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The Late Miocene global cooling (LMGC; approximately 7.9–5.8 Ma) was associated with remarkable changes in monsoon dynamics, biogenic bloom in the global oceans, and the rise of modern ecosystems at the expense of old biota. However, the possible linkage between the environmental changes and ecosystem shifts during the LMGC is still debated. In this paper, we show the high-resolution changes in the fluxes of selected radiolarian species, suggesting a drastic reorganization in the paleoceanography and ecosystem in the Japan Sea during the LMGC. The endemic radiolarian Cycladophora nakasekoi dominated the Japan Sea until 7.4 Ma when the Japan Sea sediment changed from dark radiolarian-rich sediment to organic-poor diatom ooze. Changes in the fluxes of C. nakasekoi and Tricolocapsa papillosa, the latter related to changes in the Pacific central water (PCW), show 100, 200, and ~ 500 ka cycles with their high flux mostly within the darker sediment intervals during the low-eccentricity period until 7.4 Ma, suggesting that orbitally paced PCW inflow might have been the major nutrient source into the Japan Sea. At about 7.4 Ma, these species decreased at the expense of increased Larcopyle weddellium, a radiolarian related to the North Pacific intermediate water (NPIW), and Cycladophora sphaeris, a subarctic radiolarian species, implying a decrease in PCW inflow and an increase in the inflow of NPIW and subarctic shallow water. Such a change would have been related to the LMGC-induced weakening in the Pacific Meridional overturning circulation and the southward shift of the subarctic front due to intensified East Asian winter monsoon. Such a drastic reorganization in the hydrography in the Japan Sea probably caused changes in nutrient provenance from the PCW to the NPIW and resulted in faunal turnover, marked by the disappearance of the old regional and endemic faunal components, such as C. nakasekoi.

Many studies are reconstructing flood records in the continental margins during the middle to late-Holocene. However, distinguishing the frequency and magnitude of flood events was difficult. Light gray event layers (GELs) in the sediment of Lake Suigetsu in Central Japan can solve this problem because they are recording the occurrence and magnitude of flood events during the last 80 years. Using these GELs, we aimed to reconstruct the frequency and magnitude of flood events during the last 8000 years. First, we verified whether GELs maintained the recording of flood events. We found that thin GELs (less than 40 mg/cm2 in mass) were rare, probably because of bioturbation, whereas thick GELs (larger than 40 mg/cm2 in mass) were rarely erased. We also found that GELs formed by the same amount of rainfall could have been thinner before 100 years ago. We revealed that the occurrence of extreme flood-origin event layers (EFELs: GELs thicker than 40 mg/cm2) during the last 8000 years may indicate the occurrence of extreme flood events (EFEs). Mass accumulation of EFELs may indicate the minimum estimation of rainfall on EFEs. There are several periods with higher frequency and magnitude of EFEs than those of the present level, agreeing with the periods of high flood activity in western Japan and East China. The frequency and magnitude of EFEs show different temporal variations. Northward and southward shifts in the westerly jet and monsoon fronts can partially explain such patterns.

The Japan Sea was a semi-closed marginal sea mainly connected to the subarctic northwestern Pacific via shallow seaways during the late Miocene. We use a multiple regression analysis with common extant radiolarian species groups to estimate the sea-surface temperature (SST) for the period between 9.1 and 5.3 Ma. Our results show a cooling of 8 °C between 7.9 and 6.6 Ma, when the SST dropped from 24 °C to 16 °C. We infer that this cooling dominantly reflects wintertime cooling related to an intensified East Asian winter monsoon. On the other hand, cooling of the summertime SST occurred from 6.6 to 5.8 Ma, suggesting that the late Miocene global cooling is composed of a wintertime cooling phase from 7.9 to 6.6 Ma and summertime cooling phase from 6.6 to 5.8 Ma.

The Tarim Basin is the major source of aeolian dust in the northern hemisphere. Glacial activity in the mountains, transportation by rivers and homogenization by wind are believed to be responsible for dust production within the basin. However, the major source(s) and homogenization process(es) are not clear. Moreover, provenance studies on fine fractions have never been conducted. Here, we measured electron spin resonance (ESR) signal intensity and the crystallinity index of quartz in fine (< 16 μm) and coarse (> 64 μm) fractions of river sediments, dry lake sediments and mountain loess to examine the process(es) that produce aeolian dust. The result suggests that the coarse fraction of the river sediment was derived from the bedrock in the drainage area. The ESR signal intensity and crystallinity index of the fine fraction of river sediments from the Tian Shan Mountains and mountainous rivers in the westernmost Kunlun and Pamir mountains are also similar to the coarse fraction, suggesting the same sources. However, the ESR signal intensity and crystallinity index of the fine fraction of river sediments from the Kunlun Mountains are different from the coarse fraction and converge towards values close to the average for the fine fraction of river sediments and mountain loess. Convergence of the ESR and crystallinity index values for the fine fraction of river sediments from the Kunlun Mountains can be explained by contamination of the river sediments by aeolian dust. The convergent values resulted from the homogenization of fine detrital material by repeated recycling within the basin.

International Ocean Discovery Program (IODP) conducted a series of expeditions between 2014 and 2016 that were designed to address the development of monsoon climate systems in Asia and Australia. Significant progress was made in recovering Neogene sections spanning the region from the Arabian Sea to the Japan Sea and south to western Australia. High recovery by advanced piston core (APC) technology has provided a host of semi-continuous sections that have been used to examine monsoonal evolution. Use of half APC was successful in sampling sand-rich sediment in Indian Ocean submarine fans. The records show that humidity and seasonality developed diachronously across the region, although most regions show drying since the middle Miocene and especially since ~4 Ma, likely linked to global cooling. The transition from C3 to C4 vegetation often accompanied the drying, but may be more linked to global cooling. Western Australia, and possibly southern China diverge from the general trend in becoming wetter during the late Miocene, with the Australian monsoon being more affected by the Indonesian Throughflow, while the Asian Monsoon is tied more to the rising Himalaya in South Asia and to the Tibetan Plateau in East Asia. The monsoon shows sensitivity to orbital forcing, with many regions having a weaker summer monsoon during times of Northern Hemispheric Glaciation. Stronger monsoons are associated with faster continental erosion, but not weathering intensity, which either shows no trend or decreasing strength since the middle Miocene in Asia. Marine productivity proxies and terrestrial environmental proxies are often seen to diverge. Future work on the almost unknown Paleogene is highlighted, as well as the potential of carbonate platforms as archives of paleoceanographic conditions.

Although there is increasing evidence for wet, monsoonal conditions in Southeast Asia during the late Eocene, it has not been clear when this environment became established. Cenozoic sedimentary sequences constrained by radiometrically dated igneous rocks from the Jianchuan Basin in the southeast flank of Tibetan Plateau now provide a section whose facies and climatic proxies determine this evolution. Semi-arid conditions had dominated the region since Paleocene controlled by the northern sub-tropical high pressure system, culminating in mid Eocene when desert dunes developed. From 36 Ma, the basin began to accumulate swamp sediments with coals, together with synchronous braided river deposits and diversified pollen assemblages, indicating significant increase in precipitation. This remarkable transition from dry to wet conditions precedes the Eocene/Oligocene boundary at 34 Ma, thus excluding general global cooling as the prime driver. We propose that uplift of Tibetan Plateau might have reached a threshold elevation by that time, operating through thermal and dynamic forcing, causing the inception or significant intensification of monsoonal rains to penetrate into this downwind locality.

