss the usefulness of XRF core scanning to distinguish different kinds of organic-rich sediments and peat based on examples from tropical Lakes Kumphawapi and Nong Leng Sai in Thailand. We examined how sedimentary factors influence XRF core scanning analyses by comparing elemental and scattering ratios to lithological changes and quantitative LOI, TOC, biogenic silica (BSi) and grain-size values. Our comparison suggests that the (inc/coh) scattering ratio is of limited use as an indicator for variations in LOI and TOC in peaty gyttja or peat. In Lake Kumphawapi's sediments, Si/Ti ratios reflect clastic input associated with grain-size variations rather than BSi contents. The Ti-normalized ratios of Si, Zr, Sr, K and Rb are linked to mineral input and associated grain-size variations. We conclude that XRF core scanning of organic-rich tropical lake sediments and peat is useful to infer palaeoenvironmental conditions. However, XRF core scanning data does not stand-alone and needs to be underpinned by additional proxies.

The long-term climatic and environmental history of Southeast Asia, and of Thailand in particular, is still fragmentary. Here we present a new C-14-dated, multi-proxy sediment record (TOC, C/N, CNS ...

Geochemical variables (TOC, C/N, TS, delta C-13) and diatom assemblages were analyzed in a lake sediment sequence from Nong (Lake) Han Kumphawapi in northeast Thailand to reconstruct regional climatic and environmental history during the Holocene. By around c. 10,000-9400 cal yr BP, a large shallow freshwater lake had formed in the Kumphawapi basin. Oxygenated bottom waters and a well-mixed water column were characteristic of this early lake stage, which was probably initiated by higher effective moisture and a stronger summer monsoon. Decreased run-off after c. 6700 cal yr BP favored increased aquatic productivity in the shallow lake. Multiple proxies indicate a marked lowering of the lake level around 5900 cal yr BP, the development of an extensive wetland around 5400 cal yr BP, and the subsequent transition to a peatland. The shift from shallow lake to wetland and later to a peatland is interpreted as a response to lower effective moisture. A hiatus at the transition from wetland to peatland suggests very low accumulation rates, which may result from very dry climatic conditions. A rise in groundwater and lake level around 3200 cal yr BP allowed the re-establishment of a wetland in the Kumphawapi basin. However, the sediments deposited between c. 3200 and 1600 cal yr BP provide evidence for at least two hiatuses at c. 2700-2500 cal yr BP, and at c. 1900-1600 cal yr BP, which would suggest surface dryness and consequently periods of low effective moisture. Around 1600 cal yr BP a new shallow lake became re-established in the basin. Although the underlying causes for this new lake phase remain unclear, we hypothesize that higher effective moisture was the main driving force. This shallow lake phase continued up to the present but was interrupted by higher nutrient fluxes to the lake around 1000-600 cal yr BP. Whether this was caused by intensified human impact in the catchment or, whether this signals a lowering of the lake level due to reduced effective moisture, needs to be corroborated by further studies in the region. The multi-proxy study of Kumphawapi's sediment core CP3A clearly shows that Kumphawapi is a sensitive archive for recording past shifts in effective moisture, and as such in the intensity of the Asian summer monsoon. Many more continental paleorecords, however, will be needed to fully understand the spatial and temporal patterns of past changes in Asian monsoon intensity and its ecosystem impacts. (C) 2012 Elsevier B.V. All rights reserved.