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Over the past few years, researchers have made numerous breakthroughs in the field of aluminum anodizing and faced the problem of the lack of adequate theoretical models for the interpretation of some new experimental findings. For instance, spontaneously formed anodic alumina nanofibers and petal-like patterns, flower-like structures observed under AC anodizing conditions, and hierarchical pores whose diameters range from several nanometers to sub-millimeters could be explained neither by the classical field-assisted dissolution theory nor by the plastic flow model. In addition, difficulties arose in explaining the basic indicators of porous film growth, such as the nonlinear current–voltage characteristics of electrochemical cells or the evolution of hexagonal pore patterns at the early stages of anodizing experiments. Such a conceptual crisis resulted in new multidisciplinary investigations and the development of novel theoretical models, whose evolution is discussed at length in this review work. The particular focus of this paper is on the recently developed electroconvection-based theories that allowed making truly remarkable advances in understanding the porous anodic alumina formation process in the last 15 years. Some explanation of the synergy between electrode reactions and transport processes leading to self-organization is provided. Finally, future prospects for the synthesis of novel anodic architectures are discussed.

In this work, the influence of various electrochemical parameters on the production of porous anodic alumina (PAA)-based DBRs (distributed Bragg reflector) during high-temperature-pulse-anodization was studied. It was observed that lowering the temperature from 30 to 27 &deg, C brings about radical changes in the optical performance of the DBRs. The multilayered PAA fabricated at 27 &deg, C did not show optical characteristics typical for DBR. The DBR performance was further tuned at 30 &deg, C. The current recovery (iamax) after application of subsequent UH pulses started to stabilize upon decreasing high (UH) and low (UL) voltage pulses, which was reflected in a smaller difference between initial and final thickness of alternating dH and dL segments (formed under UH and UL, respectively) and a better DBR performance. Shortening UH pulse duration resulted in a progressive shift of photonic stopbands (PSBs) towards the blue part of the spectrum while keeping intensive and symmetric PSBs in the NIR-MIR range. Despite the obvious improvement of the DBR performance by modulation of electrochemical parameters, the problem with regarding full control over the homogeneous formation of dH+dL pairs remains. Solving this problem will certainly lead to the production of affordable and efficient PAA-based photonic crystals with tunable photonic properties in the NIR-MIR region.

Vertical single-walled carbon nanotubes (v-SWCNTs) are synthesized within highly ordered porous anodic alumina (PAA) templates supported on Si substrates. A process for obtaining thin-film PAA with long-range ordered nanopores is presented in this paper. Each nanopore contains at most one v-SWCNT that is supported by a dielectric and addressed by electrochemically formed Pd nanowire source contacts and evaporated Pd drain contacts. Characteristics of these completely vertical, two-terminal nanotube devices are presented. Control of the v-SWCNT length is demonstrated using a straightforward etching process with lengths of less than 100 nm achieved without the need for complex/expensive lithography. This effective nanoscale length control of highly ordered v-SWCNTs provides a practical basis for the realization of CNT-based nanoelectronics.