The history of abrupt climate change in East Asia is often discussed from hydroclimate proxies that record the isotopic composition of rainfall. However, the underlying mechanisms remain obscure because water-isotope proxies respond to a wide variety of environmental variables. Here, we investigated millennial-scale climate variability in East Asia over the past 400,000 years using paired foraminiferal oxygen isotope and Mg/Ca records from the East Asian continental margin, thereby resolving variance into temperature and rainfall components. We found that the temperature and rainfall variabilities are largely asynchronous, with times when the global climate shifts from interglacial to glacial periods being the notable exception. These findings highlight the importance of both mean global state and magnitude of North Atlantic variability in determining the East Asian climate. Without a strong North Atlantic forcing, the regional feedback system might generate asynchronous temperature and rainfall variations, which is the background climate feature in East Asia.

The modern-day Tarim Basin is covered almost entirely by the Taklimakan sand desert and is one of the most arid regions in the world. Unraveling the aridification history of the desert is important for understanding global climate changes during the Cenozoic, yet the timing and mechanisms driving its formation remain controversial. One of the leading hypotheses is that the uplift of the Pamir, located to the west of the Tarim Basin, blocked the intrusion of moist air and induced the aridification in the Tarim Basin. In this study, we explore the linkage between the uplift of the Pamir and the desertification in the Tarim Basin from the late Eocene to the middle Miocene in the Aertashi section, which is located at the southwestern edge of the Tarim Basin and offers the longest sedimentary record with a reliable age model. Provenance changes in fluvial deposits along the Aertashi section were examined using electron spin resonance (ESR) signal intensity and crystallinity index (CI) of quartz in the sand fraction of fluvial sandstones and clast counting based on the identification of clast types by thin section observation to identify timings of tectonic events in the Pamir, from which clastic materials were supplied to the Aertashi section by rivers. Our results suggest that major provenance changes in the drainage of the paleo-Yarkand river delivering clasts to the Aertashi section occurred at ca. 27, 20, and 15 Ma. These timings are mostly consistent with those observed in previous provenance studies in the Aertashi section and probably reflect tectonic events in the Pamir. On the other hand, according to the previous studies, the first occurrence of sand dune deposits indicates that the Tarim Basin was relatively arid after ca. 34 Ma. Hence, our result does not support the hypothesis that the initial aridification in the Tarim Basin was triggered by the uplift of the Pamir and the resultant blocking of moisture supply from the Paratethys Sea, although the subsequent intensification of tectonic events at ca. 27 Ma in the Pamir might have caused aridification indicated by the initiation of loess deposition.

Aeolian dust input exerts significant influence on oceanic biogeochemical cycles and further potentially controls atmospheric CO2 concentrations. However, the possible link between long-term aeolian dust supply and primary productivity in the western North Pacific remains poorly understood. Here, we present a comprehensive study of major and trace elements and total organic carbon (TOC) concentrations of sediments from Integrated Ocean Drilling Program (IODP) Site U1430 in the southern Japan Sea, in order to reconstruct oceanic palaeoproductivity evolution and test its possible link to Asian dust input since 4 Ma. Palaeoproductivity proxies indicate remarkable increases in productivity at ∼3–2 Ma followed by high-frequency oscillations in productivity since 1.2 Ma. We suggest that higher dust-derived iron supply from Central Asia at 3–2 Ma, which was likely driven by the growth of the Northern Hemisphere ice sheets, could account for enhanced primary productivity and export production in the Japan Sea. Such increased oceanic palaeoproductivity could enhance organic carbon burial, which might contribute to the decrease in atmospheric CO2 concentrations, and provide a positive feedback to the global cooling. However, the Tsushima Warm Current (TSWC) intrusion via the southern Tsushima Strait, which was controlled by glacioeustatic sea level changes, has been the principal cause of the rapid changes in primary productivity and benthic redox condition since 1.2 Ma, regardless of continuously increased Asian dust input.

We reconstruct the provenance of aluminosilicate sediment deposited in Ulleung Basin, Japan Sea, over the last 12 Ma at Site U1430 drilled during Integrated Ocean Drilling Program Expedition 346. Using multivariate partitioning techniques (Q-mode factor analysis, multiple linear regressions) applied to the major, trace and rare earth element composition of the bulk sediment, we identify and quantify four aluminosilicate components (Taklimakan, Gobi, Chinese Loess and Korean Peninsula), and model their mass accumulation rates. Each of these end-members, or materials from these regions, were present in the top-performing models in all tests. Material from the Taklimakan Desert (50–60 % of aluminosilicate contribution) is the most abundant end-member through time, while Chinese Loess and Gobi Desert components increase in contribution and flux in the Plio-Pleistocene. A Korean Peninsula component is lowest in abundance when present, and its occurrence reflects the opening of the Tsushima Strait at c. 3 Ma. Variation in dust source regions appears to track step-wise Asian aridification influenced by Cenozoic global cooling and periods of uplift of the Tibetan Plateau. During early stages of the evolution of the East Asian Monsoon, the Taklimakan Desert was the major source of dust to the Pacific. Continued uplift of the Tibetan Plateau may have influenced the increase in aeolian supply from the Gobi Desert and Chinese Loess Plateau into the Pleistocene. Consistent with existing records from the Pacific Ocean, these observations of aeolian fluxes provide more detail and specificity regarding the evolution of different Asian source regions through the latest Cenozoic.

There are several reports of Australasian tektites found within a stratum called “laterite” layer widely distributed in Indochina. However, it has been debated whether these tektites are in situ or reworked. This uncertainty is because a detailed description of their field occurrence is lacking. Here, we describe the detailed occurrence of a cluster of tektite fragments recovered from the “laterite” layer near Huai Om, northeastern Thailand, and demonstrate the evidence of in situ occurrence of the tektites. At least 331 tektite fragments with a total weight of 713 g were found from a 40 × 30 cm area with 10 cm thickness in the uppermost part of the “laterite” layer. The very angular shapes and very poorly sorted nature of the fragments, restoration of larger tektite fragments into one ellipsoidal Muong Nong-type (MN) tektite mass, and the similar chemical composition of the fragments suggest that these MN tektite fragments represent a tektite mass that fragmented in situ. The fact that the fragments were found within the “laterite” layer is inconsistent with a previous interpretation that the upper surface of the “laterite” layer is a paleo-erosional surface, on which the tektites are reworked. The size distribution of the fragments is bi-fractal following two power laws in the range from 10 to 26 mm and from 26 to 37 mm, respectively, with fractal dimensions (Ds) of 2.2 and 7.5. The Ds for the coarse fraction of the tektite fragments is larger than the Ds for rock fragments generated by rockfalls and rock avalanches and similar to the Ds for the coarser fraction fragments generated by high-speed impact experiments, suggesting that the tektite fragments were formed through intense fragmentation by a relatively high energetic process. The occurrence of the fragments forming a cluster indicates that the fragments were not moved apart significantly after fragmentation and burial. Based on these results, we concluded that the mass of a tektite was fragmented at the time of the landing on the ground after traveling a ballistic trajectory and has not been disturbed further.

