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Observations along the southwest Atlantic WOCE A17 line made during the Dutch GEOTRACES-NL program (2010–2011) were compared with historical data from 1994 to quantify the changes in the anthropogenic component of the total pool of dissolved inorganic carbon (ΔCant). Application of the extended Multi Linear Regression (eMLR) method shows that the ΔCant from 1994 to 2011 has largely remained confined to the upper 1000 dbar. The greatest changes occur in the upper 200 dbar in the SubAntarctic Zone (SAZ), where a maximum increase of 37 μmol kg−1 is found. South Atlantic Central Water (SACW) experienced the highest rate of increase in Cant, at 0.99 ± 0.14 μmol kg−1 yr−1, resulting in a rate of decrease in pH of −0.0016 yr−1. The highest rates of acidification relative to ΔCant, however, were found in SubAntarctic Mode Water (SAMW) and Antarctic Intermediate Water (AAIW). The low buffering capacity of SAMW and AAIW combined with their relatively high rates of Cant increase of 0.53 ± 0.11 μmol kg−1 yr−1 and 0.36 ± 0.06 μmol kg−1 yr−1, respectively, will lead to rapid acidification in the SAZ and simultaneously reduce the chemical buffering capacity of this significant CO2 sink.

The Surface Ocean CO2 Atlas (SOCAT) is an effort by the international marine carbon research community. It aims to improve access to carbon dioxide measurements in the surface oceans by regular releases of quality controlled and fully documented synthesis and gridded fCO2 (fugacity of carbon dioxide) products. SOCAT version 2 presented here extends the data set for the global oceans and coastal seas by four years and has 10.1 million surface water fCO2 values from 2660 cruises between 1968 and 2011. The procedures for creating version 2 have been comparable to those for version 1. The SOCAT website (http://www.socat.info/) provides access to the individual cruise data files, as well as to the synthesis and gridded data products. Interactive online tools allow visitors to explore the richness of the data. Scientific users can also retrieve the data as downloadable files or via Ocean Data View. Version 2 enables carbon specialists to expand their studies until 2011. Applications of SOCAT include process studies, quantification of the ocean carbon sink and its spatial, seasonal, year-to-year and longer-term variation, as well as initialisation or validation of ocean carbon models and coupled-climate carbon models.