The Tarim basin is one of the most arid areas in the world and its major part is occupied by the Taklimakan desert. Although unraveling the history of aridification of Taklimakan desert is important to understand the global climate change during the Cenozoic, the timing and the mechanism of its formation are still controversial. One of the hypotheses is that the uplift of the Pamir locating to the west of the Tarim basin blocked the intrusion of the moist air and induced the aridification in the Tarim basin. In this study, we explored the linkage between the uplift of the Pamir and the desertification in the Tarim basin during the period from the late Eocene to the middle Miocene. Provenance changes of the fluvial deposits along the Aertashi section, which is located in the southwestern edge of the Tarim basin and offers the longest record with the reliable age model, was examined using Electron Spin Resonance (ESR) signal intensity and crystallinity index (CI) of quartz in the sand fraction of fluvial sandstone and the thin section observation to identify the timings of tectonic events in the Pamir from which clastic materials were supplied by rivers. Our results suggest that major provenance changes in the drainage of the river delivering the clasts to the Aertashi section occurred at ca. 26 Ma, 20 Ma, and 15 Ma. These timings are mostly consistent with the timings observed in the previous provenance studies in the Aertashi section and probably reflect tectonic events in the Pamir. On the other hand, the Tarim basin was under the relatively arid condition after ca. 34 Ma based on the first occurrence of sand dune deposit. Hence, our result does not support the hypothesis that the onset of the aridification in the Tarim basin was caused by the uplift of the Pamir and consequent shut down of the moisture supply from the Paratethys Sea although the afterward intensification of tectonic events in the Pamir might be related to the phased uplift.

High resolution multi-proxy records, including geochemical and grain-size data from detrital sediments of IODP Site U1429 in the northern Okinawa Trough, provide reliable evidence for constraining sediment source and transport processes. They also allow silicate weathering and erosion controlled by sea-level change and East Asian summer monsoon evolution since 34 ka to be reconstructed. Provenance proxies indicated that sediments in the northern Okinawa Trough were mainly supplied by the Yellow River middle reach at ~ 34–8 ka. The low sea level and proximity of paleo-Yellow River mouth to the northern Okinawa Trough were the causes of the dominant Yellow River input. After ~ 8 ka, a retreated Yellow River mouth coupled with the blocking effect of the Kuroshio Current and its branches, together with strong East Asian summer monsoon precipitation resulted in relatively strong sediment input from Kyushu to the northern Okinawa Trough. Meanwhile, Yellow River upper reach supplied more sediments to the study site than that during the ~ 34–8 ka. On glacial-interglacial scale, silicate weathering proxies indicate that the core sediment was more weathered during the last glacial and deglacial than that in the modern Yellow River. We attribute this to the increased upper reach sediment input, which supplied more weak weathered sediment to the study site during the Holocene. Besides, composite effect of weathering during glacial and deglacial sediment production and additional weathering upon subaerial exposure of shelf deposits during low sea-level stage, as well as older weathered sediments reworking during sea-level rise could also account for this weathering regime. On multi-millennial scale, from ~ 34 to 18.5 ka, silicate weathering was mainly controlled by the East Asian summer monsoon, with a cooling and drying climate associated with weakened summer monsoon activity. This is consistent with the reduced alteration of sediments eroded from the Yellow River basin. From ~ 18.5 to 8 ka, strong reworking of older weathered sediments overwhelmed the East Asian summer monsoon in controlling silicate weathering, which induced a continuous increase in chemical alteration of the sediments during this period.

Climate and vegetation in Japan are strongly influenced by the East Asian Monsoon (EAM) and the ocean environment of the Japan Sea. This study discusses the findings from a new pollen record from Integrated Ocean Drilling Program Site U1427, situated off the northern coast of the Honshu Island in western Japan, which allows for direct comparisons with other oceanographic proxies from this area. Our findings demonstrate the orbital-scale vegetation changes in this area and their land-ocean-atmosphere linkages during the last 550 ka. During surface-water freshening events in the Japan Sea, likely associated with colder water temperatures caused by the very low eustatic sea levels and the consequent isolation from the surrounding seas during the full-glacial periods, cold-cool conifer forests became dominant under the extremely dry pseudo-continental conditions in the Japanese islands. In contrast, temperate broadleaf forests increased rapidly when the surface-freshening events ended and a weak inflow of warm water began at the onset of deglaciation, in addition to the rapid atmospheric climate warming during termination periods. During the intermediate periods between the full interglacial to the full-glacial, the Tp ratio (pollen temperature index) increased in association with the summer insolation maxima caused by the Earth's precession cycle that coincide with Chinese stalagmite negative δ18O peaks, whereas Cryptomeria pollen abundance (high-precipitation index) increased in association with the winter insolation maxima. Those orbital-scale vegetation fluctuations were attributed to the changes in seasonal temperature and precipitation patterns, where were influenced by the EAM changes that were associated with seasonal insolation changes around the Japanese archipelago. Cryptomeria forests likely developed under cool and wet conditions throughout a year with low seasonal contrasts, whereas deciduous broadleaf forests increased under condition of high seasonality with cool summers and colder, drier winters. Alternating fluctuations between the Tp ratio and Cryptomeria pollen abundance following the insolation changes were typically observed after MIS 9 and are thought to have been affected by the periodicity shift in the EAM fluctuations across the Mid-Brunhes Event.

International audience; We present high-resolution analyses of clay mineral assemblages combined with analysis of Sr–Nd–Pb isotopic compositions of the

The East China Sea (ECS) is a shallow marginal sea that is sensitive to glacio-eustatic sea-level changes and is influenced by warm oligotrophic water of the Kuroshio Current (KC), the nutrient-rich Taiwan Warm Current, and freshwater discharges from rivers in southern China during the East Asian summer monsoon season. In this area, local paleoceanographic changes for times prior to 40 ka remain poorly studied because of high sediment accumulation rates on the seafloor. During Integrated Ocean Drilling Program Expedition 346, long sediment cores representing the last 400 kyr were retrieved from the northern part of the ECS (Site U1429). In these cores, radiolarians are abundant and well-preserved, thus using the ecological properties of radiolarians, we analyzed how glacio-eustatic sea-level variations have influenced the paleoceanography of the ECS over the last 400 kyr, with a focus on changes in water properties at intermediate depths. Additionally, the summer sea surface temperature (SST) and intermediate water temperature at about 500 m were quantified by means of data on selected radiolarian species. The KC influenced the shallow water at Site U1429 during each interglacial period over the last 400 kyr (marine isotope stages [MISs] 1, 5, 7, 9, and 11), causing a high summer SST (about 27 °C), although inflow of the KC into the ECS was probably delayed until after the sea-level maximum of interglacial MIS 1 and MIS 5. During this lag time, ECS shelf water was the dominant influence on the system. During glacial periods (MISs 2–4, 6, and 10), our data suggest that coastal conditions prevailed, probably because of a sea-level drop of more than 90 m. At these times, the summer SST was colder, ca. 20 °C. Changes in the relative abundance of Cycladophora davisiana indicate that the most significant changes in the bottom water occurred during MIS 6, when the bottom water likely became poorer in oxygen. An increase in the shallow-water primary productivity during MIS 7 and MIS 6 was probably the key factor causing the oxygen-poor conditions.

The marine organic carbon content in sediments is a useful tool for reconstructing past productivity in the ocean. Bromine has been proposed as a useful proxy for marine organic carbon, since bromine is more concentrated in marine organic matter compared to terrestrial organic matter. Here, we present a high-resolution Quaternary record of marine organic carbon in the hemipelagic sediments of the Japan Sea obtained during Integrated Ocean Drilling Program (IODP) Expedition 346. We measured the bromine content in the sediments using an XRF core scanner (ITRAX). The total organic carbon content, total nitrogen, and stable carbon isotope values were also measured for discrete samples from the same sediments. The total organic carbon/total nitrogen ratio and the stable carbon isotope ratio of the total organic carbon are used to estimate the marine organic carbon content within the total organic carbon. The Br counts and marine organic carbon content show a high correlation, which we used to construct a calibration equation of the marine organic carbon content from the Br counts. Using the calibration equation, we reconstructed the changes in the marine organic carbon content during the Quaternary with a time resolution of ~ 50 years using sediment cores from IODP Site U1424 in the east central Japan Sea. The method to estimate the marine organic carbon content from the Br counts measured by the XRF core scanner proposed in this paper will be a useful tool to reconstruct the organic carbon content with high resolution and high speed.

As the largest river of China, the Yangtze River transports large amounts of sediments to the adjacent oceans. Provenance of these ancient marine sediments can only be deciphered when the source-to-sink process of modern sediments in the Yangtze River is fully understood. Many methods have been used to study the provenance of river sediment and an environmental magnetic method is applied in this study because of its fast, nondestructive advantages. Magnetic properties of suspended particulate matter (SPM) along the Yangtze River were measured to provide a holistic understanding about magnetic properties of sediments in this river and its controlling factors. The results indicate that the dominant magnetic mineral in SPM is magnetite, with a small contribution of hematite and goethite. Significant spatial variation was observed in most of the magnetic parameters, which primarily reflects the distribution of major geologic units along the drainage area of the river. Anthropogenic influences are also recorded in the magnetic parameters. The Three Gorges Dam results in a dramatic decrease of magnetic minerals in the downstream reaches, since its construction in 2003. In addition, small variations in magnetic properties of SPM are found along water depth, together with a clear seasonal shift at Datong station. This seasonal variation of magnetic properties of SPM is driven by variability in both hydrology and source contributions. This complicates the use of magnetic parameters for provenance studies. Magnetic properties of sediments in rivers are capable of tracing provenance areas, but caution must be taken into account.

Asian dust has a significant impact on the natural environment. Its variability on multiple timescales modulates the ocean biogeochemistry and climate. We demonstrate that temporal changes in the deposition flux of Aeolian dust recorded in sediments from Lake Suigetsu, central Japan, during the last century exhibit a continuous decreasing trend and a decadal-scale decrease in 1952–1974. The former decreasing trend can be explained by a decrease in the dust storm frequency at source regions due to the warming of Mongolia in the twentieth century, suggesting future decrease of Asian dust transport with further warming in Mongolia. Decadal-scale decrease of Aeolian dust is explained by weaker westerlies in lower latitudes in central Japan, reflecting a weaker Aleutian Low during the corresponding period. Decadal-scale westerly change probably causes north–south shifts of the dominant dust transport path, which affects subarctic northern Pacific Ocean biogeochemistry by changing the micronutrient iron supply.

Atsushi Yoshida, Nobuhiro Moteki, Sho Ohata, Tatsuhiro Mori, Ryuji Tada, Pavla Dagsson-Waldhauserov a, and Yutaka Kondo Department of Earth and Planetary Science, The University of Tokyo, Tokyo, Japan; Faculty of Environmental Sciences, Agricultural University of Iceland, Hvanneyri, Iceland; Faculty of Physical Sciences and Faculty of Earth Sciences, University of Iceland, Reykjav ik, Iceland; Faculty of Environmental Sciences, Czech University of Life Sciences Prague, Prague, Czech Republic; Meteorology and Glaciology Group, National Institute of Polar Research, Tokyo, Japan

Astronomical solutions for planetary orbits beyond several tens of million years (Myr) ago have large uncertainties due to the chaotic nature of the Solar System, mainly Myr-scale cycles related with the Earth-Mars secular resonance. Our only accessible archive for unraveling the Earth's orbital variations in the geologic past are sedimentological records, yet their reliability and uncertainties are still debated. Here, we describe Myr-scale orbital signals of early Mesozoic monsoon records from two different sedimentary settings (lake level records of the equatorial Pangea and biogenic silica burial flux of deep-sea Panthalassa), along with a marine carbon isotope compilation. Although most of the dominant multi-Myr cycles are not exactly of the same frequency, 1.8 Myr cycles during ∼216–210 Ma are detected from the two mutually-independent sedimentary settings, and differ from available astronomical solutions. This finding provides not only convincing evidence for the chaotic nature of the Solar System in the geological past, but also additional constraints on astronomical models. On the other hand, besides the orbital cycles, tectonic forcing and consequent climatic perturbations could also have affected the proxies on multi-Myr timescales during episodes of large igneous province emplacement, such as Siberian trap volcanism (252–245 Ma), Wrangellia (233–225 Ma), Central Atlantic Magmatic Province (202–200 Ma), and Karoo-Ferrar volcanism (184–180 Ma). If we can distinguish orbital signals from other effects, such as tectonic and volcanic processes, the multi-Myr cycles in geologic records have the potential to reconstruct the chaotic evolution of the Solar System.

Previous studies showed that the evolution of the Japan Sea paleoceanography since the Miocene has been influenced by the regional tectonism (e.g., opening/closing of the connecting seaways) and regional/global climate. In the Japan Sea, Expedition 346 of the Integrated Ocean Drilling Program (IODP) retrieved core sediments dating back to the Miocene at two sites (U1425 and U1430). In this study, we reconstruct shallow-to-deep-water hydrography of the Japan Sea during the Mio-Pliocene based on radiolarian assemblages at Sites U1425 and U1430 considering the local tectonism and changes in global/regional climate. Our data suggest that glacioeustatic sea-level changes have probably had an influence on the local paleoceanography between 9.5 and 7.0 Ma. Indeed, warm water probably flowed from the North Pacific into the Japan Sea when sea level was high via shallow central and eastern seaways. In addition, the sill depth of the northern seaway was probably close to 1000 m between 9.5 and 7.8 Ma and had probably allowed inflow of oxygen minimum zone water from the North Pacific to the Japan Sea when sea level was high. In contrast, our data imply that Cycladophora nakasekoi, an endemic species to the Japan Sea, dominated between 9.5 and 7.3 Ma when sea level was low. Our data also suggest a progressive shoaling of the sill for the period since 7.8 Ma and that global climatic events such as such the late Miocene cooling (7.5–5.5 Ma) and the early Pliocene warmth have had a sustained influence on the Japan Sea. During the mid-Pliocene, a deep cooling of the subsurface to intermediate water of the Japan Sea likely occurred because species related to subarctic subsurface to intermediate waters were dominant between 5 and 3.8 Ma. The Northern Hemisphere Glaciation (ca. 3.0–2.7 Ma) and Mid-Pleistocene Transition (1.2–0.8 Ma) have both likely intensified the cooling of the Japan Sea.

The evolution of the provenance of aeolian deposits on the Chinese Loess Plateau (CLP) is closely linked to changes in source aridity and dust transport dynamics. Although previous studies have revealed that the provenance of Chinese aeolian deposits may have fluctuated on tectonic timescales, the exact timing and cause of the provenance shifts remain poorly constrained due to limitations of the isotopic and mineralogical tracers used. Here we report the results of electron spin resonance (ESR) signal intensity and crystallinity index (CI) of fine-grained (

Variation of dissolved 87 Sr/ 86 Sr in the Yangtze River is poorly documented compared to other Tibetan-sourced rivers. Here, we trace the Sr isotopic composition in space and time across the Yangtze River basin using a systematic sampling strategy. The 87 Sr/ 86 Sr values of samples collected at different depths within the water column at three gauge stations located in the upper, middle and lower reaches of the river are very similar, indicating a well-mixed water body at a given location. Data from basin wide-samples shows low 87 Sr/ 86 Sr values in the upper reaches while higher 87 Sr/ 86 Sr values in the middle-lower reaches which mainly reflect the controls of source rocks. A time series record at the lowermost reaches of the river indicates a temporal variation of 87 Sr/ 86 Sr values from 0.7101 to 0.7109, with a discharge weighted value of 0.7106. We suggest that temporal variations of the isotopic composition result from changes in the relative contributions from different terrains associated with spatial variability of rainfall within the basin. A mixing model based on Sr values deduced from basin-wide sampling from different seasons yields similar temporal variations of Sr isotopic composition compared to experimental data. Calculation of Sr fluxes indicates that the upper reaches contribute 3 times as much as the middle and lower reaches to total Sr flux. The annual Sr flux of the Yangtze River to the East China Sea is estimated to be 1.9 × 10 9 mol · a − 1 , which is one magnitude higher than that of the Brahmaputra and Ganges.

The astronomical time scale (ATS) has provided high-resolution geochronology. However, the early Mesozoic ATS is still under construction partly due to the lack of continuous pelagic sequences of the early Mesozoic. Here we present ca. ∼ 70 Myr long ATS constructed from the early Mesozoic deep-sea bedded chert sequence exposed in the Inuyama area, central Japan. The sedimentary rhythms of bedded chert display a full range of climatic precession related cycles; ∼20-kyr cycle as a chert–shale couplet and ∼100-, 405-, 2000- to 4000-, and 10,000-kyr cycles as chert bed thickness variation. The newly established ATS (Inuyama-ATS) is tuned by 405-kyr eccentricity cycle and is anchored at the end-Triassic radiolarian extinction level as 201.4 ± 0.2 Ma . This Inuyama-ATS gives ages consistent with the radiometric ages projected to the Inuyama deep-sea sequence using biostratigraphy and carbon isotope stratigraphy. The Inuyama-ATS provides the age constraints for the Triassic and Jurassic stage boundaries, which support the “Long-Norian” option of Muttoni et al. (2004) . Because the deep-sea bedded chert sequence covers a long time interval before the Cretaceous, the ATS for the bedded chert will serve as a template for the astrochronology of Mesozoic and older ages.

Two piston cores (PC-05 and PC-08) were collected on the Yamato Rise in the East Sea/Japan Sea during the KR07-12 cruise. Both cores showed typical alternations of light (high L*) and dark (low L*) layers, which are characteristic in the hemi-pelagic sediment deposited in the deep part of the East Sea/Japan Sea. A composite core was achieved with the successful replacement of almost half of the upper part of core PC-05 by the entirety of core PC-08 based on the co-equivalence of L* values and the dark layers, because an interval (170 cm–410 cm) of core PC-05 was considerably disturbed due to fluidization during the core execution. Chronostratigraphy of the composite core was constructed by the direct comparison of L* values to the well-dated core MD01-2407 that was obtained in the Oki Ridge. The lower-bottom of the composite core extended to Marine Isotope Stage (MIS) 14, based on the age estimate by LR04 stacks. Downcore opal variation of the composite core exhibited the distinct orbital-scale cyclic changes; high during the interglacial and low during the glacial periods. However, downcore CaCO3 variation showed no corresponding orbital-scale cyclic change between glacial and interglacial periods. Some intervals of both periods were high in CaCO3 content. Frequent and large fluctuations in CaCO3 content seemed to be more related to the presence of dark layers containing thin lamination (TL) within the glacial and interglacial intervals. It is worthy to note that MIS 2 and MIS 12 are characterized by distinctly high CaCO3 content, showing up to 18% and 73%, respectively, among the glacial periods. Furthermore, in terms of lithology, MIS 2 was characterized by a thick dark layer (low L* values) with TL, whereas MIS 12 preserved the distinctly light layer (high L* values) with parallel laminations. Another remarkable dissimilarity between MIS 2 and MIS 12 was the nature of their CaCO3 constituent; the CaCO3 constituent of MIS 2 consisted of mostly planktonic foraminifera, whereas that of MIS 12 was mostly dump of coccolithophorids, regardless the presence of planktonic foraminifera. The distinctness of the CaCO3 constituents between MIS 2 and MIS 12 indicates that the preservation of CaCO3 contents was different temporarily during the glacial periods in the East Sea/Japan Sea. Enhanced CaCO3 preservation in MIS 2 is attributed primarily to less dissolution during the sinking through the water column or at the seafloor, but increased CaCO3 preservation in MIS 12 is mainly due to the high primary production in the surface water. With respect to the different function of the biological pump which controls CO2 cycles, the East Sea/Japan Sea clearly experienced carbonate-ocean-like state during MIS 12, despite normally silica-ocean-like state.

Previous studies find decadal climate variability possibly related to solar activity, although the details regarding the feedback with the ocean environment and ecosystem remain unknown. Here, we explore the feedback system of solar irradiance change during the Bolling-Allerod period, based on laminated sediments in the northern Bering Sea. During this period, well-ventilated water was restricted to the upper intermediate layer, and oxygen-poor lower intermediate water preserved the laminated sediment. An 11-year cycle of diatom and radiolarian flux peaks was identified from the laminated interval. Increased fresh meltwater input and early sea-ice retreat in spring under the solar irradiance maximum follow the positive phase of Arctic Oscillation which impacted the primary production and volume of upper intermediate water production in the following winter. Strength of this 11 year solar irradiance effect might be further regulated by the pressure patterns of Pacific decadal oscillation and/or El Nino-Southern Oscillation variability.

Changes in the intensity of the influx of the Tsushima Warm Current (TWC) in the south-central part of the Japan Sea (JS), or East Sea in Korean, were reconstructed for the last 460 kyr at IODP Site U1427 using the composition and abundance of the coccolithophore assemblage. In addition, the recent distribution of coccolithophore taxa in the JS and the East China Sea was assessed using electron microscopy. Coccolithophore assemblages, dominated by Emiliania huxleyi and Gephyrocapsa species, and coccolith abundance reveal a strong relationship between sea level and ocean variability over the last five glacial/interglacial cycles, in good agreement with planktic foraminiferal data. Three different circulation modes based on calcareous nannofossil and foraminifera TWC indicators were proposed for the JS. Coccolith production was low and TWC indicators (i.e., Gephyrocapsa oceanica, Calcidiscus leptoporus s.l., and Helicosphaera carteri) absent due to the isolation of the JS during glacials in response to global sea level falls (Mode 1). In contrast, coccolith abundance and TWC indicators reach a maximum due to the most intense TWC flow through the Tsushima Strait during interglacials (Mode 3). Intermediate conditions (Mode 2) are characterized by moderate/high coccolith numbers, presence of TWC coccolith indicators, and rare TWC planktic foraminifera indicators. This mode resulted in intermittent variations in the contribution of the TWC and East China Sea coastal water due to relatively low sea level stands (ca. −90 m to −20 m). Coccoliths dominated the carbonate sequence prior to MIS 8 and were major contributors to the total carbonate of the sediment at Site U1427, suggesting high coccolithophore productivity and a bloom-type environment during MIS 11 and 9. These changes in the carbonate chemistry caused by glacio-eustacy in the JS at the northwest margin of the Pacific Ocean should be considered in future paleoceanographic and paleoclimate models.

[1] The causes of spatial and temporal changes in East Asian summer monsoon (EASM) precipitation on millennial to multimillennial time scales during the Holocene have not yet been resolved. Here, we examine the relationship between spatial variations in EASM precipitation and the westerly jet (WJ) path over East Asia during the Holocene using the provenance of eolian dust in Japan Sea sediments, which we interpret to reflect changes of the WJ path over East Asia and/or surface conditions of desert areas. The contribution of dust from the Mongolian Gobi Desert relative to that from the Taklimakan Desert shows millennial-scale to multimillennial-scale minima at 11.5–10, 7–5, and 3.5–1.5 kyr B.P., which we attribute to earlier seasonal northward progression of the WJ. These dates correlate with precipitation maxima along the present northwestern EASM margin and minima in eastern Northeast China and the Yangtze River Basin, suggesting that the WJ shifted northward earlier in the year, allowing earlier northward migration of the EASM rainband and generating abundant precipitation in the northwestern EASM margin. Therefore, during the Holocene, changes of the WJ path probably contributed to the millennial-scale to multimillennial-scale EASM precipitation changes and its northwest-southeast contrast within China. Our findings suggest that WJ path changes are critical to understand the dynamics of EASM in the past, present, and future.

The temporal change in the number of oxygen vacancies in quartz was investigated by ob-serving the E1’ center in the atmospheric depositions collected at two cities in Japan in the recent past. The depositions collected at Fukuoka in March show the ESR intensities being correlated with the sum of the number of the days, in the month, on which Kosa was observed while no such correlation was found in the deposition those collected at Akita but a trend of decrease with time. The present results suggest that the number of oxygen vacancies in quartz might be useful to estimate quantitatively the contribution of the dust originated from China to the atmospheric deposition in Japan.

[1] Electron spin resonance (ESR) signal intensity and crystallinity index (CI) of fine- ( 16 µm) quartz were measured in surface samples from the Taklimakan desert in western China, the Badain Juran, Tengger and Mu Us deserts in northern China, and the Gobi desert in southern Mongolia to evaluate whether these geophysical parameters can serve as reliable provenance tracers of Asian dust. The results indicate that spatial variability of both ESR signal intensity and CI is evident within the Taklimakan deserts and the Mongolian Gobi, but less significant in the three deserts of northern China. Coarse-grained quartz from the Mongolian Gobi and northern China deserts can be differentiated from the Taklimakan desert using the ESR signal intensity. Fine-grained quartz originating from three major Asian dust sources, i.e., the Gobi-sandy deserts in western China, northern China and southern Mongolia, can be distinguished effectively using the combination of ESR and CI signals. Our results suggest that ESR signal intensity and CI can discriminate the sources of fine-grained quartz better than coarse-grained quartz, providing an effective approach to trace the provenance of fine-grained dust deposition on the land and in the ocean.

Article history: The Paleoproterozoic (2.5-2.0 Ga) is one of the most important periods in Earth's history, and was characterized by a rise in atmospheric oxygen levels and repeated (at least three) severe glaciations (the Huronian glaciations). In this study, we investigate redox conditions in the atmosphere and in shallow- marine environments immediately after the first Huronian glaciation based on the isotopic composition of Os, and the abundance of redox-sensitive elements (Os, Re, and Mo) in sedimentary rocks from the Huronian Supergroup, Canada. We found no significant authigenic enrichment of Os in the sedimentary rocks deposited during the first Huronian deglaciation. The initial isotopic composition of Os in the sediments was close to that of chondrite at the time of deposition ( 187 Os/

In the densely populated region of East Asia, it is important to know the mechanism, scale, and frequency of heavy precipitation brought about during the monsoons and typhoons. However, observational data, which cover only several decades, are insufficient to examine the long-term trend of extreme precipitation and its background mechanism. In humid areas, the transport flux of a suspended detrital material through a river system is known to have an empirical power relationship with precipitation. Thus, the sedimentation flux of a fine detrital material could potentially be used as a proxy for reconstructing past heavy precipitation events. To test the idea that the sedimentation flux of detrital materials records past heavy precipitation events (e.g., typhoons), we focused on the detrital flux estimated from the annually laminated sediment of Lake Suigetsu, central Japan, which is capable of accurately correlating the age of detrital flux with the precipitation record. We first established a precise age model (error within ±1 year in average) beginning in 1920 A.D. on the basis of varve counting fine-tuned by correlation between event layers with historical floods. The flux of the detrital material (g/cm2/year) was estimated on the basis of Al2O3 content (wt%), dry bulk density (g/cm3), and sedimentation rate (cm/year) calculated from the age model. The detrital flux of background sedimentation showed a weak positive correlation with annual and monthly (June and September) precipitation excluding heavy precipitation that exceeded 100 mm/day. Furthermore, the thickness of instantaneous event layers, which corresponds to several maxima of detrital flux and is correlated with floods that occurred mainly during typhoons, showed a positive relationship with the total amount of precipitation that caused a flood event. This result suggests that the detrital flux maxima (deposition of event layers) record past extreme precipitation events that were likely associated with typhoons that hit the middle part of Honshu Island. Based on this result, the record of typhoon-caused flood events can go back to older period (e.g., last glacial period) on the basis of the occurrence, and thickness, or mass flux of event layers using long sediment cores from Lake Suigetsu.

Uplift of the Himalaya and Tibetan Plateau (HTP) and its linkage with the evolution of the Asian monsoon has been regarded as a typical example of a tectonic–climate linkage. Although this linkage remains unproven because of insufficient data, our understanding has greatly advanced in the past decade. It is thus timely to summarize our knowledge of the uplift history of the HTP, the results of relevant climate simulations, and spatiotemporal changes in the Indian and East Asian monsoons since the late Eocene. Three major pulses of the HTP uplift have become evident: (1) uplift of the southern and central Tibetan Plateau (TP) at ca. 40–35 Ma, (2) uplift of the northern TP at ca. 25–20 Ma, and (3) uplift of the northeastern to eastern TP at ca. 15–10 Ma. Modeling predictions suggest that (i) uplift of the southern and central TP should have intensified the Indian summer monsoon (ISM) and the Somali Jet at 40–35 Ma; (ii) uplift of the northern TP should have intensified the East Asian summer monsoon (EASM) and East Asian winter monsoon (EAWM), as well as the desertification of inland Asia at 25–20 Ma; and (iii) uplift of the northeastern and eastern TP should have further intensified the EASM and EAWM at 15–10 Ma. We tested these predictions by comparing them with paleoclimate data for the time intervals of interest. There are insufficient paleoclimate data to test whether the ISM and Somali Jet intensified with the uplift of the southern and central TP at 40–35 Ma, but it is possible that such uplift enhanced erosion and weathering that drew down atmospheric CO2 and resulted in global cooling. There is good evidence that the EASM and EAWM intensified, and desertification started in inland Asia at 25–20 Ma in association with the uplift of the northern TP. The impact of the uplift of the northeastern and eastern TP on the Asian monsoon at 15–10 Ma is difficult to evaluate because that interval was also a time of global cooling and Antarctic glaciation that might also have influenced the intensity of the Asian monsoon.

The East China Sea (ECS) responds to changes in the strength of the Kuroshio and East Asian monsoon activity. Multidecadal resolution records of the palaeotemperature indices and from core KY07-04 PC-1 show that the hydrology of the ECS responded to variability in the East Asian winter monsoon. Unlike Mg/Ca-derived sea surface temperatures, which show neither warming nor cooling trends during the Holocene, the record showed a general warming trend at a rate of 0.2°C ka−1. This warming was attributable to shrinkage of the Yellow Sea Central Cold Water and/or weaker winter cooling of the surface water. The record indicated a centennial-scale variability with an ∼1°C amplitude superimposed on the warming trend that reflected changes in the East Asian winter monsoon and/or the Kuroshio. Temperature minima appeared at ca. 3.0, 4.7, 6.2, 7.9 and 9.0 ka, and spectral analysis of the last 7 ka revealed significant peaks with periodicities of approximately 210, 250, and 440 years that were close to those observed in solar radiation. The reconstructed winter monsoon variability is consistent with Chinese documentary records for the last two millennia. Copyright © 2012 John Wiley & Sons, Ltd.

After the severest mass extinction event in the Phanerozoic, biotic recovery from the extinction at the Permian–Triassic boundary required approximately 5 my, which covers the entire Early Triassic. It is important to obtain information on the superocean Panthalassa, which occupied most of the world ocean, to explore paleoenvironmental changes during the Early Triassic at the global scale. In order to establish the continuous lithostratigraphy of pelagic sediments in Panthalassa during the Early Triassic, high-resolution reconstruction of the Lower Triassic pelagic sequence in Japan was conducted for the first time based on detailed field mapping and lithostratigraphic correlation in the Inuyama area, central Japan. The reconstructed Early Triassic sequence is approximately 9.5 m thick, consists of five rock types, and is divided into eight lithological units. For the reconstructed continuous sequence, measurement of carbon isotopic composition of sedimentary organic matter (δ13Corg) was carried out. Stratigraphic variation of the δ13Corg value shows large-amplitude fluctuations between −34.4 and −21.0‰ throughout the sequence. In order to establish a higher resolution age model for the reconstructed Lower Triassic pelagic sequence, we correlated δ13Corg records in the Inuyama area with high-resolution isotopic profiles of carbonate carbon (δ13Ccarb) from shallow-marine carbonate sequences in southern China based on the similarity in general variation patterns with age constraints by radiolarian and conodont biostratigraphy. The result provides a high-resolution time scale for the pelagic sequence of Panthalassa during the Smithian and Spathian. The age model suggests a drastic increase in sedimentation rate during the late Smithian, which should have been caused by the increase in terrigenous input to this site.

Bering Sea sediments contain detrital materials from the Yukon River. These materials may contain records of past climate changes in the Arctic area, such as the melting of glaciers around the drainage basin of the Yukon River, which help to understand hydrological cycle in this area. In the Bering Sea, however, the spatial extent and pattern of the detrital materials supplied from the Yukon River is not yet fully understood. Here we developed a method to identify clay- to sand-sized detrital materials derived from the Yukon River based on electron spin resonance (ESR) intensity of the E 1 ' center and the crystallinity of quartz. We then estimated the spatial pattern of quartz contributed by the Yukon River on the Bering Sea shelf by applying the method to core-top samples from the continental shelf and slope of the eastern Bering Sea. The results showed a large contribution of sand-sized quartz from the Yukon River to wide areas of the continental shelf and slope, whereas contributions of clay- to silt-sized quartz from the Yukon River were small, except on the northeastern shelf. These spatial distribution patterns suggest that sand-sized quartz was repeatedly reworked and transported by processes such as storm surges to the outer continental shelf, whereas the clay- to silt-sized quartz on the northeastern shelf was supplied, as suspended materials, directly from the Yukon River.

A high-resolution record of the radiolarian assemblage from 60 to 10 ka was investigated using a piston core (PC-23A) obtained from the northern slope of the Bering Sea. Faunal changes based on the 29 major radiolarian taxa demonstrated that the surface and deep water conditions in the Bering Sea were related to the orbital and millennial-scale climatic variations known as glacial–interglacial and Dansgaard–Oeschger (D–O) cycles, respectively. During interstadial periods of the D–O cycles, the assemblage was characterized by increases in the high-latitude coastal species Rhizoplegma boreale and the upper-intermediate water species Cycladophora davisiana, while the sea-ice related species Actinomma boreale and A. leptodermum and many deep-water species such as Dictyophimus crisiae and D. hirundo tended to be reduced. This trend was more apparent in two laminated intervals at 15–13.5 and 11.5–11 ka, which were correlated with well-known ice-sheet collapse events that occurred during the last deglaciation: melt-water pulse (MWP)-1A and MWP-1B, respectively. The radiolarian faunal composition in these periods suggests that oceanic conditions were different from today: (1) surface water was affected by increased melt-water discharge from continental ice-sheet, occurring at the same time as an abrupt increase in atmospheric temperature, (2) upper-intermediate water (ca. 200–500 m) was well-ventilated and organic-rich, and (3) lower-intermediate water (ca. 500–1000 m) was oxygen-poor. Conversely, the sea-ice season might have been longer during stadial periods of the D–O cycles and the last glacial maximum (LGM) compared to the interstadial periods and the earliest Holocene. In these colder periods, deep-water species were very abundant, and this corresponded to increases in the oxygen isotope value of benthic foraminifera. Our findings suggest that the oxygen-rich water was present in the lower-intermediate layer resulting from intensified ventilation.

The origin and climate implications of authigenic carbonate minerals from Lake Qarun, Egypt, were examined in relation to the mid–late Holocene climate changes. These minerals occur as very thin (0.5–3 mm), very fine, well-sorted, white to pale yellow aragonite or calcite laminae intercalated with olive green clayey silt with sharp and horizontal contacts. Under the scanning electron microscope (SEM), aragonite appears as dense euhedral and ellipsoidal (rice-grained) crystals that range in length from 0.5 to 1 micron and in width from 0.2 to 0.5 micron. The calcite crystals are stubby, equant or blocky polyhedra of about 5 microns in length. δ 18 O values range between 2.7‰ and 3.7‰ for the calcite and between 2.1‰ and 6‰ for the aragonite. δ 13 C values range between 0.4‰ and 1‰ for the calcite and between 0.5‰ and 3.4‰ for the aragonite. A very strong positive correlation is observed between carbon and oxygen isotopes for the aragonite ( r 2 = 0.9) and a more moderate positive correlation with calcite ( r 2 = 0.6). The complete absence of biological and other no-carbonate grains, the sharp contacts of laminae basal, and the occurrence of calcite and aragonite as individual euhedral crystals, rather than clusters of grain aggregation, indicate that aragonite and calcite layers represent rapid inorganic precipitation from the lake water (endogenic). The positive values of δ 18 O and δ 13 C and the strong positive correlation between δ 18 O and δ 13 C suggest prevalence of a low lake level, saline, and dry climatic conditions during their formation. The change from calcite to aragonite indicates a change in the formational conditions from less arid conditions in the case of calcite to severe arid conditions in the case of aragonite. The relative abundance of diatoms in calcite-rich laminae and the less strong positive correlation between δ 18 O and δ 13 C of calcite support this interpretation. The arid conditions in which the carbonate minerals were formed could correspond to the aridification period of the North East Africa between ca 6000–8500 BP due to the north-south shifts of the Intertropical Convergence Zone (ITCZ) that control the evaporation/precipitation balance over North East Africa and/or to dry climate and desert environment conditions in Egypt at the same period. These results are also consistent with the aridification conditions during the mid-late Holocene, suggesting its global trend.

The Asian Monsoon forms an important part of the earth’s climate system, yet our understanding of the past interactions between its different sub-systems, the East Asian and Indian monsoons, and between monsoonal winds and other prevailing wind currents such as the Westerly jet, is limited, particularly in central Asia. This in turn affects our ability to develop climate models capable of accurately predicting future changes in atmospheric circulation patterns and monsoon intensities in Asia. Provenance studies of mineral dust deposited in terrestrial settings such as peat bogs can address this problem directly, by offering the possibility to examine past deposition rates and wind direction, and hence reconstruct past atmospheric circulation patterns. However, such studies are challenged by several issues, most importantly the identification of proxies that unambiguously distinguish between the different potential dust sources and that are independent of particle size. In addition, a single analytical method that is suitable for sample preparation of both dust source (i.e. desert sand, soil) and receptor (i.e. dust archive such as peat or soil profiles) material is desirable in order to minimize error propagation derived from the experimental and analytical work. Here, an improved geochemical framework of provenance tracers to study atmospheric circulation patterns and palaeomonsoon variability in central Asia is provided, by combining for the first time mineralogical as well as major and trace elemental (Sc, Y, Th and the rare earth elements) information on Chinese (central Chinese loess plateau, northern Qaidam basin and Taklamakan, Badain Juran and Tengger deserts), Indian (Thar desert) and Tibetan (eastern Qinghai–Tibetan Plateau) dust sources. Quartz, feldspars and clay minerals are the major constituents of all studied sources, with highly variable calcite contents reflected in the CaO concentrations. Chinese and Tibetan dust sources are enriched in middle REE relative to the upper continental crust and average shale but the Thar desert has a REE signature distinctly different from all other dust sources. There are significant differences in major, trace and REE compositions between the coarse and fine fractions of the surface sands, with the finest 2 O 3 , Fe 2 O 3 , MnO, MgO and K 2 O and the ∗ (all REE normalized to post-Archean Australian shale, PAAS) are particle size-independent tracers, of which combinations of Y/∑REE, La/Yb, Y/Tb, Y/La and Eu/Eu ∗ can be used to distinguish the Thar desert, the Chinese deserts, the Chinese loess plateau and the Tibetan soils. Their independence upon grain size means that these tracers can be applied to the long-range provenance tracing of Asian dust even when only bulk samples are available in the source region. Combinations of La/Th, Y/Tb, Y/∑REE, Sc/La and Y/Er distinguish the Tibetan soils from the Chinese loess plateau and the Chinese deserts. La/Th and notably Th/∑REE isolate the signature of the Badain Juran desert and the combination of Sc/La and Y/Er that of the Taklamakan desert. The similarity in all trace and REE-based provenance tracers between the northern Qaidam basin and Tengger desert suggests that these two deposits may have a common aeolian source.

article Oxidative precipitation and authigenic enrichment of the redox sensitive element Mn in sedimentary rocks can serve as a proxy for the release of high levels of O2 during the Great Oxidization Event (GOE). Here we investigate Mn abundance in sedimentary rocks of the 2.45-2.22 Ga Huronian Supergroup, Canada. We found authigenic Mn enrichments with high Mn/Fe ratios following the appearance of Fe oxides in the Firstbrook Member of the Gowganda Formation of the Huronian Supergroup, which was deposited immediately after the last Huronian glaciation. The Mn-bearing minerals in the Firstbrook Member are spessartine-rich almandine and Mn-bearing chlorite, which are likely to have been formed through post-depositional diagenesis and/or metamorphism using Mn oxides precipitated in the ocean at the time of deposition. When assuming the solution equilibrium between the atmosphere and shallow oceans, oxidative Mn precipitation requires that atmospheric O2 be higher than ~10 �2 times the present atmospheric level (PAL). The cumulative Mn amount per unit area in the Firstbrook Member is comparable in magnitude to that in the Mn deposits in the Hotazel Formation of the Transvaal Supergroup, South Africa. Our results suggest an appearance of highly active aerobic biosphere immediately after the last Huronian glaciation, supporting the hypothesis that climatic recovery from the Huronian glaciation accelerated the GOE.

It has been established that East Asian summer monsoon intensity varies with Dansgaard–Oeschger cycles, suggesting a connection between the climates of East Asia and the North Atlantic on a millennial timescale. However, the dynamics of such a connection are still unsolved. Here we demonstrate that temporal changes in the provenance of aeolian dust in Japan Sea sediments, which we interpret to reflect changes in the westerly jet path over East Asia, exhibit variations in harmony with Dansgaard–Oeschger cycles. The dominance of dust with a Mongolian Gobi provenance during stadials suggests a westerly jet axis located to the south of the Himalaya–Tibetan Plateau throughout most of the year, whereas the co-dominance of dust from both the Taklimakan Desert and the Mongolian Gobi during interstadials suggests that the westerly jet axis jumped to the north of the Tibetan Plateau at latest in summer. As the shift of the westerly jet axis to the north of the Tibetan Plateau is closely related to the onset of the East Asian summer monsoon, changes of the westerly jet path apparently critically affect the teleconnection between the climates of Asia and North Atlantic on a millennial timescale.

OSL components from quartz from two sediment cores (MD01-2407 and KT94-15-PC5) from the Japan Sea are analysed, and the results are compared with the electron spin resonance (ESR) intensity of E 1 ’-center of quartz and the grain size of the detrital component of the sediments. The OSL components of quartz from Japanese granites and rhyolites of different ages are also analysed to investigate the relationship between the host rock age and the relative composition of OSL components in quartz. All these data are then used to examine the potential of reconstructing the provenance of the sediments. The results suggest that the ratio of the Fast component to the sum of Fast and Medium, F/(F + M) appears to increase with increasing host rock age. It is suggested that the F/(F + M) ratio in sedimentary quartz can be used as an indicator of source rock age.